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At least 613 records · Page 34

Surface Modification of 304 Stainless Steel by Electro-Spark Deposition

Electro-spark deposition (ESD) is a pulsed microwelding process that is used to apply surface coatings for the repair of damaged high value and precision products or modify their surfaces for specific properties. The low heat input, minimal heat-affected zone and the ability to form metallurgical bonding of coating to substrate are major advantages of the ESD process. Many applications require the components to have excellent surface performance, such as wear and corrosion resistance. ESD technique provides an approach to modify the component surface without compromising the bulk properties. In this study, surface modifications of 304 stainless steel by ESD were investigated. Titanium carbide (TiC), tungsten carbide (WC) and molybdenum (Mo) were employed as coating materials. Scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDX) analysis were conducted to characterize the microstructure and composition of the coatings. The coatings thicknesses were all around 40 µm. The results showed that TiC and WC coatings showed a dramatic increase in the microhardness, up to 5 times. WC coating improved the wear resistance by more than 5 times, while TiC and Mo coatings also improved it by approximately 2.5 times. Electro-chemical tests were conducted to investigate the corrosion resistance of the coatings. Mo coating exhibited a significant improvement in the corrosion resistance in 5% NaCl solutions, corroding 350 times slower than stainless steel. Synchrotron x-ray diffraction was performed to investigate the microstructure changes of the Mo-coated sample. Heat treatment was also carried out to investigate the corrosion behavior of Mo-coated 304 stainless steel at elevated service temperature in air or argon.

36 MATERIALS SCIENCE↗

Dynamic Characterization of Galfenol

A novel and precise characterization of the constitutive behavior of solid and laminated research-grade, polycrystalline Galfenol (Fe81:6Ga18:4) under under quasi-static (1 Hz) and dynamic (4 to 1000 Hz) stress loadings was recently conducted by the authors. This paper summarizes the characterization by focusing on the experimental design and the dynamic sensing response of the solid Galfenol specimen. Mechanical loads are applied using a high frequency load frame. The dynamic stress amplitude for minor and major loops is 2.88 and 31.4 MPa, respectively. Dynamic minor and major loops are measured for the bias condition resulting in maximum, quasi-static sensitivity. Three key sources of error in the dynamic measurements are accounted for: (1) electromagnetic noise in strain signals due to Galfenol's magnetic response, (2) error in load signals due to the inertial force of fixturing, and (3) time delays imposed by conditioning electronics. For dynamic characterization, strain error is kept below 1.2 % of full scale by wiring two collocated gauges in series (noise cancellation) and through lead wire weaving. Inertial force error is kept below 0.41 % by measuring the dynamic force in the specimen using a nearly collocated piezoelectric load washer. The phase response of all conditioning electronics is explicitly measured and corrected for. In general, as frequency increases, the sensing response becomes more linear due to an increase in eddy currents. The location of positive and negative saturation is the same at all frequencies. As frequency increases above about 100 Hz, the elbow in the strain versus stress response disappears as the active (soft) regime stiffens toward the passive (hard) regime.

Dynamic sensing↗

CALET on the International Space Station: the first three years of observations

The CALorimetric Electron Telescope CALET is a space instrument designed to carry out precision measurements of high energy cosmic-rays on the JEM-EF external platform on the International Space Station, where it has been collecting science data continuously since mid-October 2015. In addition to its primary goal of identifying nearby sources of high-energy electrons and possible signatures of dark matter in the electron spectrum, CALET is carrying out extensive measurements of the energy spectra, relative abundances and secondary-to-primary ratios of elements from proton to iron, and even above (up to Z = 40), studying the details of galactic particle propagation and acceleration. An overview of CALET based on the data taken during the first three years of observations is presented, including a direct measurement of the electron+positron energy spectrum from 11 GeV to 4.8 TeV. The proton spectrum has been measured from 50 GeV to 10 TeV covering, for the first time with a single space-borne instrument, the whole energy interval previously investigated in separate sub-ranges by magnetic spectrometers and calorimetric instruments. Preliminary spectra of cosmic-ray nuclei are also presented, together with gamma-ray observations and searches for an e.m. counterpart of LIGO/ Virgo GW events.

P Brogi↗

Systematic Detection of Anomalous Ionospheric Perturbations Above LEOs From GNSS POD Data Including Possible Tsunami Signatures

In this article, we show the capability of a global navigation satellite system (GNSS) precise orbit determination (POD) low Earth orbit (LEO) data to detect anomalous ionospheric disturbances in the spectral range of the signals associated with earthquakes and tsunamis, applied to two of these events in Papua New Guinea (PNG) and the Solomon Islands during 2016. This is achieved thanks to the new PIES approach (POD-GNSS LEO Detrended Ionospheric Electron Content Significant Deviations). The significance of such ionospheric signals above the swarm LEOs is confirmed with different types of independent data: in situ electron density measurements provided by the Langmuir Probe (LP) onboard swarm LEOs, DORIS, and ground-based GNSS colocated measurements, as it is described in this article. In this way, we conclude the possible detection of the tsunami-related ionospheric gravity wave in PNG 2016 event, consistent with the most-recent theory, which shows that a tsunami (which is localized in space and time) excites a spectrum of gravity waves, some of which have faster horizontal phase speeds than the tsunami. We believe that this work shows as well the feasibility of a future potential monitoring system of ionospheric disturbances, to be made possible by hundreds of CubeSats with POD GNSS receivers among other appropriate sensors, and supported for real-time or near real-time confirmation and characterization by thousands of worldwide existing ground GNSS receivers.

Global Navigation Satellite System↗

Light field–controlled PHz currents in intrinsic metals

Oriented electric currents in metals are routinely driven by applying an external electric potential. Although the response of electrons to the external electric fields occurs within attoseconds, conventional electronics do not use this speed potential. Ultrashort laser pulses with controlled shapes of electric fields that switch direction at petahertz frequencies open perspectives for driving currents in metals. Light field–driven currents were demonstrated in various media including dielectrics, semiconductors, and topological insulators. Now, our research question is whether we can drive and control orders of magnitude more charge carriers in metals enabling ultrafast switching with practically low-energy, picojoule-level pulses. Here, we demonstrate the interaction of light with nanometer-thick metallic layers, which leads to a generation of light field–controlled electric currents. We show that the implantation of metallic layers into a dielectric matrix leads to up to 40 times increase of the sensitivity in contrast to a bare dielectric, decreasing the intensity threshold for lightwave electronics.

Fehér, Beatrix [HUN-REN Wigner Research Centre for↗

Design and performance of an in-vacuum, magnetic field mapping system for the Muon g-2 experiment

The E989 Muon g-2 experiment at Fermilab aims to measure the anomalous magnetic moment, a$_\mu$, of the muon with a precision of 140 parts-per-billion. This requires a precise measurement of both the anomalous spin precession frequency, $\omega_a$, and the average magnetic field in terms of the equivalent, free proton Larmor frequency, $\omega_p$. The measurement of $\omega_p$ with a total systematic uncertainty of 70 parts-per-billion involves a combination of various NMR probes. There are 378 probes in fixed locations constantly monitoring field drifts. A water-based probe provides the calibration in terms of $\omega_p$. A crucial element for the multi-step measurement of $\omega_p$ is the regular mapping of the magnetic field over the muon storage region. The former E821 experiment at Brookhaven employed an in-vacuum field mapping system equipped with 17 NMR probes, which was developed by the University of Heidelberg. We have refurbished and upgraded this system with new probes and electronics. The upgrades include a new communication scheme incorporating time-division multiplexing to separate the important NMR reference clock from the data communication. The addition digitization of the NMR signals replaced the hardware-implemented zero-crossing counting of the E821 system. The digitized signals offer new capabilities in the NMR frequency analysis and its related systematic uncertainties. While the mechanical systems that move the field mapper around the ring have been mostly refurbished, the motion control system was completely replaced with a custom-built electronics centered around a commercial Galil motion controller. Both the field mapping NMR system and its motion control were successfully commissioned at Fermilab and have been in reliable operation during the first data taking periods. This article provides details of the upgrades of the field mapper and its performance.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A Program to Detect and Characterize Extra-Solar Giant Planets

We initiated a significant hardware upgrade to the AFOE, to increase its efficiency for precise radial velocity studies to the level where we can continue to contribute usefully to extrasolar planet research on relatively bright stars. The AFOE, at a 1.5-m telescope, will of course not have the sensitivity of radial velocity instruments at larger telescopes, such as the HIRES on Keck or the Hectochelle on the MMT telescope (about to come on line). However, it has been possible to increase its efficiency for precise radial velocity studies by a factor of 4 to 5, which-combined with the large amount of telescope time available at the 1.5-m telescope-will permit us to do intensive follow-up observations of stars brighter than about 8 magnitude. The AFOE was originally designed primarily for asteroseismology using a ThAr reference. This provided useful wavelength stability over tens of minutes as required for asteroseismology, but we were unable to get a long-term (month-to-month) velocity precision better than about 15 m/s with that setup. Hence, we implemented an iodine cell as a wavelength reference for extrasolar planet studies. However, the optical design of the original AFOE did not completely span the wavelength range covered by the iodine absorption spectrum, and furthermore the optics suffered significant light loss through optical obscuration in the camera secondary. To remedy this, we replaced the AFOE grating with a new one that covered the entire iodine spectral range at somewhat lower spectral resolution, and replaced the camera with a transmitting lens. (The use of a lens was made possible by restricting the spectral range covered by the upgraded AFOE to only the iodine region.) These upgrades were successfully completed, and the instrument was tested for three nights in fall of 2002. The expected improvement in sensitivity by a factor of 4 to 5 was observed: that is, the same velocity precision as previously attained (of order 5 to 7 m/s) was now obtained on a stars that are about 4 to 5 times fainter. Unfortunately, just after installing the new AFOE optics, there was a catastrophic failure of the old Tektronix CCD. A careful investigation was made, and it was determined that the failure was probably due to too many thermal cyclings over the previous 8 years. The only solution was to purchase a new CCD. Internal funds of $16,000 were found for this purpose, and the new CCD (a thinned, back-illuminated Marconi 2K x 2K device with 13.5 micron pixels, and employing dual readout channels to keep the readout time as short as 20 seconds) was ordered, has now arrived, and is currently under test before 1 being installed in the AFOE liquid nitrogen dewar. At the same time, we expect to implement new CCD control electronics. This system should be better in many ways than the previous detector (including eliminating the need for UV flashing to maximize the quantum efficiency). We plan to install the detector on the telescope and begin operations again in April of this year.

Lindstrom, David↗

Understanding and Manipulating Counterion Condensation within Charged Polymer Electrolytes for Selective and Low Resistant Membrane Separations

Polymeric ion-exchange membranes are found at the heart of numerous electrochemical systems spanning separations (electrodialysis and membrane capacitive deionization) and energy conversion and storage (flow batteries, fuel cells, and electrolyzers). The ion-exchange membrane separators need to be ion conducting but electron insulating, and in many scenarios selective for a particular ion to conduct. Because of their polymeric nature, the molecular architectures of ion-exchange membranes lack the molecular precision found in many inorganic materials. Plus, they contain numerous structural defects that impede ionic transport. As a result of their poor structure, it has been difficult to carefully probe the underlying physics that governs ion transport in ion-exchange membranes. We investigated counterion condensation phenomena in ion-exchange membranes and correlated it to bulk ionic charge transport and selectivity in precisely defined and long-range ordered materials afforded through the principles of directed self-assembly. A multi-faceted approach spanning i.) advanced metrology, two-dimensional atomic force microscopy, x-ray scattering, and ion-exchange equilibria, and ii.) molecular simulations (classical molecular dynamics and ab-inito molecular dynamics) that bridge multiple time and length scales, were employed to correlate the extent of counterion condensation to ionic conductivity and selectivity. After uncovering the extent of the condensation phenomena in this project, new macromolecular chemistries were employed to manipulate the ion pairing interactions of the condensed counterions to tethered ions on the polymer backbone so more facile and selective conduction rates can be attained. The research has aided in the rational design of polymeric ion-exchange membrane separators with high current density for electrochemical systems and subsequently better energy efficiency.

36 MATERIALS SCIENCE↗

The impact of pulse width modulation on heat accumulation in AlGaN channel HEMTs

The poor thermal properties of Aluminum–Gallium Nitride (AlGaN) channel High Electron Mobility Transistors (HEMTs) on sapphire limit the device’s maximum switching frequency due to high channel temperatures. Extracting the correct thermal time constants can provide guidelines for the device’s safe frequency operation. This study experimentally quantifies the impact of pulse width and duty cycle on the transient thermal dynamics of multi-finger AlGaN channel HEMTs. In most transient thermal metrology, lock-in averaging approaches are leveraged to increase signal-to-noise ratio and measure the device’s relative temperature rise. Assuming no heat accumulation, the temperature rise is used to quantify the device’s thermal resistance under continued pulsed biasing. For devices grown on sapphire substrates, however, heat accumulation leads to elevated reference temperatures and causes the differential measurement to underestimate the peak temperature. This study demonstrates the capability of transient Gate Resistance Thermometry (tGRT) to measure the absolute temperature, which is required to precisely evaluate the device’s thermal resistance. When an absolute temperature measurement is not feasible (such as thermoreflectance imaging), a solution is proposed to derive the peak temperature under pulsed biasing based on the differential temperature under pulsing and the steady-state thermal resistance (which is typically easier to obtain). Finally, additional tGRT (without averaging) is performed to demonstrate the temperature-dependent thermal time constants required to minimize heat accumulation effects.

Field effect transistors↗

Measurement of the ionization yield from nuclear recoils in liquid xenon between 0.3 -- 6 keV with single-ionization-electron sensitivity

Dual-phase xenon TPC detectors are a highly scalable and widely used technology to search for low-energy nuclear recoil signals from WIMP dark matter or coherent nuclear scattering of ~MeV neutrinos. Such experiments expect to measure O(keV) ionization or scintillation signals from such sources. However, at ~ 1 keV and below, the signal calibrations in liquid xenon carry large uncertainties that directly impact the assumed sensitivity of existing and future experiments. In this work, we report a new measurement of the ionization yield of nuclear recoil signals in liquid xenon down to 0.3 keV – the lowest energy calibration reported to date – at which energy the average event produces just 1.1 ionized electrons. Between 2 and 6 keV, our measurements agree with existing measurements, but significantly improve the precision. At lower energies, we observe a decreasing trend that deviates from simple extrapolations of existing data. We also study the dependence of ionization yield on the applied drift field in liquid xenon between 220V/cm and 6240V/cm, allowing these measurements to apply to a broad range of current and proposed experiments with different operating parameters

Dark matter↗

A micrometeoroid deceleration and capture experiment: Conceptual experiment design description

The preliminary conceptual design for a cosmic dust collector is described. For the case of low Earth orbit (LEO), dust particles enter the collector through the collimator at a few volts negative potential due to charging in the ionosphere, at a velocity of 1 to 50 km/sec. The particles then pass through an electron stream and are charged to about 1 KV negative (regardless of incoming polarity). The 1 KV negatively charged particle then passes through three sensing grids coupled to charge sensitive preamps (CSP). The comparison of the two pulses provided by S(1) and S(2) are utilized by the microprocessor to determine the charge, q, on the particle (pulse amplitude) and its velocity, v (by time of flight). The third sensing grid, S(3), is kept at about 20 KV negative so that the dust particle will now be decelerated in passing from S(2) (zero potential) to S(3). S(3) is capacitively coupled to its CSP and the pulse from S(3) is utilized by the microprocessor to determine the particle's energy, E, and therefore its mass, m (again by time of flight) by comparison with the pulses from S(1) and S(2). The microprocessor can now precisely program the high-voltage switching network for the proper timing in the grounding of the successive deceleration grids. As determined by the microprocessor, each successive deceleration grid is grounded just after the dust particle passes, thus reducing the particle's energy by the amount q*100 KV at each stage. The microprocessor also determines at which stage the particle will fall below a certain critical energy where all remaining grids remain unswitched so that the particle will drift to the collector. The collector is kept at about 100V positive and is covered with gold foil to eliminate contamination and is removable for subsequent return to earth for detailed analysis.

Wolfe, J. H.↗

COTS MEMS Flow-Measurement Probes

As an alternative to conventional tubing instrumentation for measuring airflow, designers and technicians at Glenn Research Center have been fabricating packaging components and assembling a set of unique probes that contain commercial off-the-shelf (COTS) microelectromechanical systems (MEMS) sensor chips. MEMS sensor chips offer some compelling advantages over standard macroscopic measurement devices. MEMS sensor technology has matured through mass production and use in the automotive and aircraft industries. At present, MEMS are the devices of choice for sensors in such applications as tire-pressure monitors, altimeters, pneumatic controls, cable leak detectors, and consumer appliances. Compactness, minimality of power demand, rugged construction, and moderate cost all contribute to making MEMS sensors attractive for instrumentation for future research. Conventional macroscopic flow-measurement instrumentation includes tubes buried beneath the aerodynamic surfaces of wind-tunnel models or in wind-tunnel walls. Pressure is introduced at the opening of each such tube. The pressure must then travel along the tube before reaching a transducer that generates an electronic signal. The lengths of such tubes typically range from 20 ft (approx.= 6 m) to hundreds of feet (of the order of 100 m). The propagation of pressure signals in the tubes damps the signals considerably and makes it necessary to delay measurements until after test rigs have reached steady-state operation. In contrast, a MEMS pressure sensor that generates electronic output can take readings continuously under dynamic conditions in nearly real time. In order to use stainless-steel tubing for pressure measurements, it is necessary to clean many tubes, cut them to length, carefully install them, delicately deburr them, and splice them. A cluster of a few hundred 1/16-in.- (approx.=1.6-mm-) diameter tubes (such clusters are common in research testing facilities) can be several inches (of the order of 10 cm) in diameter and could weigh enough that two technicians are needed to handle it. Replacing hard tubing with electronic chips can eliminate much of the bulk. Each sensor would fit on the tip of a 1/16-in. tube with room to spare. The Lucas NovaSensor P592 piezoresistive silicon pressure sensor was chosen for this project because of its cost, availability, and tolerance to extreme ambient conditions. The sensor chip is 1 mm square by 0.6 mm thick (about 0.039 by 0.039 by 0.024 in.) and includes 0.12-mm (approx.=0.005-in.) wire connection tabs. The figure shows a flow-angularity probe that was built by use of three such MEMS chips. It is planned to demonstrate this MEMS probe as an alternative to a standard tube-type "Cobra" probe now used routinely in wind tunnels and aeronautical hardware. This MEMS probe could be translated across a flow field by use of a suitable actuator, so that its accuracy and the shortness of its response time could be exploited to obtain precise dynamic measurements of a sort that cannot be made by use of conventional tubing-based instrumentation.

Redding, Chip↗

Microwave Structure Construction Capability Year One Accomplishments

The Microwave Structure Construction Capability (MSCC) element, part of the Moon to Mars Planetary Autonomous Construction Project (MMPACT) was initiated in 2020. MSCC is responsible for creating horizontal and vertical infrastructure on the moon using microwave energy. Microwave energy was selected since it is the only method to volumetrically heat the regolith. All other sintering/melting methods rely on thermal conduction through the very low conductivity surface, resulting in an inefficient process. Advances were achieved in materials characterization and understanding, microwave sintering in vacuum, and microwave design and analyses. Two dielectric property testing systems have been developed at Radiance Technologies and JPL. These will examine dielectric properties at cryogenic temperatures and over a broad frequency range. Permittivity and permeability testing at -60 ̊C in vacuum from 0.05 to 3 GHz has been generated at JPL. Additional modifications will be made to go to -190 ̊C (LN2). Radiance Technologies created a test system to measure dielectric properties at greater than 10 GHz and initiated work on developing a vacuum capable, portable test system to measure dielectric properties of Apollo regolith and simulants from 100 MHz to 18 GHz. These tests are to identify optimal heating frequencies and protocols. During microwave sintering at about 1100 ̊C, volatiles were creating difficulty in achieving a reasonably dense specimen. Due to processing in vacuum and the nature of the lunar regolith, some volatiles and porosity are expected. However, the Earth produced simulants have non-lunar materials in them that create volatiles that aren’t representative of lunar regolith. Therefore, a five month effort was conducted to establish a heat treat method to remove these non-lunar materials. Tests were conducted using TGA mass spectrometry, heating in vacuum and conducting mass spectrometry, dielectric and DTA, Raman, BET, particle size analysis, morphological analysis, carbon and sulfur chemical content determination and microscopy. The process has been scaled-up to 6 kg batch size and undergoing evaluation. A 36 kg batch size is the target for JSC-1A and other limited availability simulants. These calcining protocols will be standard for NASA and beyond. MSCC has also created scalable processes for fabricating synthetic lunar materials. Processes to fabricate Anorthite (plagioclase CaAl2Si2O8), Diopside (pyroxene CaMgSi₂O₆), and Enstatite (pyroxene Mg2Si2O6) have been generated. These materials will enable generation of microwave sintering models to bound various composition ranges anticipated on the Moon, therefore mitigating the need for a precise simulant with respect to location on the Moon. Successful microwave sintering in air using a horn applicator was demonstrated. All previous microwave vacuum sintering in the literature was at small scale and in a contained enclosure thus taking advantage of reflections. This is the first to use a lunar like microwave applicator to sinter ceramic in a bed as it would be done on the Moon. Small scale and inert sintering were conducted to assist in developing protocols with quicker turnaround times than larger scale testing. Testing has anchored thermal analysis predicting heat flow in vacuum during microwave sintering. Thermal conductivity testing was also initiated. Microwave coupling to the regolith has been modeled by multiple organizations and with different software packages. At least six horn designs and applicator configurations for both magnetron and solid state sources are being examined. Optimal simulant container designs for microwaves have also been generated. The power and electronics design for the solid state microwave system has been initiated. Concept designs for a lander based microwave sintering have been evaluated.

microwave↗

Digital communication constraints in prior space missions

Digital communication is crucial for space endeavors. Jt transmits scientific and command data between earth stations and the spacecraft crew. It facilitates communications between astronauts, and provides live coverage during all phases of the mission. Digital communications provide ground stations and spacecraft crew precise data on the spacecraft position throughout the entire mission. Lessons learned from prior space missions are valuable for our new lunar and Mars missions set by our president s speech. These data will save our agency time and money, and set course our current developing technologies. Limitations on digital communications equipment pertaining mass, volume, data rate, frequency, antenna type and size, modulation, format, and power in the passed space missions are of particular interest. This activity is in support of ongoing communication architectural studies pertaining to robotic and human lunar exploration. The design capabilities and functionalities will depend on the space and power allocated for digital communication equipment. My contribution will be gathering these data, write a report, and present it to Communications Technology Division Staff. Antenna design is very carefully studied for each mission scenario. Currently, Phased array antennas are being developed for the lunar mission. Phased array antennas use little power, and electronically steer a beam instead of DC motors. There are 615 patches in the phased array antenna. These patches have to be modified to have high yield. 50 patches were created for testing. My part is to assist in the characterization of these patch antennas, and determine whether or not certain modifications to quartz micro-strip patch radiators result in a significant yield to warrant proceeding with repairs to the prototype 19 GHz ferroelectric reflect-array antenna. This work requires learning how to calibrate an automatic network, and mounting and testing antennas in coaxial fixtures. The purpose of this activity is to assist in the set-up of phase noise instrumentation, assist in the process of automated wire bonding, assist in the design and optimization of tunable microwave components, especially phase shifters, based on thin ferroelectric films, and learn how to use commercial electromagnetic simulation software.

Yassine, Nathan K.↗

Signal Processing in SBND with Calibrated and Validated Electronics and Field Responses

SBND is a liquid argon time projection chamber in Fermilab’s Short-Baseline Neutrino Program, located 110 m from the neutrino source and operating in a high-rate environment with unprecedented statistics. Charged particles from neutrino interactions ionize the argon, and the resulting electrons drift to the anode wires, inducing current signals recorded as raw waveforms. These waveforms are a convolution of deposited charge with the electronics and TPC field responses, making accurate signal processing essential for recovering the true charge distribution. Signal processing forms the starting point for SBND reconstruction, directly impacting hit finding, charge calibration, clustering, and the reconstruction of tracks and showers, and therefore playing a key role in energy reconstruction and particle identification. In this poster, we present an overview of the SBND signal processing chain, including noise removal, channel-by-channel electronics correction, signal identification, and deconvolution using measured electronics and TPC field responses. We demonstrate that the two kernel functions—electronics and field responses—achieve high precision when compared to data, ensuring that the SBND signal processing chain provides a robust and accurate foundation for event reconstruction and precision physics measurements.

Singh, Prabhjot [Louisiana State U.] (ORCID:000000↗

Effects of Donor–Acceptor Quantum Coherence and Non-Markovian Bath on the Distance Dependence of Resonance Energy Transfer

Accurate information on the distance dependence of resonance energy transfer (RET) is crucial for its utilization as a spectroscopic ruler of nanometer scale distances. In this regard, understanding the effects of donor-acceptor quantum coherence and non-Markovian bath, which become significant at short distances, has significant implications. The present work investigates this issue theoretically by comparing results from a theory of coherent RET (CRET) with a nonequilibrium version of Forster’s RET (FRET) theory, both accounting for non-Markovian bath effects. Even for a model where the donor-acceptor electronic coupling is of transition dipole interaction form, it is shown that the RET rate in general deviates from the inverse sixth power distance dependence as opposed to the prediction of the original FRET. On the one hand, it is shown that the donor-acceptor quantum coherence makes the distance dependence steeper than the sixth power, although detailed manner of enhancement is sensitive to specific values of parameters. On the other hand, the non-Markovian bath effects make the distance dependence more moderate than the sixth power for both CRET and nonueqilibrium FRET, because finite time scale of the bath causes the rate to be smaller than the prediction of original FRET. While these effects are demonstrated clearly in the population dynamics at sub-picosecond time scales, their contributions to the conventional RET efficiency are relatively minor. Furthermore, this indicates that the actual detection of such effects through conventional RET efficiency measurement requires either high precision or utilization of a donor with fast spontaneous decay rate of excitation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Automated tabletop exfoliation and identification of monolayer graphene flakes

Over the past two decades, graphene has been intensively studied because of its remarkable mechanical, optical, and electronic properties. Initial studies were enabled by manual “Scotch Tape” exfoliation; nearly two decades later, this method is still widely used to obtain chemically pristine flakes of graphene and other 2D van der Waals materials. Unfortunately, the yield of large, pristine flakes with uniform thickness is inconsistent. Thus, significant time and effort are required to exfoliate and locate flakes suitable for fabricating multilayer van der Waals heterostructures. Here, we describe a relatively affordable tabletop device (the “eXfoliator”) that can reproducibly control key parameters and largely automate the exfoliation process. In a typical exfoliation run, the eXfoliator produces 3 or more large (≥ 400 μm 2 ) high-quality graphene monolayer flakes, allowing new users to produce such flakes at a rate comparable to manual exfoliation by an experienced user. Furthermore, we use an automated mapping system and a computer vision algorithm to locate candidate flakes. Our results provide a starting point for future research efforts to identify more precisely which parameters matter for the success of exfoliation and to optimize them.

47 OTHER INSTRUMENTATION↗

UAVSAR Instrument: Current Operations and Planned Upgrades

The Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) instrument is a pod-based Lband polarimetric synthetic aperture radar (SAR), specifically designed to acquire airborne repeat track SAR data for differential interferometric measurements. This instrument is currently installed on the NASA Gulfstream- III (G-III) aircraft with precision real-time Global Positioning System (GPS) and a sensor-controlled flight management system for precision repeat-pass data acquisitions. UAVSAR has conducted engineering and preliminary science data flights since October 2007 on the G-III. We are porting the radar to the Global Hawk Unmanned Airborne Vehicle (UAV) to enable long duration/long range data campaigns. We plan to install two radar pods (each with its own active array antenna) under the wings of the Global Hawk to enable the generation of precision topographic maps and single pass polarimetric-interferometry (SPI) providing vertical structure of ice and vegetation. Global Hawk's range of ~ 8000 nm will enable regional surveys with far fewer sorties as well as measurements of remote locations without the need for long and complicated deployments. We are also developing P-band polarimetry and Ka-band single-pass interferometry capabilities on UAVSAR by replacing the radar antenna and front-end electronics to operate at these

Uninhabited Airborne Vehicle Synthetic Aperture Ra↗