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NASA Quarantine Program

This presentation describes the historical context and contemporary implementation of the NASA pre-launch quarantine program known as the Health Stabilization Program (HSP).

Quarantine↗

Nonlinear Dynamic Analyses of STS-1 Forward RCS Oxidizer Tank Structural Failure

At liftoff of the first Space Shuttle mission, a strong ignition overpressure pulse excited the stack. The frequency of the experienced pressure wave exceeded pre-launch predictions, and resulted in high, alternating normal accelerations along the length of the vehicle. As result of this unexpected loading, an oxidizer tank support strut in the orbiter’s forward reaction control system module failed in buckling under axial compression, which could have led to loss of the mission, crew, and vehicle. This incident is investigated in more detail using linear and nonlinear finite element analyses, complementing previous analyses with classical structural mechanics. The results of these analyses are examined to provide additional insight into the accident and to better inform future design decisions for modern space vehicle systems and structures.

Space Shuttle↗

Nonlinear Dynamic Analyses of STS-1 Forward RCS Oxidizer Tank Structural Failure

At liftoff of the first Space Shuttle mission, a strong ignition overpressure pulse excited the stack. The frequency of the experienced pressure wave exceeded pre-launch predictions, and resulted in high, alternating normal accelerations along the length of the vehicle. As result of this unexpected loading, an oxidizer tank support strut in the orbiter’s forward reaction control system module failed in buckling under axial compression, which could have led to loss of the mission, crew, and vehicle. This incident is investigated in more detail using linear and nonlinear finite element analyses, complementing previous analyses with classical structural mechanics. The results of these analyses are examined to provide additional insight into the accident and to better inform future design decisions for modern space vehicle systems and structures.

Space Shuttle↗

Earth Independent Medical Operations (EIMO) Training Technical Interchange Meeting, 26th October 2023: Background and Summary of Discussion

On 26th October 2023, ExMC convened a panel of Subject Matter Experts (SMEs) from NASA, broadly representing Headquarters, the Human Research Program, Medical Operations, the Human Health and Performance Directorate at JSC, the Health and Medical Technical Authority, the Flight Operations Directorate, and representation from other Centers including: Ames Research Center (ARC), and Glenn Research Center (GRC). Representatives from the Canadian Space Agency also participated in this TIM. In addition, SMEs from industry included representation from the following entities: Axiom Space, Space Exploration Technologies Corporation, Level Ex, Shiny Box Interactive. Additional SMEs from academia included: University of Houston, Touro University, Weill Cornell Medical College and the Translational Research Institute for Space Health at Baylor College of Medicine. This group of stakeholders discussed the training issues related to facilitating EIMO. Sub-topics for this discussion included the following: - Pre-launch medical curriculum development - Ground-based training on medical hardware - Dental health - Behavioral health - Telemedicine - Just-in-time training - Simulation-based training (extended reality)

CMO Training↗

Fast Radiative Transfer Model and Retrieval Algorithm Development for Satellite Remote Sensing Applications

The radiative transfer model (RTM) has a wide range of applications in satellite remote sensing and atmospheric radiation studies. For example, it can be used as a forward model for an inversion algorithm and a satellite data assimilation system, or as a L1 data simulator for pre-launch end-to-end satellite sensor performance studies. However, millions of line-by-line (LBL) radiative transfer calculations at fine monochromatic frequencies are needed in order to properly calculate spectral contributions of water vapor and trace gases in the atmosphere in infrared and solar spectral regions. Therefore, fast, and accurate radiative transfer models are needed. A Principal Component-based radiative transfer model (PCRTM) was developed at NASA Langley to fulfil this need. The PCRTM can simulate the top-of-atmosphere (TOA) radiance or reflectance spectra from 250 nm to 2000 micrometers with several orders of magnitude faster speed as compared to a LBL RTM. It is also extremely accurate compared to LBL RTM benchmarks. The PCRTM model has been developed for hyperspectral sensors such as AIRS, CrIS, IASI, NAST-I, SHIS, CPF, TEMPO, EMIT, OMI, and SCIAMACHY. By using the PCRTM as forward model for an inversion algorithm, one can reduce the data dimension significantly while maintaining original information content by compressing the TOA radiance spectrum into PC-scores. The PCRTM can directly compute the PC-scores and their derivatives with respect to retrieved parameters. Examples of using various PCRTM inversion algorithms to retrieve atmospheric temperature, water vapor, and trace gas profiles, as well as cloud and surface properties from satellite hyperspectral remote sensors will be given. Some of the algorithms have been transitioned to NASA's Goddard Earth Sciences Data and Information Services Center (GES DISC) for public access of high-quality L2 and L3 data.

Xu Liu↗

JPSS-3 VIIRS Version 2 at-Launch Relative Spectral Response Characterization

The JPSS-3 VIIRS sensor has completed its pre-launch test program including measurements for characterizing the VIIRS relative spectral response (RSR) in support of the Sensor and Environmental Data Records (SDR and EDR, resp.) that will be generated from VIIRS on-orbit observations. Government team subject matter experts of the VIIRS DAWG have analyzed the VIIRS spectral measurements and produced the VIIRS spectral characterization, in the form of band-average and supporting detector level RSR for each VIIRS band. The characterization is based upon the analysis of independent SpMA dual monochromator (all bands) and GSFC GLAMR laser system (reflectance bands only) spectral measurements. The SpMA and GLAMR measurements for reflectance bands (DNB LGS and MGS, I1-I3, M1-M11) were combined to produce a “fused” RSR. For emissive bands (I4, I5, M12-M16), the SpMA measurements provide the characterization. The effort has led to the VIIRS Version 2 RSR release, the official at-launch RSR characterization for the JPSS-3 VIIRS mission. The JPSS-3 RSR are a close match to those of JPSS-2. An assessment on compliance with spectral performance metrics finds that VIIRS band-average RSR are compliant on nearly all metrics, with only a single minor exception. The Version 2 RSR release is available under EAR99 restrictions to the science community on the restricted access NASA Sharepoint.

Chris Moeller↗

BioSentinel: Leading the Way for Deep Space CubeSat Missions

Flagship science missions are not alone in Deep Space thanks to BioSentinel, a 6U spacecraft launched on Artemis-1. BioSentinel is one of the longest operating CubeSats beyond cislunar space. The subsystems and COTS components of the BioSentinel bus are a template for future deep space missions, and the lessons learned from over a year of operations will enable improved performance for the next missions. BioSentinel achieved its unprecedented performance for an SLS secondary payload due to preparation, planning, and a robust design. Pre-launch antenna and interface testing with both DSN and ESA confirmed command and data pathways and allowed for operational flexibility in the critical early hours post-deployment. Mission Operations simulations prior to launch identified potential risks and primed operators to respond in flight, preparing the team to react quickly to successfully detumble the spacecraft and enter a power-positive state. The spacecraft would not have survived without the inclusion of the trailblazing 3D-printed composite cold gas propulsion system. The non-standard tank geometry enabled efficient use of the limited space available in the CubeSat, as well as the capability to detumble the spacecraft and manage momentum, while providing sufficient margin to execute potential delta-V maneuvers. The Iris radio has operated for over 18 months with no significant issues. Initial Iris performance estimates have been accurate throughout the mission. BioSentinel continues to collect data on thermal conditions and to validate our performance models with real-world knowledge. We have received exemplary support from our DSN partners. Following the conclusion of the primary science mission, the Linear Energy Transfer (LET) Spectrometer continued to collect solar and galactic radiation data from its location in heliocentric orbit. The free space dataset offered by the BioSentinel LET is a valuable source of data for model validation and future mission planning. As the spacecraft travels farther from Earth it is poised to provide longitudinally distributed measurements of solar particle events during solar maximum. The lessons learned from BioSentinel suggest key areas to enhance performance. The ability to upload modified flight software can increase the stability of memory management. Additional heaters in the propulsion system design have already proven successful on the Starling mission. Streamlining mission operations can reduce costs, increase data return, and better utilize DSN time. Enhancements such as these will facilitate reliable, long-duration deep space exploration using the proven BioSentinel 6U CubeSat bus.

BioSentinel↗

BioSentinel: Forging the path for Deep Space CubeSat Missions

The BioSentinel mission was launched in 2022 aboard the SLS launch vehicle as part of the Artemis-I campaign and continues mission operations into 2024. The 6U CubeSat has been characterizing deep space radiation at large distances from Earth. This presentation gives a status of the mission performance to date, as well as some of the lessons learned from project. BioSentinel has achieved unprecedented performance as an SLS secondary payload due to preparation, planning, and a robust design. Pre-launch antenna and interface testing with both DSN and ESA confirmed command and data pathways and allowed for operational flexibility in the critical early hours post-deployment. Mission Operations simulations prior to launch identified potential risks and trained operators to respond in flight, preparing the team to react quickly and successfully to detumble the spacecraft and enter a power-positive state. The spacecraft would not have survived without the inclusion of the trailblazing 3D-printed composite cold gas propulsion system. The non-standard tank geometry enabled efficient use of the limited space available in the CubeSat form factor as well as the capability to detumble the spacecraft and manage momentum for extended mission durations, while providing sufficient margin to execute potential delta-V maneuvers. Following the conclusion of the primary science mission, the Linear Energy Transfer (LET) Spectrometer has continued to collect solar and galactic radiation data from its unique location in heliocentric orbit. The free space dataset offered by the BioSentinel LET is a valuable source of data for both model validation and future mission planning. As the spacecraft travels farther from Earth it is poised to provide longitudinally distributed measurements of solar particle events during solar maximum. NASA Ames led development of the BioSentinel spacecraft to operate for long durations in deep space. The novel subsystems and COTS components that comprise the BioSentinel bus can serve as a template for future deep space missions, while the lessons the team has learned from well over a year of continuous operations will enable improved performance in the generation of deep space CubeSat missions.

BioSentinel↗

A Vacuum-Compatible, Spectrally Tunable, Flat Panel Uniform Source for Testing Large Aperture Earth Observation Systems

Labsphere, Inc in conjunction with NASA GSFC and Genesis Engineering Solutions inc. has developed an innovative, fully T-VAC compatible, calibration spectro-radiometric illumination source with a highly uniform large-area rectangular flat panel active area. This source leverages a new shaped integration geometry to achieve high uniformity over a large active output area while maintaining a smaller and more robust overall form-factor when compared to previous designs or integrating spheres. This new illuminator also leverages a set of selectable LED arrays as well as broadband tungsten-halogen sources to provide multi-level, wide spectrum reference illumination to the VIIRS instrument over all optical sensor bands during pre-launch testing. The first unit has been demonstrated to meet its requirements using ambient technology and a fully-vacuum-compatible second unit is planned to allow testing for T-VAC campaigns. This technology is both flexible and capable of meeting the needs of many other instruments/missions requiring this type of test/calibration capability.

Jeff Holt↗

Upping the TEMPO on Air Pollution Observations from Space for Enhanced Science Applications

The Tropospheric Emissions: Monitoring of Pollution (TEMPO) mission was launched into Geostationary Earth Orbit (GEO) to 91°W longitude on April 7, 2023, and had a successful First Light period from July 31 – August 2 where the first hourly daytime scans across the TEMPO Field of Regard (FoR) covering greater North America were performed. First light images of nitrogen dioxide (NO2) were released to the public on August 24. In addition to NO2, TEMPO will provide hourly daytime observations of formaldehyde (HCHO), sulfur dioxide (SO2), ozone (O3), bromine (BrO), water vapor (H2O), and aerosols, at high spatial resolution (~2.0 x 4.75 km2) across the FoR. The hyperspectral ultraviolet-to-visible measurements from the TEMPO imaging grating spectrometer will permit an ozone profile retrieval capable of monitoring the diurnal evolution of ozone in the planetary boundary layer. The non-standard or special scan operations of TEMPO at sub-hourly frequency (e.g., 2-10 minutes) over selected slices of the FoR will further enhance monitoring capabilities during air quality disasters (e.g., wildfires, volcanic eruptions, dust storms, industrial accidents), research studies, and field campaign operations. A large diversity of stakeholders and end-users have been engaged in the TEMPO Early Adopters Program, supported by the NASA Applied Sciences Program, which aims to enhance health and air quality applications and maximize the societal benefit of TEMPO data when operational data becomes publicly available in the spring of 2024. Key outcomes from the Early Adopters Program include the pre-launch use of TEMPO proxy data to prepare the community for operational data, tailoring the data dissemination and visualization tools for the mission based on user needs, and enhancing the TEMPO special operations component of the mission through early adopter studies. This presentation will provide the latest TEMPO mission and Early Adopters Program updates, initiatives from the TEMPO special operations, and early demonstrations of science applications enabled through TEMPO data, while also showcasing the First Light imagery.

Air Quality↗

Prelaunch Spectral Characterization of the Operational Land Imager-2

The Landsat-9 satellite, launched in September 2021, carries the Operational Land Imager-2 (OLI-2) as one of its payloads. This instrument is a clone of the Landsat-8 OLI and its mission is to continue the operational land imaging of the Landsat program. The OLI-2 instrument is not significantly different from OLI though the instrument-level pre-launch spectral characterization process was much improved. The focal plane modules used on OLI-2 were manufactured as spares for OLI and much of the spectral characterization of the components was performed for OLI. However, while the spectral response of the fully assembled OLI was characterized by a double monochromator system, the OLI-2 spectral characterization made use of the Goddard Laser for Absolute Measurement of Radiance (GLAMR). GLAMR is a system of tunable lasers that cover 350–2500 nm which are fiber-coupled to a 30 in integrating sphere permanently monitored by NIST-traceable radiometers. GLAMR allowed the spectral characterization of every detector of the OLI-2 focal plane in nominal imaging conditions. The spectral performance of the OLI-2 was, in general, much better than requirements. The final relative spectral responses (RSRs) represent the best characterization any Landsat instrument spectral response. This paper will cover the results of the spectral characterization from the component-level to the instrument-level of the Landsat-9 OLI-2.

Landsat-9↗

STS-1 Forward RCS Oxidizer Tank Subsystem Structural Failure Assessment

The launch of the Space Shuttle Columbia on STS-1 marked the beginning of a new era in American spaceflight. It was the only crewed first flight of a launch vehicle to date, and was also the first crewed system to use large solid rockets as primary propulsion. A potential disaster was narrowly averted at liftoff when an ignition overpressure pulse swept up the Shuttle stack. The frequency of this transient shock wave exceeded pre-launch predictions, and resulted in high, alternating normal accelerations along the length of the vehicle. Among the results of this unexpected loading was failure of an oxidizer tank support strut in the orbiter’s forward reaction control system module, which could have led to loss of the mission, crew, and vehicle. This particular incident is investigated in more detail using classical structural mechanics and finite element analyses, and the results are discussed to provide additional insight.

space shuttle↗

The ARGOS Instrument for Stratospheric Aerosol Measurements

Atmospheric aerosols represent an important component of the Earth’s climate system because they can contribute both positive and negative forcing to the energy budget. We are developing the Aerosol Radiometer for Global Observations of the Stratosphere (ARGOS) instrument to provide improved measurements of stratospheric aerosols in a compact package. ARGOS makes limb scattering measurements from space in eight directions simultaneously, using two near-IR wavelengths for each viewing direction. The combination of forward and backward scattering views along the orbit track gives additional information to constrain the aerosol phase function and size distribution. Cross-track views provide expanded spatial coverage. ARGOS will have a demonstration flight through a hosted payload provider in the fall of 2024. The instrument has completed pre-launch environmental testing and radiometric characterization tests. The hosted payload approach offers advantages in size, weight, and power margins for instrument design compared to other approaches, with significant benefits in terms of reducing infrastructure requirements for the instrument team.

stratospheric aerosol↗

Performance Evaluation of Clouds and the Earth’s Radiant Energy System (CERES) Instruments in Generating A Stable Earth Radiation Budget Multi-Decadal Data Record

Clouds and the Earth’s Radiant Energy System (CERES) instrument is designed to measure the earth-reflected solar and earth-emitted longwave radiances, two components of the Earth Radiation Budget. CERES instrument measure radiances in 0.3 to 5.0 micron region with Shortwave (SW) sensor, 0.3 to >100 microns with Total (TOT) sensor, and either 8 - 12 micron with Window (WN) sensor or 5 – 35 micron with longwave (LW) sensor. The on-board internal calibration module (ICM) is used to monitor the stability of the sensors and to correct the pre-launch determined sensor gains for radiance calculations. Corrections for spectral changes occurring in different wavelength regions observed through vicarious studies were applied to sensor response function used in radiance determination. The resulting global flux long term trends from each instrument have shown consistent behavior and provided a stable global record of Top of the Atmosphere (TOA) shortwave and longwave fluxes for the Earth radiation budget climate data record.

Clouds and Earth Radiation Energy System (CERES)↗

NASA CARA Prelaunch Analysis and Process

NASA implemented an official Procedural Requirement (NPR) 8079.1 in June 2023, establishing the minimum collision avoidance requirements and associated operational protocols for NASA space flight programs, projects, and spacecraft to protect the space environment by reducing the risk of collision to an acceptable level. Part of the requirement employs a two-fold approach to analyze the satellite design process with conjunction assessment and risk mitigation in mind, during the pre-launch process, led by the Conjunction Assessment Risk Analysis (CARA) Program for non-Human Space Flight (HSF) Missions. This presentation outlines CARA coordination with missions, informed by the NPR, that spans early mission development to operations. CARA is an Agency-level resource that provides support to all NASA non-HSF missions. CARA protects the orbital environment from collision between NASA non-HSF missions and other tracked on-orbit objects. During the pre-formulation and formulation phases, NASA missions undergo a series of conjunction assessment analyses captured in the Orbital Collision Avoidance Plan (OCAP) prior to transitioning to the implementation phase (typically at the Preliminary Design Review (PDR) or equivalent). The OCAP analyses consist of a thorough review of the spacecraft(s) orbit selection and placement, deployment, cataloguing performance, trackability, ephemeris generation, conjunction mitigation options, autonomous maneuvering, and risk assessment parameters which are performed by a dedicated CARA Analysis Team. The results of these analyses, CARA’s formal recommendations, and the mission’s methods for implementing them, are documented in the OCAP. The intent of engaging in this process so early in the mission design phase, is to ensure that conjunction assessment is considered from the outset, thus mitigating costly design changes and operational risks down the road. NASA missions are also required to coordinate their operational processes and conjunction mitigation procedures with CARA in a Conjunction Assessment Operations Implementation Agreement (CAOIA). The aim of this process is to document the conjunction assessment screening process, conjunction risk assessment parameters, conjunction mitigation steps, flight dynamics operations concepts and maneuvers, and the communication and coordination process between the mission’s project manager and CARA. The intent of the CAOIA document is for it to be completed iteratively, and as missions update these elements, corresponding changes are made in the CAOIA. With this process in place, the engagement and coordination between the missions and CARA from early in the design process into mission operations, helps to ensure that missions not only have a robust conjunction assessment concept of operations to reduce conjunction risk for space sustainability, but are also able to achieve their science goals and have a successful mission.

conjunction assessment↗

Performance Evaluation of Clouds and the Earth’s Radiant Energy System (CERES) Instruments in Generating A Stable Earth Radiation Budget Multi-Decadal Data Record

Clouds and the Earth’s Radiant Energy System (CERES) instrument is designed to measure the earth-reflected solar and earth-emitted longwave radiances, two components of the Earth Radiation Budget. CERES instrument measure radiances in 0.3 to 5.0 micron region with Shortwave (SW) sensor, 0.3 to >100 microns with Total (TOT) sensor, and either 8 - 12 micron with Window (WN) sensor or 5 – 35 micron with longwave (LW) sensor. The on-board internal calibration module (ICM) is used to monitor the stability of the sensors and to correct the pre-launch determined sensor gains for radiance calculations. Corrections for spectral changes occurring in different wavelength regions observed through vicarious studies were applied to sensor response function used in radiance determination. The resulting global flux long term trends from each instrument have shown consistent behavior and provided a stable global record of Top of the Atmosphere (TOA) shortwave and longwave fluxes for the Earth radiation budget climate data record.

Earth Radiation Budget↗

Insights and Observations from Operating a Geostationary Laser Communication Relay Mission: Operational Lessons from NASA’s Laser Communications Relay Demonstration (LCRD) and Associated Optical Ground Stations (OGSs)

The NASA Laser Communications Relay Demonstration (LCRD) has operated on orbit for the last two years. The LCRD Mission consists of a geostationary payload and two optical ground stations. This technology demonstration mission is NASA’s first two-way, end-to-end optical communications relay. LCRD has performed an extensive experiment campaign to analyze laser communication performance for extended operations. This paper discusses various lessons learned while operating the optical relay mission from early commissioning through two years of operation. Before launch, engineers and operators performed analyses to generate operational procedures based on expected LCRD performance. However, only operation on orbit can supply actual performance data. Additional topics covered in this paper include pre-launch and commissioning testing, ephemeris generation and cadence, environmental configurations, and accommodation concerns. The addition of Integrated Laser Communications Relay Demonstration Low Earth Orbit User Modem and Amplifier Terminal (ILLUMA-T) to the optical network supplemented the LCRD team’s operational experiences and enabled them to garner new lessons learned. The authors of this paper include day-to-day flight leads who consulted with on-console operators, engineers, and subject matter experts analyzing data and experiment results to gather the lessons learned described in this paper. LCRD is a joint project involving NASA Goddard Space Flight Center (GSFC), the California Institute of Technology Jet Propulsion Laboratory (JPL), and Massachusetts Institute of Technology Lincoln Laboratory (MIT LL).

Lessons Learned↗

An Overview of Experiments and Modeling of Polysiloxane-Coated Thermal Protection Systems for Missions to Mars, Titan, and Beyond.

Phenolic Impregnated Carbon Ablator (PICA) gained heritage during the historic Stardust mission, where it successfully returned samples from a comet’s tail and has since been instrumental in delivering payloads to the surface of Mars [1-3]. Most recently, PICA enabled the safe return of samples collected from asteroid Bennu as part of the OSIRIS-REx mission. This rich legacy underscores PICA’s critical role in allowing NASA’s most ambitious exploration missions. However, the friable nature of its phenolic phase presents challenges during handling and pre-launch activities. To mitigate this issue, PICA is coated with a polysiloxane resin system, which serves to suppress particulate dispersion and thereby safeguard spacecraft components. A comprehensive understanding of the polysiloxane resin’s behavior is imperative, as it profoundly shapes the material response of PICA during atmospheric entry by influencing its thermal and oxidative stability. This influence extends to thermocouple plugs embedded within thermal protection systems. These plugs have demonstrated their significance in missions such as Mars Science Laboratory (MSL) and Mars 2020, where the MEDLI and MEDLI2 instrumentation suites delivered in-valuable insights into the performance of thermal protection systems during entry into the Martian atmosphere [4]. Looking ahead, missions such as Dragonfly, set to descend into Titan’s dense atmosphere, aim to leverage advanced sensor technologies to further refine our understanding of thermal protection response [5]. Moreover, thermocouple plugs play an essential role in validating cutting-edge material response models, such as those pioneered under NASA’s Entry Systems Modeling Project (ESM), designed, in-part, to predict the operational integrity of thermal protection systems under the extreme stresses of atmospheric entry. To achieve these modeling goals, ground-based experiments are crucial to provide the foundational data necessary for developing and refining these predictive tools. To this end, an extensive test campaign was conducted at the Hypersonic Materials Environmental Test System (HyMETS) to investigate the high-temperature behavior of the polysiloxane resin in an air environment [6]. These experiments revealed critical phenomena, including the formation of a silicon oxycarbide layer that enhances oxidation resistance, moderates surface temperatures, and alters in-depth thermal response. Building on these findings, subsequent tests were designed to simulate atmospheric entry conditions in reactive gases, such as CO2 and N2, to mimic the environments of Mars and Titan, respectively, as well as non-reactive gases representing the atmospheres of the Ice Giants (Neptune and Uranus). A heating rate dependent decomposition mechanism has been identified for the polysiloxane resin under oxidizing conditions (Fig. 1). In the initial stage, the resin and the underlying thermal protection system undergo pyrolysis, rapidly generating a thin amorphous silicon oxycarbide interwoven with carbonaceous char and residual fibers from PICA. During the second stage, the nascent oxide layer establishes a robust, oxidation-resistant thermal barrier coating, which significantly impedes heat transfer to the underlying carbonaceous char, resulting in a stagnation of the surface temperature. A key factor contributing to this thermal resistance is the low recombination efficiency of atomic oxygen (γ), which further diminishes the heat load on the material’s interior layers [7]. Moreover, as the surface temperature stagnates, the silicon oxycarbide phase separates into distinct regions of silica and free graphite. Ultimately, when the heat flux reaches a critical threshold, a third stage is triggered, leading to the breakdown of the coating through carbothermal reduction, exposing the underlying char layer. This exposure leads to a dramatic surface temperature spike, driven by highly exothermic reactions between atomic oxygen and the char layer, further accelerating material degradation. A detailed mass and heat transfer model of PICA coated with polysiloxane resin was implemented in the Porous material Analysis Toolbox based on OpenFOAM, PATO [8]. The initial stage was considered negligible in this model because the resin decomposition occurs rapidly within a thin surface layer. Instead, the coating was directly considered as an oxygen-resistant thermal barrier coating. For the second stage, the thin amorphous silicon oxycarbide was treated as a pure silica surface to simplify the thermochemical behavior. The model ac-counts for surface equilibrium processes using representative elements of the coating-environment system. For the third stage, specific boundary conditions were developed to estimate the onset and progression of the coating removal. Two-dimensional material response simulations were conducted to compare uncoated and coated PICA using boundary conditions calibrated with HyMETS data. Fig. 2 illustrates that the simulations closely align with experimental data, successfully reproducing measured temperature profiles. This work will include the latest advancements in the coating model, including the calibration of recombination of atomic oxygen at the surface during the second phase. These simulated results will be further validated against additional CO2 data points from HyMETS, reinforcing the models’ predictive capabilities. These mechanisms and their effects on thermal protection systems, including thermochemical behavior and thermocouple probe performance in extreme environments, provide crucial insights for optimizing spacecraft designs that safeguard scientific payload and ensure mission success in future planetary exploration endeavors.

Active Oxidation↗