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At least 631 records · Page 35

Field Demonstration of DNAPL Dehalogenation Using Emulsified Zero-Valent Iron

This paper describes the results of the first field-scale demonstration conducted to evaluate the performance of nano-scale emulsified zero-valent iron (EZVI) injected into the saturated zone to enhance in situ dehalogenation of dense, non-aqueous phase liquids (DNAPLs) containing trichloroethene (TCE). EZVI is an innovative and emerging remediation technology. EZVI is a surfactant-stabilized, biodegradable emulsion that forms emulsion droplets consisting of an oil-liquid membrane surrounding zero-valent iron (ZVI) particles in water. EZVI was injected over a five day period into eight wells in a demonstration test area within a larger DNAPL source area at NASA's Launch Complex 34 (LC34) using a pressure pulse injection method. Soil and groundwater samples were collected before and after treatment and analyzed for volatile organic compounds (V005) to evaluate the changes in VOC mass, concentration and mass flux. Significant reductions in TCE soil concentrations (>80%) were observed at four of the six soil sampling locations within 90 days of EZVI injection. Somewhat lower reductions were observed at the other two soil sampling locations where visual observations suggest that most of the EZVI migrated up above the target treatment depth. Significant reductions in TCE groundwater concentrations (57 to 100%) were observed at all depths targeted with EZVI. Groundwater samples from the treatment area also showed significant increases in the concentrations of cis-1,2-dichloroethene (cDCE), vinyl chloride (VC) and ethene. The decrease in concentrations of TCE in soil and groundwater samples following treatment with EZVI is believed to be due to abiotic degradation associated with the ZVI as well as biodegradation enhanced by the presence of the oil and surfactant in the EZVI emulsion.

Quinn, Jacqueline↗

Hot plasma composition results from the S3-3 spacecraft

The S3-3 satellite discovered the principal auroral acceleration region at altitudes of about 1 R(E) over the auroral zone. Intense fluxes of upward flowing O(+) and H(+) ions with keV energies were commonly observed in this region of the magnetosphere. The detailed morphology of these upflowing ions is described, including their latitude, local time, altitude, and magnetic activity dependences and their relationship to the trapped keV electron population. The first measurements of the composition of the trapped keV ions in the radiation belts are also described, showing the importance of the ionospheric source term to the storm time population of ions with energies equal to or less than 16 keV/e.

Sharp, R. D.↗

Interannual Variability of Martian Global Dust Storms: Simulations with a Low-Order Model of the General Circulation

We present simulations of the interannual variability of martian global dust storms (GDSs) with a simplified low-order model (LOM) of the general circulation. The simplified model allows one to conduct computationally fast long-term simulations of the martian climate system. The LOM is constructed by Galerkin projection of a 2D (zonally averaged) general circulation model (GCM) onto a truncated set of basis functions. The resulting LOM consists of 12 coupled nonlinear ordinary differential equations describing atmospheric dynamics and dust transport within the Hadley cell. The forcing of the model is described by simplified physics based on Newtonian cooling and Rayleigh friction. The atmosphere and surface are coupled: atmospheric heating depends on the dustiness of the atmosphere, and the surface dust source depends on the strength of the atmospheric winds. Parameters of the model are tuned to fit the output of the NASA AMES GCM and the fit is generally very good. Interannual variability of GDSs is possible in the IBM, but only when stochastic forcing is added to the model. The stochastic forcing could be provided by transient weather systems or some surface process such as redistribution of the sand particles in storm generating zones on the surface. The results are sensitive to the value of the saltation threshold, which hints at a possible feedback between saltation threshold and dust storm activity. According to this hypothesis, erodable material builds up its a result of a local process, whose effect is to lower the saltation threshold until a GDS occurs. The saltation threshold adjusts its value so that dust storms are barely able to occur.

Pankine, A. A.↗

Geospatial Cluster Analysis of the State, Duration and Severity of Drought Over Paraíba State, Northeastern Brazil

Droughts threaten water resources, agriculture, socio-economic activities and the population at the global and regional level, so identifying areas with homogeneous drought behaviors is an important consideration in improving the management of water resources. The objective of this study is to identify homogenous zones over Paraíba State in relation to the state, duration and severity of droughts that have occurred over the last 20 years (1998–2017) using hierarchical cluster analysis based on both gauge-measured and Tropical Rainfall Measuring Mission (TRMM) estimated rainfall data (TMPA 3B42). The drought series were calculated using the Standardized Precipitation Index (SPI) based on eight time scales and were grouped according to drought state, duration and severity time series. The integrated results of state, duration and severity of droughts indicate that there is a basis for dividing Paraíba State into two major regions (a) Zone I, formed by Mata Paraibana and Agreste Paraibano, and (b) Zone II, composed by Borborema and Sertão Paraibano. This division is evident when assessing short-term droughts, but in the case of long-term droughts, Paraíba State has a high similarity in terms of drought state, duration, and severity. Factors such as proximity to the ocean, active climatic systems, and the local relief configuration were identified as influencing the drought regime. Finally, it is concluded that TMPA rainfall estimates represent a valuable source of data to regionalize and identify drought patterns over this part of Brazil and that other studies of this type should be carried out to monitor these phenomena based on other satellite-based rainfall data, including the Global Precipitation Mission (GPM).

SPI↗

Effects Of Electric Field On Hydrocarbon-Fueled Flames

It has been observed that flames are susceptible to electric fields that are much weaker than the breakdown field strength of the flame gases. When an external electric field is imposed on a flame, the ions generated in the flame reaction zone drift in the direction of the electric forces exerted on them. The moving ions collide with the neutral species and change the velocity distribution in the affected region. This is often referred to as ionic wind effect. In addition, the removal of ions from the flame reaction zone can alter the chemical reaction pathway of the flame. On the other hand, the presence of space charges carried by moving ions affects the electric field distribution. As a result, the flame often changes its shape, location and color once an external electric field is applied. The interplay between the flame movement and the change of electric field makes it difficult to determine the flame location for a given configuration of electrodes and fuel source. In normal gravity, the buoyancy-induced flow often complicates the problem and hinders detailed study of the interaction between the flame and the electric field. In this work, the microgravity environment established at the 2.2 Second Drop Tower at the NASA Glenn Research Center is utilized to effectively remove the buoyant acceleration. The interaction between the flame and the electric field is studied in a one-dimensional domain. A specially designed electrode makes flame current measurements possible; thus, the mobility of ions, ion density, and ionic wind effect can be evaluated.

Yuan, Z.-G.↗

Massive Young Stellar Objects in the Galactic Center: Spectroscopic Identification from Spitzer/IRS Observations - 1

We present results from our spectroscopic study, using the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope, designed to identify massive young stellar objects (YSOs) in the Galactic Center (GC). Our sample of 107 YSO candidates was selected based on IRAC colors from the high spatial resolution, high sensitivity Spitzer/IRAC images in the Central Molecular Zone (CMZ), which spans the central approximately 300 pc region of the Milky Way Galaxy. We obtained IRS spectra over 5 micron to 35 micron using both high- and low-resolution IRS modules. We spectroscopically identify massive YSOs by the presence of a 15.4 micron shoulder on the absorption profile of 15 micron CO2 ice, suggestive of CO2 ice mixed with CH30H ice on grains. This 15.4 micron shoulder is clearly observed in 16 sources and possibly observed in an additional 19 sources. We show that 9 massive YSOs also reveal molecular gas-phase absorption from C02, C2H2, and/or HCN, which traces warm and dense gas in YSOs. Our results provide the first spectroscopic census of the massive YSO population in the GC. We fit YSO models to the observed spectral energy distributions and find YSO masses of 8 - 23 solar Mass, which generally agree with the masses derived from observed radio continuum emission. We find that about 50% of photometrically identified YSOs are confirmed with our spectroscopic study. This implies a preliminary star formation rate of approximately 0.07 solar mass/yr at the GC.

An, Deokkeun↗

Passive microwave measurements of temperature and salinity in coastal zones

Experimental methods and results from the maritime remote sensing (MARSEN) experiments using dual frequency microwave radiometer detecting systems on board aircraft are described. The radiometers were operated at 1.43 and 2.65 GHz and flown above U.S. Atlantic coastal areas, Chesapeake Bay, around Puerto Rico, and over the German Bight. The advanced switched radiometers used were configured to be independent of gain variations and errors originating from front-end losses and determined the absolute brightness temperatures to within a few tenths Kelvin. Corrections to the observed brightness temperature of the ocean are analytically defined, including accounts made for roughness, the cosmic background radiation, and the solar radio source. The coastal flight data for salinity gradients and surface temperatures were compared with sea truth measured from ships and found to be accurate to within 1 C and 1 pph.

Blume, H.-J. C.↗

Slowly cooled microgabbros 15555 and 15065

An experimental study involving equilibration of Apollo 15 samples 15555 and 15065 in high-purity iron capsules is described. Comparison of mineral zoning trends with the experimental sequence suggests that the early crystallizing phases in the rock maintained surface equilibrium with the liquid. Olivine and pyroxene chemistry indicates that 15555 cooled slightly more rapidly than 15065, which cooled at approximately 0.2-0.3 C/day. It is suggested that 15065 and 15555 represent liquid compositions, and that these liquids appear to have been fractionated during ascent through the crust (15065), or to have been derived from an olivine-pyroxene source (15555) with Fe/(Fe + Mg) approximately equal to 0.73 at a depth between 150-200 km.

Walker, D.↗

The Phase Space Structure Near Neptune Resonances in the Kuiper Belt

The Solar system beyond Neptune is believed to house a population of small primordial bodies left over from the planet formation process. The region up to heliocentric distance -50 AU (a.k.a. the Kuiper Belt) may be the source of the observed short-period comets. In this region, the phase space structure near orbital resonances with Neptune is of special interest for the long-term stability of orbits. There is reason to believe that a significant fraction (perhaps most) of the Kuiper Belt objects reside preferentially in these resonance locations. This paper describes the dynamics of small objects near the major orbital resonances with Neptune. Estimates of the widths of stable resonance zones as well as the properties of resonant orbits are obtained from the circular, planar restricted three-body model. Although this model does not contain the full complexity of the long-term orbital dynamics of Kuiper Belt objects subject to the full N-body perturbations of all the planets, it does provide a baseline for the phase space structure and properties of resonant orbits in the trans-Neptunian Solar system.

Malhotra, Renu↗

Exploiting the Convergence of Evidence in Satellite Data for Advanced Weather Index Insurance Design

The goal of drought-related weather index insurance (WII) is to protect smallholder farmers against the risk of weather shocks and to increase their agricultural productivity. Estimates of precipitation and vegetation greenness are the two dominant satellite datasets. However, ignoring additional moisture- and energy-related processes that influence the response of vegetation to rainfall leads to an incomplete representation of the hydrologic cycle. This study evaluates the added value of considering multiple independent satellite-based variables to design, calibrate, and validate weather insurance indices on the African continent. The satellite data include two rainfall datasets, soil moisture, the evaporative stress index (ESI), and vegetation greenness. We limit artificial advantages by resampling all datasets to the same spatial (0.25°) and temporal (monthly) resolution, although datasets with a higher spatial resolution might have an added value, if considered as the single source of information for localized applications. A higher correlation coefficient between the moisture-focused variables and the normalized difference vegetation index (NDVI), an indicator for vegetation vigor, provides evidence for the datasets’ capability to capture agricultural drought conditions on the ground. The Climate Hazards Group Infrared Precipitation with Stations (CHIRPS) rainfall dataset, soil moisture, and ESI show higher correlations with the (lagged) NDVI in large parts of Africa, for different land covers and various climate zones, than the African Rainfall Climatology, version 2 (ARC2), rainfall dataset, which is often used in WII. A comparison to drought years as reported by farmers in Ethiopia, Senegal, and Zambia indicates a high “hit rate” of all satellite-derived anomalies regarding the detection of severe droughts but limitations regarding moderate drought events.

drought↗

Geoid anomalies in the vicinity of subduction zones

The regional geoid of the southwest Pacific is matched reasonably well by results from a model of the upper mantle density structure (including slabs) associated with subduction zones of the region. Estimates of the geoid are obtained from Geos-3 and Seasat radar altimeter data. These data are very well suited to the task of detecting intermediate wavelength (600-4000 km) geopotential variations. Actually, subducting slabs can be expected to produce primarily intermediate and longer wavelength variations. Gravimetric profiles across trench/island arc complexes resolve primarily short wavelengths. The model represents subducting slabs as thin surfaces of anomalous mass per unit area. These surfaces are positioned using published seismicity results which detail the configuration of the Benioff zones. Crustal effects are ignored. Effects due to the contrast between the young thermal lithosphere of the behind-arc regions (marginal basins) and the older lithosphere seaward of the trench are modelled. Results indicate that the New Hebrides slab possesses an average areal density anomaly of about 300,000 gm/sq cm. This is about three times that which is estimated for the Tonga-Kermadec slab. Additional modelling suggests that slabs worldwide may be an important source of large, long wavelength gravity highs; i.e., they may contribute substantially to geopotential power of harmonic degree as low as three or four up to twenty or more.

Mcadoo, D. C.↗

The classification of stars from IRAS colors

IRAS stars with reliable fluxes at 12, 25, and 60 microns were investigated which fell into three main types: (1) bright; (2) O-rich; and (3) C-rich. The three star types had a tendency to separate in the IRAS color-color diagram such that almost nonoverlapping zones could be defined for the groups with about 70 percent of the stars included. The O-rich stars tended to be redder in (12) - (25) than bright stars, and C-rich stars tended to be redder in (25) - (60) than bright and O-rich stars. It is suggested that the flattening of the underlying continuum slope may be the dominant cause of the change in (12) - (25). Of the 4300 unassociated IRAS point sources considered, amost 50 percent are late-type stars.

Walker, H. J.↗

Electrode performance parameters for a radioisotope-powered AMTEC for space power applications

The alkali metal thermoelastic converter (AMTEC) is a device for the direct conversion of heat to electricity. Recently a design of an AMTEC using a radioisotope heat source was described, but the optimum condenser temperature was hotter than the temperatures used in the laboratory to develop the electrode performance model. Now laboratory experiments have confirmed the dependence of two model parameters over a broader range of condenser and electrode temperatures for two candidate electrode compositions. One parameter, the electrochemical exchange current density at the reaction interface, is independent of the condenser temperature, and depends only upon the collision rate of sodium at the reaction zone. The second parameter, a morphological parameter, which measures the mass transport resistance through the electrode, is independent of condenser and electrode temperatures for molybdenum electrodes. For rhodium-tungsten electrodes, however, this parameter increases for decreasing electrode temperature, indicating an activated mass transport mechanism such as surface diffusion.

Underwood, M. L.↗

Multi-Species Test of Ion Cyclotron Resonance Heating at High Altitudes

Observations of ion distributions and plasma waves obtained by the Dynamics Explorer 1 satellite in the high-altitude, nightside auroral zone are used to study ion energization for three ion species. A number of theoretical models have been proposed to account for the transverse heating of these ion populations. One of these, the ion cyclotron resonance heating (ICRH) mechanism, explains ion conic formation through ion cyclotron resonance with broadband electromagnetic wave turbulence in the vicinity of the characteristic ion cyclotron frequency. The cyclotron resonant heating of the ions by low- frequency electromagnetic waves is an important energy source for the transport of ions from the ionosphere to the magnetosphere. In this paper we test the applicability of the ICRH mechanism to three simultaneously heated and accelerated ion species by modelling the ion conic formation in terms of a resonant wave-particle interaction in which the ions extract energy from the portion of the broadband electromagnetic wave spectrum which includes the ion cyclotron frequency. Using a Monte Carlo technique we evaluate the ion heating produced by the electromagnetic turbulence at low frequencies and find that the wave amplitudes near the ion cyclotron frequencies are sufficient to explain the observed ion energies.

Persoon, A. M.↗

Multi-Species Test of Ion Cyclotron Resonance Heating at High Altitudes

Observations of ion distributions and plasma waves obtained by the Dynamics Explorer 1 satellite in the high-altitude, nightside auroral zone are used to study ion energization for three ion species. A number of theoretical models have been proposed to account for the transverse heating of these ion populations. One of these, the ion cyclotron resonance heating (ICRH) mechanism, explains ion conic formation through ion cyclotron resonance with broadband electromagnetic wave turbulence in the vicinity of the characteristic ion cyclotron frequency. The cyclotron resonant heating of the ions by low-frequency electromagnetic waves is an important energy source for the transport of ions from the ionosphere to the magnetosphere. In this paper we test the applicability of the ICRH mechanism to three simultaneously heated and accelerated ion species by modelling the ion conic formation in terms of a resonant wave-particle interaction in which the ions extract energy from the portion of the broadband electromagnetic wave spectrum which includes the ion cyclotron frequency. Using a Monte Carlo technique we evaluate the ion heating produced by the electromagnetic turbulence at low frequencies and find that the wave amplitudes near the ion cyclotron frequencies are sufficient to explain the observed ion energies.

Persoon, A. M.↗

Cathodoluminescence zoning and minor elements in forsterites from the Murchison (C2) and Allende (C3V) carbonaceous chondrites

Cathodoluminescence has been applied to look for textural features of olivine in carbonaceous meteorites relevant to the unresolved dispute over the origin of the olivine, whether from a vapor or a liquid. Cathodoluminescence photographs of forsterite grains in Murchison (C2) and Allende (C3) meteorites presented here reveal a blue core with planar boundaries to a red or dark rim. High-precision electron microprobe analyses have been performed which reveal unusually large amounts of the 'minor' elements Al, Ti, and Ca in the blue cores of these forsterites, suggesting formation by crystallization at high temperatures from a source rich in these metals. Following conclusions drawn from previous analyses of olivine in meteorites, it is argued that the minor element signature should be able to characterize olivines in micrometeorites and in deep-sea particles.

Steele, I. M.↗

Application of thematic mapper-type data over a porphyry-molybdenum deposit in Colorado

The objective of the study was to evaluate the utility of thematic mapper data as a source of geologically useful information for mountainous areas of varying vegetation density. Much of the processing was done in an a priori manner without prior ground-based information. This approach resulted in a successfull mapping of the alteration associated with the Mt. Emmons molybdenum ore body as well as several other hydrothermal systems. Supervised classification produced a vegetation map at least as accurate as the mapping done for the environmental impact statement. Principal components were used to map zones of general, subtle alteration and to separate hematitically stained rock from staining associated with hydrothermal activity. Decorrelation color composites were found to be useful field mapping aids, easily delineating many lithologies and vegetation classes of interest. The factors restricting the interpretability and computer manipulation of the data are examined.

Rickman, D. L.↗

Neutrino tomography - Tevatron mapping versus the neutrino sky

The feasibility of neutrino tomography of the earth's interior is discussed, taking the 80-GeV W-boson mass determined by Arnison (1983) and Banner (1983) into account. The opacity of earth zones is calculated on the basis of the preliminary reference earth model of Dziewonski and Anderson (1981), and the results are presented in tables and graphs. Proposed tomography schemes are evaluated in terms of the well-posedness of the inverse-Radon-transform problems involved, the neutrino generators and detectors required, and practical and economic factors. The ill-posed schemes are shown to be infeasible; the well-posed schemes (using Tevatrons or the neutrino sky as sources) are considered feasible but impractical.

Wilson, T. L.↗