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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34

Recovery Act - Demonstration of Sodium Ion Battery for Grid Level Applications

Aquion Energy received a $5.179 million cooperative research agreement under the Department of Energy's Smart Grid Demonstration Program Demonstration of Promising Energy Storage Technologies (Program Area 2.5) of FOA DE-FOE-0000036. The main objective of this project was to demonstrate Aquion's low cost, grid-scale, ambient temperature sodium ion energy storage device. The centerpiece of the technology is a novel hybrid energy storage chemistry that has been proven in a laboratory environment. The objective was to translate these groundbreaking results from the small-batch, small-cell test environment to the pilot scale to enable significant numbers of multiple ampere-hour cells to be manufactured and assembled into test batteries. Aquion developed a proof of concept demonstration unit that showed similar performance and major cost improvement over existing technologies. Beyond minimizing cell and system cost, Aquion built a technology that is safe, environmentally benign and durable over many thousands of cycles as used in a variety of grid support roles.

25 ENERGY STORAGE↗

Implications of Aerosol Physicochemical Properties Including Ice Nucleation at ARM Mega Sites for Improved Understanding of Microphysical Atmospheric Cloud Processes (Final Technical Report)

Continuous, long-term measurements of atmospheric ice-nucleating particles (INPs) that influence clouds and precipitation were conducted to investigate the abundance and variability of ground-level INPs across the world. Three field campaigns were organized by the DOE Atmospheric Radiation Measurement (ARM) program, including Examining INP from Southern Great Plains (ExINP-SGP, 2019), Examining INP from Eastern North Atlantic (ExINP-ENA, 2020 – 2021), and Examining INP from North Slope of Alaska (ExINP-NSA, 2021 – 2024). Additional small-scale supporting field experiments were performed in 2019 and 2021 to collect airborne particulate matter at SGP for complementary laboratory characterization of the particles’ physical and chemical properties [Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY), 2019; ExINP-SGP II, 2021]. In these studies, the PI’s team measured INP concentration with both real-time and laboratory measurements in a wide range of freezing temperatures ($T$ from 0 °C to about –30 °C). This project elucidated spatial variability and seasonality in the abundance of immersion mode active INPs across three ARM sites using a single instrument, a Portable Ice Nucleation Experiment (PINE) chamber version 03 (PINE-03 hereafter). Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient INP abundance, air mass origin region, and meteorological variability. Our findings suggest very high freezing efficiency of INPs at the NSA site across the measured temperatures (ice nucleation active surface site density, $n_s(T)$, $\approx 2 \times 10^{8} - 10^{10}$ m -2 for from –16 to –31 °C), which is a factor of 10 – 1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in autumn using the same instrument; surprisingly high INP abundance ($\ge 1 \text{ L}^{-1}$ at –25 °C) for the examined temperatures throughout the year that PINE-03 did not measure at other sites; and high INP concentration in spring, possibly related to arctic haze episodes.

58 GEOSCIENCES↗

Advanced modeling to accelerate the scale up of carbon capture technologies

In order to help meet the goals of the DOE carbon capture program, the Carbon Capture Simulation Initiative (CCSI) was launched in early 2011 to develop, demonstrate, and deploy advanced computational tools and validated multi-scale models to reduce the time required to develop and scale-up new carbon capture technologies. This article focuses on essential elements related to the development and validation of multi-scale models in order to help minimize risk and maximize learning as new technologies progress from pilot to demonstration scale.

20 FOSSIL-FUELED POWER PLANTS↗

High Temperature Steam Electrolysis Process Performance and Cost Estimates - DOE Hydrogen Program AMR Presentation

Technology readiness levels (TRLs) of electrolysis systems have dramatically increased in recent years as the interest in clean hydrogen production and decarbonization of transportation, industrial and other sectors increases across the globe. This is especially true of high temperature steam electrolysis (HTSE) / solid oxide electrolysis cell (SOEC) systems which show promise of much higher system efficiencies than other more developed electrolysis technologies. This possibility of higher efficiencies of HTSE / SOEC systems has been previously assumed to be theoretically possible but in recent years it has become less theoretical and more realistic as an increasing amount of suppliers complete lab and pilot tests showing very promising results. Research in the areas of manufacturing techniques, material selection, electrode and electrolyte compositions, and balance of plant size and integration continues at a fast pace as an increasing number of suppliers both internationally and domestically become involved. The advantages of HTSE become more pronounced when HTSE is coupled with nuclear power plants (NPPs). This is because thermal energy produced by the nuclear reactor can be used in a series of heat transfer loops and heat exchangers to vaporize HTSE feedwater, which drastically improves the economics of the process. Idaho National Laboratory (INL) has been very involved in the research and modeling of HTSE systems for a number of years, in collaboration with other national laboratories, academia, and industry stakeholders both on the hydrogen production as well as the hydrogen demand side. The modeling completed over the years on a large variety of projects has led to a wealth of knowledge at INL including in the area of the technoeconomic assessment (TEA) of HTSE systems. TEAs include process modeling of the HTSE systems to calculate system energy requirements and equipment sizing, followed by estimation of capital and operating costs to enable calculation of the levelized cost of hydrogen (LCOH). The TEA work performed has produced incremental improvements and tuning of the methods, assumptions, models, and results of the analyses as well as providing some opportunities for validating these results. The purpose of this document is to record the current baseline HTSE analyses led by INL to show the current status of assumptions and costs of these systems. Given the rapid development of this technology, the variety of suppliers entering the space, and the increasing attention government and industry are giving to such systems, this document may be updated on a periodic basis with updated analysis and assumptions. This document compiles various analyses results and approaches completed over a period of years into a single document to be used as a baseline going forward. It represents what the INL HTSE analysis group assumes to be the internal best estimate of the current operation, costs, and landscape of the HTSE industry state of the art capability for current SOEC technology in an Nth-of-a-Kind (NOAK) plant, which in this study is defined as existence of the manufacturing capacity to support previous deployment of N = 100 count of 25 MWe modular HTSE blocks (with modular equipment component cost reductions specified as following a 95% learning curve). That said, this is a public document and as such so no proprietary data was used or included in this report. There may be HTSE suppliers that have performance specifications, and cost estimates, and test data that differ from the analysis presented in this document. This document is meant to be a best conservative estimate of the technology and not an absolute reference.

08 HYDROGEN↗

Plant-Scale Concentration Column Designs for SHINE Target Solution Utilizing AG 1 Anion Exchange Resin

Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop SHINE, an accelerator-driven process that will utilize a uranyl-sulfate solution for the production of fission product Mo-99. An integral part of the process is the development of a column for the separation and recovery of Mo-99, followed by a concentration column to reduce the product volume from 15-25 L to <1 L. Argonne has collected data from batch studies and breakthrough column experiments to utilize the VERSE (Versatile Reaction Separation) simulation program (Purdue University) to design plant-scale product recovery and concentration processes.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

REaCH iT- Research, Education and Collaborative Healthcare in Tennessee

A self-evaluation of the strengths and weaknesses of the University of Tennessee Cancer Institute programs revealed several major weaknesses impairing progress toward advancing translational research into the detection and treatment of cancer patients in Tennessee. The stated goal of the grant was to bring together cancer researchers in the state of Tennessee in a network to develop multidisciplinary approaches to the prevention, diagnosis and treatment of cancers. This goal was met through a number of mechanisms that were funded under the auspices of this DOE grant, which included pilot project grants, seminars, symposia, scientific retreats, and the purchase of common equipment for investigators housed in the newly built Cancer Research Building at the UTHSC in Memphis. These approaches will have a major impact on the diagnosis and treatment of patients that suffer from various forms of cancer.

59 BASIC BIOLOGICAL SCIENCES↗

Codes Don't Always Get Enforced, But Contracts Do: Changing the Procurement Paradigm to Drive Building Energy Performance

New construction could account for more than 25% of the U.S. energy consumption by 2030. Millions of square feet are built every year that will not perform as expected - despite advancing codes, rating systems, super-efficient technologies, and advanced utility programs. With retrofits of these under-performers decades away, savings potential will be lost for years to come. Only the building owner is in the driver's seat to demand - and verify - higher-performing buildings. Yet our current policy and market interventions really target the design team, not the owner. Accelerate Performance, a U.S. Department of Energy funded initiative, is changing the building procurement approach to drive deeper, verified savings in three pilot states: Illinois, Minnesota, and Connecticut. Performance-based procurement ties energy performance to design and contractor team compensation while freeing them to meet energy targets with strategies most familiar to them. The process teases out the creativity of the design and contracting teams to deliver energy performance - without driving up the construction cost. The paper will share early results and lessons learned from new procurement and contract approaches in government, public, and private sector building projects. The paper provides practical guidance for building owners, facilities managers, design, and contractor teams who wish to incorporate effective performance-based procurement for deeper energy savings in their buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Alternate Packaging Options for Remote-Handled Transuranic Waste Disposal at WIPP - 19093

Sandia National Laboratories/New Mexico (Sandia) began a remote-handled (RH) transuranic (TRU) repackaging campaign two weeks before the Waste Isolation Pilot Plant (WIPP) shutdown in February 2014. Since a contract with Nuclear Waste Partnerships (NWP), the WIPP Management and Operation (M and O) contractor, was already in place for certified visual examination (VE) and dose-to-curie (DTC) support, repackaging continued and was completed in October 2015. Twenty-five 55-gallon drums of RH TRU waste were packaged, awaiting certification and shipment to WIPP. However, in February 2017 at the National TRU Program (NTP) Corporate Board meeting, Sandia learned that RH TRU waste normally transported in removable lid canisters (RLCs) and 72-B casks was not being accepted for disposal when WIPP re-opened after the shutdown. One option, shielded container assemblies (SCAs), was available and approved for RH TRU waste disposal at the WIPP. Sandia made the decision to pursue the use of SCAs. The use of SCAs allow RH TRU waste to be shipped as contact-handled (CH) in HalfPACTs, emplaced on the floor of the WIPP instead of in boreholes in the walls, if the dose rate is less than 200 millirem/hour on contact. The RH TRU waste remains on the WIPP inventory as RH. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Phase II Cost-Benefit Analysis: Economic Impact Assessment For Indonesia Building Sector Whole-Building Cooling Solutions

The Net Zero World (NZW) Initiative Collaborative Work Program with the Government of Indonesia (GoI) includes technical assistance and investment mobilization facilitation to accelerate deployment of energy efficiency technologies and solutions for the building sector. A February 2023 US–Indonesia Joint Workshop on Decarbonizing the Building Sector yielded a NZW Indonesia Building Decarbonization Working Group (NZW IBDWG) with four sub working groups (SWGs): SWG-A National Center, SWG-B Capacity Building, SWG-C Investment and Financing, and SWG-D Pilot Projects.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Integration Of PanDA Workload Management System With Supercomputers for ATLAS and Data Intensive Science

The Large Hadron Collider (LHC), operating at the international CERN Laboratory in Geneva, Switzerland, is leading Big Data driven scientific explorations. Experiments at the LHC explore the fundamental nature of matter and the basic forces that shape our universe, and were recently credited for the discovery of a Higgs boson. ATLAS, one of the largest collaborations ever assembled in the sciences, is at the forefront of research at the LHC. To address an unprecedented multi-petabyte data processing challenge, the ATLAS experiment is relying on a heterogeneous distributed computational infrastructure. The ATLAS experiment uses PanDA (Production and Data Analysis) Workload Management System for managing the workflow for all data processing on over 150 data centers. Through PanDA, ATLAS physicists see a single computing facility that enables rapid scientific breakthroughs for the experiment, even though the data centers are physically scattered all over the world. While PanDA currently uses more than 250,000 cores with a peak performance of 0.3 petaFLOPS, LHC data taking runs require more resources than Grid computing can possibly provide. To alleviate these challenges, LHC experiments are engaged in an ambitious program to expand the current computing model to include additional resources such as the opportunistic use of supercomputers. We will describe a project aimed at integration of PanDA WMS with supercomputers in United States, Europe and Russia (in particular with Titan supercomputer at Oak Ridge Leadership Computing Facility (OLCF), MIRA supercomputer at Argonne Leadership Computing Facilities (ALCF), Supercomputer at the National Research Center Kurchatov Institute , IT4 in Ostrava and others). Current approach utilizes modified PanDA pilot framework for job submission to the supercomputers batch queues and local data management, with light-weight MPI wrappers to run single threaded workloads in parallel on LCFs multi-core worker nodes. This implementation was tested with a variety of Monte-Carlo workloads on several supercomputing platforms for ALICE and ATLAS experiments and it is in full production for the ATLAS experiment since September 2015. We will present our current accomplishments with running PanDA WMS at supercomputers and demonstrate our ability to use PanDA as a portal independent of the computing facilities infrastructure for High Energy and Nuclear Physics as well as other data-intensive science applications, such as bioinformatics and astro-particle physics.

Data-intensive science↗

Current Status of the DOE/NNSA Nuclear Criticality Safety Program Hands-On Criticality Safety Training [Abstract]

The U.S. Department of Energy/National Nuclear Security Administration (DOE/NNSA) Nuclear Criticality Safety Program (NCSP) has conducted two-week Nuclear Criticality Safety (NCS) Practitioner courses since 2011 to support the training and qualification of new NCS staff. The course was developed in accordance with the American National Standard Institute/American Nuclear Society (ANSI/ANS) standard for NCS training and qualifications (ANSI/ANS-8.26-2007). In 2013, an NCS Manager’s course was developed for process supervisors, managers, regulators, and other professionals with NCS-related responsibilities. This course was revised in 2019 for Criticality Safety Officers (CSOs) based on an NCSP Criticality Safety Support Group tasking (2018-01). This course was piloted at the Nevada Field Office and the National Criticality Experiments Research Center (NCERC) in June 2021. These courses consist of the following training components: classroom education, facility training, and hands-on subcritical and critical experiments training. The two-week Practitioner course offers a week of classroom training, with practical workshops and exercises focused on teaching students how to perform an NCS evaluation. The second week of training involves hands-on critical and subcritical experiments and measurements. The first week is offered in Las Vegas, Nevada, at the DOE Nevada Field Office or the National Atomic Testing Museum. Depending on the student’s clearance level, the second week is offered at Sandia National Laboratory (SNL) (uncleared and L-cleared students) or at the National Criticality Experiments Research Center (Q-cleared students). The one-week Manager’s course is offered at SNL or NCERC, depending on clearance or interest, and includes classroom and hands-on critical and subcritical experiments and measurements. This paper provides an overview and status report for the DOE/NNSA NCSP training courses in NCS and to provide information about future course offerings. This paper will also discuss the challenges associated with executing the training courses during the COVID-19 pandemic. The 2-week Practitioner and 1-week manager courses are currently offered twice per year and adjustments are made based upon demand.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Current Status of the DOE/NNSA Nuclear Criticality Safety Program Hands-On Criticality Safety Training

The U.S. Department of Energy/National Nuclear Security Administration (DOE/NNSA) Nuclear Criticality Safety Program (NCSP) has conducted two-week Nuclear Criticality Safety (NCS) Practitioner courses since 2011 to support the training and qualification of new NCS staff. The course was developed in accordance with the American National Standard Institute/American Nuclear Society (ANSI/ANS) standard for NCS training and qualifications (ANSI/ANS-8.26-2007). In 2013, an NCS Manager’s course was developed for process supervisors, managers, regulators, and other professionals with NCS-related responsibilities. This course was revised in 2019 for Criticality Safety Officers (CSOs) based on an NCSP Criticality Safety Support Group tasking (2018-01). This course was piloted at the Nevada Field Office and the National Criticality Experiments Research Center (NCERC) in June 2021. These courses consist of the following training components: classroom education, facility training, and hands-on subcritical and critical experiments training. The two-week Practitioner course offers a week of classroom training, with practical workshops and exercises focused on teaching students how to perform an NCS evaluation. The second week of training involves hands-on critical and subcritical experiments and measurements. The first week is offered in Las Vegas, Nevada, at the DOE Nevada Field Office or the National Atomic Testing Museum. Depending on the student’s clearance level, the second week is offered at Sandia National Laboratory (SNL) (uncleared and L-cleared students) or at the National Criticality Experiments Research Center (Q-cleared students). The one-week Manager’s course is offered at SNL or NCERC, depending on clearance or interest, and includes classroom and hands- on critical and subcritical experiments and measurements. This paper provides an overview and status report for the DOE/NNSA NCSP training courses in NCS and to provide information about future course offerings. This paper discusses the challenges associated with executing the training courses during the COVID-19 pandemic. The 2-week Practitioner and 1-week manager courses are currently offered twice per year and adjustments are made based upon demand.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Evolution of CMS Workload Management Towards Multicore Job Support

The successful exploitation of multicore processor architectures is a key element of the LHC distributed computing system in the coming era of the LHC Run 2. High-pileup complex-collision events represent a challenge for the traditional sequential programming in terms of memory and processing time budget. The CMS data production and processing framework is introducing the parallel execution of the reconstruction and simulation algorithms to overcome these limitations. CMS plans to execute multicore jobs while still supporting singlecore processing for other tasks difficult to parallelize, such as user analysis. The CMS strategy for job management thus aims at integrating single and multicore job scheduling across the Grid. This is accomplished by employing multicore pilots with internal dynamic partitioning of the allocated resources, capable of running payloads of various core counts simultaneously. An extensive test programme has been conducted to enable multicore scheduling with the various local batch systems available at CMS sites, with the focus on the Tier-0 and Tier-1s, responsible during 2015 of the prompt data reconstruction. Scale tests have been run to analyse the performance of this scheduling strategy and ensure an efficient use of the distributed resources. This paper presents the evolution of the CMS job management and resource provisioning systems in order to support this hybrid scheduling model, as well as its deployment and performance tests, which will enable CMS to transition to a multicore production model for the second LHC run.

Perez-Calero Yzquierdo, A.↗

NRG CO 2 NCEPT - Confirmation Of Novel Cost-effective Emerging Post-combustion Technology

Under DOE's solicitation DE-FOA-0001190, NRG and Inventys conceptualized a Large-Scale pilot (>10MWe) post-combustion CO 2 capture project using Inventys' VeloxoThermTM carbon capture technology. The technology is comprised of an intensified thermal swing adsorption (TSA) process that uses a patented architecture of structured adsorbent and a novel process design and embodiment to capture CO 2 from industrial flue gas streams. The result of this work concluded that the retrofit of this technology is economically and technically viable, but that the sorbent material selected for the program would need improving to meet the techno-economic performance requirements of the solicitation.

20 FOSSIL-FUELED POWER PLANTS↗

Army Re-tuning™ Implementation Guides

The Army is a large, geographically dispersed organization with 156 installations and over 980 million square feet of building space to operate and maintain. The building stock spans a wide range of vintages and missions, with many serving cross-cutting functions and purposes. To meet Federal mandates and reduction goals organizationally, in recent years the Army has aggressively pursued policy and energy efficiency projects and programs resulting in a 9.6% reduction in energy use intensity (EUI) from fiscal year (FY) 2015 to FY2017. Despite these successes, the Army remains the largest consumer of electricity in the Federal government and spent approximately $1.1 billion in energy-related costs in FY2017 The Pacific Northwest National Laboratory (PNNL), in support of the Assistant Secretary of the Army (Installations, Energy and Environment) (ASA (IE&E)), was tasked with a multi-year study and pilot demonstration to develop a business case for the potential energy and cost reduction benefits from re-tuning™ efforts for the Army. Re tuning is a systematic process aimed at minimizing building energy consumption by identifying and correcting operational problems that plague buildings. The methodology was developed by PNNL research staff in an effort to improve building operational efficiency at no- or low-cost, primarily through building automation system (BAS) controls. The methodology is based on two basic principles: If the equipment is not needed, turn it off; and if the equipment is not needed at full power, turn it down. Implementation of identified low-cost/no-cost operational improvements through the re-tuning process results in increased building energy efficiency, reduced operating costs, and improvement to occupant comfort.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Geochemical and Solute Transport Modeling of In Situ Biological Treatment of Chromium in Groundwater - 19334

Reactive transport modeling is an ideal tool for developing better site-specific understanding and predictive capability to design and optimize in situ remedial strategies. However, the widespread use of these models for in situ groundwater remediation applications is limited by increased model complexity. This paper discusses the challenges encountered and strategies developed while constructing site-relevant geochemical and solute transport models to describe an in situ groundwater treatment program for chromium. The treatment strategy chosen for the site includes injection of dissolved organic carbon to establish reducing conditions in conjunction with a groundwater recirculation/plume flushing program. The reducing conditions established result in the immobilization of hexavalent chromium as insoluble trivalent chromium hydroxides. Hydrogeochemical models were employed during design to describe and predict long-term treatment performance and secondary effects, such as the generation and attenuation of byproducts (including dissolved arsenic, manganese, and iron), water quality changes (including pH, alkalinity, and TDS), and potential permeability changes. A reactive transport model was developed using PHT3D, calibrated from bench-scale and pilot-scale testing and aquifer hydrologic characterization. A 'hybrid' geochemical/solute transport modeling approach was developed, resulting in substantial reduction in model complexity and computation time. These results present a unique strategy for striking the balance between model sophistication and model complexity - adequately capturing the complex hydrogeological and biogeochemical processes at work within the system - which can be readily applied to other in situ groundwater treatment implementations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Brine Availability Test in Salt (BATS) FY21 Update

This report summarizes the 2021 fiscal year (FY21) status of ongoing borehole heater tests in salt funded by the disposal research and development (R&D) program of the Office of Spent Fuel & Waste Science and Technology (SFWST) of the US Department of Energy’s Office of Nuclear Energy’s (DOE-NE) Office of Spent Fuel and Waste Disposition (SFWD). This report satisfies SFWST milestone M2SF- 21SN010303052 by summarizing test activities and data collected during FY21. The Brine Availability Test in Salt (BATS) is fielded in a pair of similar arrays of horizontal boreholes in an experimental area at the Waste Isolation Pilot Plant (WIPP). One array is heated, the other unheated. Each array consists of 14 boreholes, including a central borehole with gas circulation to measure water production, a cement seal exposure test, thermocouples to measure temperature, electrodes to infer resistivity, a packer-isolated borehole to add tracers, fiber optics to measure temperature and strain, and piezoelectric transducers to measure acoustic emissions. The key new data collected during FY21 include a series of gas tracer tests (BATS phase 1b), a pair of liquid tracer tests (BATS phase 1c), and data collected under ambient conditions (including a period with limited access due to the ongoing pandemic) since BATS phase 1a in 2020. A comparison of heated and unheated gas tracer test results clearly shows a decrease in permeability of the salt upon heating (i.e., thermal expansion closes fractures, which reduces permeability).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Subtask 3.4 – Fischer–Tropsch Fuels Development

Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing Fischer–Tropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO 2 and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO 2 , but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding for BP1 was provided by the North Dakota Industrial Commission’s (NDIC) Renewable Energy Council.

10 SYNTHETIC FUELS↗