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At least 613 records · Page 34

The Parameterization of Solid Metal-Liquid Metal Partitioning of Siderophile Elements

The composition of a metallic liquid can significantly affect the partitioning behavior of elements. For example, some experimental solid metal-liquid metal partition coefficients have been shown to increase by three orders of magnitude with increasing S-content of the metallic liquid. Along with S, the presence of other light elements, such as P and C, has also been demonstrated to affect trace element partitioning behavior. Understanding the effects of metallic composition on partitioning behavior is important for modeling the crystallization of magmatic iron meteorites and the chemical effects of planetary differentiation. It is thus useful to have a mathematical expression that parameterizes the partition coefficient as a function of the composition of the metal. Here we present a revised parameterization method, which builds on the theory of the current parameterization of Jones and Malvin and which better handles partitioning in multi-light-element systems.

Chabot, N. L.↗

In Situ Instrumentation for Sub-Surface Planetary Geochemistry

Novel instrumentation is under development at NASA's Goddard Space Flight Center, building upon earth-based techniques for hostile environments, to infer geochemical processes important to formation and evolution of solid bodies in our Solar System. A prototype instrument, the Pulsed Neutron Generator Gamma Ray and Neutron Detectors (PNG-GRAND), has a 14 MeV pulsed neutron generator coupled with gamma ray and neutron detectors to measure quantitative elemental concentrations and bulk densities of a number of major, minor and trace elements at or below the surfaces with approximately a meter-sized spatial resolution down to depths of about 50 cm without the need to drill. PNG-GRAND's in situ a meter-scale measurements and adaptability to a variety of extreme space environments will complement orbital kilometer-scale and in-situ millimeter scale elemental and mineralogical measurements to provide a more complete picture of the geochemistry of planets, moons, asteroids and comets.

Bodnarik, J.↗

The Search for Truly "Regolithic" Howardites

The howardite meteorites are polymict breccias of eucrite (basaltic) and diogenite (orthopyroxenitic) material [1] that likely originate from the asteroid 4 Vesta [2]. The true regolithic nature of the suite is not well defined, with previous research suggesting correlations between Ni and solar wind noble gas contents, and minimal variation in Al2O3 content [3]. Through combined petrological, compositional and noble gas analyses, we aim to better understand howardite petrological diversity, regolith formation processes on the parent asteroid, and to establish what defines a truly "regolithic" howardite. Our petrological study of 30 polymict eucrites and howardites has identified regolithic features (e.g. melt clasts, chondrite fragments), used to develop a regolith grading scheme. Bulk major element com-positional data have been collected [4], and both trace-element and noble gas analyses are underway. We expect those howardites with regolithic petrological and chemical features to have high abundances of implanted solar wind noble gases.

Cartwright, J. A.↗

The influence of water, diet, and temperature on 87 Sr/ 86 Sr in fin spines of juvenile Atlantic Sturgeon Acipenser oxyrinchus oxyrinchus

Analysis of microchemistry in fish fin spines offers a non-lethal approach to address key questions relating to spatial patterns and habitat use of fish. Reconstruction of life history is based on chemical changes within calcified structures with an underlying assumption of elemental incorporation relative to environmental concentration. However, information is limited on the relative influence of water and diet concentrations of elements to corresponding concentrations within fin spines. Strontium (Sr) is commonly used in trace element studies because of its predictable changes within watersheds, with recent applications showing utility of 87 Sr/ 86 Sr for greater spatial resolution. Therefore, this study evaluated the influence of water and diet 87 Sr/ 86 Sr on pectoral fin spines of Atlantic Sturgeon A. oxyrinchus oxyrinchus in controlled laboratory experiments. In the first experiment, fish were exposed to a control, water spiked with 0.10 mg/L of 87 Sr or diet spiked with 0.25 µg/g or 0.50 µg/g of 87 Sr in replicated tanks for 12 weeks. In a second experiment, to determine the time duration required to occupy a different environment for fin spine chemistry to change, fish were maintained in water- or diet-spiked treatments for 1, 2, 3, or 6 weeks. Additionally, to determine if temperature has an influence on 87 Sr/ 86 Sr in fin spines, fish were held at 15 and 25°C for 12 weeks. Fin spines were analyzed using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS), and water and diet samples were analyzed using solution based ICP-MS. Results from Experiment 1 indicate water is the primary contributor and diet a secondary contributor of 87 Sr/ 86 Sr in pectoral fin spines of Atlantic Sturgeon. Results from Experiment 2 indicate fin spine 87 Sr/ 86 Sr can be influenced by water after 1 week and diet after 12 weeks. Additionally, although sample size was limited (n=3), water temperature did not have an effect on 87 Sr/ 86 Sr fin spine chemistry. In conclusion, these results provide guidance for interpretation of 87 Sr/ 86 Sr in pectoral fin spines of sturgeon and indicate usefulness of the technique for retrospectively estimating movement and habitat use.

59 BASIC BIOLOGICAL SCIENCES↗

Mineralogical, Elemental, and Tomographic Reconnaissance Investigation for CLPS (METRIC)

METRIC is a robotic science laboratory that can determine the mineralogy, elemental chemistry, micromorphology, and thermophysical properties of planetary regolith. The METRIC suite comprises METRIC XRD/F, an X-ray diffraction/X-ray fluorescence instrument that can determine the mineralogy and elemental chemistry of regolith samples; METRIC XCT, a micro X-ray computed tomography instrument that can be used to evaluate grain/crystallite sizes and textures; METRIC IRS, an imaging spectrometer mounted on a rover that can determine mineralogy and thermophysical properties at the landing site; and a pneumatic sample collection, processing, distribution system developed by Honeybee Robotics. The payload elements could be deployed on a static lander or a rover. Data returned from the METRIC payload would inform origin, formation, and evolution of rocky planetary bodies. METRIC XRD/F draws on heritage from the CheMin instrument on the Mars Science Laboratory (MSL) Curiosity rover [1], with a few important improvements. Like CheMin, METRIC XRD/F operates in transmission geometry and uses piezoelectric actuators on sample cells in a tuning fork geometry to induce convective grain motion of the regolith to create a randomly oriented powder. MSL CheMin uses an energy-sensitive CCD to collect XRD patterns and XRF spectra simultaneously from the same sample cell, resulting in qualitative XRF data. METRIC XRD/F uses two different sample cells, one optimized for XRD and one optimized for XRF, and a silicon drift detector to detect fluoresced X-rays. This improvement to the XRF capabilities provides quantitative geochemical data of major elements down to Z = 11 and allows for the detection of minor and trace elements that are critical for evaluating geologic evolution of the Moon (e.g., P and Th). Modest improvements to the XRD geometry and hardware allow for better angular resolution and the ability to distinguish between members of the pyroxene group. METRIC XCT uses the same geometry and much of the same hardware as METRIC XRD/F, where a CCD would capture images of a regolith sample in a 3 mm diameter sample tube that is rotated 360° in steps <1°. Image brightness can be used to infer compositional data, where brighter materials indicate a higher Z, much like scanning electron microscopy. Data from METRIC XCT complement those from METRIC XRD/F. Particle size, shape, and texture can provide petrologic and provenance information, whereas vesicle size and morphology in volcanic or impact melt lithologies can inform cooling rates. METRIC IRS is a hyperspectral thermal imager that can be mounted to a lander or rover to provide mineralogical data from the broader landing site and help determine whether the samples analyzed by METRIC XRD/F and XCT are representative. The METRIC IRS spectral range (8–14 μm) and resolution (10.8 cm-1) allow for quantitative mineralogy from modelling Reststrahlen bands of major rock-forming minerals (e.g., silicates, phosphates). Radiance cubes can be processed and modelled with an onboard high-performance computer to determine mineral abundances of plagioclase, high-Ca pyroxene, pigeonite, orthopyroxene, olivine, and glass. Regolith samples can be acquired, processed, and delivered to the X-ray instruments via multiple sample handling systems, but the pneumatic sampling systems developed by Honeybee Robotics [e.g., 2] are best suited for relatively low-cost missions that are being competed for the Moon (e.g., NASA’s Payloads and Research Investigations for the Surface of the Moon program). There are pneumatic sampling systems that collect surface material and other systems that pneumatically drill up to ~1 m below the surface, providing material that has not been space weathered and has not been affected by the lander’s exhaust. [1] Blake, D. F., Vaniman, D., Achilles, C., Anderson, R., Bish, D., et al. (2012). Space Sci. Rev. 170, 341-478. https://doi.org/10.1007/s11214-012-9905-1. [2] Zacny, K., Betts, B., Hedlund, M., Long, P., Gramlich, M., Tura, K., Chu, P., Jacob, A., Garcia, A. (2014). IEEE Aerospace Conference, 3-7 March 2014, Big Sky, MT, U.S.A.

X-ray diffraction↗

Surface Water Quality Data from Beaver-Impacted Streams; Trail Creek and East River, Colorado 2025

This data package contains surface water chemistry measurements collected in 2025 to evaluate how beaver damming and low-tech process-based stream restoration influence water quality and metal mobility in mountainous headwater systems of the Upper Colorado River Basin. Sampling was conducted at Trail Creek (Taylor Park watershed, Colorado), a tributary undergoing restoration through installation of low-tech process-based structures (i.e., beaver dam analogs), and at off-channel beaver ponds within the East River floodplain (East River watershed, Colorado). Samples were collected along longitudinal transects spanning upstream control reaches, beaver-influenced ponded reaches, and downstream segments. Additional samples were collected from near-surface pore waters within a beaver dam seepage face. The dataset includes concentrations of major and trace elements measured by inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES), major anions measured by ion chromatography (IC), and dissolved organic carbon (DOC; reported as non-purgeable organic carbon, NPOC). Samples were size-fractionated at 0.45 micrometers (µm), 0.22 µm, and 0.02 µm to distinguish particulate (>0.45 µm), colloidal (0.22–0.02 µm), and dissolved (<0.02 µm) fractions. The data package consists of comma-separated value (.csv) files containing tabulated chemical concentration data, sample metadata (site identifiers, geographic coordinates, sampling dates, fraction type), and quality control flags. All files are provided in open, non-proprietary formats that can be accessed using standard data analysis software such as Microsoft Excel, R, Python, MATLAB, or other programs capable of reading .csv files. Units, detection limits, and analytical methods are documented in accompanying metadata files. The dataset is designed to support analyses of (1) how beaver impoundment and restoration structures alter elemental partitioning and transport, (2) the role of iron and organic carbon in mediating trace metal mobility, and (3) reach-scale changes in water quality across restoration gradients. This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231. Part of this work was performed at SLAC Accelerator Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-76SF00515.

Anions↗

Complementary rare earth element patterns in unique achondrites, such as ALHA 77005 and shergottites, and in the earth

Abundances of major, minor, and trace elements are determined in the Antarctic achondrite Allan Hills (ALHA) 77005 via sequential instrumental and radiochemical neutron activation analysis. The rare earth element (REE) abundances of ALHA 77005 reveal a unique chondritic normalized pattern; that is, the REEs are nearly unfractionated from La to Pr at approximately 1.0X chondrites, monotonically increased from Pr to Gd at approximately 3.4X with no Eu anomaly, nearly unfractionated from Gd and Ho and monotonically decreased from Ho to Lu at approximately 2.2X. It is noted that this unique REE pattern of ALHA 77005 can be modeled by a melting process involving a continuous melting and progressive partial removal of melt from a light REE enriched source material. In a model of this type, ALHA 77005 could represent either a crystallized cumulate from such a melt or the residual source material. Calculations show that the parent liquids for the shergottites could also be derived from a light REE enriched source material similar to that for ALHA 77005.

Ma, M.-S.↗

The effect of heavy element opacity on the structure of H II regions

In the modeling of H II regions, there generally has been universal dismissal of opacity due to elements other than H and He. It is found that in certain cases, the trace elements do contribute substantially to the opacity, modifying the ionization equilibrium directly and having feedback on the thermal structure. When important, this effect will reduce the volume where some lines from high ionization states are produced and will decouple transition zones that have traditionally been assumed to be coextensive. The possible reconciliation of some recent problems where observations and theory appeared to be inconsistent with one another are discussed.

Rubin, R. H.↗

The chemistry and origin of the ordinary chondrites Implications from refractory-lithophile and siderophile elements

Thirty-eight ordinary chondrites (17 H, 20 L, and 1 LL) have been analyzed for major and selected trace elements. These data indicate that the lithophile elements Mg, Ca, Al, Cr, and V normalized to Si are in higher abundance in the H than in the L chondrites. The siderophile elements Ni, Co, and Fe show very good correlation within, as well as between, the two major ordinary chondrite groups. Twenty-four of the analyses are of Antarctic finds, while ten are samples of falls. Comparing the Antarctic data with the fall data reveals no evidence that any of the elements studied here have been mobilized by terrestrial weathering processes. Within the H and L chondrite groups there is little chemical variation, indicating that the source of these samples is remarkably homogeneous. Equilibrium condensate fractionation from a nebula of CI composition can result in the observed ordinary chondrite compositions. The fractionation of metal at about 1440 K (and 0.001 atm) into high and low iron groups, followed by a gas-solid fractionation at about 1380 K with the H group losing more solids than the L, will produce the observed H and L compositions and intragroup trends.

Fulton, C. R.↗

The Effects of Experimentally Induced Zircon Annealing on Melt Inclusion-Zircon Geochemistry: A Case Study of Archean Zircon From the Barberton Complex

Crystalline melt inclusions (MIs) in Archean zircons can potentially constrain the evolution of magmatic processes. However, to obtain a homogeneous glassy MI representative of the parent melt, devitrified MIs must be heated at temperatures above the liquidus. Although, it is well known that radiation damaged domains in MI-host zircon undergo temperature-time dependent annealing, the effects of annealing on zircon stable isotope and trace element compositions has received less attention. In this study, we heated multiple aliquots of low-magnetism zircons with relatively low levels of radiation damage (Deff<9.6x1014 α-events/mg) from a 3.304 Ga tonalite gneiss xenolith from the Barberton greenstone belt (sample B87-18; Kamo and Davis, 1994) in an internally-heated pressure vessel at 0.4GPa and 1000–1200°C. Zircons were imaged by SEM (CL, BSE) to determine the zoning patterns around the MIs. The radiation damage preserved in the heated and unheated zircons was determined by measuring broadening of the 3(SiO4) Raman stretching band of zircon (FWHM). Oxygen isotope ratios (δ18O), OH/O ratios, and trace and rare earth element (TREE) concentrations were measured in the zircons and MIs using SIMS. The FWHM and Raman shift of the zircon 3(SiO4) band show a systematic increase of zircon crystallinity with increasing experimental temperature. Despite increasing crystallinity, the 3(SiO4) FWHM is not correlated with δ18O(Zrn) values in the heated or unheated zircons, suggesting that δ18O was not altered by laboratory heating in these low initial radiation damage zircons. FWHM and OH/O are positively correlated in both heated and unheated zircons. The unheated zircons have the largest FWHM and OH/O (OH/OMAX=3.5×10-4) suggesting that H2O was lost during experimental heating due to the progressive annealing of radiation-damaged domains in the zircons. Zircon TREE concentrations and FWHM values are not correlated despite the presence of TREE altered domains in both the heated and unheated zircons. Our results demonstrate that pre-experimental zircon TREE concentrations and δ18O(Zrn) remain intact during laboratory heating of crystalline MIs in zircon, while secondary H2O hosted in radiation damaged domains is partially lost. Thus, MIs in low initial radiation damage Archean zircon are a potentially viable tool for constraining melt compositions.

Joseph P. Gonzalez↗

Compositional Analysis of Martian Soil: Synergism of APEX and MECA Experiments on MPS 2001

The APEX (ATHENA Precursor Experiment) payload for the Mars 2001 mission will analyze soil and dust with a multispectral panoramic imager and an emission spectrometer on a mast on the lander, a Moessbauer spectrometer on the lander robotic arm (RA), and APXS measurements on the Marie Curie rover. These analytical methods will provide data on elemental abundances and mineralogy. The MECA payload on the lander will apply microscopy, AFM, wet chemistry, adhesive substrates, and electrometry to determine the shape and size of particles in the soil and dust, the presence of toxic substances, and electrostatic, magnetic, and hardness qualities of particles. The two experiments will complement one another through several interactions: (1) The panoramic imager provides the geological setting in which both APEX and MECA samples are acquired, (2) The RA provides samples to MECA from the surface and subsurface and will permit APEX analytical tools access to materials below the inunediate surface, (3) Comparisons can be made between elemental analyses of the Moessbauer, IR, APXS on APEX and the wet chemistry of MECA which will define trace elements (ionic species in solution) and soil redox potential and conductivity. (4) APEX bulk compositional measurements will place MECA trace measurements in context, and similarly, MECA microscopy will provide particle size data that may correlate with compositional differences determined by the APEX instruments. Additionally, lithic fragments viewed by the NMCA microscope station should correlate with mineral/rock species inferred by APEX data, (5) If APEX instruments detect quartz for example, the scratch plates of the N4ECA microscope stage will define if a mineral of this hardness is registered during abrasion tests. This is by no means an exhaustive list of potential interactions, but it is clear that both the sheer number of analytical techniques and their complementarity should provide an analytically powerful capability for both planetary and BEDS communities.

Arvidson, R.↗

Compositional Analysis of Martian Soil: Synergism of APEX and MECA Experiments on MPS 2001

The APEX (ATHENA Precursor Experiment) payload for the Mars 2001 mission will analyze soil and dust with a multispectral panoramic imager and an emission spectrometer on a mast on the lander, a Moessbauer spectrometer on the lander robotic arm (RA), and APXS measurements on the Marie Curie rover. These analytical methods will provide data on elemental abundances and mineralogy. The MECA payload on the lander will apply microscopy, AFM, wet chemistry, adhesive substrates, and electrometry to determine the shape and size of particles in the soil and dust, the presence of toxic substances, and electrostatic, magnetic, and hardness qualities of particles. The two experiments will complement one another through several interactions: (1) The panoramic imager provides the geological setting in which both APEX and MECA samples are acquired, (2) The RA provides samples to MECA from the surface and subsurface and will permit APEX analytical tools access to materials below the immediate surface, (3) Comparisons can be made between elemental analyses of the Moessbauer, IR, APXS on APEX and the wet chemistry of MECA which will define trace elements (ionic species in solution) and soil redox potential and conductivity. (4) APEX bulk compositional measurements will place MECA trace measurements in context, and similarly, MECA microscopy will provide particle size data that may correlate with compositional differences determined by the APEX instruments. Additionally, lithic fragments viewed by the MECA microscope station should correlate with mineral/rock species inferred by APEX data, (5) If APEX instruments detect quartz for example, the scratch plates of the MECA microscope stage will define if a mineral of this hardness is registered during abrasion tests. This is by no means an exhaustive list of potential interactions, but it is clear that both the sheer number of analytical techniques and their complementarity should provide an analytically powerful capability for both planetary and HEDS communities.

Arvidson, R.↗

Air pollution source identification

The techniques available for source identification are reviewed: remote sensing, injected tracers, and pollutants themselves as tracers. The use of the large number of trace elements in the ambient airborne particulate matter as a practical means of identifying sources is discussed. Trace constituents are determined by sensitive, inexpensive, nondestructive, multielement analytical methods such as instrumental neutron activation and charged particle X-ray fluorescence. The application to a large data set of pairwise correlation, the more advanced pattern recognition-cluster analysis approach with and without training sets, enrichment factors, and pollutant concentration rose displays for each element is described. It is shown that elemental constituents are related to specific source types: earth crustal, automotive, metallurgical, and more specific industries. A field-ready source identification system based on time and wind direction resolved sampling is described.

Fordyce, J. S.↗

Chemical clocks: using otolith geochemistry to enhance estimation of age and growth of white hake (Urophycis tenuis)

The white hake (Urophycis tenuis) is a groundfish distributed throughout the Gulf of Maine. Catch advice is based on stock assessments done with age-based population dynamics models; however, otolith aging is challenging because of unclear growth increments. To address this concern, we compared the consistency of aging with counts of visual annuli to that of aging with cycles of elemental concentrations measured by using laser ablation inductively coupled plasma mass spectrometry. We tested the hypothesis that oscillations in both environmental conditions and internal physiology through time influence uptake of elements during otolith mineralization. Concentrations of manganese, in comparison with those of the other investigated trace elements (magnesium, strontium, and barium), had the most promising correlation with visual growth increments (~100% age agreement, ±1 year), offering an additional tool to enhance increment identification. In our examination of 550 otoliths collected during 2007–2021, we found that white hake lived a maximum of 10.3 years and exhibited sexual dimorphism in maximum length and age. By using generated von Bertalanffy growth functions, L(t)=110(1–e–0.113(t+0.45)) for males and L(t)=140(1–e–0.113(t–0.30)) for females (where L(t) is length at time t), size and age at maturity were calculated for males (37.4 cm in total length (TL), 3.3 years) and females (47.4 cm TL, 4.2 years). These results demonstrate that otolith geochemistry can be used to improve the accuracy and precision of the estimation of fish age and maturity, even for challenging species.

59 BASIC BIOLOGICAL SCIENCES↗

A Thorium-rich Mare Basalt Rock Fragment from the Apollo 12 Regolith: A Sample from a Young Procellarum Flow?

In this abstract, we report on the composition, mineralogy and petrography of a basaltic rock fragment, 12032,366-18, found in the Apollo 12 regolith. Age data, collected as part of an investigation by Barra et al., will be presented in detail in. Here, only the age dating result is summarized. This rock fragment garnered our attention because it is significantly enriched in incompatible elements, e.g., 7 ppm thorium, compared to other known lunar basalts. Its mineral- and trace-element chemistry set it apart from other Apollo 12 basalts and indeed from all Apollo and Luna basalts. What makes it potentially very significant is the possibility that it is a sample of a relatively young, thorium-rich basalt flow similar to those inferred to occur in the Procellarum region, especially northwestern Procellarum, on the basis of Lunar Prospector orbital data. Exploiting the lunar regolith for the diversity of rock types that have been delivered to a landing site by impact processes and correlating them to their likely site of origin using remote sensing will be an important part of future missions to the Moon. One such mission is Moonrise, which would collect regolith samples from the South Pole-Aitken Basin, concentrating thousands of rock fragments of 3-20 mm size from the regolith, and returning the samples to Earth.

Jolliff, B. L.↗

Inorganic chemical investigation by X-ray fluorescence analysis - The Viking Mars Lander

The inorganic chemical investigation experiment added in August 1972 to the Viking Lander scientific package uses an energy-dispersive X-ray fluorescence spectrometer in which four sealed, gas-filled proportional counters detect X-rays emitted from samples of the Martian surface materials irradiated by X-rays from radioisotope sources (Fe-55 and Cd-109). The instrument is inside the Lander body, and samples are to be delivered to it by the Viking Lander Surface Sampler. Instrument design is described along with details of the data processing and analysis procedures. The results of the investigation will characterize the surface materials of Mars as to elemental composition with accuracies ranging from a few tens of parts per million (at the trace-element level) to a few per cent (for major elements) depending on the element in question.

Toulmin, P., III↗

Bulk compositions of the moon and earth, estimated from meteorites

The present work calculates the bulk compositions of the earth and moon, based on the assumption that these planets formed by the same processes as chondrites. In terms of the model presented, the earth contains 9.2% early condensate and 1.5% carbonaceous, volatile-rich silicate. For the moon these percentages are 30.1 and 0.04, respectively. When lunar and terrestrial basalt data are normalized to these model compositions, element abundance patterns based on the percentages (assuming that each component carried its cosmic complement of trace elements) demonstrate the essential identity of igneous processes on both celestial bodies.

Ganapathy, R.↗

Extraction and Separation of Rare-Earth Elements from Coal Fly Ash and Leachate using a Recyclable Ionic Liquid

Coal fly ash (CFA) can be a promising source for recovering rare-earth elements (REEs), as it contains a broad range of REEs with average concentrations frequently exceeding those in traditional rare earth mines. Recent research from our group has demonstrated that REEs can be preferentially extracted from CFA solids using a recyclable ionic liquid (IL), betainium bis-(trifluoromethylsulfonyl)imide ([Hbet][Tf2N]). When CFA was heated with the mixture of IL and an aqueous solution above 65°C, most leached REEs partitioned into the IL phase and were separated from the bulk elements. Subsequent acid stripping of the REE-loaded IL removed the REEs and regenerated the IL for reuse in multiple extraction cycles. This IL-based REE-CFA recovery method has been applied to ten CFA samples derived from different coal sources, including ash recovered from disposal ponds. Analysis of 34 elements confirmed the process consistently achieved high REE recovery efficiency, with strong selectivity over bulk and trace elements across diverse CFA types. In addition to the IL-solid extraction, the performance of [Hbet][Tf2N] in extracting REEs from fly-ash leachates have been evaluated by four commonly used leaching reagents, including HCl, HNO3, H2SO4, and citrate. During the IL-leachate extraction, [Hbet][Tf2N] was mixed and heated with a Class C fly ash leachate generated from each leaching reagent, followed by an acid stripping. It was observed that the partitioning and recovery of REEs increased as the leachate pH increased from 3 to 11. Among the investigated leachates, HCl and citrate proved to be the most compatible with IL extraction, exhibiting a slightly higher REE recovery and a lower non-REE co-extraction compared to the IL-solid extraction. Sc, Y, Nd, Sm, Gd, Dy, and Yb consistently showed a high recovery rate from both CFA solids and leachates. Notably, Pr, Tb, and Ho, which were not previously leached from the CFA solids, were partially recovered from the leachates. Overall, our studies revealed the strong potential of [Hbet][Tf2N] for effectively recovering REEs from leachates, highlighting its applicability as a sustainable strategy for other aqueous REE feedstocks. Furthermore, a techno-economic analysis will be performed to quantify the economic viability of the IL-based REE recovery method and guide future process improvement.

42 ENGINEERING↗