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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Adsorption mechanism of alkyl hydroxamic acid onto bastnäsite: Fundamental steps toward rational collector design for rare earth elements

Rare earth element (REE) production is limited in part by inefficient strategies for beneficiation. Hydroxamic acid ligands are promising reagents for the selective flotation of bastnäsite [(Ce,La)FCO 3 ], a major REE ore mineral, but the mechanism and energetics of adsorption are not understood, interfering with the design of new, more efficient reagents. In this work, the adsorption of octyl hydroxamic acid onto bastnäsite was calculated using a combination of experimental and computational methods. In-situ attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy revealed changes in the hydroxamate functional group vibrational frequencies, corresponding to chelation with cerium cations at the bastnäsite surface. The results indicate a monodentate chemisorption mechanism at low surface loading that changes to bidentate chemisorption at higher concentrations. This interpretation is supported by molecular vibrational frequency shifts calculated using density functional theory (DFT), and orientation of the hydrocarbon chain measured by sum frequency generation (SFG) vibrational spectroscopy. The binding enthalpies of octyl hydroxamic acid interacting with La and Ce-bastnäsite surfaces were measured using isothermal titration calorimetry (ITC) revealing a stronger coordinating ability with bastnäsite than with a common gangue mineral, calcite (CaCO 3 ). Because octyl hydroxamate favors monodentate adsorption at low surface coverages, the relative chelating strength of metal ions could be a poor predictor for selectivity under monolayer adsorption conditions. At higher surface loadings, where the bidentate mode of adsorption is active, selectivity is likely to be limited by increased flotation of gangue ores.

58 GEOSCIENCES↗
NASA NTRSDate not supplied

A Novel Bone Marrow Single Cell Atlas of Mechanotransduction in Microgravity, Normal Gravity, Exercise, and Hindlimb Unloading for WT and CDKN1A-Null Regenerative Mice

Mechanical loading of adult stem cell progenitors is a key factor in modulating their proliferation, differentiation, and tissue regenerative potential, with loading generally promoting tissue formation and unloading mediating tissue loss. To address the role of mechanotransduction in maintaining stem cell-based tissue regenerative health, we generated a single cell transcriptomic atlas mapping responses of femur bone marrow mesenchymal and hematopoietic lineages to a range of altered mechanical loading conditions, both in WT B1629SF2/J mice as well as the p21/CDKN1A-null regenerative mice. We selected the femur marrow compartment as a model because of the diversity and high numbers of stem cell progenitor stages present, and because it undergoes static and cyclic hydrostatic pressure loading associated with weight-bearing and ambulation. Our study included normally loaded mice at 1g, unloading in microgravity during spaceflight as well as tail suspension hindlimb unloading, and voluntary running wheel exercise. Basal, one-year natural aging, and habitat controls were also conducted. Overall, the atlas encompasses 18 different experimental conditions with N=3 mice per condition and includes more than 500,000 single cell expressomes. Key specific findings include: increased mature reticulocyte populations in aging and unloading mice compared to active mice; greater hematopoietic and mesenchymal differentiating progenitors cluster identification in CDKN1A-null samples, especially the exercise model; distinct pseudotime cell trajectory shifts in the hematopoietic lineage for spaceflight and unloaded mice; and shifts in monocytic cell populations toward osteoclastic bone degenerative lineages in unloading and spaceflight samples. Overall mechanical loading shows increased marrow progenitor population differentiation while unloading is associated with increased CDKN1A expression and maintenance of marrow population stemness. Deletion of CDKN1A appears to remove a negative check on progenitor lineages commitment to differentiation. Finally, the Bone Marrow Mechanotransduction Single Cell Atlas will serve as a reference tool for studying marrow regenerative responses across a range of mechanical environments as they relate to CDKN1A status.

single-cell↗
DOE OSTI2025

Potential Impacts of Dynamic Electricity Pricing in California: Load Shape and Customer Bill Impacts Under Elastic Customer Response

The increasing penetration of renewable energy in California has intensified grid management challenges, exemplified by the “duck curve” and the resulting need for steep ramping and curtailment of renewables. To address these issues, dynamic electricity tariffs that vary in near-real time are being considered to incentivize customers to shift demand and support the grid. This study extends previous work on the bill impacts of such tariffs in the absence of load response by quantifying the system-level and customer impacts of load response based on customer price elasticity. Customer-level load response modeling was conducted using meter data from 411,000 customers across residential, commercial, and industrial sectors. Customer demand elasticity was estimated using literature-based values, with scenarios ranging from low to high elasticity, including an automation-enhanced scenario. Results indicate that universal adoption of, and response to, dynamic tariffs can significantly reduce peak net load (by 15%) and maximum ramping requirements (by 20%) with moderate elasticity, delivering demand response resources comparable to or exceeding current programs at all elasticity levels. Bill analysis shows that, when responding elastically to dynamic prices, most non-PV customers experience modest savings, while PV customers may see higher effective rates due to lower compensation for exports during low-price periods. Emissions analysis reveals a reduction in per-kWh emissions system-wide, with a total absolute load increase of 2% accompanied by a negligible absolute emissions increase. The study concludes that while dynamic tariffs offer substantial grid benefits, customer bill savings under modeled response behaviors may be too modest to drive widespread adoption without additional incentives or enabling technologies. Future research should model flexible loads and advanced control technologies with greater fidelity to better represent the potential opportunities of dynamic tariffs.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Occupant-driven end use load models for demand response and flexibility service participation of residential grid-interactive buildings

As demand response becomes increasingly used as a tool to support improved grid flexibility, it is important to consider that there are many potential types of energy end uses that may be used to support such flexibility. Residential appliances, often accounting for 30 % or more of residential energy use, are a currently untapped source of demand flexibility, particularly when aggregated together across homes. To date there has been very limited analysis of residential appliances for use as grid-interactive loads. As such, this research uses disaggregated energy end use data for 564 households, to model the electricity demand flexibility potential of the use of residential dishwashers, clothes washers, clothes dryers, ovens, and ranges (oven + stovetop) on both weekdays and weekends. This includes both at the building level, as well as aggregated to the grid level, specifically the Midcontinent Independent System Operator (MISO) region. This study was divided into two parts. Part 1 focuses on determining appliance-level loads, and Part 2, which involves aggregation to the grid. Findings suggest that among the studied appliances, clothes dryers provide the greatest demand reduction potential for most times of the day, followed by dishwashers and clothes washers. The maximum potential reduction for clothes dryers is found to be approximately at 11:00 a.m. and this potential sustains throughout most of the daytime period. When considering the willingness of households to participate, based on a survey of households in the Midwest region, clothes dryers still have the most potential for demand reduction. The availability of appliances for load modulation on weekdays and weekends indicates similar load reduction potential for all appliances. Overall, the results of this study suggest that there is an opportunity for shifting appliance usage to optimize grid efficiency and enhance demand response strategies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2018

Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. The catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

ICECUBE NONDETECTION OF GAMMA-RAY BURSTS: CONSTRAINTS ON THE FIREBALL PROPERTIES

The increasingly deep limit on the neutrino emission from gamma-ray bursts (GRBs) with IceCube observations has reached a level that could place useful constraints on the fireball properties. We first present a revised analytic calculation of the neutrino flux that predicts a flux of one order of magnitude lower than that obtained by the IceCube Collaboration. For the benchmark model parameters (e.g., the bulk Lorentz factor is {Gamma} = 10{sup 2.5}, the observed variability time for the long GRBs is t{sup ob}{sub v} = 0.01 s, and the ratio between the energy in the accelerated protons and in the radiation is {eta}{sub p} = 10 for every burst) in the standard internal shock scenario, the predicted neutrino flux from 215 bursts during the period of the 40- and 59-string configurations is a factor of {approx}3 below the IceCube sensitivity. However, if we accept the recently found inherent relation between the bulk Lorentz factor and the burst energy, then the expected neutrino flux significantly increases and the spectral peak shifts to a lower energy. In this case, the nondetection implies that the baryon-loading ratio should be {eta}{sub p} {approx}< 10 if the variability time of the long GRBs is fixed to t{sup ob}{sub v} = 0.01 s. Instead, if we relax the standard internal-shock scenario but still assume {eta}{sub p} = 10, then the nondetection constrains the dissipation radius, R {approx}> 4 Multiplication-Sign 10{sup 12} cm, assuming the same dissipation radius for every burst and benchmark parameters for the fireballs. We also calculate the diffuse neutrino flux from the GRBs for different luminosity functions from the literature. The expected flux exceeds the current IceCube limit for some of the luminosity functions, and, thus, the nondetection constrains {eta}{sub p} {approx}< 10 when the variability time of the long GRBs is fixed at t{sup ob}{sub v} = 0.01 s.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2016

Assess How Changes in Fuel Cycle Operation Impact Safeguards

Since the beginning of commercial nuclear power generation in the 1960s, the ability of researchers to understand and control the isotopic content of spent fuel has improved. It is therefore not surprising that both fuel assembly design and fuel assembly irradiation optimization have improved over the past 50+ years. It is anticipated that the burnup and isotopics of the spent fuel should exhibit less variation over the decades as reactor operators irradiate each assembly to the optimum amount. In contrast, older spent fuel is anticipated to vary more in burnup and resulting isotopics for a given initial enrichment. Modern fuel therefore should be more uniform in composition, and thus, measured safeguards results should be easier to interpret than results from older spent fuel. With spent fuel ponds filling up, interim and long-­term storage of spent fuel will need to be addressed. Additionally after long periods of storage, spent fuel is no longer self-­protecting and, as such, the IAEA will categorize it as more attractive; in approximately 20 years many of the assemblies from early commercial cores will no longer be considered self-­protecting. This study will assess how more recent changes in the reactor operation could impact the interpretation of safeguards measurements. The status quo for spent fuel assay in the safeguards context is that the overwhelming majority of spent fuel assemblies are not measured in a quantitative way except for those assemblies about to be loaded into a difficult or impossible to access location (dry storage or, in the future, a repository). In other words, when the assembly is still accessible to a state actor, or an insider, when it is cooling in a pool, the inspectorate does not have a measurement database that could assist them in re-­verifying the integrity of that assembly. The spent fuel safeguards regime would be strengthened if spent fuel assemblies were measured from discharge to loading into a difficult or impossible to access location. The primary driver for suggesting this shift in approach is the change in robotic technology and information technology in general. It should be possible, with minimal impact to the facility, to measure each assembly every time that it is moved in the pool, with the first measurements being made at discharge. The following conclusions were reached: The total neutron count rate can be accurately predicted at any future moment in time based upon the measured count rate at discharge, provided the initial enrichment and burnup of the assembly is known at discharge. It is expected that the total neutron count rate measured at discharge will be indicative of the initial enrichment and burnup of that assembly. If the automated robot were to focus on measuring the assemblies in the rack without moving them, the time available would increase immensely.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Impact of Connected Communities

Buildings account for 35% of CO 2 emissions and almost 40% of the United States’ energy use. High-performance homes and neighborhoods play an important role in supporting efforts to decarbonize the US power system by 2035. Significant reductions in CO 2 emissions within the residential sector can be realized through electrification of loads paired with the flexibility created by leveraging smart Internet of Things (IoT) capabilities to shift energy use based on grid signals, thus improving generation/distribution efficiency and maximizing the use of renewable generation capacity. All of this can be achieved while allowing smart home appliances and equipment to meet homeowner needs – including reducing power bills - while optimizing operation in conjunction with the grid using novel control techniques. The Grid-Interactive Efficient Buildings Roadmap by the US Department of Energy’s (DOE’s) Building Technologies Office (BTO) notes that implementing grid-interactive efficient building (GEB) technology has the potential to reduce CO 2 emissions by 80 million tons/year—roughly equivalent to 17 million cars. To achieve this vision, the US Department of Energy’s Oak Ridge National Laboratory (ORNL)—in collaboration with Southern Company Research & Development, Alabama Power, Georgia Power, BTO and the US DOE’s Office of Electricity (OE) —is developing and demonstrating novel connected communities at two locations. Southern Company in turn engaged with industry partners, including design firms, residential developers, and residential HVAC and appliance manufacturers because their participation would be critical to the success of the initial research project, as well as the future scaling to the Southern Company service territory and beyond. Impacts of the Connected Communities projects in Alabama and Georgia are outlined including: energy, grid services and data management learnings; homeowner feedback; vendor engagement; adoption by utilities; technical, policy and business model challenges.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1980

Cell module and fuel conditioner

Measurements of stack height changes with temperature and cell material characteristics were made. Stack 559 was assembled and components were fabricated for 560, 561, and 562. Stack 425 was transferred from the parallel DOE program and installed in the OS/IES simulation loop for mechanical and electrical testing. Construction and preliminary checkout of the 2 kW test facility was completed and design and procurement of the 8 kW test facility was initiated. The fuel conditioning subsystem design continued to evolve and the state points for the current design were calculated at full and part load conditions. Steam reforming catalyst activity tests were essentially completed and aging tests and CO shift converter tests were initiated.

Hoover, D. Q., Jr.↗
NASA NTRS1983

Dynamic tooth loads and stressing for high contact ratio spur gears

An analysis and computer program were developed for calculating the dynamic gear tooth loading and root stressing for high contact ratio gearing (HCRG) as well as LCRG. The analysis includes the effects of the variable tooth stiffness during the mesh, tooth profile modification, and gear errors. The calculation of the tooth root stressing caused by the dynamic gear tooth loads is based on a modified Heywood gear tooth stress analysis, which appears more universally applicable to both LCRG and HCRG. The computer program is presently being expanded to calculate the tooth contact stressing and PV values. Sample application of the gear program to equivalent LCRG (1.566 contact ratio) and HCRG (2.40 contact ratio) revealed the following: (1) the operating conditions and dynamic characteristics of the gear system an affect the gear tooth loading and root stressing, and therefore, life significantly; (2) the length of the profile modification affect the tooth loading and root stressing significantly, the amount depending on the applied load, speed, and contact ratio; and (3) the effect of variable tooth stiffness is small, shifting and increasing the response peaks slightly from those for constant tooth stiffness.

Cornell, R. W.↗
NASA NTRS1986

Structural qualification of large spacecraft

Over the past twenty-five (25) years of the space program, the major challenge in the structural qualification of the primary structure has shifted from conducting a test that simulated the environment to accurately predicting the structural member loads in flight. Once the flight loads are avaliable, a number of different test methods are used to qualify the structure by subjecting it to the proper loads. The qualification challenge for future large spacecraft will be to adequately predict its dynamic characteristic in space to assure that it can be controlled to meet the mission objectives. A new test concept that may allow acquisition of modal data by ground tests for verification of mathematical models of large flexible space structures which can't be ground tested by conventional methods is discussed.

Wada, Ben K.↗
NASA NTRS1994

Vibration Test Force Limits Derived From Frequency Shift Method

The two-degree-of-freedom system (TDFS) method used to derive force specifications for force limited vibration tests at JPL is reviewed and some of the limitations of the method and of the simple TDFS model are discussed. A new improved frequency shift force prediction method is developed and applied to a more complex model where the load and source have both residual and modal masses.

force↗
DOE OSTI2014

Perspective: The Climate-Population-Infrastructure Modeling and Simulation Fertile Area for New Research

Managing the risks posed by climate change and extreme weather to energy production and delivery is a challenge to communities worldwide. As climate conditions change, populations will shift, and demand will re-locate; and networked infrastructures will evolve to accommodate new load centers, and, hopefully, minimize vulnerability to natural disaster. Climate effects such as sea level rise, increased frequency and intensity of natural disasters, force populations to move locations. Displaced population creates new demand for built infrastructure that in turn generates new economic activity that attracts new workers and associated households to the new locations. Infrastructures and their interdependencies will change in reaction to climate drivers as the networks expand into new population areas and as portions of the networks are abandoned as people leave. Thus, infrastructures will evolve to accommodate new load centers while some parts of the network are underused, and these changes will create emerging vulnerabilities. Forecasting the location of these vulnerabilities by combining climate predictions and agent based population movement models shows promise for defining these future population distributions and changes in coastal infrastructure configurations. By combining climate and weather data, engineering algorithms and social theory it has been only recently possible to examine electricity demand response to increased climactic temperatures, population relocation in response to extreme cyclonic events, consequent net population changes and new regional patterns in electricity demand. These emerging results suggest a research agenda of coupling these disparate modelling approaches to understand the implications of climate change for protecting the nation s critical infrastructure.

Climate↗
NASA NTRS1979

Elevated-temperature effects on strain gages on the YF-12A wing

A general study is made of the effects of structural heating on calibrated-strain-gage load measurements on the wing of a supersonic airplane. The primary emphasis is on temperature-induced effects as they relate to slope changes and thermal shifts of the applied load/strain relationships. These effects are studied by using the YF-12A airplane, a structural computer model, and subsequent analyses. Such topics as the thermal environment of the structure, the variation of load paths at elevated temperature, the thermal response characteristics of load equations, elevated-temperature load-measurement approaches, the thermal calibration of wings, and the correlation of strains are discussed. Ways are suggested to measure loads with calibrated strain gages in the supersonic environment.

Jenkins, J. M.↗
NASA NTRS2008

Assessment of Proper Bonding Methods and Mechanical Characterization FPGA CQFPs

This presentation discusses fractured leads on field-programmable gate array (FPGA) during flight vibration. Actions taken to determine root cause and resolution of the failure include finite element analysis (FEA) and vibration testing and scanning electron microscopy (with X-ray microanalysis) and energy dispersive spectrometry (SEM/EDS) failure assessment. Bonding methods for surface mount parts is assessed, including critical analysis and assessment of random fatigue damage. Regarding ceramic quad flat pack (CQFP) lead fracture, after disassembling the attitude control electronics (ACE) configuration, photographs showed six leads cracked on FPGA RTSX72SU-1 CQ208B package located on the RWIC card. An identical package (FPGA RTSX32SU-1 CQ208B) mounted on the RWIC did not results in cracked pins due to vibration. FPGA lead failure theories include workmanship issues in the lead-forming, material defect in the leads of the FPGA packages, and the insecure mounting of the board in the card guides, among other theories. Studies were conducted using simple calculations to determine the response and fatigue life of the package. Shorter packages exhibited more response when loaded by out-of-plane displacement of PCB while taller packages exhibit more response when loaded by in-plane acceleration of PCB. Additionally, under-fill did not contribute to reducing stress in leads due to out-of-plane PCB loading or from component twisting, as much as corner bonding. The combination of corner bond and under-fill is best to address mechanical and thermal S/C environment. Test results of bonded parts showed reduced (dampened) amplitude and slightly shifted peaks at the un-bonded natural frequency and an additional response at the bonded frequency. Stress due to PCBB out-of-plane loading was decreased on in the corners when only a corner bond was used. Future work may address CQFP fatigue assessment, including the investigation of discrepancy in predicted fatigue damage, as well as comparing fatigue life and fatigue damage cycle ration computed using FEA and Miner's rule to results from a fatigue assessment software program.

Davis, Milton C.↗
DOE OSTI2019

End-Use Load Profiles for the U.S. Building Stock: Market Needs, Use Cases, and Data Gaps

States and utilities are developing increasingly ambitious energy goals. Part of the solution to meeting these goals is improving electric grid flexibility. This includes shifting electric demand to align with grid needs. Thus, identifying and using building energy efficiency and other distributed energy resources to produce the highest grid value requires highly resolved, accurate and accessible electricity end-use load profiles (EULPs).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Techno-Economic and Deployment Analysis of Fossil Fuel-Based Power Generation with Integrated Energy Storage

Most existing coal-fired power plants were designed for sustained operation at full load to maximize efficiency, reliability, and revenues. Depending on plant type and design, these plants can adjust output within a fixed range in response to plant or market conditions. The need for flexibility driven by increased penetration of variable and non-dispatchable power generation such as wind and solar is shifting traditional mission profile of thermoelectric power plants in three ways: more frequent shutdowns when market or grid conditions warrant, more aggressive load ramp rates (rate of output change), and lower minimum sustainable load, which provides a wider operating range and helps avoid costly plant shutdowns. The recent studies have shown that flexibility of a coal-fired power plant can be improved by the energy storage. The objective of this project was to analyze a set of energy storage options (technologies) and determine their impact on flexibility and economics of a representative coal-fired power plant. The effect of five Energy Storage Systems (ESSs) integrated with a coal power plant on plant flexibility and economics was investigated in this study. The results obtained in this project and presented in this report showed that ESS integrated with a thermal power plant improves plant flexibility and participation in the Energy and Ancillary Services markets and also improves plant financial performance.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2022

End-Use Load Profiles for the U.S. Building Stock: Methodology and Results of Model Calibration, Validation, and Uncertainty Quantification

The United States is embarking on an ambitious transition to a 100% clean energy economy by 2050, which will require improving the flexibility of electric grids. One way to achieve grid flexibility is to shed or shift demand to align with changing grid needs. To facilitate this, it is critical to understand how and when energy is used. High- quality end-use load profiles (EULPs) provide this information, and can help cities, states, and utilities understand the time-sensitive value of energy efficiency, demand response, and distributed energy resources. Publicly available EULPs have traditionally had limited application because of age and incomplete geographic representation (Frick, Eckman, and Goldman 2017; Frick 2019). To help fill this gap, the U.S. Department of Energy (DOE) funded a three-year project - End-Use Load Profiles for the U.S. Building Stock - that culminated in the release of a publicly available dataset1 of simulated EULPs representing residential and commercial buildings across the contiguous United States. The motivation for this work is further detailed in a November 2019 report: Market Needs, Use Cases, and Data Gaps (Mims Frick et al. 2019). This Methodology and Results report provides detailed descriptions of how the dataset was developed, intended for an audience of dataset and model users interested in the technical details. These details include descriptions of all of the model improvements made for calibration and the final comparisons to empirical data sources. A companion report, End-Use Load Profiles for the U.S. Building Stock: Applications and Opportunities, will be published subsequently and will describe example applications and considerations for using the dataset, intended for an audience of general dataset users.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗