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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Weak lensing of large scale structure in the presence of screening

A number of alternatives to general relativity exhibit gravitational screening in the non-linear regime of structure formation. We describe a set of algorithms that can produce weak lensing maps of large scale structure in such theories and can be used to generate mock surveys for cosmological analysis. By analysing a few basic statistics we indicate how these alternatives can be distinguished from general relativity with future weak lensing surveys.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Magnetothermal disc winds in X-ray binaries: poloidal magnetic fields suppress thermal winds

Magnetic, radiation pressure, and thermal driving are the three mechanisms capable of launching accretion disc winds. In X-ray binaries, radiation pressure is often not significant, as in many systems the luminosity is too low for driving due to continuum transitions yet too high for driving due to line transitions. This leaves thermal and magnetic driving as the contender launching mechanisms in these systems. Using ATHENA++, here we perform axisymmetric ideal MHD simulations that include radiative heating and cooling processes appropriate for Compton heated winds to show that the inclusion of magnetic fields into a thermally driven wind has the opposite effect of what one might expect: rather than provide a velocity boost, the thermal wind is suppressed in low-plasma beta regions where the field lines are strong enough to reshape the direction of the flow. Our analysis reveals that magneto-centrifugal launching is present but weak, while the reduction in wind velocity is not due to the change in gravitational potential through the magnetically imposed streamline geometry, but rather due to the increased flow tube area just above the surface of the disc, which is less conducive to acceleration. Finally, our results suggest that for magnetothermal wind models to be successful at producing fast dense outflows in low-mass X-ray binaries, the winds must be magnetically launched well within the Compton radius.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Electronic and topological properties of the van der Waals layered superconductor PtTe

We report the crystal growth and structural and electronic properties of superconducting, van der Waals layered PtTe. Easily cleavable crystals with a platelike morphology consistent with the layered structure were grown from a platinum-rich flux. A consistent determination of T c = 0.57 K is made from the onset of diamagnetism, the zero of resistivity, and the midpoint of the heat-capacity jump. The observed behavior is consistent with type-II superconductivity, with upper critical field at T = 0 estimated using the Werthamer-Helfand-Hohenberg theory to be 143 and 65 Oe for fields out of and in the plane, respectively. The heat-capacity discontinuity is close to the weak-coupling BCS value. Density-functional theory calculations and analysis of the electronic structure finds that PtTe is a topological semimetal with numerous surface states but suggests that the superconducting state itself may be topologically trivial. Additionally, angle-resolved photoemission spectroscopy reveals a normal-state Fermi surface in remarkable agreement with theory and confirms the overall topological nature of the material by experimental identification of the surface bands. Together, these findings identify PtTe as an interesting example of a cleavable, topological, and superconducting material.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Effect of Swelling on Irradiation-Assisted Stress Corrosion Cracking

A highly irradiated stainless steel 304 material irradiated to 27 dpa in the Experimental Breeder Reactor-II was used to investigate the relation between void swelling, grain boundary cohesion and intergranular crack growth rate under solicitation by irradiation assisted stress corrosion cracking. The material selected offered two different swelling amounts (about 2% and 3.7%) in the same material at high dose. The material had been irradiated at the same time, same condition, only the temperature gradient led to different swelling. This material, however, proved to be very resistant to irradiation assisted stress corrosion cracking under pressurized water reactor conditions. The crack growth rates measured were very low with the lowest being obtained with the material exhibiting the most amount of swelling. Micromechanical testing performed with the material exhibiting the higher crack propagation rate demonstrated that the irradiation damages (including void swelling) did not decrease grain boundary cohesion enough to make the grain boundaries the weak points under load solely. Crack path and crack tip analysis showed evidence of material modification ahead of the crack but it is not clear, at this point, if the changes observed were caused by the crack advance or if their presence in front of the crack was causing the low crack growth rate measured.

36 MATERIALS SCIENCE↗
DOE OSTI2016

RIEGER-TYPE PERIODICITY DURING SOLAR CYCLES 14–24: ESTIMATION OF DYNAMO MAGNETIC FIELD STRENGTH IN THE SOLAR INTERIOR

Solar activity undergoes a variation over timescales of several months known as Rieger-type periodicity, which usually occurs near maxima of sunspot cycles. An early analysis showed that the periodicity appears only in some cycles and is absent in other cycles. But the appearance/absence during different cycles has not been explained. We performed a wavelet analysis of sunspot data from the Greenwich Royal Observatory and the Royal Observatory of Belgium during cycles 14–24. We found that the Rieger-type periods occur in all cycles, but they are cycle dependent: shorter periods occur during stronger cycles. Our analysis revealed a periodicity of 185–195 days during the weak cycles 14–15 and 24 and a periodicity of 155–165 days during the stronger cycles 16–23. We derived the dispersion relation of the spherical harmonics of the magnetic Rossby waves in the presence of differential rotation and a toroidal magnetic field in the dynamo layer near the base of the convection zone. This showed that the harmonics of fast Rossby waves with m = 1 and n = 4, where m ( n ) indicates the toroidal (poloidal) wavenumbers, perfectly fit with the observed periodicity. The variation of the toroidal field strength from weaker to stronger cycles may lead to the different periods found in those cycles, which explains the observed enigmatic feature of the Rieger-type periodicity. Finally, we used the observed periodicity to estimate the dynamo field strength during cycles 14–24. Our estimations suggest a field strength of ∼40 kG for the stronger cycles and ∼20 kG for the weaker cycles.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1984

Accuracy of diagnostic heat and moisture budgets using SESAME-79 field data as revealed by observing system simulation experiments

Observing system simulation experiments are used to investigate the accuracy of diagnostic heat and moisture budgets which employ the AVE-SESAME 1979 data. The time-including, four-dimensional data set of a mesoscale model is used to simulate rawinsonde observations from AVE-SESAME 1979. The 5 C/day (heat budget) and 2 g/kg per day (moisture budget) magnitudes of error obtained indicate difficulties in the diagnosis of the heating rate in weak convective systems. The influences exerted by observational frequency, objective analysis, observational density, vertical interpolation, and observational errors on the budget are also studied, and it is found that the temporal and spatial resolution of the SESAME regional network is marginal for diagnosing convective effects on a horizontal time scale of 550 x 550 km.

Kuo, Y.-H.↗
NASA NTRS1996

Optimization Methodology for Unconventional Rocket Nozzle Design

Several current rocket engine concepts such as the bell-annular tripropellant engine, and the linear aerospike being proposed for the X-33, require unconventional three-dimensional rocket nozzles which must conform to rectangular or sector-shaped envelopes to meet integration constraints. These types of nozzles exist outside the current experience database, therefore, development of efficient design methods for these propulsion concepts is critical to the success of launch vehicle programs. Several approaches for optimizing rocket nozzles, including streamline tracing techniques, and the coupling of CFD analysis to optimization algorithms are described. The relative strengths and weaknesses of four classes of optimization algorithms are discussed: Gradient based methods, genetic algorithms, simplex methods, and surface response methods. Additionally, a streamline tracing technique, which provides a very computationally efficient means of defining a three-dimensional contour, is discussed. The performance of the various optimization methods on thrust optimization problems for tripropellant and aerospike concepts is assessed and recommendations are made for future development efforts.

Follett, W.↗
NASA NTRS1998

Re-Observing the First Hours of Supernova 1987A

This project was designed to use archival data from the International Ultraviolet Explorer (IUE) to measure the flux from the shock breakout from SN 1987A, emitted in the first few hours of the event, reflected from neighboring dust clouds in the form of a light echo. Such hot flux from the initial moments of a SN had never been observed before, and this offers a unique opportunity to measure it in reflection. Gilmozzi (1991, in "SN 1987A and Other Supernova") had reported such a detection of using IUE from observations made in 1988 and 1989. Our analysis of these data showed that this detection was very weak, and subject to changes comparable to the size of the signal according to various reasonable means of extracting the spectra. In fact, the features reported by Gilmozzi (1998 in "Ultraviolet Astrophysics Beyond IUE") are not found in a conventional NEWSIPS extraction or extended-source extraction of these data. The 1995 and 1996 IUE data collected for Crotts and Gilmozzi shows a more robust signal (about 20sigma,) from a cloud that echoes brighter in the optical than the 1988 feature. This shows a well-detected signal of about 5 x 10(exp -16) ergs per s/sq cm/Angstroms/arc sq sec at 1300 Angstroms, with a declining slope to redder wavelengths. This surface brightness, while detected with confidence in both large and small SVVT apertures, is still fainter than the reflected flux expected for most models of shock breakout. We have also taken the opportunity to recover the echo signal from exposures taken on Astro-1 and Astro-2 flights of the Ultraviolet Imaging Telescope (UIT) while pointed towards SN 1987A. These data yield a complementary result on the reflected flux, an upper limit of about 5 x 10(exp -17) ergs per s/sq cm/Angstroms/arc sq sec, spread over fainter optically echoing clouds, and over the same band where the signal was detected by IUE. While this appears in contradiction with the IUE result, it is made consistent by the corresponding strengths of the echoes in the optical.

Crotts, Arlin P. S.↗
NASA NTRS2015

Growth of InSb and InI Crystals on Earth and in Microgravity

During the past 40 years, dozens of semiconductor crystal growth experiments have been conducted in space laboratories. The subsequent analysis of the space-grown crystals revealed (i) that weak convection existed in virtually all melt-growth experiments, (ii) de-wetting significantly reduced the level of stress-induced defects, and (iii) particularly encouraging results were obtained in vapor-growth experiments. In 2002, following a decade of ground based research in growing doped Ge and GaSb crystals, a series of crystal growth experiments was performed at the ISS, within the SUBSA (Solidification Using a Baffle in Sealed Ampoules) investigation. Te- and Zn-doped InSb crystals were grown from the melt. The specially designed furnace provided a side-view of the melt and precise seeding measurement of the growth rate. At present, under sponsorship of CASIS (Center for the Advancement of Science in Space, www.iss-casis.org), we are conducting ground-based experiments with indium mono-iodide (InI) in preparation for the "SUBSA II" ISS investigation, planned for 2017. The experiments include: i) Horizontal Bridgman (HB) growth and ii) Vapor Transport (VT) growth. Finite element modeling will also be conducted, to optimize the design of the flight ampoules, for vapor and melt growth.

Ostrogorsky, A. G.↗
DOE OSTI2016

Investigating shape evolution and the emergence of collectivity through the synergy of Coulomb excitation and beta decay

The synthesis of Coulomb excitation and decay offers very practical advantages in the study of nuclear shapes and collectivity. For instance, Coulomb excitation is unique in its ability to measure the electric quadrupole moments, i.e., I2 ||M(E2)||I1 matrix elements, of excited, non-isomeric states in atomic nuclei, providing information on the intrinsic shape. However, the Coulomb excitation analysis and structural inter- pretation can be strongly dependent upon weak transitions or decay branches, which are often obscured by the Compton background. Transitions of particular interest are those low in energy and weak in intensity due to the E 5 attenuation factor. These weak decay branches can often be determined with high precision from -decay studies. Recently, 106Mo and 110Cd were studied by both Coulomb excitation and decay. Preliminary results of new weak decay branches following decay of 110mAg to 110Cd are presented; these results will challenge competing interpretations based on vibrations and configuration mixing.

Allmond, James M↗
DOE OSTI2014

Molecular Electronic Level Alignment at Weakly Coupled Organic Film/Metal Interfaces

Electronic level alignment at interfaces of molecular materials with inorganic semiconductors and metals controls many interfacial phenomena. How the intrinsic properties of the interacting systems define the electronic structure of their interface remains one of the most important problems in molecular electronics and nanotechnology that can be solved through a combination of surface science experimental techniques and theoretical modeling. In this article, we address this fundamental problem through experimental and computational studies of molecular electronic level alignment of thin films of C6F6 on noble metal surfaces. The unoccupied electronic structure of C6F6 is characterized with single molecule resolution using low-temperature scanning tunneling microscopy-based constant-current distance-voltage spectroscopy. The experiments are performed on several noble metal surfaces with different work functions and distinct surface-normal projected band structures. In parallel, the electronic structures of the quantum wells (QWs) formed by the lowest unoccupied molecular orbital state of the C6F6 monolayer and multilayer films and their alignment with respect to the vacuum level of the metallic substrates are calculated by solving the Schrödinger equation for a semiempirical one-dimensional (1D) potential of the combined system using input from density functional theory. Our analysis shows that the level alignment for C6F6 molecules bound through weak van der Waals interactions to noble metal surfaces is primarily defined by the image potential of metal, the electron affinity of the molecule, and the molecule surface distance. We expect the same factors to determine the interfacial electronic structure for a broad range of molecule/metal interfaces.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2018

Increasing the Separation Capacity of Intact Histone Proteoforms Chromatography Coupling Online Weak Cation Exchange-HILIC to Reversed Phase LC UVPD-HRMS

Top-down proteomics is an emerging analytical strategy to characterize combinatorial protein post-translational modifications (PTMs). However, sample complexity and small mass differences between chemically closely related proteoforms often limit the resolution attainable by separations employing a single liquid chromatographic (LC) principle. In particular, for ultra-modified proteins like histones, extensive and time-consuming fractionation is needed to achieve deep proteoform coverage. Herein, we present the first online nano-flow comprehensive two-dimensional liquid chromatography (nLC×LC) platform top-down mass spectrometry analysis of histone proteoforms. The described two-dimensional LC system combines weak cation exchange chromatography under hydrophilic interaction LC conditions (i.e. charge- and hydrophilicity-based separation) with reversed phase liquid chromatography (i.e. hydrophobicity-based separation). The two independent chemical selectivities were run at nanoflows (300 nL/min) and coupled online with high-resolution mass spectrometry employing ultraviolet photodissociation (UVPD-HRMS). The nLC×LC workflow increased the number of intact protein masses observable relative to one-dimensional approaches and allowed characterization of hundreds of proteforms starting from limited sample quantities (~1.5 µg).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

The significance of structural power in Strategic Environmental Assessment

This article presents a study of how power dynamics enables and constrains the influence of actors upon decision-making and Strategic Environmental Assessment (SEA). Based on structuration theory, a model for studying power dynamics in strategic decision-making processes is developed. The model is used to map and analyse key decision arenas in the decision process of aluminium production in Greenland. The analysis shows that communication lines are an important resource through which actors exercise power and influence decision-making on the location of the aluminium production. The SEA process involved not only reproduction of formal communication and decision competence but also production of alternative informal communication structures in which the SEA had capability to influence. It is concluded, that actors influence strategic decision making, and attention needs to be on not only the formal interactions between SEA process and strategic decision-making process but also on informal interaction and communication between actors as the informal structures, which can be crucial to the outcome of the decision-making process. This article is meant as a supplement to the understanding of power dynamics influence in IA processes and as a contribution to the IA research field with a method to analyse power dynamics in strategic decision-making processes. The article also brings reflections of strengths and weaknesses of using the structuration theory as an approach to power analysis. - Highlights: Black-Right-Pointing-Pointer Informal interaction influenced process despite the presence of formalised rules. Black-Right-Pointing-Pointer Interdependence of actors influenced SEA effectiveness. Black-Right-Pointing-Pointer SEA practitioners successfully exercised power to influence decision-making. Black-Right-Pointing-Pointer Power dynamics are properties of actors' interactions in decision-making. Black-Right-Pointing-Pointer Power structures can be enabling and not solely limiting.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Public participation in and learning through SEA in Kenya

Meaningful public engagement is a challenging, but promising, feature of strategic environmental assessment (SEA) due to its potential for integrating sustainability principles into policies, plans and programs in developing countries such as Kenya. This research examined two selected SEA case studies to identify the extent of participation, learning outcomes attributable to participation, and if any learning outcomes led to social action for sustainability at the community level. Strengths across the two cases were the inclusion of marginalized populations and consideration of socio-economic concerns. Consistent weaknesses included inadequate notice, document inaccessibility, lack of feedback and communication, and late analysis of alternatives. Despite some learning conditions being unfulfilled, examples of instrumental, communicative, and transformative learning were identified through a focus group and semi-structured interviews with community participants and public officials. Some of these learning outcomes led to individual and social actions that contribute to sustainability. -- Highlights: • The strengths and weaknesses of Kenyan SEA public participation processes were identified. • Multiple deficiencies in the SEA process likely frustrate meaningful public engagement. • Participant learning was observed despite process weaknesses. • Participant learning can lead to action for sustainability at the community level.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Efficient Clustering of Software Vulnerabilities using Self Organizing Map (SOM)

The common vulnerabilities and exposures (CVE) database was created with a mission to ``identify, define, and catalog publicly disclosed cybersecurity vulnerabilities''. This rich body of information can be used to enable rapid and efficient response to secure and defend cyber operations and protect critical cyber infrastructure. The main goal of this paper is to develop a visual analytics tool to enable deep analysis of CVEs using unsupervised clustering techniques. We enhance our analysis by first mapping CVEs to hierarchical-classes in Common Weakness Enumeration (CWE) using information in the National Vulnerability Database (NVD). Both the mapping and the numerical representation of CVEs are enabled by V2W-BERT, which uses natural language processing of the extensive information in NVD to generate a large tabular database of 137,226 CVE entries from 1999 to 2020, where each CVE is represented by a vector of 768 numerical features. The vectorized data is processed by Self-Organizing Maps (SOM), which is an unsupervised machine learning technique for dimensionality reduction, visual representation and clustering. Using a Torus map of 6417 units, we achieve ~10-fold data compression of ~140k CVEs using SOM. The trained map is further clustered using standard K-means clustering into 138 clusters of CVEs. We conducted a brief investigation of the rich mapping of CVEs to best-matching-units to K-means clusters, as well as CVEs to CWEs. For example, this novel mapping provided insight into the role of CWE-59 and CWE-264 in several CVEs that is otherwise hard to explore in the original data. We conclude that our this novel approach will not only enable deep analysis of the complex relationships between CVEs and CWEs, but also a mechanism to quickly respond to and design mitigation actions for rapidly evolving vulnerabilities that have not been mapped to existing CWEs.

Panchal, Khyati↗
DOE OSTI2024

Cosmological Constraints from Combining Photometric Galaxy Surveys and Gravitational Wave Observatories

Spatial variations in survey properties due to selection effects generate substantial systematic errors in large-scale structure measurements in optical galaxy surveys on very large scales. On such scales, the statistical sensitivity of optical surveys is also limited by their finite sky coverage. By contrast, gravitational wave (GW) sources appear to be relatively free of these issues, provided the angular sensitivity of GW experiments can be accurately characterized. We quantify the expected cosmological information gain from combining the forecast LSST 3$\times$2pt analysis (combination of three 2-point correlations of galaxy density and weak lensing shear fields) with the large-scale auto-correlation of GW sources from proposed next-generation GW experiments. We find that in $\Lambda$CDM and $w$CDM models, there is no significant improvement in cosmological constraints from combining GW with LSST 3$\times$2pt over LSST alone, due to the large shot noise for the former; however, this combination does enable a $\sim6\%$ constraint on the linear galaxy bias of GW sources. More interestingly, the optical-GW data combination provides tight constraints on models with primordial non-Gaussianity (PNG), due to the predicted scale-dependent bias in PNG models on large scales. Assuming that the largest angular scales that LSST will probe are comparable to those in Stage III surveys ($\ell_{\rm min}\sim50$), the inclusion of next-generation GW measurements could improve constraints on the PNG parameter $f_{\rm NL}$ by up to a factor of $\simeq6.6$ compared to LSST alone, yielding $\sigma(f_{\rm NL})=8.5$. These results assume the expected capability of a network of Einstein Telescope-like GW observatories, with a detection rate of $10^6$ events/year. We investigate the sensitivity of our results to different assumptions about future GW detectors as well as different LSST analysis choices.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Modelling single atom catalysts for water splitting and fuel cells: A tutorial review

Here, in this tutorial review, we report the state-of-the-art of the modeling approaches of Single Atom Catalysts (SAC) for water splitting and fuel cells reactions. The discussion applies for Hydrogen Evolution Reaction (HER), Oxygen Reduction Reaction (OER), Hydrogen Oxidation Reaction (HOR), and Oxygen Reduction Reaction (ORR). The main scope of this work is to underline the relevant aspects of SACs modelling. On the one hand, the review could help computational chemists aiming to start the study of SACs. On the other hand, experimentalists could find the critical analysis of DFT results of interest to understand better the strengths and weaknesses of simulations, and how to interpret computational results. After an introductory section of SACs, we start by briefly presenting the state-of-the-art methodologies. Then, we analyze the critical aspects for a reliable prediction of the electronic properties, and we discuss the robustness of the structural models and ways to validate them. Furthermore, we discuss the main approaches to predict catalytic activity and selectivity, which is the final goal of the computational catalysis. We conclude this review with a critical analysis of the current challenges in the field, and the main limitations of the modeling approaches that are described.

25 ENERGY STORAGE↗
DOE OSTI2021

Evidence Theory Representations for Properties Associated With Weak Link/Strong Link Systems, Part 3: Margins for Failure Time and Failure Temperature

The use of evidence theory and associated cumulative plausibility functions (CPFs), cumulative belief functions (CBFs), cumulative distribution functions (CDFs), complementary cumulative plausibility functions (CCPFs), complementary cumulative belief functions (CCBFs), and complementary cumulative distribution functions (CCDFs) in the analysis of time and temperature margins associated with loss of assured safety (LOAS) for one weak link (WL)/two strong link (SL) systems is illustrated. Article content includes cumulative and complementary cumulative belief, plausibility, and probability for (i) SL/WL failure time margins defined by (time at which SL failure potentially causes LOAS) – (time at which WL failure potentially prevents LOAS), (ii) SL/WL failure temperature margins defined by (the temperature at which SL failure potentially causes LOAS) – (the temperature at which WL failure potentially prevents LOAS), and (iii) SL/SL failure temperature margins defined by (the temperature at which SL failure potentially causes LOAS) – (the temperature of SL whose failure potentially causes LOAS at the time at which WL failure potentially prevents LOAS).

42 ENGINEERING↗