Kinetic and mechanistic study of bimetallic Pt-Pd/Al2O3 catalysts for CO and C3H6 oxidation
Not Available
Hazlett, Melanie J.↗
SEARCH · Search NASA
Results for “Partial observability”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Cardiovascular examinations and observations of deconditioning during the Space Shuttle orbital flight test program
During the first four flights of the Space Shuttle, cardiovascular data were obtained on each crewmember as part of the operational medicine requirements for crew health and safety. From monitoring blood pressure and electrocardiographic data, it was possible to estimate the degree of deconditioning imposed by exposure to the microgravity environment. For this purpose, a quantitative cardiovascular index of deconditioning (CID) was derived to aid the clinician in his assessment. Isotonic saline was then investigated as a countermeasure against orthostatic intolerance and found to be effective in partially reversing the hemodynamic consequences. It was observed that the space flight environment of reentry might potentially be arrhythmogenic in at least one individual.
Bungo, M. W.↗
Anderson acceleration stability in NDA-accelerated k-eigenvalue problems
Anderson acceleration (AA) has been used to improve the stability and convergence rate of multiphysics iterative methods for reactor analysis. Most applications studied assume a tightly converged solution for the different physics problems, and AA is usually applied to state variables like temperature, density, and heat generation rate. In this paper, we study the theoretical performance of AA in NDA-accelerated k-eigenvalue problems. The problems and algorithms studied are simplified from the coupled iteration scheme adopted by MPACT and many other high-fidelity whole-core reactor codes. Compared to previous analyses of AA for these iteration schemes, we study the case with a partially converged neutronics solution and possibly partially converged nonlinear diffusion acceleration (NDA)/coarse mesh finite difference (CMFD) solutions. We observe that the performance of the iteration scheme with AA is very sensitive to the initial guess and is affected by the partially converged CMFD solutions. When the NDA solution is fully converged, using AA cannot achieve the optimal convergence rate in large-sized problems. Conversely, if the NDA solution is partially converged, the iteration scheme with AA can diverge or converge extremely slowly. It is found that the loss of robustness for AA is due to the fact that it is applied to the iterative subspace of state variables rather than the fundamental unknowns of the governing equations. To improve the robustness, the scalar flux should also be considered in the implementation of AA. After considering the residuals of flux, we observe that the stability is regardless of the partial convergence of NDA solutions. (authors)
22 GENERAL STUDIES OF NUCLEAR REACTORS↗
Ion-Neutral Coupling in Solar Prominences
Interactions between ions and neutrals in a partially ionized plasma are important throughout heliophysics, including near the solar surface in prominences. Understanding how ion-neutral coupling affects formation, support, structure, and dynamics of prominences will advance our physical understanding of magnetized systems involving a transition from a weakly ionized dense gas to a fully ionized tenuous plasma. We address the fundamental physics of prominence support, which is normally described in terms of a magnetic force on the prominence plasma that balances the solar gravitational force, and the implications for observations. Because the prominence plasma is only partially ionized, it is necessary to consider the support of the both the ionized and neutral components. Support of the neutrals is accomplished through a frictional interaction between the neutral and ionized components of the plasma, and its efficacy depends strongly on the degree of ionization of the plasma. More specifically, the frictional force is proportional to the relative flow of neutral and ion species, and for a sufficiently weakly ionized plasma, this flow must be relatively large to produce a frictional force that balances gravity. A large relative flow, of course, implies significant draining of neutral particles from the prominence. We evaluate the importance of this draining effect for a hydrogen-helium plasma, and consider the observational evidence for cross-field diffusion of neutral prominence material.
Gilbert, Holly↗
Investigation of deformation micro-mechanisms in nickel consolidated from a bimodal powder by spark plasma sintering
Bulk polycrystalline nickel compact was processed by spark plasma sintering from heterogeneous powder consisting of a mixture of nanometer and micrometer sized particles. The consolidated samples inherited the bimodal structure of the starting powder and was composed of ~ 55 vol.% coarse-grained (with the grain size larger than 1 μm) and ~ 45 vol.% ultrafine-grained (with an average grain size of ~ 550 nm) components. The deformation mechanisms were established by EBSD, X-ray line profile analysis and in-situ TEM observations. In the ultrafine-grained volume, the deformation occurred mainly through the activation of dislocation sources emitting full or partial dislocation either from grain interior or grain boundaries. Besides dislocation activity, rolling and sliding of nanograins were also observed during deformation by in-situ transmission electron microscopy, which have a considerable contribution to the observed high strain rate sensitivity of the bimodal microstructure. The cracks formed during deformation easily propagated in the nanograin regions due to the weaker particle bonding caused by the relatively high fraction of native oxide layer on the surface of the initial nanoparticles. - Highlights: • Bulk bimodal polycrystalline Ni was processed by SPS from a heterogeneous powder. • High SRS of the flow stress was observed which enhanced ductility and strength. • In-situ TEM revealed dislocation sources inside and at the boundaries of UFGs. • Twinning, partial dislocation and NG rolling were observed at crack tip vicinity. • The high SRS pertained to both dislocation activity in CG and NG rolling.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Large Eddy Simulations of the Atmospheric Boundary Layer Over Satellite‐Sensed Sea Ice Maps
Surface heterogeneity in the marginal ice zone (MIZ) causes multiscale secondary atmospheric circulations that are challenging to model or observe. The absence or inadequate representation of these circulations in ocean‐atmosphere exchange schemes in climate models is partially responsible for the underestimation of Arctic sea ice loss. Observationally, such circulations obfuscate the interpretation of polar atmospheric chemistry measurements, among others. To address this open challenge, large‐eddy simulations are conducted over real‐world satellite‐sensed sea ice maps with an ice‐sea temperature contrast, as well as over idealizations of these maps that alter the ice pattern but conserve its fraction, showing that the ice fraction of a surface is not sufficient to predict the surface heat flux. In a second suite of simulations, three other heterogeneity metrics (representing the surface fragmentation, patch edge tortuosity, and patch size variability) are introduced to complement the ice fraction in describing the surface. Simulations varying these parameters suggest that they also significantly impact surface‐air interactions. A roughness contrast is then added to the surface temperature contrast, indicating that the contribution of roughness changes to the resulting atmospheric circulations is less pronounced than that of thermal heterogeneity. Based on these results, we illustrate, using a multi‐linear regression on these map features, that MIZ surface parameterizations in Earth Systems Models can be improved if they account for these various characteristics of the sea‐ice patterns.
54 ENVIRONMENTAL SCIENCES↗
Impulsive phase of solar flares
The present understanding of the impulsive phase of a solar flare, characterized by short-duration bursts of impulsive hard X-ray, EUV, optical and radio emission indicating the release of energetic electrons is reviewed. Observations of the spectral distribution of impulsive hard X-ray bursts and of Type III and radio continuum bursts are presented and interpreted in terms of energetic electron distributions, and impulsive EUV, XUV, soft X-ray and optical observations, which provide a lower limit to total energy release during the impulsive phase, are discussed. The role of energetic electrons in exciting the hard X-ray, EUV and microwave emissions is considered, and thin-target, thick-target, partial-precipitation and thermal models of impulsive phase electron acceleration are evaluated in light of the observations. It is noted that available data do not allow discrimination between a thermal or a nonthermal electron distribution, on which depends the proportion of flare energy supplied by the energetic electrons, and that data favors models which permit at least partial electron precipitation. Future observational and theoretical work is indicated.
Kane, S. R.↗
The SiH vibrational stretch as an indicator of the chemical state of interstellar grains
The infrared spectra of amorphous silicate grains and films formed in a variety of laboratory experiments have been measured. It is found that the frequency of the SiH fundamental stretch is extremely sensitive to the chemical environment of the grain in which the silicon is bound and varies from 2270/cm in oxidized grains to 2110/cm in a reducing environment. It is proposed that features previously observed in W33A could be due to -SiH groups in amorphous silica, partially reduced silica, silicon nitride or slightly oxidized silicon carbide. It is predicted that observations at 2270/cm will reveal a feature due to -SiH groups in highly oxidized interstelar and circumstellar grains. Such a feature might also appear in the spectra of comets.
Moore, Marla H.↗
High-Altitude Aircraft and Balloon-Borne Observations of OH, HO2, ClO, BrO, NO2, ClONO2, ClOOCl, H2O, and O3 in Earth's Stratosphere
Using observations from balloon-borne instruments and aircraft-borne instruments the investigation arrived at the following developments.: (1) Determination of the dominant catalytic cycles that destroy ozone in the lower stratosphere; (2) The partial derivatives of the rate limiting steps are observables in the lower stratosphere; (3) Recognition that the "Low NOx" condition is the regime that holds the greatest potential for misjudgement of Ozone loss rates; (4) Mapping of the Bromine radical contribution to the ozone destruction rate in the lower stratosphere; (5) Observation of OH, HO2 and ClO in the plume of the Concorde SST in the stratosphere; (6) Determination of the diurnal behavior of OH in the lower stratosphere; (7) Observed OH and H02 in the Troposphere and the interrelationship between Ozone and OH, HO2, CO and NO; (8) Analysis of the Catalytic Production of Ozone and Reactions that Couple OH and H02 in the Troposphere; (9) The continuing development of the understanding of the Tropopause temperatures, water vapor mixing ratios, and vertical advection and the mixing in of mid-latitude air; (10) Performed Multiple Tracer Analyses as a diagnostic of water vapor intrusion into the "Middle World" (i.e., the lowermost stratsophere); (11) Flight testing of a new instrument for the In Situ detection of ClON02 from the ER-2; (12) Laser induced fluorescence detection of NO2. There is included an in depth discussion of each of these developments and observations.
Anderson, James G.↗
INTERACTION OF TWO FILAMENT CHANNELS OF DIFFERENT CHIRALITIES
We present observations of the interactions between the two filament channels of different chiralities and associated dynamics that occurred during 2014 April 18–20. While two flux ropes of different helicity with parallel axial magnetic fields can only undergo a bounce interaction when they are brought together, the observations at first glance show that the heated plasma is moving from one filament channel to the other. The SDO /AIA 171 Å observations and the potential-field source-surface magnetic field extrapolation reveal the presence of a fan-spine magnetic configuration over the filament channels with a null point located above them. Three different events of filament activations, partial eruptions, and associated filament channel interactions have been observed. The activation initiated in one filament channel seems to propagate along the neighboring filament channel. We believe that the activation and partial eruption of the filaments brings the field lines of flux ropes containing them closer to the null point and triggers the magnetic reconnection between them and the fan-spine magnetic configuration. As a result, the hot plasma moves along the outer spine line toward the remote point. Utilizing the present observations, for the first time we have discussed how two different-chirality filament channels can interact and show interrelation.
79 ASTRONOMY AND ASTROPHYSICS↗
Deducing neutron star equation of state from telescope spectra with machine-learning-derived likelihoods
The interiors of neutron stars reach densities and temperatures beyond the limits of terrestrial experiments, providing vital laboratories for probing nuclear physics. While the star's interior is not directly observable, its pressure and density determine the star's macroscopic structure which affects the spectra observed in telescopes. The relationship between the observations and the internal state is complex and partially intractable, presenting difficulties for inference. Previous work has focused on the regression from stellar spectra of parameters describing the internal state. We demonstrate a calculation of the full likelihood of the internal state parameters given observations, accomplished by replacing intractable elements with machine learning models trained on samples of simulated stars. Our machine-learning-derived likelihood allows us to perform maximum a posteriori estimation of the parameters of interest, as well as full scans. We demonstrate the technique by inferring stellar mass and radius from an individual stellar spectrum, as well as equation of state parameters from a set of spectra. Our results are more precise than pure regression models, reducing the width of the parameter residuals by 11.8% in the most realistic scenario. The neural networks will be released as a tool for fast simulation of neutron star properties and observed spectra.
79 ASTRONOMY AND ASTROPHYSICS↗
The effects of shock wave compaction on the transition temperatures of A15 structure superconductors
Several superconductors with the A15 structure exhibit a positive pressure coefficient, indicating that their transition temperatures increase with applied pressure. Powders of the composition Nb3Al, Nb3Ge, Nb3(Al0.75Ge0.25), and V3Si were compacted by explosive shock waves. The superconducting properties of these materials were measured before and after compaction and it was found that regardless of the sign of the pressure coefficient, the transition temperature is always lowered. The decrease in transition temperature is associated with a decrease in the particle diameter. The shock wave passage through a 3Nb:1Ge powder mixture leads to the formation of at least one compound (probably Nb5Ge3). However, the formation of the A15 compound Nb3Ge is not observed. Elemental niobium powder can be compacted by converging shock waves close to the expected value of the bulk density. Under special circumstances a partial remelting in the center of the sample is observed.
Otto, G. H.↗
Impedances of Li/SO2 cells retrieved from the Long Duration Exposure Facility (LDEF satellite) and comparison with cells stored terrestrially
Impedances were measured on several Li/SO2 cells retrieved from the Long Duration Exposure Facility (LDEF) satellite. These cells were used to power instruments and recorders and had all been partially or fully discharged. Impedances were also measured on several cells that were stored in cold storage since manufacture. Unfortunately, none of the cells stored terrestrially had undergone any discharge, whereas all of the cells on the satellite were at least partially discharged early in the mission and then remained on orbit for about 5 years further. It has been observed by others that storage of an Li/SO2 cell after partial discharge, increases the resistance and thickness of the passive film on the Li electrode, as indicated by an increase in the time for recovery of voltage when a load is applied (voltage lag), or in some cases by an inability of a cell to sustain a normal current after such storage. Since the cells stored terrestrially were not discharged in the same manner as the LDEF cells, a direct comparison cannot be made. Thus, the effects of the space environment cannot be separated from the effects of storage after partial discharge. It is believed that the increases in impedance in the LDEF cells are largely due to the storage upon partial discharge rather than the effects of the space environment.
Reid, Margaret A.↗
Stacking faults and interface roughening in semipolar (202{sup ¯}1{sup ¯}) single InGaN quantum wells for long wavelength emission
The microstructure of InGaN single quantum wells (QWs) grown in semipolar (202{sup ¯}1{sup ¯}) orientation on GaN substrates was studied by transmission electron microscopy. Stress relaxation in the lattice mismatch In{sub x}Ga{sub 1−x}N layer was realized by forming partial misfit dislocations associated with basal plane stacking faults (BPSFs). For given composition x = 0.24, BPSFs formation was observed when the QW thickness exceeded 4 nm. The high density of partial threading dislocations that bound the BPSFs is detrimental to light-emitting device performance. Interface roughening (faceting) was observed for both upper and lower QW interfaces (more pronounced for upper interface) and was found to increase with the thickness of the QW. BPSFs had a tendency to nucleate at roughened interface valleys.
36 MATERIALS SCIENCE↗
Direct Linearization and Adjoint Approaches to Evaluation of Atmospheric Weighting Functions and Surface Partial Derivatives: General Principles, Synergy and Areas of Application
This slide presentation reviews the observable radiances as functions of atmospheric parameters and of surface parameters; the mathematics of atmospheric weighting functions (WFs) and surface partial derivatives (PDs) are presented; and the equation of the forward radiative transfer (RT) problem is presented. For non-scattering atmospheres this can be done analytically, and all WFs and PDs can be computed analytically using the direct linearization approach. For scattering atmospheres, in general case, the solution of the forward RT problem can be obtained only numerically, but we need only two numerical solutions: one of the forward RT problem and one of the adjoint RT problem to compute all WFs and PDs we can think of. In this presentation we discuss applications of both the linearization and adjoint approaches
remote sensing↗
Extended quantum anomalous Hall states in graphene/hBN moiré superlattices
Electrons in topological flat bands can form new topological states driven by correlation effects. The pentalayer rhombohedral graphene/hexagonal boron nitride (hBN) moiré superlattice was shown to host fractional quantum anomalous Hall effect (FQAHE) at approximately 400 mK, triggering discussions around the underlying mechanism and role of moiré effects. In particular, new electron crystal states with non-trivial topology have been proposed. Here, in this paper, we report electrical transport measurements in rhombohedral pentalayer and tetralayer graphene/hBN moiré superlattices at electronic temperatures down to below 40 mK. We observed two more fractional quantum anomalous Hall (FQAH) states and smaller R xx values in pentalayer devices than those previously reported. In the new tetralayer device, we observed FQAHE at moiré filling factors v = 3/5 and 2/3. With a small current at the base temperature, we observed a new extended quantum anomalous Hall (EQAH) state and magnetic hysteresis, where R xy = h/e 2 and vanishing R xx spans a wide range of v from 0.5 to 1.3. At increased temperature or current, EQAH states disappear and partially transition into the FQAH liquid. Furthermore, we observed displacement field-induced quantum phase transitions from the EQAH states to the Fermi liquid, FQAH liquid and the likely composite Fermi liquid. Our observations established a new topological phase of electrons with quantized Hall resistance at zero magnetic field and enriched the emergent quantum phenomena in materials with topological flat bands.
36 MATERIALS SCIENCE↗
A microflare-related activation of a filament observed in H-alpha and C IV lines
A filament in active region AR 2717 was observed in two lines formed at different temperatures (H-alpha at 10 exp 4 K and C IV at 10 exp 5 K) with the multichannel-double-pass (MSDP) spectrograph and the ultraviolet spectrometer and polarimeter (UVSP). The partial disparition brusque (DB) of the filament as observed in H-alpha was due to the heating of a filament section in the vicinity of a bright point. A propagating disturbance followed this event. A detailed analysis of C IV rasters shows that this disturbance was not a passive perturbation, but was itself triggering active phenomena at various locations along its path, resulting in energy releases. It is suggested that this propagation of brightness was due to fast successive reconnections between fine looplike structures of the filament.
Schmieder, B.↗
The magnetic field of Neptune
A model is given of the planetary magnetic field of Neptune based on a spherical harmonic analysis of the observations obtained by the Voyager 2. Generalized inverse techniques are used to partially solve a severely underdetermined inverse problem, and the resulting model is nonunique since the observations are limited in spatial distribution. Dipole, quadrupole, and octupole coefficients are estimated independently of other terms, and the parameters are shown to be well constrained by the measurement data. The large-scale features of the magnetic field including dipole tilt, offset, and harmonic content are found to characterize a magnetic field that is similar to that of Uranus. The traits of Neptune's magnetic field are theorized to relate to the 'ice' interior of the planet, and the dynamo-field generation reflects this poorly conducting planet.
Connerney, J. E. P.↗