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Results for “Optical Properties Polarization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Seasonal and global cloud variations deduced from polar orbiting satellite radiance measurements

The utility of currently available satellite radiance data for determining cloud radiative effects is evaluated. Each location observed by satellite is classified as clear or cloudy by comparison of measured radiances with specified values. Clear scene radiances are functions of time and location which represent the actual variation of the surface and atmospheric properties that affect the measured radiances. Cloud properties are determined by comparison of model and observed radiance. The seasonal change in cloud properties is shown, displaying the difference between July and January monthly mean values of cloud cover fraction, cloud top temperature, cloud top altitude, and cloud optical thickness.

Rossow, W. B.↗
NASA NTRS2017

Comparison of Commonly-Used Microwave Radiative Transfer Models for Snow Remote Sensing

This paper reviews four commonly-used microwave radiative transfer models that take different electromagnetic approaches to simulate snow brightness temperature (T(sub B)): the Dense Media Radiative Transfer - Multi-Layer model (DMRT-ML), the Dense Media Radiative Transfer - Quasi-Crystalline Approximation Mie scattering of Sticky spheres (DMRT-QMS), the Helsinki University of Technology n-Layers model (HUT-nlayers) and the Microwave Emission Model of Layered Snowpacks (MEMLS). Using the same extensively measured physical snowpack properties, we compared the simulated T(sub B) at 11, 19 and 37 GHz from these four models. The analysis focuses on the impact of using different types of measured snow microstructure metrics in the simulations. In addition to density, snow microstructure is defined for each snow layer by grain optical diameter (Do) and stickiness for DMRT-ML and DMRT-QMS, mean grain geometrical maximum extent (D(sub max)) for HUT n-layers and the exponential correlation length for MEMLS. These metrics were derived from either in-situ measurements of snow specific surface area (SSA) or macrophotos of grain sizes (D(sub max)), assuming non-sticky spheres for the DMRT models. Simulated T(sub B) sensitivity analysis using the same inputs shows relatively consistent T(sub B) behavior as a function of Do and density variations for the vertical polarization (maximum deviation of 18 K and 27 K, respectively), while some divergences appear in simulated variations for the polarization ratio (PR). Comparisons with ground based radiometric measurements show that the simulations based on snow SSA measurements have to be scaled with a model-specific factor of Do in order to minimize the root mean square error (RMSE) between measured and simulated T(sub B). Results using in-situ grain size measurements (SSA or D(sub max), depending on the model) give a mean T(sub B) RMSE (19 and 37 GHz) of the order of 16-26 K, which is similar for all models when the snow microstructure metrics are scaled. However, the MEMLS model converges to better results when driven by the correlation length estimated from in-situ SSA measurements rather than D(sub max) measurements. On a practical level, this paper shows that the SSA parameter, a snow property that is easy to retrieve in-situ, appears to be the most relevant parameter for characterizing snow microstructure, despite the need for a scaling factor.

Snow↗
DOE OSTI2023

Domain-dependent strain and stacking in two-dimensional van der Waals ferroelectrics

Van der Waals (vdW) ferroelectrics have attracted significant attention for their potential in next-generation nano-electronics. Two-dimensional (2D) group-IV monochalcogenides have emerged as a promising candidate due to their strong room temperature in-plane polarization down to a monolayer limit. However, their polarization is strongly coupled with the lattice strain and stacking orders, which impact their electronic properties. Here, we utilize four-dimensional scanning transmission electron microscopy (4D-STEM) to simultaneously probe the in-plane strain and out-of-plane stacking in vdW SnSe. Specifically, we observe large lattice strain up to 4% with a gradient across ~50 nm to compensate lattice mismatch at domain walls, mitigating defects initiation. Additionally, we discover the unusual ferroelectric-to-antiferroelectric domain walls stabilized by vdW force and may lead to anisotropic nonlinear optical responses. Our findings provide a comprehensive understanding of in-plane and out-of-plane structures affecting domain properties in vdW SnSe, laying the foundation for domain wall engineering in vdW ferroelectrics.

42 ENGINEERING↗
DOE OSTI2026

Single-particle detection of enhanced polarizability in Au-decorated semiconducting nanorods via scanning dielectric microscopy

Hybrid nanostructures that combine semiconducting and metallic components offer great potential for photothermal therapy, optoelectronics, and sensing, by integrating tunable optical properties with enhanced light absorption and charge transport. Boosting the integrated performance of these hybrid systems demands techniques capable of probing local variations of the physical properties inaccessible to bulk analysis. Here, we report the single-particle dielectric characterization of hybrid, semiconducting bismuth sulfide (Bi 2 S 3 ) nanorods (NR) decorated with metallic Au nanoparticles (NP), employing scanning dielectric microscopy, which uses electrostatic force microscopy in combination with finite-element numerical simulations. We reveal a pronounced enhancement in the local dielectric response of Bi2S3 upon Au decoration, attributed to interfacial polarization and electron transfer from Au to the Bi 2 S 3 matrix, thus suggesting a enhanced metallic-like polarizability at the single-particle level. Numerical simulations show that the response is dominated by the vertical component of the permittivity and that the decorating metallic Au NP produce only moderate shielding of the semiconductor Bi 2 S 3 NR core, indicating that the large increase in the dielectric response originates primarily from intrinsic modifications within the NR. Overall, these findings provide direct insight into structure–property relationships at the single-particle level, supporting the rational design of advanced hybrid nanostructures with tailored electronic functionalities.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Topological nanophotonics for photoluminescence control

Rare-earth-doped nanocrystals are emerging light sources that can produce tunable emissions in colours and lifetimes, which has been typically achieved in chemistry and material science. However, one important optical challenge – polarization of photoluminescence – remains largely out of control by chemistry methods. Control over photoluminescence polarization can be gained via coupling of emitters to resonant nanostructures such as optical antennas and metasurfaces. However, the resulting polarization is typically sensitive to position disorder of emitters, which is difficult to mitigate. Recently, new classes of disorder-immune optical systems have been explored within the framework of topological photonics. Here we explore disorder-robust topological arrays of Mie-resonant nanoparticles for polarization control of photoluminescence of nanocrystals. We demonstrate polarized emission from rare-earth-doped nanocrystals governed by photonic topological edge states supported by zigzag arrays of dielectric resonators. We verify the topological origin of polarized photoluminescence by comparing emission from nanoparticles coupled to topologically trivial and nontrivial arrays of nanoresonators. We expect that our results may open a new direction in the study of topology-enable emission properties of topological edge states in many photonic systems.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Growth of Large‐Sized 2D Ultrathin SnSe Crystals with In‐Plane Ferroelectricity

Abstract Tin (II) selenide (SnSe) is an emerging 2D material with many intriguing properties, such as record‐high thermoelectric figure of merit (ZT), purely in‐plane ferroelectricity, and excellent nonlinear optical properties. To explore these functional properties and related applications, a crucial step is to develop controllable routes to synthesize large‐area, ultrathin, and high‐quality SnSe crystals. Physical vapor deposition (PVD) constitutes a reliable method to synthesize 2D SnSe, however, effects of various growth parameters have not yet been systematically investigated, and current PVD‐synthesized flakes are often thick (>10 nm) with small lateral sizes (<10 µm). In this work, high‐quality 2D SnSe crystals are synthesized via low‐pressure PVD, which display in‐plane ferroelectric domains observed by piezoresponse force microscopy and polarization‐dependent reflection spectroscopy. Detailed studies regarding the roles of various parameters are further carried out, including substrate pre‐annealing, growth duration, temperature, and pressure, which enable to rationally optimize the growth and obtain 2D SnSe crystals with lateral sizes up to ≈23.0 µm and thicknesses down to ≈2.0 nm (3–4 layers). This work paves the way for the controlled growth of large‐area 2D SnSe, facilitating the future exploration of many interesting multiferroic properties and applications with atomic thickness.

2D materials↗
NASA NTRS1979

Discovery of a soft X-ray flux from AN Ursae Majoris

During November 1975, the soft X-ray detectors on the SAS 3 satellite scanned across AN Ursae Majoris, a star very similar to AM Herculis in its unusual optical properties. A soft (0.1-0.4 keV) X-ray flux averaging 2.8 x 10 to the -11th erg/sq cm-sec was detected from AN UMa, as had been anticipated by analogy with AM Her. Folding the X-ray flux measurement with the known binary period reveals an X-ray light curve with approximately 100% modulation, and thereby secures the identification of the X-ray source as AN UMa. Unlike the case in AM Her, the X-ray minimum in AN UMa occurs midway between optical linear-polarization peaks.

Hearn, D. R.↗
NASA NTRS1994

Ocean color remote sensing using polarization properties of reflected sunlight

The effects of the atmosphere and surface on sunlight backscattered to space by the ocean may be substantially reduced by using the unpolarized component of reflectance instead of total reflectance. At 450 nm, a wavelength of interest in ocean color remote sensing, and for typical conditions, 45% of the unpolarized reflectance may originate from the water body instead of 20% of the total reflectance, which represents a gain of a factor 2.2 in useful signal for water composition retrieval. The best viewing geometries are adjacent to the glitter region; they correspond to scattering angles around 100 deg, but they may change slightly depending on the polarization characteristics of the aerosols. As aerosol optical thickness increases, the atmosphere becomes less efficient at polarizing sunlight, and the enhancement of the water body contribution to unpolarized reflectance is reduced. Since the perturbing effects are smaller on unpolarized reflectance, at least for some viewing geometries, they may be more easily corrected, leading to a more accurate water-leaving signal and, therefore, more accurate estimates of phytoplankton pigment concentration.

R. Frouin↗
DOE OSTI2025

Anomalous neutron nuclear-magnetic interference spectroscopy

The electron–phonon interaction plays a critical role in materials’ electrical, thermal, optical, and superconducting properties. However, measuring the phonon mode-resolved electron–phonon interaction has been challenging. Here we propose neutron-scattering-based Anomalous Neutron nUclear-Magnetic Interference Spectroscopy (ANUBIS), where the co-existence of neutron nuclear scattering and magnetic scattering leads to anomalous dynamical structure factor under the presence of the electron–phonon interaction. Such anomalous structure factor is linear in electron–phonon coupling constant at the phonon wavevector, and is directly proportional to the momentum and energy-resolved dielectric function. The experimental configuration can be achieved using existing polarized inelastic neutron scattering setup, and an order-of-magnitude estimate shows the viability to observe the anomalous scattering signal is around to 10 –4 to 10 –3 relative to phonon scattering, which is examined through the preliminary experiments and achievable at emerging neutron facilities. As a result, our proposal offers an alternative neutron-based metrology to probe the crucial electronic properties.

Electron-phonon interactions↗
NASA NTRS1998

Clouds, Radiation, and Climate from the Earth Observing System

In this presentation, I will present and discuss key areas of scientific uncertainty in understanding climate and global change, focusing on specific examples of how EOS will contribute to improving our understanding of global change. In particular, I will describe how scientists intend to use MODIS, an earth-viewing cross-track scanning spectroradiometer to be flown on the Earth Observing System (EOS) AM-1 satellite to be launched in summer 1998, for the remote sensing of cloud properties. MODIS will scan a swath width sufficient to provide nearly complete global coverage every two days from a polar-orbiting, sun-synchronous, platform at an altitude of 705 km, and will provide images in 36 spectral bands between 0.415 and 14-235 microns with spatial resolutions of 250 m (2 bands), 500 m (5 bands) and 1000 m (29 bands). These bands have been carefully selected to enable advanced studies of land, ocean, and atmosphere processes. As part of this presentation, I will review the various methods that have been developed for the remote sensing of atmospheric properties using MODIS, placing primary emphasis on the principal atmospheric applications of determining the optical, microphysical and physical properties of clouds and aerosol particles from spectral reflection and thermal emission measurements. Additional applications of MODIS data to the determination of precipitable water over land will be described, as will the MODIS cloud mask used to distinguish clouds, clear sky, heavy aerosol, shadows on the ground, and fires. The physical principles behind the determination of each of these atmospheric products will be described, together with an example of their application to aircraft and/or satellite measurements.

King, Michael D.↗
NASA NTRS1988

Soft X-ray/extreme ultraviolet images of the solar atmosphere with normal incidence multilayer optics

High-resolution images of the sun in the soft-X-ray/XUV range have been obtained with normal-incidence multilayer coated optics (MCOs) during a sounding-rocket flight on October 23, 1987 from White Sands. MCOs were used in two Cassegrain telescopes, as off-axis primary mirrors, and as tertiary mirrors operating with a Wolter-Schwarzschild (WS) grazing-incidence mirror. The inherent energy-selective property of MCOs allowed distinct groups of emission lines to be isolated in the solar corona and the transition region. Images were recorded at 173 and 256 A with the Cassegrain telescopes, at 256 A with a Herschelian telescope, and at 44, 173, and 256 A with the WS hybrid telescope. In addition, soft-X-ray images in the 8-18-A bandpass were obtained at the prime focus of the WS optics. The images show many features of the solar corona and transition region, including magnetically confined loops of hot solar plasma, coronal plumes, polar coronal holes, supergranulation, and features associated with overlying cool prominences.

Lindblom, Joakim F.↗
NASA NTRS1992

Disk instability and outburst properties of the intermediate polar GK Persei

The present study reproduces the observed recurrence time scales and duration of the 1981-1989 dwarf nova-type outbursts of the intermediate polar GK Per with a model based on the time-dependent disk instability model. The model gives approximately symmetric (type B, inside-out) outbursts, as observed. This agreement suggests that the outbursts cannot result from a mass transfer instability. A modest variation of the mass transfer rate from the companion is sufficient to account for the variable outburst recurrence time scale. Contamination from the companion and the hot spot dominate the light from the disk except during a bright outburst. An intermediate temperature stagnation wave followed by a full heating wave is consistent with the observed rapid rise and double-peaked structure in the UV and optical light curves. It is argued that the hard X-ray efficiency is dime-dependent, and it is found to be much smaller in outburst than in quiescence.

Kim, Soon-Wook↗
DOE OSTI2022

Charge carrier coupling to the soft phonon mode in a ferroelectric semiconductor

Many crystalline solids possess strongly anharmonic “soft” phonon modes characterized by diminishing frequency as temperature approaches a critical point associated with a symmetry breaking phase transition. While electron–soft phonon coupling can introduce unique scattering channels for charge carriers in ferroelectrics, recent studies on the nonferroelectric lead halide perovskites have also suggested the central role of anharmonic phonons bearing resemblance to soft modes in charge carrier screening. Here we apply coherent phonon spectroscopy to directly study electron coupling to the soft transverse optical phonon mode in a ferroelectric semiconductor SbSI. Photogenerated charge carriers in SbSI are found to be exceptionally long lived and are associated with a transient electro-optical effect that can be explained by interactions between charge carriers and thermally stimulated soft phonon excitations. Furthermore, these results provide strong evidence for the role of electron–soft phonon coupling in the efficient screening of charge carriers and in reducing charge recombination rates, both desirable properties for optoelectronics.

36 MATERIALS SCIENCE↗
NASA NTRS2016

The Role of Cloud Contamination, Aerosol Layer Height and Aerosol Model in the Assessment of the OMI Near-UV Retrievals Over the Ocean

Retrievals of aerosol optical depth (AOD) at 388 nm over the ocean from the Ozone Monitoring Instrument (OMI) two-channel near-UV algorithm (OMAERUV) have been compared with independent AOD measurements. The analysis was carried out over the open ocean (OMI and MODerate-resolution Imaging Spectrometer (MODIS) AOD comparisons) and over coastal and island sites (OMI and AERONET, the AErosol RObotic NETwork). Additionally, a research version of the retrieval algorithm (using MODIS and CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) information as constraints) was utilized to evaluate the sensitivity of the retrieval to different assumed aerosol properties. Overall, the comparison resulted in differences (OMI minus independent measurements) within the expected levels of uncertainty for the OMI AOD retrievals (0.1 for AOD less than 0.3, 30% for AOD greater than 0.3). Using examples from case studies with outliers, the reasons that led to the observed differences were examined with specific purpose to determine whether they are related to instrument limitations (i.e., pixel size, calibration) or algorithm assumptions (such as aerosol shape, aerosol height). The analysis confirms that OMAERUV does an adequate job at rejecting cloudy scenes within the instrument's capabilities. There is a residual cloud contamination in OMI pixels with quality flag 0 (the best conditions for aerosol retrieval according to the algorithm), resulting in a bias towards high AODs in OMAERUV. This bias is more pronounced at low concentrations of absorbing aerosols (AOD 388 nm approximately less than 0.5). For higher aerosol loadings, the bias remains within OMI's AOD uncertainties. In pixels where OMAERUV assigned a dust aerosol model, a fraction of them (less than 20 %) had retrieved AODs significantly lower than AERONET and MODIS AODs. In a case study, a detailed examination of the aerosol height from CALIOP and the AODs from MODIS, along with sensitivity tests, was carried out by varying the different assumed parameters in the retrieval (imaginary index of refraction, size distribution, aerosol height, particle shape). It was found that the spherical shape assumption for dust in the current retrieval is the main cause of the underestimate. In addition, it is demonstrated in an example how an incorrect assumption of the aerosol height can lead to an underestimate. Nevertheless, this is not as significant as the effect of particle shape. These findings will be incorporated in a future version of the retrieval algorithm.

aerosols↗
DOE OSTI2026

Tunable Electronic Energy Level Alignment and Exciton Diversity in Organic–Inorganic van der Waals Heterostructures

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic monolayers, incorporating molecular monolayers introduces additional degrees of tunability and functionality. Here, in this study, we investigate hybrid bilayers composed of atomically thin perylene-based molecular crystals interfaced with monolayer transition metal dichalcogenides (TMDs), specifically MoS 2 and WS 2 . Using the ab initio many-body perturbation theory within the GW approximation and the Bethe-Salpeter equation approach, we predict emergent properties beyond those of the isolated constituent systems. Notably, we find substantial renormalization of monolayer molecular crystal band gap due to TMD-induced polarization. Furthermore, by varying the TMD monolayer, we demonstrate tuning of the energy level alignment of the bilayer and subsequent control over a diversity of lowest-energy excitons, which include strongly bound hybrid excitons and long-lived charge-transfer excitons. These findings establish organic-inorganic van der Waals heterostructures as a promising class of materials for tunable optoelectronic devices and quantum excitonic phenomena, expanding the design space for low-dimensional systems.

GW-BSE calculations↗
NASA NTRS2010

The Formation of Graphite Whiskers in the Primitive Solar Nebula

It has been suggested that carbonaceous grains are efficiently destroyed in the interstellar medium and must either reform in situ at very low pressures and temperatures or in an alternative environment more conducive to grain growth. Graphite whiskers have been discovered associated with high-temperature phases in meteorites such as calcium aluminum inclusions and chondrules, and it has been suggested that the expulsion of such material from proto stellar nebulae could significantly affect the optical properties of the average interstellar grain population. We have experimentally studied the potential for Fischer-Tropsch and Haber-Bosch type reactions to produce organic materials in protostellar systems from the abundant H2, CO, and N2 reacting on the surfaces of available silicate grains. When graphite grains are repeatedly exposed to H2, CO, and N2 at 875 K abundant graphite whiskers are observed to form on or from the surfaces of the graphite grains. In a dense, turbulent nebula, such extended whiskers are very likely to be broken off, and fragments could be ejected either in polar jets or by photon pressure after transport to the outer reaches of the nebula.

Nuth, Joseph A., III↗
NASA NTRS2010

The Vector Vortex Coronagraph: Sensitivity to Low-Order Aberrations, Central Obscuration, Chromaticism, and Polarization

The Vector Vortex Coronagraph is a phase-based coronagraph, one of the most efficient in terms of inner working angle, throughput, discovery space, contrast, and simplicity. Using liquid-crystal polymer technology, this new coronagraph has recently been the subject of lab demonstrations in the near-infrared, visible and was also used on sky at the Palomar observatory in the H and K bands (1.65 and 2.2 micrometers, respectively) to image the brown dwarf companion to HR 7672, and the three extasolar planets around HR 8799. However, despite these recent successes, the Vector Vortex Coronagraph is, as are most coronagraphs, sensitive to the central obscuration and secondary support structures, low-order aberrations (tip-tilt, focus, etc), bandwidth (chromaticism), and polarization when image-plane wavefront sensing is performed. Here, we consider in detail these sensitivities as a function of the topological charge of the vortex and design properties inherent to the manufacturing technology, and show that in practice all of them can be mitigated to meet specific needs.

large ground-based telescopes↗
NASA NTRS2000

Development of Highly Fluorescent Materials Based on Thiophenylimidazole Dyes

Organic fluorescent materials are expected to find many potential applications in optical devices and photo-functionalized materials. Although many investigations have been focused on heterocyclic compounds such as coumarins, bipyridines, rhodamines, and pyrrole derivatives, little is known for fluorescent imidazole materials. We discovered that one particular class of imidazole derivatives is highly fluorescent. A series of monomeric and polymeric based fluorescent dyes were prepared containing a thiophene unit at the second position of the imidazole ring. Dependence of fluorescence efficiency on parameters such as solvent polarity and substituent groups has been investigated. It was found that a formyl group at the 2-position of the thiophene ring dramatically enhance fluorescence properties. Ion recognition probes indicated their potential as sensor materials. These fluorophores have flexibility for introduction of versatile substituent groups that could improve the fluorescence efficiency and sensor properties.

Santos, Javier↗