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At least 649 records · Page 36

Degradation of Spacecraft Materials in the Space Environment

When we think of space, we typically think of a vacuum containing very little matter that lies between the Earth and other planetary and stellar bodies. However, the space above Earth's breathable atmosphere and beyond contains many things that make designing durable spacecraft a challenge. Depending on where the spacecraft is flyng, it may encounter atomic oxygen, ultraviolet and other forms of radiation, charged particles, micrormeteoroids and debris, and temperature extremes. These environments on their own and in combination can cause degradation and failure of polymers, composites, paints and other materials used on the exterior of spacecraft for thermal control, structure, and power generation. This article briefly discusses and gives examples of some of the degradation experienced on spacecraft and night experiments as a result of the space environment and the use of ground and space data to predict durability.

Miller, Sharon K. R.↗

Computation of Effective Mechanical Properties and Mechanical Erosion Modeling of TPS Materials

The goal of this presentation is to provide a general overview of the multi-scale modeling formulation to determine if there is additional surface recession in Thermal Protection Systems (TPS) materials as a result of mechanical erosion due to high shear conditions during atmospheric entry. This modeling process is performed at different scales by leveraging two computational frameworks developed at NASA: the Porous Microstructure Analysis (PuMA) software, and the Porous material Analysis Toolbox based on OpenFOAM (PATO). PuMA specializes in computing effective macro-scale material properties by performing material response simulations on 3D digital micro-scale representations of porous micro-structures. The modeling of TPS materials at the micro-scale is essential to understand how they behave as part of a heat shield assembly. The first part of the presentation will detail the implementation of PuMA’s cell-centered finite volume elasticity solver, which allows the computation of macro-scale effective mechanical properties of heterogeneous and anisotropic materials such as fibrous and woven TPS composites. These homogenized mechanical properties are used by PATO’s mechanical erosion model to predict the TPS material’s recession at a larger scale. This work will also provide some examples of multi-scale analysis from the fiber level up to the unit cell. The second part of the presentation will focus on the macro-scale approach to determine if erosion at the heat shield’s surface occurs due to mechanical and thermal loads experienced during atmospheric entry. To accomplish this, a solid mechanics module was integrated within PATO enabling it to model the potential mechanical erosion in three steps: first, after obtaining the effective mechanical properties with PuMA, the implemented stress analysis solver computes the stress and the displacement fields for the TPS material using the wall shear stress tensor, computed using a CFD solver, as boundary conditions; then, regions on the surface where the stress meets the failure criteria are identified; finally, the failed material is removed and the mesh is redistributed accordingly. The outcome is a model capable of predicting the total recession in the material due to surface chemistry and mechanical erosion.

Mechanical Properties↗

Mechanical and Thermal Forcing for Upslope Flows and Cumulus Convection over the Sierras de Córdoba

Abstract The upslope flow processes affecting the vertical extent of orographic cumulus convection are examined using observations from the Cloud, Aerosol, and Complex Terrain Interactions (CACTI) field campaign. Specifically, clear air returns from the U.S. Department of Energy (DOE) second-generation C-band scanning Atmospheric Radiation Measurement (ARM) precipitation radar (CSAPR2) are used to characterize the structure and variability of the ridge-normal (i.e., up/downslope) flow components, which transport mass to the crest of Argentina’s Sierras de Córdoba and contribute to convective initiation. Data are compiled for the entire CACTI period (October–April), including days with clear skies, shallow cumuli, cumulus congestus, and deep convection. To examine shared variability among >70 000 radar scans, we use (i) a principal component analysis (PCA) to isolate modes of variability in the upslope flow and (ii) composite analysis based on convective outcomes, determined from GOES-16 satellite observations. These data are contextualized with observed surface sensible heat fluxes, thermodynamic profiles, and synoptic-scale analysis. Results indicate distinct thermally and mechanically forced upslope flow modes, modulated by diurnal heating and synoptic-scale variations, respectively. In some instances, there is a superposition of thermal and mechanical forcing, yielding either deeper or shallower upslope flow. The composite analyses based on satellite data show that successively deeper convective outcomes are associated with successively deeper upslope flow layers that more readily transport mass to the ridge crest in conjunction with lower lifting condensation levels, facilitating convective initiation. These results help to isolate the forcing mechanisms for orographic convection and thus provide a foundation for parameterizing orographic convective processes in coarse resolution models.

Meteorology & Atmospheric Sciences↗

Science applications

Possible scientific applications in the field of the neutral ionized atmosphere and of the solid Earth in terms of the TSS are summarized. Studies of the vertical, zonal, and meridional neutral winds and temperature, whose extensive variations suggest the importance of energy transfer mechanism in modifying the structural properties of the region are reviewed. Layers below the F region of high plasma density that propagate to lower altitudes with drift velocities will be studied for their electron and ion composition and motion. These are to be measured by the TSS in conjunction with ground based radar observations. Basic fluid dynamics problems will be studied onboard tethered satellites. Studies will be conducted on the structure of the equatorial electrojet, in particular its longitudinal and meridional extent. Magnetic measurements will also be used to probe the tether current distribution in the plasma sheath.

Mariani, F.↗

Nimbus-7 Stratospheric and Mesospheric Sounder (SAMS) experiment data user's guide

The Stratospheric and Mesospheric Sounder (SAMS) aboard Nimbus-7 observes infrared radiation from the atmospheric limb. Global upper atmosphere temperature profiles and vertical concentrations of H2O, NO, N2O, CH4 and CO2 are derived from these measurements. The status of all channels was carefully monitored. Temperature and composition were retrieved from the measurements by linearizing the direct equation about an a priori profile and using an optimum statistical estimator to find the most likely solution. The derived temperature and composition profiles are archived on two tape products whose file structure and record formats are described in detail. The gridded retrieved temperature tape (GRID-T) contains daily day and night average temperatures at 62 pressure levels in a 2.5 degree latitude by 10 degree longitude grid extending from 67.5 degrees N to 50 degrees S. The zonal mean methane and nitrous oxide composition tape (ZMT-G) contains zonal mean day and night average CH4 and N2O mixing ratios at 31 pressure levels for 2.5 degrees latitude zones extending from 67.5 degrees N to 50 degrees S.

Taylor, F. W.↗

Multilayer Impregnated Fibrous Thermal Insulation Tiles

The term "secondary polymer layered impregnated tile" ("SPLIT") denotes a type of ablative composite-material thermal- insulation tiles having engineered, spatially non-uniform compositions. The term "secondary" refers to the fact that each tile contains at least two polymer layers wherein endothermic reactions absorb considerable amounts of heat, thereby helping to prevent overheating of an underlying structure. These tiles were invented to afford lighter-weight alternatives to the reusable thermal-insulation materials heretofore variously used or considered for use in protecting the space shuttles and other spacecraft from intense atmospheric-entry heating.

Tran, Huy K.↗

Jarosite in the Shergottite Que 94201

Veins of the hydroxylated, potassium ferric sulfate mineral jarosite - KFe3(SO4)2(OH)6 - have been identified in the martian meteorite Queen Alexandra Range (QUE) 94201. Iron potassium sulfate had been reported in QUE 94201 by Wentworth and Gooding. Jarosite has been reported in other Martian meteorites - Roberts Massif (RBT) 04262, Miller Range (MIL) 03346, and Yamato 000593 - and it has been identified on the Martian surface by Moessbauer spectroscopy. Given the presence of jarosite on Mars, and the burgeoning interest in water-rock interactions on Mars, the question arises whether jarosite in Martian meteorites is formed by aqueous alteration on Mars, or in Antarctica. Hydrogen isotopes are potentially sensitive indicators of the site of formation or last equilibration of hydrous alteration minerals, because of the large difference between D/H ratio of the Martian atmosphere (and also presumably the cryosphere) and terrestrial hydrogen. The Martian atmospheric delta D(sub SMOW) ratio is approximately +4200%o, igneous minerals with substantial hydrogen (phosphates) have high D, ~ +2000%o to +4700%o versus terrestrial waters with approximately 480%o to +130%o. The crystal chemistry and structure of jarosite are reviewed in Papi ke et al. Here we report hydrogen isotopes measured in jarosite in QUE 94201 by ion microprobe, and also report on the major element composition of jarosite measured by electron microprobe.

Ross, D. K.↗

Implications of L1 Observations for Slow Solar Wind Formation by Solar Reconnection

While the source of the fast solar wind is known to be coronal holes, the source of the slow solar wind has remained a mystery. Long time scale trends in the composition and charge states show strong correlations between solar wind velocity and plasma parameters, yet these correlations have proved ineffective in determining the slow wind source. We take advantage of new high time resolution (12 min) measurements of solar wind composition and charge state abundances at L1 and previously identified 90 min quasi periodic structures to probe the fundamental timescales of slow wind variability. The combination of new high temporal resolution composition measurements and the clearly identified boundaries of the periodic structures allows us to utilize these distinct solar wind parcels as tracers of slowwind origin and acceleration. We find that each 90 min (2000 Mm) parcel of slow wind has near-constant speed yet exhibits repeatable, systematic charge state and composition variations that span the entire range of statistically determined slow solar wind values. The classic composition-velocity correlations do not hold on short, approximately hour long, time scales. Furthermore, the data demonstrate that these structures were created by magnetic reconnection. Our results impose severe new constraints on slow solar wind origin and provide new, compelling evidence that the slow wind results from the sporadic release of closed field plasma via magnetic reconnection at the boundary between open and closed flux in the Sun's atmosphere.

Kepko, L.↗

In-Situ Investigation of Advanced Structural Coatings and Composites

The premise of this project is a comprehensive study that involves the in-situ characterization of advanced coatings and composites by employing both neutron and x-ray diffraction techniques in a complementary manner. The diffraction data would then be interpreted and used in developing or validating advanced micromechanics models with life prediction capability. In the period covered by this report, basic work was conducted to establish the experimental conditions for various specimens and techniques. In addition, equipment was developed that will allow the in-situ studies under a range of conditions (stress, temperature, atmosphere, etc.).

Ustundag, Ersan↗

The Role of Entrained Surface Oxides in RS-PM Aluminum Alloys on Resultant Structures and Properties

The RS-PM aluminum alloys which show less than anticipated toughness properties were studied. After eliminating negative variables such as sodium and potassium in lithium containing alloys, hydrogen in all Al alloys, and trapped impurities from the atomization processing the data pointed to fine oxides, as the primary cause of poor toughness properties. The oxide content of aluminum powders increases with: decreasing powder size, deviations from spherical powder shapes, exposure to moist atmospheres either during atomization or in subsequent powder handling, and alloy compositions which contain significant amounts of lithium, magnesium, cerium, and other reactive elements.

Grant, N. J.↗

3D printing of metal containing structures

In an aspect, a method for making a metal-containing material comprises steps of: forming a metal-containing hydrogel from an aqueous precursor mixture using a photopolymerization; wherein the aqueous precursor mixture comprises water, one or more aqueous photosensitive binders, and one or more aqueous metal salts; and thermally treating the metal-containing hydrogel to form the metal-containing material; wherein the metal-containing hydrogel is exposed to a thermal-treatment atmosphere during the step of thermally treating; wherein a composition of the metal-containing material is at least partially determined by a composition of the thermal-treatment atmosphere during the thermally treating step.

Yee, Daryl Wei Liang↗

Growth and Performance of High-Quality SWCNT Forests on Inconel Foils as Lithium-Ion Battery Anodes

Large-scale production of vertically aligned single-walled carbon nanotubes (VA-SWCNTs) on metal foils promises to enable technological advancements in many fields, from functional composites to energy storage to thermal interfaces. In this work, we demonstrate growth of high-quality (G/D > 6, average diameters ~ 2–3 nm, densities > 10 12 cm –2 ) VA-SWCNTs on Inconel metal for use as a lithium-ion battery (LIB) anode. Scale-up of SWCNT growth on Inconel 625 to 100 cm 2 exhibits nearly invariant CNT structural properties, even when synthesis is performed near atmospheric pressure, and this robustness is attributed to a growth kinetic regime dominated by the carbon precursor diffusion in the bulk gas mixture. SWCNT forests produced on large-area metal substrates at close to atmospheric pressure possess a combination of structural features that are among the best demonstrated so far in the literature for growth on metal foils. Leveraging these achievements for energy applications, we demonstrate a VA-SWCNT LIB anode with capacity >1200 mAh/g at 1.0C and stable cycling beyond 300 cycles. Furthermore, this robust synthesis of high-quality VA-SWCNTs on metal foils presents a promising route toward mass production of high-performance CNT devices for a broad range of applications.

Energy↗

Airborne In Situ and Ground-based Polarimetric Radar Measurements of Tropical Convection in Support of CRYSTAL-FACE

This report describes the work performed by the University of North Dakota (UND) under NASA Grant NAG5-11509, titled Airborne In Situ and Ground-based Polarimetric Radar Measurements of Tropical Convection in Support of CRYSTAL-FACE. This work focused on the collection of data by two key platforms: the UND Citation II research aircraft and the NASA NPOL radar system. The CRYSTAL-FACE (C-F) mission addresses several key issues from the NASA Earth System Enterprise, including the variability of water in the atmosphere, the forcing provided by tropical cirrus and the response of the Earth system to this forcing. In situ measurements and radar observations of tropical convection, cirrus clouds and their environment are core elements of C-F. One of the primary issues that C-F is addressing is the relationship of tropical cirrus anvils to precipitating deep convection. The in situ measurements from C-F are being used to validate remote sensing of Earth-Atmosphere properties, increase our knowledge of upper tropospheric water vapor and its distribution, and increase our knowledge of tropical cirrus cloud morphology and composition. Radar measurements, especially polarimetric diversity observations available fiom the NASA NPOL radar, are providing essential information about the initiation, modulation, and dissipation of convective cores and the generation of associated anvils in tropical convection. Specifically, NPOL radar measurements contain information about convective intensity and its vertical structure for comparison with thermodynamic and kinematic environmental measurements observed from soundings. Because of the polarimetric diversity of MOL, statistics on bulk microphysical properties can be retrieved and compared to the other characteristics of convection and associated cirrus anvils. In summary, the central objectives of this proposal were to deploy the UND Citation research aircraft as an in situ sensing platform for this mission and to provide collaborative analyses of the recorded data and to deploy the NPOL radar to observe the characteristics of cirrus and parent convection.

Poellot, Michael R.↗

pCAM precursor produced from electroextraction technology and its application in synthesis of NMC 811 cathode material

The synthesis and characterization of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (LNMC811) cathodes produced from recycled hydroxide precursors obtained from spent lithium-ion batteries is evaluated. Two precursor batches (Sample 1 and Sample 2) are prepared using modified recycling processes to examine how residual impurities and processing conditions influence the properties of the regenerated materials. Structural and compositional characterization by X-ray diffraction, ICP and SEM shows that the recycled precursors exhibit layered hydroxide structures containing both α Ni(OH) 2 and β Ni(OH) 2 phases. Trace impurities including sodium, boron, and aluminum are detected and partially mitigated during processing, with boron found to play a beneficial role in electrochemical behavior. Following lithiation with lithium carbonate and lithium hydroxide at 800 °C under an oxygen rich atmosphere, the resulting LNMC811 materials show electrochemical performance comparable to conventionally synthesized cathodes. Sample 2, which contains higher boron levels and improved cation ordering, delivers an initial discharge capacity of 174 mAh g -1 and retains more than 93 percent of its capacity after 50 cycles. The stable cycling behavior and structural integrity of these materials demonstrate that recycled precursors can be converted into high performance layered cathodes and support recycling as a practical and sustainable route for lithium-ion battery manufacturing.

25 ENERGY STORAGE↗

Data Democratization: Challenges and Opportunities

Democratizing Earth data is one of the challenges many organizations around the world face in order to maximize the use of their Earth data for research, applications, education, and societal benefits. For example, at the NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC), over 1600 global and regional datasets in several NASA Earth science focus areas, including atmospheric composition, water and energy cycles, and climate variability, are archived and distributed to the public. Giovanni, the Geospatial Interactive Online Visualization and Analysis Infrastructure, was developed by GES DISC to facilitate data access and exploration, especially for novice users of Earth science. With Giovanni, users can analyze and visualize over 2000 Earth science variables (e.g., precipitation, aerosol, surface wind) without downloading data, software, the expert understanding of data formats and structures, and coding skills, lowering the barrier to data analysis/comparison by preprocessing and accessing to the data. Results of data analysis and visualization can be accessed in several popular formats (e.g., NetCDF, CSV). As a result of Giovanni's efforts, more than 3000 referral papers have been published in various fields. In spite of this, Giovanni is still difficult to use for some users. For instance, if one searches for "precipitation," it will return over 150 related variables. The question is, which one to use? Furthermore, variables from different data providers (e.g., satellites and models) are named differently with different units, further confusing users, especially those outside the communities. Data democratization is complex and multifaceted. Challenges include service and data discovery, user experiences, visualization, data quality, trustworthiness, and more. In this presentation, we will examine Giovanni as an example of challenges and opportunities in developing data democratization services.

data democratization↗

Spatially-Resolved Characterization Techniques and Their Implications for Nuclear Debris Formation.

Debris from nuclear tests has a complex formation process and can inform multiple fields of study such as geology, atmospheric science, shock physics, and chemistry under extreme conditions. Macroscopic nuclear debris forms as the result of fireball interaction with surrounding materials (e.g., structural and environmental component), which rapidly undergo melting and vaporization followed by condensation, convective/diffusive mixing, and solidification over the course of seconds. In atmospheric events, some of this material may disperse over long distances, but much of the material is deposited close-in to ground zero, often in multicomponent, partially (or entirely) amorphous debris formations. During the U.S. nuclear testing program, this material was collected and analyzed, particularly for radionuclide composition. Fallout formation models were developed from nuclear test data based on such radionuclide compositional analyses. These models were not just used to understand fallout dispersion (i.e. the spread of radioactivity over geographical regions) but also guide radiochemical interpretations of historical nuclear tests.6 Developments in analytical techniques over the past several decades have made it possible to make new analyses on historical debris, some of which may be more than a half-century old. For example, inductively-coupled plasma mass spectrometry (ICP-MS) has been used to look at the trace elements in glassy fallout material from aboveground nuclear tests (including the Trinity test). Advanced analyses using X-ray absorption allowed for the measurement of oxidation state of fallout constituents, including actinides. The ability to measure trace actinides and their subsequent oxidation state is important to understanding how the surrounding environment may have influenced the resultant fallout composition and may have implications for why certain fractionation trends have been observed. Here we present data from historic nuclear test debris illustrating the power of spatially resolved methods to connect interaction of the near-field environment with the explosion and provide new insights into nuclear debris formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Arc jet diagnostics tests

Two objectives were addressed during a 10 week 1988 NASA/ASEE summer faculty fellowship at the Johnson Space Center Atmospheric Reentry Materials Structures Evaluation Facility (ARMSEF). These objectives were the evaluation of mass spectrometry for the measurement of atomic and molecular species in an arc jet environment, and the determination of atomic recombination coefficients for reaction cured glass (RCG) coated high temperature surface insulation (HRSI) materials subjected to simulated reentry conditions. Evaluation of mass spectrometry for the measurement of atomic and molecular species provided some of the first measurements of point compositions in arc jet tunnel environments. A major objective of this project centered around the sampling residence time. A three staged vacuum sampling system pulled the molecules and atoms from the arc jet to a quadrupole ionization mass spectrometer in 400 milliseconds. Conditions investigated included a composition survey across the nozzle exit at 3 cm z-distance from the nozzle exit for 3 different currents. Also, a point composition survey was taken around a shock created by the presence of a blunt body.

Willey, Ronald J.↗

GMI-IPS: Processing & Visualization Software Used in ATom DC-8 Aircraft Studies

NASA's Atmospheric Tomography Mission (ATom) deployed in each of the four seasons during 2016-2018, the DC-8 aircraft in order to establish global-scale datasets intended to improve the representation of chemically reactive gases in global atmospheric chemistry models (ACMs). The Global Modeling Initiative (GMI) executed simulations for each ATom flight using the GMI Chemistry Transport Model (GMI-CTM) to provide species concentrations of chemical gases along the DC-8 flight transects. To solve the problem of translating the GMI-CTM simulation data to the unique spatial resolutions of each ATom flight, the GMI ICARTT Processing Software (GMI-IPS) was developed.The GMI-IPS is written in Python and provides data processing, flight extraction, and visualization support for aircraft research projects using ICARTT format, which is a standard format for airborne instrument data. Additionally, the GMI-IPS interpolates global gridded model data from Hierarchical Data Format (HDF) to ICARTT compatible flight transects. Software classes for instruments and collections provided by the ATom DC-8 aircraft such as MER10, MMS, etc. are derived from a common base class. Other functionality provided by the GMI-IPS are: deriving missing flight entries along a transect, reading ICARTT entries from file, and providing Python data structures for storing flight and model information, and more.The GMI-IPS is GIT source controlled, has approximately 30,000 lines of code, and supports parallelization across data collections. It delivered GMI-CTM data for more than forty distinct DC-8 aircraft flights that took place under ATom. The output ICARTT files adhere to format standard V1.1, and pass the scan utility provided by NASA LaRC Airborne Science Data for Atmospheric Composition. This presentation will include a software and methods overview, and results from ATom, including assessments using the GMI-CTM showing how well observations from ATom flight transects represent a broader region.

Damon, M. R.↗