SEARCH · Search NASA

Results for “Hydrothermal processing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 631 records · Page 35

All sources NASA NTRS DOE OSTI

DOE OSTI2019

Graphene Wrapped FeSe 2 Nano–Microspheres with High Pseudocapacitive Contribution for Enhanced Na–Ion Storage

Pseudocapacitance is a Faradaic process that involves surface or near surface redox reactions. Increasing the pseudocapacitive contribution is one of the most effective means to improve the rate performance of electrode materials. In this study, graphene oxide is used as a template to in situ synthesize burr globule–like FeSe 2 /graphene hybrid (B–FeSe 2 /G) using a facile one–step hydrothermal method. Structural characterization demonstrates that graphene layers not only wrap the surfaces of FeSe 2 particles, but also stretch into the interior of these particles, as a result of which the unique nano–microsphere structure is successfully established. When serving as anode material for Na–ion batteries, B–FeSe 2 /G hybrid displays high electrochemical performance in the voltage range of 0.5–2.9 V. The B–FeSe 2 /G hybrid has high reversible capacity of 521.6 mAh·g –1 at 1.0 A g –1 . Meanwhile, after 400 cycles, high discharge capacity of 496.3 mAh g –1 is obtained at a rate of 2.5 A g –1 , with a high columbic efficiency of 96.6% and less than 1.0% loss of discharge capacity. Even at the ultrahigh rate of 10 A g –1 , a specific capacity of 316.8 mAh g –1 can be achieved. Furthermore, kinetic analyses reveal that the excellent performance of the B–FeSe 2 /G hybrid is largely attributed to the high pseudocapacitive contribution induced by the special nano–micro structure.

25 ENERGY STORAGE↗

DOE OSTI2020

Brief Update on Advancements by Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction

In 2011, Pacific Northwest National Laboratory (PNNL), working as a partner in the National Advanced Biofuels Consortium, issued a report assessing the viable industrial feed system and pump options for a 2000 dry metric tons per day production-scale hydrothermal liquefaction (HTL) plant (Berglin et al. 2012). This report was issued as PNNL-21981, Review and Assessment of Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction, and will be referred to as “Pump Survey” for reference. It had the following scope: • Identify relevant applications and industries operating at comparable scales • Interact with commercial vendors and pursue integration between vendors • Take advantage of commercial off-the-shelf (COTS) technology • Supply and support vendor needs for biomass feedstock rheology characterization • Provide vendors with process requirements to support selection of conceptual design for feedstock handing and pump system • Obtain cost data to the extent possible from equipment vendors to support the technical economic analysis (TEA) • Identify issues associated scale-up. The current document represents an update to the prior report in order to: 1. Identify advancements in vendor-reported technologies 2. List reports of new experience or trials with biomass pumping applications 3. Determine if technology/application gaps identified in the prior report have been filled 4. Capture ideas on future research.

09 BIOMASS FUELS↗

DOE OSTI2017

Hydrocarbons as ore fluids

Conventional wisdom holds that aqueous solutions are the only non-magmatic fluids capable of concentrating metals in the Earth’s crust. The role of hydrocarbons in metal concentration is relegated to providing geochemical barriers at which the metals are reduced and immobilised. Liquid hydrocarbons, however, are also known to be able to carry appreciable concentrations of metals, and travel considerable distances. Here we report the results of an experimental determination of bulk solubilities of Au, Zn, and U in a variety of crude oils at temperatures up to 300 °C and of the benchtop-scale transport experiments that simulate hydrocarbon-mediated re-deposition of Zn at 25–200 °C. It has been demonstrated that the metal concentrations obtained in solubility experiments are within the range of concentrations that are typically considered sufficient for aqueous fluids to form ore bodies. It has also been shown that Zn can be efficiently transported and re-deposited by hydrocarbons. In conclusion, these results provide direct evidence of the ability of natural crude oils to mobilise metals available in hydrocarbon-associated host rocks, and transport them in concentrations sufficient to contribute to ore-forming processes.

58 GEOSCIENCES↗

NASA NTRS1974

Iron-absorption band analysis for the discrimination of iron-rich zones

The author has identified the following significant results. Most major rock units and unaltered and altered areas in the study area can be discriminated on the basis of visible and near-infrared spectral reflectivity differences recorded from satellite altitude. These subtle spectral differences are detectable by digital ratioing of the MSS bands and subsequent stretching to increase the contrast to enhance spectral differences. Hydrothermally altered areas appear as anomalous color patches within the volcanic-rock areas. A map has been prepared which can be regarded as an excellent reconnaissance exploration map, for use in targeting areas for more detailed geological, geochemical, and geophysical studies. Mafic and felsic rock types are easily discriminated on the color stretched-ratio composite. The ratioing process minimizes albedo effects, leaving only the recorded characteristic spectral response. The spectra of unaltered rocks appear different from those of altered rocks, which are typically dominated by limonite and clay minerals. It seems clear that differences in spectral shape can provide a basis for discrimination of geologic material, although the relations between visible and near-infrared spectral reflectivity and mineralogical composition are not yet entirely understood.

Rowan, L. C.↗

NASA NTRS1985

Anorthositic oceanic crust in the Archean Earth

Ultrapure minerals separated from eclogite inclusions in kimberlites were analyzed for Sm, Nd, Sr, and oxygen isotopes and for major and trace elements. Clinopyroxene (cpx) and garnet (gnt) are the only primary mineral phases in these rocks, and mineral phases and their alteration products. The WR sub calc. is the reconstructed bulk composition excluding all the contamination influences. Two groups of eclogites: are distinguished: (1) type A Noritic-anorthositic eclogites; and (2) type B Ti-ferrogabbroic eclogites. The oxygen isotopes are primary mantle-derived features of these rocks and are not caused by posteruption processes, as they were measured on unaltered, clean mineral separates and show a correlation with REE pattern and Sr and Nd isotopes. It is suggested that the variation of the oxygen isotopes are caused by crustal-level fluid-rock interaction at relatively low temperature. It is shown that oxygen isotopes variation in MORB basalts caused by the hydrothermal system are in the same range as the observed oxygen isotope variation in eclogites. A model to explain the new set of data is proposed. It is thought that some of these eclogites might be emplaced into the upper lithosphere or lower crust at the time corresponding to their internal isochron age. The calculated WR composition was used to estimate model ages for these rocks.

Jagoutz, E.↗

NASA NTRS1997

Searching for Biogeochemical Cycles on Mars

The search for life on Mars clearly benefits from a rigorous, yet broad, definition of life that compels us to consider all possible lines of evidence for a martian biosphere. Recent studies in microbial ecology illustrate that the classic definition of life should be expanded beyond the traditional definition of a living cell. The traditional defining characteristics of life are threefold. First, life is capable of metabolism, that is, it performs chemical reactions that utilize energy and also synthesize its cellular constituents. Second, life is capable of self-replication. Third, life can evolve in order to adapt to environmental changes. An expanded, ecological definition of life also recognizes that life is a community of organisms that must interact with their nonliving environment through processes called biogeochemical cycles. This regenerative processing maintains, in an aqueous conditions, a dependable supply of nutrients and energy for growth. In turn, life can significantly affect those processes that control the exchange of materials between the atmosphere, ocean, and upper crust. Because metabolic processes interact directly with the environment, they can alter their surroundings and thus leave behind evidence of life. For example, organic matter is produced from single-carbon-atom precursors for the biosynthesis of cellular constituents. This leads to a reservoir of reduced carbon in sediments that, in turn, can affect the oxidation state of the atmosphere. The harvesting of chemical energy for metabolism often employs oxidation-reduction reactions that can alter the chemistry and oxidation state of the redox-sensitive elements carbon, sulfur, nitrogen, iron, and manganese. Have there ever been biogeochemical cycles on Mars? Certain key planetary processes can offer clues. Active volcanism provides reduced chemical species that biota can use for organic synthesis. Volcanic carbon dioxide and methane can serve as greenhouse gases. Thus the persistence of volcanism on Mars may well have influenced the persistence of a martian biosphere. The geologic processing of the crust can affect the availability of nutrients and also control the deposition of minerals that could have served as a medium for the preservation of fossil information. Finally, the activity of liquid water is crucial to life. Was there ever an Earth-like hydrologic cycle with rainfall? Has aqueous activity instead been restricted principally to hydrothermal activity below the surface? To what extent did the inorganic chemistry driven by sunlight and hydrothermal activity influence organic chemistry (prebiotic chemical evolution)? This paper addresses these and other key questions.

DesMarais, David J.↗

NASA NTRS2015

Insights into the Martian Regolith from Martian Meteorite Northwest Africa 7034

Everything we know about sedimentary processes on Mars is gleaned from remote sensing observations. Here we report insights from meteorite Northwest Africa (NWA) 7034, which is a water-rich martian regolith breccia that hosts both igneous and sedimentary clasts. The sedimentary clasts in NWA 7034 are poorly-sorted clastic siltstones that we refer to as protobreccia clasts. These protobreccia clasts record aqueous alteration process that occurred prior to breccia formation. The aqueous alteration appears to have occurred at relatively low Eh, high pH conditions based on the co-precipitation of pyrite and magnetite, and the concomitant loss of SiO2 from the system. To determine the origin of the NWA 7034 breccia, we examined the textures and grain-shape characteristics of NWA 7034 clasts. The shapes of the clasts are consistent with rock fragmentation in the absence of transport. Coupled with the clast size distribution, we interpret the protolith of NWA 7034 to have been deposited by atmospheric rainout resulting from pyroclastic eruptions and/or asteroid impacts. Cross-cutting and inclusion relationships and U-Pb data from zircon, baddelleyite, and apatite indicate NWA 7034 lithification occurred at 1.4-1.5 Ga, during a short-lived hydrothermal event at 600-700 C that was texturally imprinted upon the submicron groundmass. The hydrothermal event caused Pb-loss from apatite and U-rich metamict zircons, and it caused partial transformation of pyrite to submicron mixtures of magnetite and maghemite, indicating the fluid had higher Eh than the fluid that caused pyrite-magnetite precipitation in the protobreccia clasts. NWA 7034 also hosts ancient 4.4 Ga crustal materials in the form of baddelleyites and zircons, providing up to a 2.9 Ga record of martian geologic history. This work demonstrates the incredible value of sedimentary basins as scientific targets for Mars sample return missions, but it also highlights the importance of targeting samples that have not been overprinted by metamorphic processes, which is the case for NWA 7034.

McCubbin, Francis M.↗

DOE OSTI2019

Self-healing, re-adhering, and carbon-steel corrosion mitigating properties of fly ash-containing calcium aluminum phosphate cement composite at 300 °C hydrothermal temperature

This study assesses here the ability of calcium aluminate phosphate (CAP)/fly ash F (FAF) blend composite to self-heal at early age; to re-adhere to the casing surfaces after debonding and to protect carbon steel (CS) against brine-caused corrosion before and after the re-adherence. The composite was damaged after autoclaving for 24 h at 300 °C and then exposed to the same conditions for 5 more days for the self-healing and re-adhering processes. The ability of the blend to self-heal and re-adhere to CS was evaluated 1) by measurements of the recovery of compressive and bond strengths and Young's modulus; 2) by performing the 3-dimensional micro-image analysis of sealed cracks; 3) by phase identification in composite matrix and in the cracks after the healing; 4) by measurements of CS corrosion impediment by the re-adhered composite after 300°C-5-day restoration period. After the healing, the two factors, sealing effect of cracks by reaction products and change in phase composition of cement matrix, essentially governed the recovery of the original mechanical strength. For the former, analcime phase derived from pozzolanic FAF autogenous healing aid played the major role in sealing the cracks, while the well-formed hydroxyapatite phase contributed to the latter factor. The lap-shear bond with the strength of 1.11 MPa at CS plate/composite adhesive/CS plate joint failed cohesively, showing higher bond strength than strength of the composite matrix. The rebonded composite-CS plates developed a 0.37 MPa bond strength after the 5-day restoration period. The results of electrochemical polarization corrosion tests revealed that the re-adhered composite covering CS plate significantly inhibited the brine-caused corrosion of CS, leading to 0.011 mm/year corrosion rate, corresponding to 50% reduction compared with that of before re-adhering. There were two factors governing such corrosion mitigation: enhanced adhesive contact of composite with CS and increased coverage by the re-adhering composite.

36 MATERIALS SCIENCE↗

NASA NTRS1988

Chemical and physical studies of type 3 chondrites. IX - Thermoluminescence and hydrothermal annealing experiments and their relationship to metamorphism and aqueous alteration in type below 3.3 ordinary chondrites

Thermoluminescence (TL) properties were measured in samples of four type-3.0 chondrites annealed at 400-850 C and 0.77-1 kbar in the presence of various amounts of water and sodium disilicate. Several changes recorded in TL characteristics, such as the lowering of TL sensitivity in certain samples, its increase in other samples, and changes in the peak position and peak width of TL suggested the occurrence of metamorphic processes in these samples. It is suggested that, for the chondrite types above 3.2, the observed changes in TL are consistent with the TL-metamorphism trends, being due to the formation of feldspar by the devitrification of chondrule glass during metamorphism. For types below 3.2, the TL data are consistent with the hypothesis that these chondrules experienced lower levels of metamorphism than the higher types or, alternatively, with the hypothesis that the type 3.0 chondrules are being produced from higher types by aqueous alteration.

Guimon, R. Kyle↗

NASA NTRS2000

The Evolution and Disruption of Planetary Systems

Planetary systems that encounter passing stars can experience severe orbital disruption, and the efficiency of this process is greatly enhanced when the impinging systems are binary pairs rather than single stars. Using a Monte Carlo approach, we have performed nearly half a million numerical experiments to examine the long term ramifications of planetary scattering on planetary systems. We have concluded that systems which form in dense environments such as Orion's Trapezium cluster have roughly a ten percent chance of being seriously disrupted. We have also used our programs to explore the long-term prospects for our own Solar system. Given the current interstellar environment, we have computed the odds that Earth will find its orbit seriously disrupted prior to the emergence of a runaway greenhouse effect driven by the Sun's increasing luminosity. This estimate includes both direct disruption events and scattering processes that seriously alter the orbits of the Jovian planets, which then force severe changes upon the Earth's orbit. We then explore the consequences of the Earth being thrown into deep space. The surface biosphere would rapidly shut down under conditions of zero insolation, but the Earth's radioactive heat is capable of maintaining life deep underground, and perhaps in hydrothermal vent communities, for some time to come. Although unlikely for the Earth, this scenario may be common throughout the universe, since many environments where liquid water could exist (e.g., Europa and Callisto) must derive their energy from internal (rather than external) heating.

Laughlin, Gregory↗

DOE OSTI2018

Facile synthesis and photocatalytic activity of Ag3PO4 decorated MoS2 nanoflakes on carbon fiber cloth

Highlights: • A novel CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure is fabricated by a facile method. • The growth process of CC@MoS{sub 2} is investigated. • The heterostructure displays an excellent photocatalytic property. • Cyclic Voltammetry is utilized to investigate the photocatalytic mechanism. - Abstract: A novel CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure, composed of Ag{sub 3}PO{sub 4} nanoparticles decorated MoS{sub 2} nanosheets on carbon fiber cloth (CC), is fabricated by a simple hydrothermal method and a successive ionic layer absorption reaction. The CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure displays an excellent photocatalytic activity of ∼96% degradation rate for RhB solution under simulated daylight, which is more than 10 times as much as that of pure Ag{sub 3}PO{sub 4} or MoS{sub 2}. The CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure with optimized photoactivity is investigated by optical and electrochemical measurements. The CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure can not only broaden the photoresponse range of MoS{sub 2}, but also alleviate the photodegradation of Ag{sub 3}PO{sub 4}, and the easily separated CC provides a proper conductive substrate and rapid charge transfer channels. The probable photocatalytic mechanism of CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure is discussed in detail. Therefore, the CC@MoS{sub 2}-Ag{sub 3}PO{sub 4} heterostructure with high efficient photocatalytic performance and easy separation is a promising photocatalytic material.

36 MATERIALS SCIENCE↗

DOE OSTI2022

The Dopamine Assisted Synthesis of MoO3/Carbon Electrodes With Enhanced Capacitance in Aqueous Electrolyte

A capacitance increase phenomenon is observed for MoO 3 electrodes synthesized via a sol-gel process in the presence of dopamine hydrochloride (Dopa HCl) as compared to α-MoO 3 electrodes in 5M ZnCl 2 aqueous electrolyte. The synthesis approach is based on a hydrogen peroxide-initiated sol-gel reaction to which the Dopa HCl is added. The powder precursor (Dopa) x MoO y , is isolated from the metastable gel using freeze-drying. Hydrothermal treatment (HT) of the precursor results in the formation of MoO 3 accompanied by carbonization of the organic molecules; designated as HT-MoO 3 /C. HT of the precipitate formed in the absence of dopamine in the reaction produced α-MoO 3 , which was used as a reference material in this study (α-MoO 3 -ref). Scanning electron microscopy (SEM) images show a nanobelt morphology for both HT-MoO 3 /C and α-MoO 3 -ref powders, but with distinct differences in the shape of the nanobelts. The presence of carbonaceous content in the structure of HT-MoO 3 /C is confirmed by FTIR and Raman spectroscopy measurements. X-ray diffraction (XRD) and Rietveld refinement analysis demonstrate the presence of α-MoO 3 and h-MoO 3 phases in the structure of HT-MoO 3 /C. The increased specific capacitance delivered by the HT-MoO 3 /C electrode as compared to the α-MoO 3 -ref electrode in 5M ZnCl 2 electrolyte in a −0.25–0.70 V vs. Ag/AgCl potential window triggered a more detailed study in an expanded potential window. In the 5M ZnCl 2 electrolyte at a scan rate of 2 mV s −1 , the HT-MoO 3 /C electrode shows a second cycle capacitance of 347.6 F g −1 . The higher electrochemical performance of the HT-MoO 3 /C electrode can be attributed to the presence of carbon in its structure, which can facilitate electron transport. Our study provides a new route for further development of metal oxides for energy storage applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2001

A Structural and Molecular Approach for the Study Biomarkers

Investigation of the nucleation and growth of crystals in both abiotic and biotic systems is critical to seemingly diverse disciplines of geology, biology, environmental science, and astrobiology. While there are abundant studies devoted to the determination of the structure and composition of inorganic crystals, as well as to the development of thermodynamic and kinetic models, it is only recently that research efforts have been directed towards understanding mineralization in biological systems (i.e., biomineralization). Biomineralization refers to the processes by which living organisms form inorganic solids. Studies of the processes of biomineralization under low temperature aqueous conditions have focused primarily on magnetite forming bacteria and shell forming marine organisms. Many of the biological building materials consist of inorganic minerals (calcium carbonate, calcium phosphate, silica or iron oxide) intricately combined with organic polymers (like proteins). More recently, efforts have been undertaken to explore the nature of biological activities in ancient rocks. In the absence of well-preserved microorganisms or genetic material required for the polmerase chain reaction (PCR) method in molecular phylogenetic studies, using biominerals as biomarkers offers an alternative approach for the recognition of biogenic activity in both terrestrial and extraterrestrial environments. The primary driving force in biomineralization is the interaction between organic and inorganic phases. Thus, the investigation of the ultrastructure and the nature of reactions at the molecular level occurring at the interface between inorganic and organic phases is essential to understanding the processes leading to the nucleation and growth of crystals. It is recognized that crystal surfaces can serve as the substrate for the organization of organic molecules that lead to the formation of polymers and other complex organic molecules, and in discussions of the origins of life, is referred to as organic synthesis on mineral surfaces. Furthermore, it is suggested that the interaction between mineral surfaces and simple organic molecules resulted in the formation of amino acids, RNA, and perhaps other more complex molecules such as proteins. On the other hand, in natural systems, it is recognized that functional groups on cell walls or membranes of microorganisms serve as sites of nucleation and crystallization. The precise replication of biominerals with controlled structure, morphology, size and texture is not confined to higher organisms as it also occurs in primitive prokaryotic cells such as magnetotactic bacteria and cyanobacteria. This suggests that the principal strategies of biomineralization were established early on in the evolutionary history of organisms. It is critical, therefore, to search for common mechanisms within diverse biological systems. One such common factor is the capability for organization and self-assembly. Organic macromolecules such as proteins and lipids can aggregate and polymerize forming membranes or extracellular matrix. At the organic-inorganic interface, several factors such as lattice geometry, polarity, stereochemistry and topography may act in concert to control nucleation and growth of crystals. Although several models have been proposed that discuss the significance of these factors for biomineralization, no comprehensive experimental data are available. In contrast to crystallization in exclusively inorganic systems, the kinetics of reaction and structural relationships between organic and inorganic phases in biominerals or biomimetic material is poorly understood. For example, it is not clear if the concept of epitactic growth (geometrical matching of unit cells at the interface of a secondary crystal growing on a primary crystal) applies to organic-inorganic systems. In contrast to inorganic templates that often have a smooth and rigid surface that promotes epitactic growth, biological substrates are usually rough and result in a large degree of mismatch. It is apparent that factors controlling the reaction at the crystal-matrix interface are strongly dependent upon the nature of the substrate. Therefore, characterization of the assembled organic surface and surface structure of the inorganic phase is crucial to understanding the processes of biomineralization. The focus of our research is the investigation of the processes leading to the nucleation and growth of crystals on both natural and synthetic systems through an interdisciplinary approach that integrates molecular biology, morphology and mineralogy using advanced preparation and analytical techniques. We have studied run-products, particularly magnetite, siderite and other carbonates, that resulted from extracellular biomineralization by extremophiles isolated from a variety of extreme environments ranging from permafrost to hydrothermal vent systems. The results of this study are critical to recognizing biomarkers in terrestrial and extraterrestrial environments.

Thomas-Keprta, Kathie↗

NASA NTRS2005

Mapping Weathering and Alteration Minerals in the Comstock and Geiger Grade Areas using Visible to Thermal Infrared Airborne Remote Sensing Data

To support research into both precious metal exploration and environmental site characterization a combination of high spatial/spectral resolution airborne visible, near infrared, short wave infrared (VNIR/SWIR) and thermal infrared (TIR) image data were acquired to remotely map hydrothermal alteration minerals around the Geiger Grade and Comstock alteration regions, and map the mineral by-products of weathered mine dumps in Virginia City. Remote sensing data from the Airborne Visible Infrared Imaging Spectrometer (AVIRIS), SpecTIR Corporation's airborne hyperspectral imager (HyperSpecTIR), the MODIS-ASTER airborne simulator (MASTER), and the Spatially Enhanced Broadband Array Spectrograph System (SEBASS) were acquired and processed into mineral maps based on the unique spectral signatures of image pixels. VNIR/SWIR and TIR field spectrometer data were collected for both calibration and validation of the remote data sets, and field sampling, laboratory spectral analyses and XRD analyses were made to corroborate the surface mineralogy identified by spectroscopy. The resulting mineral maps show the spatial distribution of several important alteration minerals around each study area including alunite, quartz, pyrophyllite, kaolinite, montmorillonite/muscovite, and chlorite. In the Comstock region the mineral maps show acid-sulfate alteration, widespread propylitic alteration and extensive faulting that offsets the acid-sulfate areas, in contrast to the larger, dominantly acid-sulfate alteration exposed along Geiger Grade. Also, different mineral zones within the intense acid-sulfate areas were mapped. In the Virginia City historic mining district the important weathering minerals mapped include hematite, goethite, jarosite and hydrous sulfate minerals (hexahydrite, alunogen and gypsum) located on mine dumps. Sulfate minerals indicate acidic water forming in the mine dump environment. While there is not an immediate threat to the community, there are clearly sources of acidic drainage that were identified remotely.

imaging spectroscopy↗

NASA NTRS2015

Astrobiology, Mars Exploration and Lassen Volcanic National Park

The search for evidence of life beyond Earth illustrates how the charters of NASA and the National Park Service share common ground. The mission of NPS is to preserve unimpaired the natural and cultural resources of the National Park System for the enjoyment, education and inspiration of this and future generations. NASA's Astrobiology program seeks to understand the origins, evolution and distribution of life in the universe, and it abides by the principles of planetary stewardship, public outreach, and education. We cannot subject planetary exploration destinations to Earthly biological contamination both for ethical reasons and to preserve their scientific value for astrobiology. We respond to the public's interest in the mysteries of life and the cosmos by honoring their desire to participate in the process of discovery. We involve youth in order to motivate career choices in science and technology and to perpetuate space exploration. The search for evidence of past life on Mars illustrates how the missions of NASA and NPS can become synergistic. Volcanic activity occurs on all rocky planets in our Solar System and beyond, and it frequently interacts with water to create hydrothermal systems. On Earth these systems are oases for microbial life. The Mars Exploration Rover Spirit has found evidence of extinct hydrothermal system in Gusev crater, Mars. Lassen Volcanic National Park provides a pristine laboratory for investigating how microorganisms can both thrive and leave evidence of their former presence in hydrothermal systems. NASA scientists, NPS interpretation personnel and teachers can collaborate on field-oriented programs that enhance Mars mission planning, engage students and the public in science and technology, and emphasize the ethics of responsible exploration.

Lassen Volcanic National Park↗

DOE OSTI2022

Sustainable Aviation Fuel from Hydrothermal Liquefaction of Wet Wastes

Hydrothermal liquefaction (HTL) uses heat and pressure to liquefy the organic matter in biomass/waste feedstocks to produce biocrude. When hydrotreated the biocrude is converted into transportation fuels including sustainable aviation fuel (SAF). Further, by liquifying the organic matter in wet wastes such as sewage sludge, manure, and food waste, HTL can prevent landfilling or other disposal methods such as anerobic digestion, or incineration. A significant roadblock to the development of a new route for SAF is the strict approval process, and the large volumes required (>400 L) for testing. Tier α and β testing can predict some of the properties required for ASTM testing with <400 mL samples. The current study is the first to investigate the potential for utilizing wet-waste HTL biocrude (WWHTLB) as an SAF feedstock. Herein, several WWHTLB samples were produced from food waste, sewage sludge, and fats, oils, and grease, and subsequently hydrotreated and distilled to produce SAF samples. The fuels (both undistilled and distilled samples) were analyzed via elemental and 2D-GC-MS. Herein, we report the Tier α and β analysis of an SAF sample derived originally from a WWHTLB. The results of this work indicate that the upgraded WWHTLB material exhibits key fuel properties, including carbon number distribution, distillation profile, surface tension, density, viscosity, heat of combustion, and flash point, which all fall within the required range for aviation fuel. WWHTLB has therefore been shown to be a promising candidate feedstock for the production of SAF.

09 BIOMASS FUELS↗

NASA NTRS1998

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗

DOE OSTI2017

Washington Geothermal Play Fairway Analysis Data From Potential Field Studies

A recent study which adapts play fairway analysis (PFA) methodology to assess geothermal potential was conducted at three locations (Mount Baker, Mount St. Helens seismic zone, and Wind River valley) along the Washington Cascade Range (Forson et al. 2017). Potential field (gravity and magnetic) methods which can detect subsurface contrasts in physical properties, provides a means for mapping and modeling subsurface geology and structure. As part of the WA-Cascade PFA project, we performed potential field studies by collecting high-resolution gravity and ground-magnetic data, and rock property measurements to (1) identify and constrain fault geometries (2) constrain subsurface lithologic distribution (3) study fault interactions (4) identify areas favorable to hydrothermal flow, and ultimately (5) guide future geothermal exploration at each location.

15 GEOTHERMAL ENERGY↗