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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

In-situ integrated processing and characterization of thin films of high temperature superconductors, dielectrics and semiconductors by MOCVD

In this strategy of depositing the basic building blocks of superconductors, semiconductors, and dielectrics having common elements, researchers deposited superconducting films of Y-Ba-Cu-O, semiconductor films of Cu2O, and dielectric films of BaF2 and Y2O3 by metal oxide chemical vapor deposition (MOCVD). By switching source materials entering the chamber, and by using direct writing capability, complex device structures like three terminal hybrid semiconductor/superconductor transistors can be fabricated. The Y-Ba-Cu-O superconducting thin films on BaF2/YSZ substrates show a T(sub c) of 80 K and are textured with most of the grains having their c-axis or a-axis perpendicular to the substrate. Electrical characteristics as well as structural characteristics of superconductors and related materials obtained by x-ray deffraction, electron microscopy, and energy dispersive x-ray analysis are discussed.

Singh, R.↗
NASA NTRS2014

The Geology of the Marcia Quadrangle of Asteroid Vesta: Assessing the Effects of Large, Young Craters

We used Dawn spacecraft data to identify and delineate geological units and landforms in the Marcia quadrangle of Vesta as a means to assess the role of the large, relatively young impact craters Marcia (approximately 63 kilometers diameter) and Calpurnia (approximately 53 kilometers diameter) and their surrounding ejecta field on the local geology. We also investigated a local topographic high with a dark-rayed crater named Aricia Tholus, and the impact crater Octavia that is surrounded by a distinctive diffuse mantle. Crater counts and stratigraphic relations suggest that Marcia is the youngest large crater on Vesta, in which a putative impact melt on the crater floor ranges in age between approximately 40 and 60 million years (depending upon choice of chronology system), and Marcia's ejecta blanket ranges in age between approximately 120 and 390 million years (depending upon choice of chronology system). We interpret the geologic units in and around Marcia crater to mark a major Vestan time-stratigraphic event, and that the Marcia Formation is one of the geologically youngest formations on Vesta. Marcia crater reveals pristine bright and dark material in its walls and smooth and pitted terrains on its floor. The smooth unit we interpret as evidence of flow of impact melts and (for the pitted terrain) release of volatiles during or after the impact process. The distinctive dark ejecta surrounding craters Marcia and Calpurnia is enriched in OH- or H-bearing phases and has a variable morphology, suggestive of a complex mixture of impact ejecta and impact melts including dark materials possibly derived from carbonaceous chondrite-rich material. Aricia Tholus, which was originally interpreted as a putative Vestan volcanic edifice based on lower resolution observations, appears to be a fragment of an ancient impact basin rim topped by a dark-rayed impact crater. Octavia crater has a cratering model formation age of approximately 280-990 million years based on counts of its ejecta field (depending upon choice of chronology system), and its ejecta field is the second oldest unit in this quadrangle. The relatively young craters and their related ejecta materials in this quadrangle are in stark contrast to the surrounding heavily cratered units that are related to the billion years old or older Rheasilvia and Veneneia impact basins and Vesta's ancient crust preserved on Vestalia Terra.

Asteroid Vesta↗
NASA NTRS1990

In-situ integrated processing and characterization of thin films of high temperature superconductors, dielectrics and semiconductors by MOCVD

In this strategy of depositing the basic building blocks of superconductors, semiconductors, and dielectric having common elements, researchers deposited superconducting films of Y-Ba-Cu-O, semiconductor films of Cu2O, and dielectric films of BaF2 and Y2O3 by metal oxide chemical vapor deposition (MOCVD). By switching source materials entering the chamber, and by using direct writting capability, complex device structures like three-terminal hybrid semiconductors/superconductors transistors can be fabricated. The Y-Ba-Cu-O superconducting thin films on BaF2/YSZ substrates show a T(sub c) of 80 K and are textured with most of the grains having their c-axis or a-axis perpendicular to the substrate. Electrical characteristics as well as structural characteristics of superconductors and related materials obtained by x-ray defraction, electron microscopy, and energy dispersive x-ray analysis are discussed.

Singh, R.↗
NASA NTRS2007

Quantum Approximate Methods for the Atomistic Modeling of Multicomponent Alloys

This chapter describes the role of quantum approximate methods in the understanding of complex multicomponent alloys at the atomic level. The need to accelerate materials design programs based on economical and efficient modeling techniques provides the framework for the introduction of approximations and simplifications in otherwise rigorous theoretical schemes. As a promising example of the role that such approximate methods might have in the development of complex systems, the BFS method for alloys is presented and applied to Ru-rich Ni-base superalloys and also to the NiAI(Ti,Cu) system, highlighting the benefits that can be obtained from introducing simple modeling techniques to the investigation of such complex systems.

Bozzolo, Guillermo↗
NASA NTRS1987

Dynamic response of a viscoelastic Timoshenko beam

The analysis presented in this study deals with the vibratory response of viscoelastic Timoshenko (1955) beams under the assumption of small material loss tangents. The appropriate method of analysis employed here may be applied to more complex structures. This study compares the damping ratios obtained from the Timoshenko and Euler-Bernoulli theories for a given viscoelastic material system. From this study the effect of shear deformation and rotary inertia on damping ratios can be identified.

Kalyanasundaram, S.↗
NASA NTRS1988

Noise-margin limitations on gallium-arsenide VLSI

Two factors which limit the complexity of GaAs MESFET VLSI circuits are considered. Power dissipation sets an upper complexity limit for a given logic circuit implementation and thermal design. Uniformity of device characteristics and the circuit configuration determines the electrical functional yield. Projection of VLSI complexity based on these factors indicates that logic chips of 15,000 gates are feasible with the most promising static circuits if a maximum power dissipation of 5 W per chip is assumed. While lower power per gate and therefore more gates per chip can be obtained by using a popular E/D FET circuit, yields are shown to be small when practical device parameter tolerances are applied. Further improvements in materials, devices, and circuits wil be needed to extend circuit complexity to the range currently dominated by silicon.

Long, Stephen I.↗
NASA NTRS1989

Scatter from optical components; Proceedings of the Meeting, San Diego, CA, Aug. 8-10, 1989

Various papers on scatter from optical components are presented. Individual topics addressed include: BRDF of SiC and Al foam compared to black paint at 3.39 microns, characterization of optical baffle materials, bidirectional transmittance distribution function of several IR materials at 3.39 microns, thermal cycling effects on the BRDF of beryllium mirrors, BTDV of ZnSe with multilayer coatings at 3.39 microns, scattering from contaminated surfaces, cleanliness correlation by BRDF and PFO instruments, contamination effects on optical surfaces, means of eliminating the effects of particulate contamination on scatter measurements of superfine optical surfaces, vacuum BRDF measurement of cryogenic optical surfaces, Monte Carlo simulation of contaminant transport to and deposition on complex spacecraft surfaces, surface particle observation and BRDF predictions, satellite material contaminant optical properties, dark field photographic techniques for documenting optical surface contamination, design of a laboratory study of contaminant film darkening in space, contamination monitoring approaches for EUV space optics.

Stover, John C.↗
NASA NTRS2018

A Case for High-Fidelity Material Response Modeling

Material response modeling of heatshields for planetary entry vehicles has remained largely unchanged since Aerotherm Corp. introduced the CMA program in 1967. Modern models, like FIAT, have tread the same path, introducing efficiencies and better material property data along the way, but otherwise following the same underlying model paradigm. The CMA approach has worked well for heatshield design up to this point. However, there are three motivations for the material response community to pursue higher fidelity beyond simplified, CMA-derived models. The first motivation is that missions are becoming increasingly demanding and complex and, as they do, confidence in simplified models naturally decreases. Second, reliability of materials is now as much or more of a driving concern for mission designers than thermal response. Third, NASA and other agencies are increasingly interested in flight instrumentation for engineering science. This latter motivation places far stricter requirements on model accuracy in order to meet requirements for flight environment reconstruction.

Barnhardt, Michael D.↗
NASA NTRS1988

Optical properties of cometary grains

An analysis of visible/near IF polarimetry of Comet Halley leads to a variation of the complex refractive index m = n - i x k of grain material with wavelength, i.e., a slight decrease of n from 1.39 at lambda = 0.37 micrometer to 1.37 at lambda = 2.2 micrometers, in constrast to an increase of k from 0.024 at lambda = 0.37 micrometer to 0.042 at lambda 2.2 micrometers. The mass distribution of grains reported by Mazets et al. from in situ measurements of Vega 2 was applied in the analysis. Combining these optical constants with those of astronomical silicate proposed by Draine, cometary silicate is presented as a candidate for cometary grains. The complex refractive index of the proposed cometary silicate is shown. Based on Mie theory, an emission coefficiency of each of the grains in computed as well as its temperature, as functions of grain radius and sun comet (grain) distance. It is found that the tentative thermal spectrum from these cometary silicates, where the mass distribution of grains reported by Mazets from Vega 2 was applied, fits very well to the IR spectrum of Comet Halley. This means that cometary silicate can explain not only the phase angle and wavelength dependences of visible/near IF polarization, but also the thermal emission.

Mukai, Tadashi↗
NASA NTRS2016

Synthesis, Structure, Characterization, and Decomposition of Nickel Dithiocarbamates: Effect of Precursor Structure and Processing Conditions on Solid-State Products

Single-crystal X-ray structures of four nickel dithiocarbamate complexes, the homoleptic mixed-organic bis-dithiocarbamates Ni[S2CN(isopropyl)(benzyl)]2, Ni[S2CN(ethyl)(n-butyl)]2, and Ni[S2CN(phenyl)(benzyl)]2, as well as the heteroleptic mixed-ligand complex NiCl[P(phenyl)3][(S2CN(phenyl)(benzyl)], were determined. Synthetic, spectroscopic, structural, thermal, and sulfide materials studies are discussed in light of prior literature. The spectroscopic results are routine. A slightly distorted square-planar nickel coordination environment was observed for all four complexes. The organic residues adopt conformations to minimize steric interactions. Steric effects also may determine puckering, if any, about the nickel and nitrogen atoms, both of which are planar or nearly so. A trans-influence affects the Ni-S bond distances. Nitrogen atoms interact with the CS2 carbons with a bond order of about 1.5, and the other substituents on nitrogen display transoid conformations. There are no strong intermolecular interactions, consistent with prior observations of the volatility of nickel dithiocarbamate complexes. Thermogravimetric analysis of the homoleptic species under inert atmosphere is consistent with production of 1:1 nickel sulfide phases. Thermolysis of nickel dithiocarbamates under flowing nitrogen produced hexagonal or -NiS as the major phase; thermolysis under flowing forming gas produced millerite (-NiS) at 300 C, godlevskite (Ni9S8) at 325 and 350 C, and heazlewoodite (Ni3S2) at 400 and 450 C. Failure to exclude oxygen results in production of nickel oxide. Nickel sulfide phases produced seem to be primarily influenced by processing conditions, in agreement with prior literature. Nickel dithiocarbamate complexes demonstrate significant promise to serve as single-source precursors to nickel sulfides, a quite interesting family of materials with numerous potential applications.

microscopy↗
NASA NTRS1975

Ultraviolet complex refractive index of Martian dust Laboratory measurements of terrestrial analogs

The optical complex index of refraction of four candidate Martian surface materials has been determined between 0.185 and 0.4 microns using a modified Kubelka-Munk scattering theory. The cadidate materials were limonite, andesite, montmorillonite, and basalt. The effect of scattering has been removed from the results. Also presented are diffuse reflection and transmission data on these samples.

Egan, W. G.↗
NASA NTRS1976

A correlation study based on Al/Si X-ray fluorescence data from southwestern part of Mare Serenitatis

A correlation study based on Al/Si intensity ratios, broad-spectrum visible-albedo measurements, color-difference photography, color-ratio images, and spectral-reflectivity curves was undertaken to understand why the Tacquet Formation in southwestern Mare Serenitatis has unusually low visible albedos for the Al/Si intensity ratios measured by the Apollo 15 X-ray fluorescence experiment. The statistical analysis of the Al/Si data is described, general correlations among all the remote-sensing data are noted, and correlations in the area of the Tacquet Formation are examined. It is shown that the discrepancy between visible albedos and Al/Si intensities may be due primarily to the presence of unevenly deposited highland-type ejecta from Menaleus crater, although the possibility cannot be excluded that the Tacquet Formation is more complex than a simple mixture of highland and mare materials.

Andre, C. G.↗
NASA NTRS1976

Trapped rubber processing for advanced composites

Trapped rubber processing is a molding technique for composites in which precast silicone rubber is placed within a closed cavity where it thermally expands against the composite's surface supported by the vessel walls. The method has been applied by the Douglas Aircraft Company, under contract to NASA-Langley, to the design and fabrication of 10 DC-10 graphite/epoxy upper aft rudder assemblies. A three-bay development tool form mold die has been designed and manufactured, and tooling parameters have been established. Fabrication procedures include graphite layup, assembly of details in the tool, and a cure cycle. The technique has made it possible for the cocured fabrication of complex primary box structures otherwise impracticable via standard composite material processes.

Marra, P. J.↗
NASA NTRS1982

A study of the nature of solid particle impact and shape on the erosion morphology of ductile metals

Impulsive versus steady jet impingement of spherical glass bead particles on metal surfaces was studied using a gas gun facility and a commercial sand blasting apparatus. Crushed glass particles were also used in the sand blasting apparatus as well as glass beads. Comparisons of the different types of erosion patterns were made. Scanning electron microscopy, surface profilometry and energy dispersive X-ray spectroscopy analysis were used to characterize erosion patterns. The nature of the wear can be divided into cutting and deformation, each with its own characteristic features. Surface chemistry analysis indicates the possibility of complex chemical and/or mechanical interactions between erodants and target materials.

Rao, P. V.↗
NASA NTRS1982

Extension of the hole-drilling method to birefringent composites

A complete stress analysis and reliable failure criteria are essential for important structural applications of composites in order to fully utilize their unique properties. The inhomogeneity, anisotropy and inelasticity of many composites make the use of experimental methods indispensable. Among the experimental techniques, transmission photoelasticity has been extended to birefringent composites in recent years. The extension is not straight-forward, in view of the complex nature of the photoelastic response of such model materials. This paper very briefly reviews the important developments in the subject and then describes the theoretical basis for a new method of determining the individual values of principal stresses in composite models. The method consists in drilling very small holes at points where the state of stress has to be determined. Experiments are then described which verify the theoretical predictions. The limitations of the method are pointed out and it is concluded that valuable information concerning the state of stress in a composite model can be obtained through the suggested method.

Prabhakaran, R.↗
NASA NTRS1984

A study of the effect of solid particle impact and particle shape on the erosion morphology of ductile metals

Impulsive versus steady jet impingement of spherical glass bead particles on metal surfaces was studied using a gas gun facility and a commercial sand blasting apparatus. Crushed glass particles were also used in the sand blasting apparatus as well as glass beads. Comparisons of the different types of erosion patterns were made. Scanning electron microscopy, surface profilometry and energy dispersive X-ray spectroscopy analysis were used to characterize erosion patterns. The nature of the wear can be divided into cutting and deformation, each with its own characteristic features. Surface chemistry analysis indicates the possiblity of complex chemical and/or mechanical interactions between erodants and target materials.

Rao, P. V.↗
NASA NTRS1991

Computational simulation of the creep-rupture process in filamentary composite materials

A computational simulation of the internal damage accumulation which causes the creep-rupture phenomenon in filamentary composite materials is developed. The creep-rupture process involves complex interactions between several damage mechanisms. A statistically-based computational simulation using a time-differencing approach is employed to model these progressive interactions. The finite element method is used to calculate the internal stresses. The fibers are modeled as a series of bar elements which are connected transversely by matrix elements. Flaws are distributed randomly throughout the elements in the model. Load is applied, and the properties of the individual elements are updated at the end of each time step as a function of the stress history. The simulation is continued until failure occurs. Several cases, with different initial flaw dispersions, are run to establish a statistical distribution of the time-to-failure. The calculations are performed on a supercomputer. The simulation results compare favorably with the results of creep-rupture experiments conducted at the Lawrence Livermore National Laboratory.

Slattery, Kerry T.↗
NASA NTRS1991

Infrared observations of small solar system bodies

Infrared reflectance spectra were measured of dark primitive asteroids in the 2 to 5 micron wavelength region. The search was for organic complexes such and CN, CH, and NH in dark material on small bodies in the solar system. A search and study was made of volatiles such as nitrogen, methane, ammonia, and carbon monoxide, both as free ices and hydrates/clathrates, on icy surfaces in the outer solar system, using high resolution spectra obtained with a multichannel cooled grating, infrared spectrometer. An absorption that can be attributed to X-C (triple bond) N in the matrix of dark materials on the primitive asteroids.

Brown, R. H.↗