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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35

Introduction to a series of LiNi 0.8 Co 0.2 O 2 -based high-power lithium-ion battery positive electrodes analyzed by x-ray photoelectron spectroscopy

High-power lithium-ion batteries are rapidly replacing the nickel metal hydride batteries currently used for energy storage in hybrid electric vehicles. Widespread commercialization of these batteries for vehicular applications is, however, limited by calendar-life performance, thermal abuse characteristics, and cost. The Advanced Technology Development Program was established by the U.S. Department of Energy to address these limitations. An important objective of this program was the development and application of diagnostic tools that provide unique ways to investigate the phenomena that limit lithium-ion cell life, performance, and safety characteristics. This report introduces a set of six Surface Science Spectra xray photoelectron spectroscopy (XPS) comparison records of data collected from positive electrodes (cathode) harvested from cylindrically wound, 18650-type, 1 A h capacity cells. The cathodes included in this study are (1) fresh, (2) following three formation cycles, (3) following calendar-life test for 12 weeks at 40 C, 60% state-of-charge (SOC), (4) following calendar-life test for 8 weeks at 50 C, 60% SOC, (5) following calendar-life test for 8 weeks at 60 C, 60% SOC, and (6) following calendar-life test for 2 weeks at 70 C, 60% SOC.

XPS↗

The Value of Resilience for Distributed Energy Resources: An Overview of Current Analytical Practices

Recent extreme weather events, natural disasters, and cyber incursions have brought the vulnerability of the electric system into sharp focus. These events have demonstrated that planning for long-duration power interruptions caused by high-impact, low-probability events will require new approaches to power system resilience above and beyond previous hardening efforts. At the same time, the rapid growth and declining costs of distributed energy resources (DERs) such as microgrids, solar photovoltaics, and batteries have introduced new technology options for energy resilience. Consequently, state policymakers across the country have established electricity resilience policies and programs, with several states focusing specifically on resilient DERs as part of clean energy programs and grid modernization efforts. Although it is clear that DERs offer resilience benefits, it is unclear how to determine the value of those benefits. Identifying appropriate methodologies to calculate the value of resilience will be an important step toward ensuring that resilient DERs are considered alongside alternatives and integrated into future energy infrastructure and investment planning efforts. This paper reviews current practices for calculating the value of resilience with a focus on valuing resilient DERs installed within the distribution system. It examines both regulatory decision-making and non-regulatory cost-benefit analyses in order to determine if, and how, a value of resilience was calculated and applied. The paper is designed to address questions that utility regulators have identified as being of interest: (1) Have regulators identified and utilized a value of resilience in regulatory decisions related to resilient DERs? (2) Is the value of resilience being used to analyze resilient DERs in venues other than regulatory proceedings? (3) What are the different methods to value energy resilience? (4) What are the pros and cons of different methods used to value resilience? (5) Can regulators adopt or improve value of resilience methods to support their decisions?

14 SOLAR ENERGY↗

Solar and chemical power systems.

Dynamic conversion of solar and chemical energy, discussing power conditioning, Brayton-cycle system with inert gas and spacecraft batteries

SOLAR ENERGY THERMIONIC /SET/ PROGRAM↗

Non-gassing nickel-cadmium battery electrodes and cells: Testing of 25 Ah cells

The testing of 30 practical size, experimental 25 ampere hour cells constructed as part of an earlier negative limited cell development program is discussed. The test results showed that the negative limited cell is a possible means of developing a long-lived secondary cell. The cells were tested for 500 cycles using an accelerated regime approximating a 90-minute orbit period. Three groups of ten cells were tested at 0,25, and 40 C. The cycle data showed that the negative limited cells had higher degradation rates at the higher operating temperatures. At the conclusion of 500 cycles, the three groups had average capacities of 16.83, 12.74, and 5.71 ampere hours for testing at 0, 25, 40 C, respectively. The conditioning capacities of these cells was in the 25 ampere hours range. The internal cell pressures of the three groups was also temperature dependent and was, in general, in the 2 psig range during the course of the test program. No periodic variation of the internal pressure with the state-of-charge was observed except with some cells tested at 40 C.

Luksha, E.↗

Development of a simple, self-contained flight test data acquisition system

The system concepts and the flight test program results for a NASA designed in-flight data acquisition system are described. The system draws power from a rechargeable battery pack and intrudes on the aircraft systems only with a total pressure probe, a static pressure probe, and control position transducers, which are simply taped to the frame. A 4000 byte microcomputer forms the heart of the data recording system for cassette tape storage, and is expansion coupled to an eight-bit interactive microcomputer which interfaces with a transducer package for 16-channel demultiplexing. The transducers, ranges, and accuracies are listed, and a five/sec data acquisition rate minimum requirement is noted, although a 10/sec rate is used. The system components are detailed, along with the control and data processing procedures, and the results of dynamic flight testing are presented.

Renz, R. R. L.↗

An L$_0$L$_1$-norm compressive sensing paradigm for the construction of sparse predictive lattice models using mixed integer quadratic programming

First-principles based lattice models allow the modeling of ab initio thermodynamics of crystalline mixtures for applications such as the construction of phase diagrams and the identification of ground state atomic orderings. The recent development of compressive sensing approaches for the construction of lattice models has further enabled the systematic construction of sparse physical models without the need for human intuition other than requiring the compactness of effective cluster interactions. However, conventional compressive sensing based on L1-norm regularization is strictly only applicable to certain classes of optimization problems and is otherwise not guaranteed to generate optimally sparse and transferable results, so that the method can only be applied to some materials science applications. In this paper, we illustrate a more robust L0L1-norm compressive-sensing method that removes the limitations of conventional compressive sensing and generally results in sparser lattice models that are at least as predictive as those obtained from L1-norm compressive sensing. Apart from the theory, a practical implementation based on state-of-the-art mixed-integer quadratic programming (MIQP) is proposed. The robustness of our methodology is illustrated for four different transition-metal oxides with relevance as battery cathode materials: Li2xTi2(1-x)O2, Li2xNi2yO2, MgxCr2O4, and NaxCrO2. This method provides a practical and robust approach for the construction of sparser and more predictive lattice models, improving on the compressive sensing paradigm and making it applicable to a much broader range of applications.

Huang, W↗

A New Generation High Density Thermal Battery Based on Advanced Metal Hydride

In a world that is facing an energy crisis and environmental pollution, the development of an electric vehicle (EV) as zero-emission, energy-efficiency mode of transportation has taken on an accelerated pace. Most of major automotive manufacturers have launched aggressive programs to develop new-generation EVs, and some economical EVs have been commercialized. Moreover, market forecasting has suggested that Hybrid Electric Vehicles (HEVs), Plug-in Hybrid Electric Vehicles (PHEVs), and Electric Vehicles (EV), will be a growing component of the US vehicle fleets in the near future. By supplying power to EV, a rechargeable electric battery is one of the most crucial components in EV. However, the capacity and cost of an electric battery represent the highest barriers to wide scale adoption of electric vehicles as the large and expensive batteries needed to provide significant driving range can result in unattractive vehicle design and price points. In addition to the electric energy that has been used in powertrain, a key drain on the electrical battery system of an EV is needed to serve cabin heating and cooling loads. Cabin climate conditioning can significantly reduce the electric range of plug-in and full electric vehicles, by as much as 40% in extreme cases, or inversely and can increase the battery size and cost by a comparable amount for the same range. Therefore, significant reduction in the size/cost of EV batteries or a significant increase in driving range can be enabled by eliminating the need for cabin climate load to draw on the electrical battery system. The work of this project focused on a concept that employs metal hydride materials and chloride-ammonia as energy storage materials to build a new generation thermal battery with sufficient energy density to meet the above requirements. The high-energy density of metal hydride material makes the thermal battery meet the requirements of HVAC system for EB automobiles. The present research focused on a specific on-board application to develop a novel HVAC system for EV. However, the methodology of the thermal battery could be extended to a much broader range of applications, including other transportation vehicles such as long haul trucks, stationary HVAC, solar thermal energy storage systems, and waste heat recovery and storage systems. Multiple prototypes were designed, fabricated, and tested. The results successfully demonstrate the principles of the thermal battery using advanced metal hydrides. The performance of the concept-demonstration-unit showed both high heating/cooling power and high energy densities. Although the feasibility of the “Thermal Battery” has been demonstrated by this project, the commercial applications of this technology remain challenging. Either the volumetric or the gravimetric energy density of the materials used often cannot be both met. The solution to this problem is to work with vehicle HAVC designers to identify design innovations that can take advantages of the thermal battery without compromising the performance of the vehicles.

25 ENERGY STORAGE↗

County Connection Battery Electric Bus Demonstration: Preliminary Project Results

The U.S. Federal Transit Administration (FTA) funds a variety of research projects that support the commercialization of zero-emission bus technology. To evaluate projects funded through these programs, FTA has enlisted the help of the National Renewable Energy Laboratory (NREL) to conduct third-party evaluations of the technologies deployed under the FTA programs. NREL works with the selected agencies to evaluate the performance of the zero-emission buses compared to baseline conventional buses in similar service. The evaluation effort will advance the knowledge base of zero-emission technologies in transit bus applications and provide 'lessons learned' to aid other fleets in incrementally introducing next generation zero-emission buses into their operations. This report provides preliminary performance evaluation results from a demonstration of four all-electric trolley-replica buses and two electric vehicle charging stations at County Connection in the San Francisco Bay Area. NREL developed this preliminary results report to quickly disseminate evaluation results to stakeholders. Detailed evaluation results will be published in future reports.

25 ENERGY STORAGE↗

ARPA-E Program: Advanced Management Protection of Energy Storage Devices (AMPED) - Fifth Quarterly Project Report - FY14 Q1

Technology has been developed that enables monitoring of individual cells in high - capacity lithium-ion battery packs, with a distributed array of wireless Bluetooth 4.0 tags and sensors, and without proliferation of extensive wiring harnesses. Given the safety challenges facing lithium-ion batteries in electric vehicle, civilian aviation and defense applications, these wireless sensors may be particularly important to these emerging markets. These wireless sensors will enhance the performance, reliability and safety of such energy storage systems. Specific accomplishments to date include, but are not limited to: (1) the development of wireless tags using Bluetooth 4.0 standard to monitor a large array of sensors in battery pack; (2) sensor suites enabling the simultaneous monitoring of cell voltage, cell current, cell temperature, and package strain, indicative of swelling and increased internal pressure, (3) small receivers compatible with USB ports on portable computers; (4) software drivers and logging software; (5) a 7S2P battery simulator, enabling the safe development of wireless BMS hardware in the laboratory; (6) demonstrated data transmission out of metal enclosures, including battery box, with small variable aperture opening; (7) test data demonstrating the accurate and reliable operation of sensors, with transmission of terminal voltage, cell temperature and package strain at distances up to 110 feet; (8) quantification of the data transmission error as a function of distance, in both indoor and outdoor operation; (9) electromagnetic interference testing during operation with live, high -capacity battery management system at Yardney Technical Products; (10) demonstrat ed operation with live high-capacity lithium-ion battery pack during charge-discharge cycling; (11) development of special polymer-gel lithium-ion batteries with embedded temperature sensors, capable of measuring the core temperature of individual of the cells during charge-discharge cycling at various temperatures, thereby enabling earlier warning of thermal runaway than possible with external sensors. Ultimately, the team plans to extend this work to include: (12) flexible wireless controllers, also using Bluetooth 4.0 standard, essential for balancing large-scale battery packs. LLNL received $925K for this project, and has $191K remaining after accomplishing these objectives.

25 ENERGY STORAGE↗

Capacity Optimization of a Centralized Charging Station in Joint Operation with a Wind Farm

In the context of large-scale wind power integration and rapid development of electric vehicles (EVs), a joint operation pattern was proposed to use a centralized charging station (CCS) to address high uncertainties incurred by wind power integration. Additionally, this would directly remove the significant indeterminacy of wind power. Because the CCS is adjacent to a wind power gathering station, it could work jointly with wind farms to operate in power system as an independent enterprise. By combining the actual operational characteristics of the wind farm and the CCS, a multidimensional operating index evaluation system was created for the joint system. Based on the wind farm’s known capacity, a multi-target capacity planning model was established for CCS to maximize the probability of realizing diverse indices of the system based on dependent-chance goal programming. In this model, planning and dispatching are combined to improve the feasibility of results in the operational stage. This approach takes the effects of randomness into account for wind power and battery swapping. The model was solved through combining Monte Carlo simulation and a genetic algorithm (GA) based on segmented encoding. Finally, as shown in the simulation results, the proposed model could comprehensively include factors such as initial investment, wind power price, battery life, etc., to optimize CCS capacity and to ultimately improve the operating indices of the joint system.

17 WIND ENERGY↗

An underground, wireless, open-source, low-cost system for monitoring oxygen, temperature, and soil moisture

Abstract. The use of wireless sensor networks to measure soil parameters eliminates the need to remove sensors for field operations, such as tillage, thus allowing long-term measurements without multiple disturbances to soil structure. Wireless sensors also reduce above-ground cables and the risk of undesired equipment damage and potential data loss. However, implementing wireless sensor networks in field studies usually requires advanced and costly engineering knowledge. This study presents a new underground, wireless, open-source, low-cost system for monitoring soil oxygen, temperature, and soil moisture. The process of system design, assembly, programming, deployment, and power management is presented. The system can be left underground for several years without the need to change the battery. Emphasis was given on modularity so that it can be easily duplicated or changed if needed and deployed without previous engineering knowledge. Data from this type of system have a wide range of applications, including precision agriculture and high-resolution modelling.

54 ENVIRONMENTAL SCIENCES↗

Time-Dependent Material Data Essential for the Durability Analysis of Composite Flywheels Provided by Compressive Experiments

Successful spaceflight operations require onboard power management systems that reliably achieve mission objectives for a minimal launch weight. Because of their high specific energies and potential for reduced maintenance and logistics, composite flywheels are an attractive alternative to electrochemical batteries. The Rotor Durability Team, which comprises members from the Ohio Aerospace Institute (OAI) and the NASA Glenn Research Center, completed a program of elevated temperature testing at Glenn' s Life Prediction Branch's Fatigue Laboratory. The experiments provided unique design data essential to the safety and durability of flywheel energy storage systems for the International Space Station and other manned spaceflight applications. Analysis of the experimental data (ref. 1) demonstrated that the compressive stress relaxation of composite flywheel rotor material is significantly greater than the commonly available tensile stress relaxation data. Durability analysis of compression preloaded flywheel rotors is required for accurate safe-life predictions for use in the International Space Station.

Thesken, John C.↗

Continuous Improvement in Battery Testing at the NASA/JSC Energy System Test Area

The Energy Systems Test Area (ESTA) at the Lyndon B. Johnson Space Center in Houston, Texas conducts development and qualification tests to fulfill Energy System Division responsibilities relevant to ASA programs and projects. EST A has historically called upon a variety of fluid, mechanical, electrical, environmental, and data system capabilities spread amongst five full-service facilities to test human and human supported spacecraft in the areas of propulsion systems, fluid systems, pyrotechnics, power generation, and power distribution and control systems. Improvements at ESTA are being made in full earnest of offering NASA project offices an option to choose a thorough test regime that is balanced with cost and schedule constraints. In order to continue testing of enabling power-related technologies utilized by the Energy System Division, an especially proactive effort has been made to increase the cost effectiveness and schedule responsiveness for battery testing. This paper describes the continuous improvement in battery testing at the Energy Systems Test Area being made through consolidation, streamlining, and standardization.

Boyd, William↗

An Overview of the Automated Dispatch Controller Algorithms in the System Advisor Model (SAM)

Three automatic dispatch modes have been added to the battery model within the System Adviser Model. These controllers have been developed to perform peak shaving in an automated fashion, providing users with a way to see the benefit of reduced demand charges without manually programming a complicated dispatch control. A flexible input option allows more advanced interaction with the automated controller. This document will describe the algorithms in detail and present brief results on its use and limitations.

25 ENERGY STORAGE↗