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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36

Life Cycle Greenhouse Gas Emissions from Electricity Generation: Update

As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on greenhouse gas (GHG) emissions from various sources of energy to inform policy, planning, and investment decisions. Since the National Renewable Energy Laboratory (NREL) published original results from the Life Cycle Assessment Harmonization Project (Heath and Mann 2012), it has updated estimates of electricity generation GHG emissions factors as part of several recent studies. This fact sheet updates an earlier version (NREL 2013).

air quality↗

Combined Techno-Economic Analysis and Life Cycle Assessment of an Integrated Direct Air Capture System with Advanced Algal Biofuel Production

The continuous increase in carbon dioxide (CO2) concentration in the atmosphere since the First Industrial Revolution correlates convincingly with the ongoing rise of the Earth's global average temperature contributing to climate change. As a response, carbon capture and sequestration (CCS) technologies are being implemented to mitigate anthropogenic CO2 emissions by capturing CO2 from high emitting point sources, such as power plants, refineries, and cement factories, and subsequently buried in geological formations underground for long term storage. Recently direct air capture (DAC) has emerged as a promising alternative technology that captures CO2 directly from the atmosphere for use or sequestration. This study investigates the potential synergistic benefits of integrating a solid amine-based DAC system with advanced algal biofuel production in photobioreactors (PBRs). DAC utilization allows the removal of atmospheric CO2 while also decoupling algae production facilities from anthropogenic point CO2 sources and avoiding the cost and logistics challenges of transporting CO2 long distances to remote facilities. Techno-economic analysis and life cycle assessment are performed to assess the economic and environmental benefits of heat and mass integration between the DAC and the PBR for biofuel production. The DAC-PBR system integration also considers on-site flue gas handling options, DAC capital utilization, the tradeoff between centralization or decentralization of key unit operations, and the PBR array. This presentation will discuss how optimizing DAC-PBR process integration can enhance the algal biofuel's economic and environmental sustainability and the prospect of DAC enabling the circular carbon economy.

algal biofuel production↗

Regulatory and Policy Considerations for the Reuse and End-of-Life Management of Solar and Batteries in the U.S.

The demand for solar photovoltaics (PV) and lithium-ion batteries (LIB) is expected to continue in the U.S. as the call for solar is projected to quadruple by 2030 to meet renewable energy and decarbonization goals. The expected demand for PV and LIB brings supply chain concerns and a growing need for a circular economy for PV and LIB materials. Domestic reuse and recycling is one potential circular economy solution for PV and LIB. This presentation explores the current U.S. law and regulatory landscape for the reuse and recycling of PV and LIB materials, and how certain policy frameworks impact reuse and end-of-life management decisions for PV and LIB materials.

batteries↗

Overview of Carbon Conversion Life Cycle Analysis at NETL

A presentation providing an overview of the work the NETL life cycle analysis (LCA) team performs to support the U.S. DOE Carbon Conversion program, including the NETL CO2U LCA Guidance Toolkit and other LCA-related tasks. Presented at the 2022 Carbon Management Project Review Meeting in Pittsburgh, PA on August 15, 2022.

Krynock, Michelle↗

WBS 1.2.3.405 - Life Cycle Assessment of Storage Technologies

Recent commitments by the Biden administration have established targets to achieve a net-zero energy system by 2050. Meeting these targets will spur a rapid transition to clean energy technologies and a commensurate need to develop and deploy energy storage technologies at scale. Pumped Storage Hydro (PSH) is expected to be part of this solution because its ability to provide grid flexibility and stability and enable the dispatching of disparate variable renewable energy technologies. Despite PSH being a mature technology with a history of deployment dating back several decades, there is very little information on the greenhouse gas (GHG) implications of PSH as compared to other storage technologies. The objective of this project is to perform a full lifecycle assessment (LCA) of new PSH projects in the U.S. This LCA includes all project phases (resource extraction, construction, operation, maintenance, end-of-life). The functional unit for this study is 1 kWh electricity delivered by system to grid substation connection point and the estimated lifetime for our base case is 80 years. Data used in this study are based on over 30 potential PSH projects that are in preliminary planning phases and are represent a wide range of potential closed-loop PSH systems in terms of location, technology, and capacity. The project approach, data sources, and modeling assumptions have been informed by a technical review committee of stakeholders that include experts from academia, national and international government, industry, and utilities. The GHGs and energy return on investment (EROI) from PSH will be compared to other storage technologies (e.g., stationary battery storage). Results from this project will improve the PSH community's understanding of the environmental impacts and sustainability of new PSH projects and how PSH compares to other storage technologies. The approach used in this project relies on open-source programming. The analysis framework (source code and data) and will be made publicly available at the end of the project. In addition to reporting results for the base case, we will perform rigorous sensitivity analysis to identify the major drivers, understand impacts of different configurations, and future energy markets. Results from this project will be published in a suitable journal.

ENERGY PLANNING, POLICY, AND ECONOMY,HYDRO ENERGY↗

Performance Advantaged ..beta..-Ketone Containing Polymers - Benefits in Manufacturing, Performance, and End-of-Life

Biomass derived chemicals can possess extended functionality, often in the form of heteroatoms like oxygen and nitrogen, that can enable performance advantaged properties in emergent materials. These performance advantages can manifest in multiple ways such as reduced manufacturing intensity, better performance, or enhanced end-of-life options. One illustrative example of this concept is ..beta..-ketoadipic acid (..beta..KA), a C6 dicarboxylic acid with a ketone in its backbone. ..beta..KA can be obtained via biological cultivation from aromatic compounds, sugars, and even waste plastics. When ..beta..KA is implemented into polymers, namely nylons, in place of adipic acid the overall material properties are increased. Specifically, the glass transition temperature (which is the measurement at which temperature a plastic softens) is increased by 69 degrees C and the water permeability is reduced by 20%. Molecular dynamic (MD) simulations reveal that the ..beta..-ketone in ..beta..KA leads to restricted movement across multiple backbone carbons when compared to adipic acid. Furthermore, MD simulations reveal that the ..beta..-ketone, when compared to no-ketone or an a-ketone, can lead to an increase in hydrogen bonding between neighboring chains. Both phenomena may help explain the molecular origin of the increases in polymer performance. When implemented into polyesters, namely PET, ..beta..KA can maintain the requisite performance while enabling enhanced degradation. Aside from performance advantages in thermomechanical performance, the production of ..beta..KA also is advantaged in its manufacturing. Although estimates for the minimum selling price (MSP) of ..beta..KA exceed adipic acid the manufacture of ..beta..KAwould reduce supply chain energy and GHG emissions by >50% and >30% respectively. Further TEA analysis reveals that the MSP of ..beta..KA is primarily driven by the feedstock cost while the capital expenditures are driven largely by fermentation costs. Overall, the work presented within will be illustrative of how biomass derived molecules, namely ..beta..KA, can manifest performance advantages across multiple benchmarks and may enable a path to market for biomass-derived materials.

ADVANCED PROPULSION SYSTEMS,BIOMASS FUELS↗

Techno-Economic Analysis and Life-Cycle Assessment of Emerging Technologies for Bioprocessing Separations

Limited availability, rising costs, and environmental concerns about fossil fuels have generated considerable interest in finding alternative, renewable sources including biomass, which can be converted into a number of biofuels and bioproducts. In comparison to petroleum-based products, high processing costs, mainly associated with bioprocessing separations, limit widespread implementation of biofuels and bioproducts. Bioprocess-related separations are also complicated, regardless of the conversion pathway, due to the dilute nature of products and the chemically complex mixtures that result from biomass deconstruction. In many cases, bioprocessing separation approaches lack a technology baseline, or definition of the state of technology (SOT). This work focuses on evaluating the technology readiness of novel separations technologies for the conversion of biomass into biofuels and bioproducts and will address three key topics: 1) SOT description, 2) economic viability analysis of both SOT and innovative separations, and 3) environmental impact assessment of both SOT and novel processes. The current SOT for lignin valorization, dilute carbon recovery, and impurity removal is used to identify potential opportunities for improvement and provide a baseline for comparison with the emerging technologies. Detailed techno-economic analysis (TEA) and life cycle assessment (LCA) are applied to understand the key drivers and challenges related to the economic feasibility and environmental impacts, respectively.

BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗

Performance Advantaged Thermosets from Bioderived Amines: Benefits in Manufacturing, Performance, and End-of-Life

Biomass derived monomers can offer unique functionality, often in the forms of heteroatoms, that is not easily accessible by routine petrochemical routes. Importantly, many of these monomers offer the potential to replace the petrochemical monomers used in the manufacture of thermosets to enable expanded functionality and performance. In the present work, we leverage amine containing monomers that can be obtained via biological conversions in both epoxy and benzoxazine thermosets. These monomers have a wide degree of functionality available to them that augment the material properties. In the case of benzoxazines, monomers that contain both an amine and carboxylic acid are used and the presence of the carboxylic acid leads to an acceleration in cure kinetics and a dramatic reduction in cure temperature. For the epoxy thermosets, multifunctional amine monomers are used as a hardener and the properties of the resultant materials are found to scale with the spacing and identity between reactive centers. The amines can be further modified and reacted to produce a mixed network of triazines and epoxy-amines that enables the end-of-life degradation of these materials. Importantly, subsequent process analysis reveals that the use of bioderived amines can present dramatic reductions in both supply chain energy and GHG emissions while possessing a cost similar to their petrochemical counterparts. Overall, this work demonstrates the robust potential to use bioderived amines for performance advantaged properties.

bioderived monomers↗

Technical Performance and Cost Optimization of Unobtrusive Multi-static Serial LiDAR Imager (UMSLI) for Wide-area Surveillance and Identification of Marine Life at Marine Energy Installations

Florida Atlantic University developed an underwater optical monitoring system prototype - Unobtrusive Multi-static Serial LiDAR Imager (UMSLI) - suitable for marine energy full project lifecycle observation (baseline, commissioning, and decommissioning), with an automated real-time classification of marine animals. With precursor 2014 DOE funding (award DE-EE0006787), a prototype UMSLI was demonstrated in a controlled laboratory environment and achieved a TRL 6. This EERE DE-EE0007828 award aimed to both increase the TRL of the UMSLI by improving the technology performance (e.g., increase distance of marine animal target detection capability, add additional species classification capabilities, improve the system performance during the day, etc.) and reduce the cost. The UMSLI presents a novel application of underwater distributed Light Detection And Ranging (LiDAR), an advanced remote sensing method that uses light in the form of laser pulses for an application, this paired with an algorithm provides 360 degrees underwater detection, imaging, and classification of marine life. This solution for underwater monitoring of biota preserves the advantages of traditional optical and acoustic solutions while overcoming many associated disadvantages for marine energy site environmental monitoring, such as difficulties in species detection and classification in low light or night and turbid environments. This new approach is a purposefully designed, reconfigurable adaptation of an existing class 3B laser technology into one UMSLI instrument that can be easily mounted on or around different classes of marine energy equipment, such as devices to capture ocean current energy or wave energy. The system uses relatively low average power, utilizes far-red (> 635nm) laser illumination to be invisible and eye-safe to marine animals, is compact, and cost-effective. The equipment is designed for long-term, maintenance-free operations (i.e., current design is targeting more than 7 days continuous operation), to inherently generate a sparse primary dataset that only includes detected anomalies, and to allow robust real-time automated animal classification and identification with a low data bandwidth requirement. The technology’s overarching goal for application, is a system that can be deployed to collect pre-installation baseline species observations at a proposed marine energy deployment site with minimal post-processing overhead. The envisioned system will also produce high-resolution imagery of marine animals through a wide range of conditions and support automated tracking and notification of the presence of managed animals within established perimeters of marine energy equipment to satisfy deployed marine energy projects’ endangered and threatened species monitoring requirements. Through the current project, we demonstrated the UMSLI prototype in an operational environment and increased the UMSLI’s Technology Readiness Level from 6 to 7. The project resulted in many novel technologies, including: 1) an eye-safe red laser based, low-cost LiDAR system that can detect targets up to 10 meters distance; 2) the GAN-based machine learning underwater LiDAR image enhancement technique (this is the first known application of GAN technique in underwater LiDAR); 3) LiDAR-based real-time automated detection capabilities; and 4) a template matching based automated classification tool. These technologies build a solid foundation for future efforts to develop an extended range electro-optical monitoring system suitable for marine energy deployments. In addition to technology development, a key lesson learned is that addressing regulatory and safety requirements must be front and center in any marine energy monitoring applications.

16 TIDAL AND WAVE POWER↗

The Wind Turbine Design Guideline DG03: Yaw and Pitch Rolling Bearing Life Revisited - An Outline of Suggested Changes: Preprint

The Design Guideline 03 (DG03) published by the National Renewable Energy Laboratory in 2009 is widely used in the wind industry. It allows engineers to get acquainted with design aspects and methodologies to determine pitch and yaw bearing static capacity and fatigue life. The combination of the detailed theoretical descriptions and practical examples makes it a highly application-oriented document. Since its publication, the knowledge about oscillating bearings, slewing bearings, and wind turbines has grown significantly. Some aspects of the DG03 need updates to reflect the current state of the art. This work covers proposed changes for an upcoming revision of DG03.

design guideline↗

Carbon Conversion Life Cycle Analysis at NETL

Presentation given to the CCU TEA and LCA Guidance – A Harmonized Approach Workshop on May 18, 2023. Describes carbon conversion-related life cycle analysis efforts at NETL.

Krynock, Michelle↗

Industry Facing PV Degradation Prediction Tool and Database to Enable a 50-Year Life Module

The Photovoltaic (PV) industry constantly aims for lower costs, higher-efficiency cells, and improved module designs. These trends lead to using new materials, designs, and manufacturing processes, resulting in a continually changing technological landscape. These changes can potentially introduce new, unknown degradation mechanisms and failure modes that are difficult to diagnose, analyze, test, and model. This introduces uncertainty into the expected lifetime of PV modules of 25 years. Furthermore, research efforts aim for up to 50 years of service life while keeping performance degradation at a minimum for decades of outdoor weathering - putting additional pressure on improving the accuracy of long-term durability and reliability assessments. Here there is a need to organize the existing degradation data into an accessible format and to provide industry relevant tools for extrapolation from laboratory to field conditions. Because the core of this type of analysis involves calculations that are complicated but ubiquitous for many degradation processes, an enhanced predictive modeling framework will facilitate the analysis to help researchers keep up with the rapid pace of technological changes. In this work, we present an online tool that can be used to search for and analyze degradation information and extrapolate PV module performance and durability to field exposure. A graphical user interface will aid in the understanding of the results. The prediction tool will be built modular and published as open source, enabling users to expand on the existing framework. We use an integration pipeline approach that allows us to leverage weather data from the National Solar Radiation Database to perform geospatial degradation analysis in the US and worldwide. Our repository will contain various degradation models and material parameters suitable for the reliability and durability assessment of materials and components deployed outdoors. We hope to become a repository that can be used for weathering and degradation analysis for various applications beyond the PV industry.

degradation↗

Distribution, Ecology, Life History, and Conservation Status of the Berry Cave Salamander (Gyrinophilus gulolineatus)

The Berry Cave Salamander (Gyrinophilus gulolineatus) is a neotenic, stygobitic salamander endemic to eight cave systems and an isolated surface record in the Appalachian Valley and Ridge of eastern Tennessee. We conducted surveys for G. gulolineatus from 2017–2019 to assess the status of the species, locate new populations, and address knowledge gaps related to life history and population ecology required for conservation assessment. We confirmed G. gulolineatus presence at four historical sites, but we did not observe the species at any additional caves. At the three known sites with greatest abundance, visual counts per survey ranged 0–19 salamanders in 2017–2019. There was no apparent trend in abundance at Berry Cave. Visual counts declined 65% since the mid-2000s at Meads Quarry Cave and 80% since the early 1980s at Mudflats Cave. Mark-recapture studies in 160-m of cave stream at Berry Cave in 2017–2018 and 900-m of cave stream at Meads Quarry Cave in 2008 yielded population size estimates that ranged from 34–78 and 15–65 individuals, respectively. We identified 13 existing or potential threats to populations. Habitat degradation and groundwater contamination (associated with urbanization of the Knoxville metropolitan area and past mining operations) represent the most evident threats to long-term viability. Based on our conservation assessments, we recommend a rank of Endangered under IUCN Red List criteria and Critically Imperiled–Imperiled (G1G2) under NatureServe criteria. In opposition to the recent U.S. Fish & Wildlife Service decision, we advocate that, at minimum, G. gulolineatus remain a Candidate Species. Given the identified threats and these ranks, we offer several recommendations for research, conservation, and management of this rare salamander.

59 BASIC BIOLOGICAL SCIENCES↗

Emerging Contaminants: Identification, Life Cycle, and Key Challenges - 20415

The term 'emerging contaminants' and its multiple variants has come to refer to previously overlooked compounds discovered in the environment which represent a potential threat to human and ecological receptors. These compounds may be discovered in the environment as new analytical techniques are developed and/or as new monitoring programs for drinking water and groundwater are implemented, while the threat to receptors may be realized through advances in understanding of toxicology and pathways to receptors. Emerging contaminants present unique and considerable challenges as demands to address them can outpace the understanding of their toxicity, their need for regulation, their occurrence, and techniques for treating the environmental media they affect. With these challenges in mind, this paper serves as a primer for understanding emerging contaminants. The paper will lay a foundation for understanding emerging contaminants through three key topics: 1. Who identifies emerging contaminants? An overview of the various stakeholder groups around the world working on identifying potential emerging contaminants and developing systems for screening potential candidates, prioritizing, and ultimately generating regulations will be provided. 2. How Chemicals Rise into Awareness as Emerging Contaminants. The process by which contaminants emerge through a cycle of awareness, characterization, management and regulation will be discussed. Current emerging contaminants will be discussed in the context of the life cycle: emerging contaminants where impacts to drinking water supplies are driving public awareness (e.g. per and polyfuoroalkyl substances (PFASs) and 1,4-dioxane), emerging contaminants impacted by changing regulatory standards or development and debate on toxicity (e.g., hexavalent chromium, 1,2,3-trichloropropane, trichloroethylene in vapor intrusion), and those with evolving understanding of impacts and usage (e.g., microplastics). 3. Key Challenges. Unique challenges associated with emerging contaminants, including visibility and public sensitivity, uncertainty and vulnerability, will be discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗