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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1994

UV laser long-path absorption spectroscopy

Long path Differential Optical Absorption Spectroscopy (DOAS) using a picosecond UV laser as a light source was developed in our institute. Tropospheric OH radicals are measured by their rotational absorption lines around 308 nm. The spectra are obtained using a high resolution spectrograph. The detection system has been improved over the formerly used optomechanical scanning device by application of a photodiode array which increased the observed spectral range by a factor of 6 and which utilizes the light much more effectively leading to a considerable reduction of the measurement time. This technique provides direct measurements of OH because the signal is given by the product of the absorption coefficient and the OH concentration along the light path according to Lambert-Beers law. No calibration is needed. Since the integrated absorption coefficient is well known the accuracy of the measurement essentially depends on the extent to which the OH absorption pattern can be detected in the spectra. No interference by self generated OH radicals in the detection lightpath has been observed. The large bandwidth (greater than 0.15 nm) and the high spectral resolution (1.5 pm) allows absolute determination of interferences by other trace gas absorptions. The measurement error is directly accessible from the absorption-signal to baseline-noise ratio in the spectra. The applicability of the method strongly depends on visibility. Elevated concentrations of aerosols lead to considerable attenuation of the laser light which reduces the S/N-ratio. In the moderately polluted air of Julich, where we performed a number of OH measurement spectra. In addition absorption features of unidentified species were frequently detected. A quantitative deconvolution even of the known species is not easy to achieve and can leave residual structures in the spectra. Thus interferences usually increase the noise and deteriorate the OH detection sensitivity. Using diode arrays for sensitive absorption measurements some specific problems of those detectors have to be solved experimentally (i.e. fixed pattern noise, dark signal noise, nonuniform efficiency of individual elements, spatial sensitivity variations). In order to improve the low spatial resolution we performed laboratory studies using a multiple reflection cell to convert the long path technique to a real in situ point measurement. Under the conditions of field experiments in Julich residual absorbance signals at present are about 1.5x10(exp -4) corresponding to an OH detection sensitivity of 2x10(exp 6) OH/cm(exp 3) using a light path of 5.8 km. Total integration times for one measurement point vary between a few minutes and an hour.

Dorn, Hans-Peter↗
NASA NTRS1994

Numerical modeling studies of wake vortex transport and evolution within the planetary boundary layer

The proposed research involves four tasks. The first of these is to simulate accurately the turbulent processes in the atmospheric boundary layer. TASS was originally developed to study meso-gamma scale phenomena, such as tornadic storms, microbursts and windshear effects in terminal areas. Simulation of wake vortex evolution, however, will rely on appropriate representation of the physical processes in the surface layer and mixed layer. This involves two parts. First, a specified heat flux boundary condition must be implemented at the surface. Using this boundary condition, simulation results will be compared to experimental data and to other model results for validation. At this point, any necessary changes to the model will be implemented. Next, a surface energy budget parameterization will be added to the model. This will enable calculation of the surface fluxes by accounting for the radiative heat transfer to and from the ground and heat loss to the soil rather than simple specification of the fluxes. The second task involves running TASS with prescribed wake vortices in the initial condition. The vortex models will be supplied by NASA Langley Research Center. Sensitivity tests will be performed on different meteorological environments in the atmospheric boundary layer, which include stable, neutral, and unstable stratifications, calm and severe wind conditions, and dry and wet conditions. Vortex strength may be varied as well. Relevant non-dimensional parameters will include the following: Richardson number or Froude number, Bowen ratio, and height to length scale ratios. The model output will be analyzed and visualized to better understand the transport, decay, and growth rates of the wake vortices. The third task involves running simulations using observed data. MIT Lincoln Labs is currently planning field experiments at the Memphis airport to measure both meteorological conditions and wake vortex characteristics. Once this data becomes available, it can be used to validate the model for vortex behavior under different atmospheric conditions. The fourth task will be to simulate the wake in a more realistic environment covering a wider area. This will involve grid nesting, since high resolution will be required in the wake region but a larger total domain will be used. During the first allocation year, most of the first task will be accomplished.

Lin, Yuh-Lang↗
NASA NTRS1994

Comparison and analysis of aircraft measurements and mesoscale atmospheric chemistry model simulations of tropospheric ozone

The Regional Acid Deposition Model (RADM) has been applied to several of the field experiments which were part of the Acid Models Operational and Diagnostic Evaluation Study (Acid MODES). The experiment which was of particular interest with regards to ozone photochemistry involved horizontal zig-zag flight patterns (ZIPPER) over an area from the eastern Ohio River valley to the Adirondacks of New York. Model simulations by both the standard resolution RADM (delta x = 80 km) and the nested grid RADM (delta x = 26.7 km) compare well to measurements in the low emission regions in central Pennsylvania and upstate New York, but underestimate in the high emission upper Ohio River valley. The nested simulation does considerably better, however, than the coarse grid simulation in terms of horizontal pattern and concentration magnitudes. Analysis of NO(x) and HO(x) concentrations and photochemical products rates of ozone show that the model's response to large point source emissions is very unsystematic both spatially and temporally. This is due to the models instability to realistically simulate the small scale (subgrid) gradients in precursor concentrations in and around large point source plumes.

Pleim, Jonathan E.↗
NASA NTRS1994

Tropospheric ozone and aerosol variability observed at high latitudes with an airborne lidar

Large-scale summertime (July-August) distributions of O3 and aerosols were observed in a broad range of atmosphere conditions over the tundra, ice, and ocean regions near Alaska in 1988 and over the lowlands and boreal forests of Canada in 1990. The tropospheric O3 budget in the high-latitude regions was found to be strongly influenced by stratospheric intrusions, and deposition at the surface was found to be the main sink for O3 in the troposphere. Enhanced levels of O3 were observed in plumes from fires in Alaska and Canada. This paper discusses the large-scale variability of O3 and aerosols observed in the high-latitude regions during these field experiments.

Browell, Edward V.↗
NASA NTRS1994

Advanced Turbine Technology Applications Project (ATTAP)

Reports technical effort by AlliedSignal Engines in sixth year of DOE/NASA funded project. Topics include: gas turbine engine design modifications of production APU to incorporate ceramic components; fabrication and processing of silicon nitride blades and nozzles; component and engine testing; and refinement and development of critical ceramics technologies, including: hot corrosion testing and environmental life predictive model; advanced NDE methods for internal flaws in ceramic components; and improved carbon pulverization modeling during impact. ATTAP project is oriented toward developing high-risk technology of ceramic structural component design and fabrication to carry forward to commercial production by 'bridging the gap' between structural ceramics in the laboratory and near-term commercial heat engine application. Current ATTAP project goal is to support accelerated commercialization of advanced, high-temperature engines for hybrid vehicles and other applications. Project objectives are to provide essential and substantial early field experience demonstrating ceramic component reliability and durability in modified, available, gas turbine engine applications; and to scale-up and improve manufacturing processes of ceramic turbine engine components and demonstrate application of these processes in the production environment.

Source record↗
NASA NTRS1994

Optical Rain Gauge Performance: Second Workshop on Optical Rain Gauge Measurements

The primary focus of the workshop was on the performance and reliability of STi mini-Optical Rain Gauges in a number of environments, including deployments on ships and buoys in the western equatorial Pacific Ocean during the TOGA/COARE field experiment, deployments on buoys in U.S. coastal waters, and comparisons with other types of rain gauges on the Virginia coast and in Florida. The workshop was attended by 20 investigators, representing 10 different institutions, who gathered to present new results obtained since the first workshop (April 1993), to discuss problems, to consider solutions, and to chart future directions. Post-TOGA/COARE calibration studies were also presented.

Short, David A.↗
NASA NTRS1993

Classification of the LCVF AVIRIS test site with a Kohonen artificial neural network

We present a classification of an AVIRIS spectral image of the Lunar Crater Volcanic Field (LCVF). Geologic mapping from such data is made possible by distinctive mineral signatures: absorption features and the shape of the spectral continuum. The subtle spectral shape differences between some of the geological units in this scene along with the high dimensionality of the spectral presents a challenging pattern recognition task. We found an artificial neural network powerful in separating 13 geological units based on the full spectral resolution. The LCVF, in northern Nye County, Nevada, was the primary focus of the NASA-sponsored Geologic Remote Sensing Field Experiment in the summer of 1989. It consists of over 100 square miles of Quaternary basaltic pyroclastic and flow deposits. These deposits lie atop ignimbrites and silicic lava flows of Tertiary age and in turn are overlain by Quaternary alluvial and playa deposits. This AVIRIS image was collected on September 29, 1989 at 11:44 at 11:44 PDT. The 256-by-256 pixel subsection in this study contains oxidized basaltic cinder deposits, the southern half of the Lunar Lake playa, and outcrops of the Rhyollite of Big Sand Spring Valley. Vegetation in LCVF is sparse, but locally abundant within washes and near springs.

Merenyi, Erzsebet↗
NASA NTRS1993

A comparison of spectral mixture analysis an NDVI for ascertaining ecological variables

In this study, we compare the performance of spectral mixture analysis to the Normalized Difference Vegetation Index (NDVI) in detecting change in a grassland across topographically-induced nutrient gradients and different management schemes. The Konza Prairie Research Natural Area, Kansas, is a relatively homogeneous tallgrass prairie in which change in vegetation productivity occurs with respect to topographic positions in each watershed. The area is the site of long-term studies of the influence of fire and grazing on tallgrass production and was the site of the First ISLSCP (International Satellite Land Surface Climatology Project) Field Experiment (FIFE) from 1987 to 1989. Vegetation indices such as NDVI are commonly used with imagery collected in few (less than 10) spectral bands. However, the use of only two bands (e.g. NDVI) does not adequately account for the complex of signals making up most surface reflectance. Influences from background spectral variation and spatial heterogeneity may confound the direct relationship with biological or biophysical variables. High dimensional multispectral data allows for the application position of techniques such as derivative analysis and spectral curve fitting, thereby increasing the probability of successfully modeling the reflectance from mixed surfaces. The higher number of bands permits unmixing of a greater number of surface components, separating the vegetation signal for further analyses relevant to biological variables.

Wessman, Carol A.↗
NASA NTRS1993

Comparison of inversion models using AIRSAR data for Death Valley, California

Polarimetric Airborne Synthetic Aperture Radar (AIRSAR) data were collected for the Geologic Remote Sensing Field Experiment (GRSFE) over Death Valley, California, USA, in September 1989. AIRSAR is a four-look, quid-polarizaiton, three frequency instrument. It collects measurements at C-band (5.66 cm), L-band (23.98 cm), and P-band (68.13 cm), and has a GIFOV of 10 meters and a swath width of 12 kilometers. Because the radar measures at three wavelengths, different scales of surface roughness are measured. Also, dielectric constants can be calculated from the data. The scene used in this study is in Death Valley, California and is located over Trail Canyon alluvial fan, the valley floor, and Artists Drive alluvial fan. The fans are very different in mineralogic makeup, size, and surface roughness. Trail Canyon fan is located on the west side of the valley at the base of the Panamint Range and is a large fan with older areas of desert pavement and younger active channels. The source for the material on southern part of the fan is mostly quartzites and there is an area of carbonate source on the northern part of the fan. Artists Drive fan is located at the base of the Black Mountains on the east side of the valley and is a smaller, young fan with its source mostly from volcanic rocks. The valley floor contains playa and salt deposits that range from smooth to Devil's Golf course type salt pinnacles.

Kierein-Young, Kathryn S.↗
NASA NTRS1995

Thermal barrier coatings for aircraft engines: History and directions

Thin thermal barrier coatings for protecting aircraft turbine section airfoils are examined. The discussion focuses on those advances that led first to their use for component life extension and more recently as an integral part of airfoil design. It is noted that development has been driven by laboratory rig and furnace testing corroborated by engine testing and engine field experience. The technology has also been supported by performance modeling to demonstrate benefits and life modeling for mission analysis. Factors which have led to the selection of the current state-of-the-art plasma sprayed and physical vapor deposited zirconia-yttria/MCrAlY TBC's is emphasized in addition to observations fundamentally related to their behavior. Current directions in research into thermal barrier coatings and recent progress at NASA is also noted.

Miller, R. A.↗
NASA NTRS1994

Recommended techniques for effective maintainability. A continuous improvement initiative of the NASA Reliability and Maintainability Steering Committee

This manual presents a series of recommended techniques that can increase overall operational effectiveness of both flight and ground based NASA systems. It provides a set of tools that minimizes risk associated with: (1) restoring failed functions (both ground and flight based); (2) conducting complex and highly visible maintenance operations; and (3) sustaining a technical capability to support the NASA mission using aging equipment or facilities. It considers (1) program management - key elements of an effective maintainability effort; (2) design and development - techniques that have benefited previous programs; (3) analysis and test - quantitative and qualitative analysis processes and testing techniques; and (4) operations and operational design techniques that address NASA field experience. This document is a valuable resource for continuous improvement ideas in executing the systems development process in accordance with the NASA 'better, faster, smaller, and cheaper' goal without compromising safety.

Source record↗
NASA NTRS1995

In-flight radiometric calibration of AVIRIS in 1994

The AVIRIS sensor must be calibrated at the time it measures spectra from the ER-2 airborne platform in order to achieve research and application objectives that are both quantitative and physically based. However, the operational environment inside the Q-bay of the ER-2 at 20 km altitude differs from that in the AVIRIS laboratory with respect to temperature, pressure, vibration, and high-frequency electromagnetic fields. Experiments at surface calibration targets are used in each flight season to confirm the accuracy of AVIRIS in-flight radiometric calibrations. For these experiments, the MODTRAN radiative transfer code is constrained by using in situ measurements to independently predict the upwelling spectral radiance arriving at AVIRIS for a specific calibration target. AVIRIS calibration is validated in flight by comparing the MODTRAN-predicted radiance to the laboratory-calibrated radiance measured by the AVIRIS sensor for the same time over the calibration target. We present radiometric calibration results for the AVIRIS in-flight calibration experiment held at the beginning of the 1994 flight season.

Green, Robert O.↗
NASA NTRS1995

Integration of AIRSAR and AVIRIS data for Trail Canyon alluvial fan, Death Valley, California

Combining quantitative geophysical information extracted from the optical and microwave wavelengths provides complementary information about both the surface mineralogy and morphology. This study combines inversion results from two remote sensing instruments, a polarimetric synthetic aperture radar, AIRSAR, and an imaging spectrometer, AVIRIS, for Trail Canyon alluvial fan in Death Valley, California. The NASA/JPL Airborne Synthetic Aperture Radar (AIRSAR) is a quad-polarization, three frequency instrument. AIRSAR collects data at C-band = 5.66 cm, L-band = 23.98 cm, and P-band = 68.13 cm. The data are processed to four-looks and have a spatial resolution of 10 m and a swath width of 12 km. The AIRSAR data used in this study were collected as part of the Geologic Remote Sensing Field Experiment (GRSFE) over Death Valley on 9/14/89. The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is a NASA/JPL instrument that flies in an ER-2 aircraft at an altitude of 20 km. AVIRIS uses four spectrometers to collect data in 224 spectral channels from 0.4 micrometer to 2.45 micrometer. The width of each spectral band is approximately 10 nm. AVIRIS collects data with a swath width of 11 km and a pixel size of 20 m. The AVIRIS data used in this study were collected over Death Valley on 5/31/92.

Kierein-Young, Kathryn S.↗
NASA NTRS1994

Linking boundary-layer circulations and surface processes during FIFE89. Part 1: Observational analysis

Surface, aircraft, and satellite observations are analyzed for the 21-day 1989 intensive field campaign of the First ISLSCP Field Experiment (FIFE) to determine the effect of precipitation, vegetation, and soil moisture distributions on the thermal properties of the surface including the heat and moisture fluxes, and the corresponding response in the boundary-layer circulation. Mean and variance properties of the surface variables are first documented at various time and space scales. These calculations are designed to set the stage for Part 2, a modeling study that will focus on how time-space dependent rainfall distribution influences the intensity of the feedback between a vegetated surface and the atmospheric boundary layer. Further analysis shows strongly demarked vegetation and soil moisture gradients extending across the FIFE experimental site that were developed and maintained by the antecedent and ongoing spatial distribution of rainfall over the region. These gradients are shown to have a pronounced influence on the thermodynamic properties of the surface. Furthermore, perturbation surface wind analysis suggests for both short-term steady-state conditions and long-term averaged conditions that the gradient pattern maintained a diurnally oscillating local direct circulation with perturbation vertical velocities of the same order as developing cumulus clouds. Dynamical and scaling considerations suggest that the embedded perturbation circulation is driven by surface heating/cooling gradients and terrain ef fects rather than the manifestation of an inertial oscillation. The implication is that at even relatively small scales (less than 30 km), the differential evolution in vegetation density and soil moisture distribution over a relatively homogenous ecotone can give rise to preferential boundary-layer circulations capable of modifying local-scale horizontal and vertical motions.

Smith, Eric A.↗
NASA NTRS1994

Airborne boundary layer flux measurements of trace species over Canadian boreal forest and northern wetland regions

Airborne heat, moisture, O3, CO, and CH4 flux measurements were obtained over the Hudson Bay lowlands (HBL) and northern boreal forest regions of Canada during July - August 1990. The airborne flux measurements were an integral part of the NASA/Arctic Boundary Layer Expedition (ABLE) 3B field experiment executed in collaboration with the Canadian Northern Wetlands Study (NOWES). Airborne CH4 flux measurements were taken over a large portion of the HBL. The surface level flux of CH4 was obtained from downward extrapolations of multiple-level CH4 flux measurements. Methane source strengths ranged from -1 to 31 mg m(exp -2)/d, with the higher values occurring in relatively small, isolated areas. Similar measurements of the CH4 source strength in the boreal forest region of Schefferville, Quebec, ranged from 6 to 27 mg m(exp -2)/d and exhibited a diurnal dependence. The CH4 source strengths found during the ABLE 3B expedition were much lower than the seasonally averaged source strength of 51 mg m(exp -2)/d found for the Yukon-Kuskokwim delta region of Alaska during the previous ABLE 3A study. Large positive CO fluxes (0.31 to 0.53 parts per billion by volume (ppbv) m/s) were observed over the inland, forested regions of the HBL study area, although the mechanism for the generation of these fluxes was not identified. Repetitive measurements along the same ground track at various times of day near the Schefferville site also suggested a diurnal dependence for CO emissions. Measurements of surface resistance to the uptake of O3 (1.91 to 0.80 s/cm) for the HBL areas investigated were comparable to those observed near the Schefferville site (3.40 to 1.10 s/cm). Surface resistance values for the ABLE 3B study area were somewhat less than those observed over the Yukon-Kuskokwim delta during the previous ABLE 3A study. The budgets for heat, moisture, O3, CO, and CH4 were evaluated. The residuals from these budget studies indicated, for the cases selected, a moderate net photochemical production of O3 present in the boundary layer over the HBL that coincided with an in situ destruction of CO, although the mechanism responsible for the destruction of CO was not identified. Results from the O3 budget analysis indicate the importance of in situ photochemical production and its possible dominance over surface deposition to the local O3 budget at the Schefferville site. Measurements of the in situ production of O3 indicated a direct relationship between the presence of biomass burning or large-scale pollution effects. Residuals from budget calculations for conserved quantities (heat, moisture, and CH4) were compared with their respective surface fluxes to provide a measure of the internal self-consistency of the flux measurements.

Ritter, John A.↗
NASA NTRS1994

Size distribution and scattering phase function of aerosol particles retrieved from sky brightness measurements

Ground-based measurements of the solar transmission and sky radiance in a horizontal plane through the Sun are taken in several geographical regions and aerosol types: dust in a desert transition zone in Israel, sulfate particles in Eastern and Western Europe, tropical aerosol in Brazil, and mixed continental/maritime aerosol in California. Stratospheric aerosol was introduced after the eruption of Mount Pinatubo in June 1991. Therefore measurements taken before the eruption are used to analyze the properties of tropospheric aerosol; measurements from 1992 are also used to detect the particle size and concentration of stratospheric aerosol. The measurements are used to retrieve the size distribution and the scattering phase function at large scattering angles of the undisturbed aerosol particles. The retrieved properties represent an average on the entire atmospheric column. A comparison between the retrieved phase function for a scattering angle of 120 deg, with phase function predicted from the retrieved size distribution, is used to test the assumption of particle homogeneity and sphericity in radiative transfer models (Mie theory). The effect was found to be small (20% +/- 15%). For the stratospheric aerosol (sulfates), as expected, the phase function was very well predicted using the Mie theory. A model with a power law distribution, based on the spectral dependence of the optical thickness, alpha, cannot estimate accurately the phase function (up to 50% error for lambda = 0.87 microns). Before the Pinatubo eruption the ratio between the volumes of sulfate and coarse particles was very well correlated with alpha. The Pinatubo stratospheric aerosol destroyed this correlation. The aerosol optical properties are compared with analysis of the size, shape, and composition of the individual particles by electron microscopy of in situ samples. The measured volume size distribution before the injection of stratospheric aerosol consistently show two modes, sulfate particles with r(sub m) less than 0.2 microns and coarse paritcles with r(sub m) greater than 0.7 microns. The 'window' in the tropospheric aerosol in this radius range was used to observe a stable stratospheric aerosol in 1992, with r(sub m) approximately 0.5 microns. A combination of such optical thickness and sky measurements can be used to assess the direct forcing and the climatic impact of aerosol. Systematic inversion for the key aerosol types (sulfates, smoke, dust, and maritime aerosol) of the size distribution and phase function can give the relationship between the aerosol physical and optical properties that can be used to compute the radiative forcing. This forcing can be validated in dedicated field experiments.

Kaufman, Y. J.↗
NASA NTRS1994

Budget analysis of FIFE 1987 sonde data

Mean thermodynamic profiles are presented for the daytime convective boundary layer evolution for three groups of sunny days in late June and early July, August, and October using data from the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE) 1987 Kansas experiment. Budget models for the mixed layer evolution and the boundary layer rise are used to estimate the boundary layer top entrainment parameter. A value of A(sub R) = 0.44 +/- 0.21 is found for the mean ratio of the inversion level virtual heat flux to the surface virtual heat flux.

Betts, Alan K.↗
NASA NTRS1995

An airborne study of microwave surface sensing and boundary layer heat and moisture fluxes for FIFE

The objectives of this work were to perform imaging radar and scatterometer measurements over the Konza Prairie as a part of the First International land surface climatology project Field Experiments (EIFE) and to develop an mm-wave radiometer and the data acquisition system for this radiometer. We collected imaging radar data with the University of Kansas Side-Looking Airborne Radar (SLAR) operating at 9.375 GHz and scatterometer data with a helicopter-mounted scatterometer at 5.3 and 9.6 GHz. We also developed a 35-GHz null-balancing radiometer and data acquisition system. Although radar images showed good delineation of various features of the FIFE site, the data were not useful for quantitative analysis for extracting soil moisture information because of day-to-day changes in the system transfer characteristics. Our scatterometer results show that both C and X bands are sensitive to soil moisture variations over grass-covered soils. Scattering coefficients near vertical are about 4 dB lower for unburned areas because of the presence of a thatch layer, in comparison with those for burned areas. The results of the research have been documented in reports, oral presentations, and published papers.

Gogineni, S. P.↗