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At least 613 records · Page 34

Excimer lasers

The results of a two-year investigation into the possibility of developing continuous wave excimer lasers are reported. The program included the evaluation and selection of candidate molecular systems and discharge pumping techniques. The K Ar/K2 excimer dimer molecules and the xenon fluoride excimer molecule were selected for study; each used a transverse and capillary discharges pumping technique. Experimental and theoretical studies of each of the two discharge techniques applied to each of the two molecular systems are reported. Discharge stability and fluorine consumption were found to be the principle impediments to extending the XeF excimer laser into the continuous wave regime. Potassium vapor handling problems were the principal difficulty in achieving laser action on the K Ar/K2 system. Of the four molecular systems and pumping techniques explored, the capillary discharge pumped K Ar/K2 system appears to be the most likely candidate for demonstrating continuous wave excimer laser action primarily because of its predicted lower pumping threshold and a demonstrated discharge stability advantage.

Palmer, A. J.↗

Early detection of disease: The correlation of the volatile organic profiles from patients with upper respiratory infections with subjects of normal profiles

A method is described whereby a transevaporator is used for sampling 60-100 microns of aqueous sample. Volatiles are stripped from the sample either by a stream of helium and collection on a porous polymer, Tenax, or by 0.8 ml of 2-chloropropane and collected on glass beads. The volatiles are thermally desorbed into a precolumn which is connected to a capillary gas chromatographic column for analysis. The technique is shown to be reproducible and suitable for determining chromatographic profiles for a wide variety of sample types. Using a transevaporator sampling technique, the volatile profiles from 70 microns of serum were obtained by capillary column gas chromatography. The complex chromatograms were interpreted by a combination of manual and computer techniques and a two peak ratio method devised for the classification of normal and virus infected sera. Using the K-Nearest Neighbor approach, 85.7 percent of the unknown samples were classified correctly. Some preliminary results indicate the possible use of the method for the assessment of virus susceptibility.

Zlatkis, A.↗

Effect of gravitational overloads, hypokinesia and hypodynamia on the vessels of the pulmonary blood circuit

Vessels of the pulmonary circuit are studied under normal conditions, in exposure to single stress or continuous threshold endurable chestspine gravitational stresses, and one to eight weak hypokinesia and hypodynamic effects followed by stress. Examination methods include rentgenography and microrentgenography, clearing, and histology. In exposure to gravitational stress the distal portions of the arterial vessels of the 3 and 4 orders constrict, while all veins dilate. Sinuosity of all vessels is noted. The volume of the capillary bed increases and signs of perivascular edema occur. Due to hypokinesia and hypodynamia the arteries constricted and the arterial bed becomes poor. The veins of all orders dilate and the volume of the capillary bed increases. The changes grew greater the longer the terms of hypodyamic effects. Successive combination of hypokinesia and hypodynamia and gravitational stresses cause more pronounced changes than separate effects of these two factors and result in great deformity of the vascular walls, including their rupture and penetration of formed elements beyond the limits of the vascular bed.

Kasimtsev, A. A.↗

Investigation of the effect of space flight factors on chromosomes in seeds

Frequency of mutations in postflight air-dry Crepis capillaris seeds, kept for five days aboard an artificial satellite was 36.0 + or - 1.9%, vs. 19.01 + or - 1.2% for seeds in a similar ground experiment. Both groups of seeds were prepared in identical concentrations and were treated by the same mutagen. The spectrum of mutations in postflight Crepis capillaris seeds contained a large number of chromosome-type mutations and some cells showed multiple alterations. Postflight seeds not treated with mutagens had a slightly higher level of mutability.

Dubinina, L. G.↗

Determination of surface tension at the phase interface

A method was developed for determining the surface tension coefficient at the interface of two immiscible liquids or of a gas and a liquid. Basic in this method is the measurement of the capillary rise of a droplet of one of the phases placed on the surface of the other phase. It is shown that the capillary rise is a function of the surface energy of the droplet and the viscous friction of the phases. A mathematical model of the dynamics of a liquid droplet is supported by experiments.

Dobychin, Y. I.↗

Microwave scatterometer measurements of oceanic wind vector

Results from Seasat-A scatterometer (SASS) remote sensing of oceanic wind vectors are reviewed, together with the theory of radar backscattering. The SASS was designed to measure the surface wind stress and neutral stability wind vector at 19.5 m altitude. Requirements included windspeeds from 4-24 m/sec to within 2 m/sec or 10%, a 1000 km swath, directions from 0-360 deg to within 20 deg, a 50 km resolution cell, and cross-track and along-track spacing between resolution cells of 100 km. The method was based on Bragg scattering of microwaves from cm-length capillary ocean waves. The strength of the backscatter is proportional to the capillary wave amplitude, which is in equilibrium with the ocean surface wind speed. The measurement grouping, least-squares estimator, and dB deviation model function table for the SASS geophysical algorithm are discussed. Comparisons of SASS, GOASEX, and ground truth wind data are made, and a 0.92 correlation between SASS and ground truth data is determined from regression analysis.

Jones, W. L.↗

Pore size engineering applied to the design of separators for nickel-hydrogen cells and batteries

Pore size engineering in starved alkaline multiplate cells involves adopting techniques to widen the volume tolerance of individual cells. Separators with appropriate pore size distributions and wettability characteristics (capillary pressure considerations) to have wider volume tolerances and an ability to resist dimensional changes in the electrodes were designed. The separators studied for potential use in nickel-hydrogen cells consist of polymeric membranes as well as inorganic microporous mats. In addition to standard measurements, the resistance and distribution of electrolyte as a function of total cell electrolyte content were determined. New composite separators consisting of fibers, particles and/or binders deposited on Zircar cloth were developed in order to engineer the proper capillary pressure characteristics in the separator. These asymmetric separators were prepared from a variety of fibers, particles and binders.

Abbey, K. M.↗

Particle analyzing method and apparatus

The rapid chemical analysis of particles in aerosols can be accomplished using an apparatus which produces a controlled stream of individual particles from an environment, and another apparatus which vaporizes and ionizes the particles moving in free flight, for analysis by a mass spectrometer. The device for producing the stream of particles includes a capillary tube through which the air with suspended particles moves, a skimmer with a small opening spaced from an end of the capillary tube to receive particles passing through the tube, and a vacuum pump which removes air from between the tube and skimmer and creates an inflow of air and particles through the tube. The particles passing through the skimmer opening can be simultaneously vaporized and ionized while in free flight, by a laser beam of sufficient intensity that is directed across the path of the free flying particles.

Sinha, M. P.↗

An investigation into the injection molding of PMR-15 polyimide

The chemorheological behavior of the PRM-15 molding compounds were characterized, the range of suitable processing parameters for injection molding in a reciprocating screw injection molding machine was determined, and the effects of the injection molding processing parameters on the mechanical properties of molded PMR-15 parts were studied. The apparatus and procedures for measuring viscosity and for determining the physical response of the material during heating are described. Results show that capillary rheometry can be effectively used with thermosets if the equipment is designed to overcome some of the inherent problems of these materials. A uniform temperature was provided in the barrel by using a circulating hot oil system. Standard capillary rheometry methods can provide the dependence of thermoset apparent viscosity on shear rate, temperature, and time. Process conditions resulting in complete imidization should be carefully defined. Specification of controlled oven temperature is inadequate and can result in incomplete imidization. For completely imidized PMR-15 heat at 15 C/min melt flow without gas evolution occurs in the temperature range of 325 C to 400 C.

Colaluca, M. A.↗

Does the scatterometer see wind speed or friction velocity?

Studies of radar backscatter from the sea surface are referred either to the wind speed, U, or friction velocity, u(sub *). Bragg scattering theory suggests that these variations in backscatter are directly related to the height of the capillary-gravity waves modulated by the larger waves in tilt and by straining of the short wave field. The question then arises as to what characteristic of the wind field is most probably correlated with the wave number spectrum of the capillary-gravity waves. The justification for selecting U as the appropriate meteorological parameter to be associated with backscatter from L-band to Ku-band are reviewed. Both theoretical reasons and experimental evidence are used to demonstrate that the dominant parameter is U/C(lambda) where U is the wind speed at a height of about lambda/2 for waves having a phase speed of C(lambda).

Donelan, M. A.↗

Concept evaluation of four thermal utility systems for low orbit spacecraft

Attention is given to the design features and comparative performance of four two-phase heat transport systems under consideration by NASA as long term space mission devices for the collection, transportation and rejection of waste heat from spacecraft components over the zero-100 C temperature range. The system types are: a mechanically pumped two-phase loop, a capillary pumped loop, an osmotic pumped loop, and a loop employing a biomorph pump. The principal advantage of a capillary pumped loop is that it is a passive system with few moving parts that inherently possesses high reliability. The working fluid recommended for use in such a thermal utility is NH3, which has the requisite combination of high latent heat of vaporization and high surface tension.

Peterson, G. P.↗

The non-Gaussian joint probability density function of slope and elevation for a nonlinear gravity wave field

On the basis of the mapping method developed by Huang et al. (1983), an analytic expression for the non-Gaussian joint probability density function of slope and elevation for nonlinear gravity waves is derived. Various conditional and marginal density functions are also obtained through the joint density function. The analytic results are compared with a series of carefully controlled laboratory observations, and good agreement is noted. Furthermore, the laboratory wind wave field observations indicate that the capillary or capillary-gravity waves may not be the dominant components in determining the total roughness of the wave field. Thus, the analytic results, though derived specifically for the gravity waves, may have more general applications.

Huang, N. E.↗

Pore size engineering applied to the design of separators for nickel-hydrogen cells and batteries

Pore size engineering in starved alkaline multiplate cells involves adopting techniques to widen the volume tolerance of individual cells. Separators with appropriate pore size distributions and wettability characteristics (capillary pressure considerations) to have wider volume tolerances and an ability to resist dimensional changes in the electrodes were designed. The separators studied for potential use in nickel-hydrogen cells consist of polymeric membranes as well as inorganic microporous mats. In addition to standard measurements, the resistance and distribution of electrolyte as a function of total cell electrolyte content were determined. New composite separators consisting of fibers, particles and/or binders deposited on Zircar cloth were developed in order to engineer the proper capillary pressure characteristics in the separator. These asymmetric separators were prepared from a variety of fibers, particles and binders. Previously announced in STAR as N83-24571

Abbey, K. M.↗

Fluid surface behavior in low gravity. Center discretionary fund no. 83-21

Measurements of rotating equilibrium bubble shapes in the low-gravity environment of a free-falling aircraft are presented. Emphasis is placed on bubbles which intersect the container boundaries. These data are compared with theoretical profiles derived from Laplace's formula and are in good agreement with the measurements. Two types of instability are explored. The first occurs when the baffle spacing is too large for the bubble to intersect both the top and bottom boundaries. The second occurs when the hydrostatic pressure beneath a displaced free surface does not compensate for pressure change due to capillary forces. The interface shape depends on the contact angle, the radius of intersection with container, and the parameter F which is a measure of the relative importance of centrifugal force to surface tension. For isolated bubbles, F has a maximum value of 1/2. A further increase in F causes the bubble to break contact with the axis of rotation. For large values of F, the bubble becomes more cylindrical and the capillary rise occurs over a thinner layer so that the small radius of curvature can generate enough pressure drop to balance the increased hydrostatic contribution.

Leslie, F.↗

Studies related to ocean dynamics. Task 3.2: Aircraft Field Test Program to investigate the ability of remote sensing methods to measure current/wind-wave interactions

The feasibility of remote sensing of current flows in the ocean and the remote sensing of ocean currents by backscattering cross section techniques was studied. It was established that for capillary waves, small scale currents could be accurately measured through observation of wave kinematics. Drastic modifications of waves by changing currents were noted. The development of new methods for the measurement of capillary waves are discussed. Improvement methods to resolve data processing problems are suggested.

Huang, N. E.↗

Multi-leg heat pipe evaporator

A multileg heat pipe evaporator facilitates the use and application of a monogroove heat pipe by providing an evaporation section which is compact in area and structurally more compatible with certain heat exchangers or heat input apparatus. The evaporation section of a monogroove heat pipe is formed by a series of parallel legs having a liquid and a vapor channel and a communicating capillary slot therebetween. The liquid and vapor channels and interconnecting capillary slots of the evaporating section are connected to the condensing section of the heat pipe by a manifold connecting liquid and vapor channels of the parallel evaporation section legs with the corresponding liquid and vapor channels of the condensing section.

Alario, J. P.↗

Measuring Viscosities of Gases at Atmospheric Pressure

Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

Singh, Jag J.↗

Use of hydrophilic polymer coatings for control of electroosmosis and protein adsorption

The purpose of this project was to examine the utility of polyethylene glycol (PEG) and dextran coatings for control of electroosmosis and protein adsorption; electroosmosis is an important, deleterious process affecting electrophoretic separations, and protein adsorption is a factor which needs to be controlled during protein crystal growth to avoid multiple nucleation sites. Performance of the project required use of X-ray photoelectron spectroscopy to refine previously developed synthetic methods. The results of this spectroscopic examination are reported. Measurements of electroosmotic mobility of charged particles in appropriately coated capillaries reveals that a new, one-step route to coating capillaries gives a surface in which electroosmosis is dramatically reduced. Similarly, both PEG and dextran coatings were shown by protein adsorption measurements to be highly effective at reducing protein adsorption on solid surfaces. These results should have impact on future low-g electrophoretic and protein crystal growth experiments.

Harris, J. Milton↗