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At least 649 records · Page 36

Ensuring Flexibility and Security in SDN-Based Spacecraft Communication Networks Through Risk Assessment

Software-defined networking (SDN) has enabled elastic networking and resource distribution in cloud computing. The centralization and separation of the Control Plane also offers a high degree of network configurability and management, which can be used to mitigate and manage threats to the network. Space communication networks have historically been restricted and circuit switching in these networks has been a manual process. This study evaluates the potential role of SDN in space communication networks from a networking security standpoint. The evaluation covers the networking security needs of spacecraft missions and their associated assets. The results from the evaluation lead to a risk assessment that identifies vulnerabilities in an SDN-based communications architecture. Security challenges introduced into the network from integrating SDN are also considered. A risk register summarizes the severity of the attack outcomes, as well as occurrence likelihood. The study identifies Denial-of-Service (DoS) attacks as a new threat (presently unmitigated by existing security controls) that would be prevalent in an SDN-based space communication environment. A Mininet-based emulation testbed is built to demonstrate the susceptibility of spacecraft flight software to a flooding DoS attack when on an interconnected SDN-managed network. This type of attack would be highly consequential to mission assets, and therefore SDN-based space communications would need to be resilient to such attacks. Future work will need to be performed to fully characterize DoS attack methods that can apply to the space communication scenario, as well as to devise a comprehensive DoS-resilient solution.

Baker, Dylan Z.↗

An Experimental Investigation concerning the Effects of AFP Defects on Progressive Failure of Tensile Coupons

This paper discusses characterization approaches for the evaluation of potential defects that may occur during the automated fiber placement (AFP) process. Two nondestructive evaluation techniques were utilized simultaneously, acoustic emission (AE) and digital image correlation (DIC), to investigate correlations between mechanical properties and damage propagation during tension tests. The layup configuration is designed with the defect running across the width, and the stacking sequence with seven layers is produced: [−45/0/45/̅9̅̅0̅]s. A total of 3 panels were manufactured: one containing a gap defect in the middle layer, another one with an overlap defect, and a pristine panel for baseline comparison. Each panel accommodates six coupons having dimensions of 20” x 2”. The results indicate that defects caused during the manufacturing process affect damage initiation and growth.

Anay, Rafal↗

CarbonSAFE Illinois - Macon County

CarbonSAFE Illinois is a a Feasibility study to develop an established geologic storage complex in Macon County, Illinois, for commercial-scale storage of industrially sourced CO2. Feasibility activities are focused on the Mt. Simon Storage Complex; a step-out well will be drilled near existing storage sites (i.e., the Midwest Geological Sequestration Consortium’s Illinois Basin – Decatur Project and the Illinois Industrial Carbon Capture and Storage Project) to further establish commercial viability of this complex and to evaluate EOR potential in a co-located oil-field trend. The Archer Daniels Midland facility (ethanol plant), City Water, Light, and Power in Springfield, Illinois (coal-fired power station), and other regional industries are potential sources of anthropogenic CO2 for storage at this complex. Site feasibility will be evaluated through drilling results, static and dynamic modeling, and quantitative risk assessment. Both studies will entail stakeholder engagement, consideration of infrastructure requirements, existing policy, and business models. Project data will help calibrate the National Risk Assessment Partnership (NRAP) Toolkit to better understand the risks of commercial-scale carbon storage.

Whittaker, Steve↗

Integrated Pre-Feasibility Assessment for a Northern Michigan Basin CarbonSAFE CO 2 Storage Complex

One of the key gaps in the critical path toward carbon capture and storage (CCS) deployment is the development of commercial-scale (50+ million metric tons carbon dioxide [CO2]) geologic storage sites for CO 2 from industrial sources. There has been relatively little effort by the private sector to identify and certify (i.e., regulatory permit) geologic storage sites that are capable of storing commercial-scale volumes of CO 2 , primarily because of the lack of immediate economic incentives. As a result, commercial-scale CO 2 sources that want to develop CCS projects face the risk of not finding a suitable saline storage site for their captured CO 2 . Carbon Storage Assurance Facility Enterprise (CarbonSAFE) is a U.S. Department of Energy (DOE)-sponsored effort to develop an integrated CCS storage complex constructed and permitted for operation in the 2025 timeframe over a series of sequential phases of development: Integrated CCS Pre-Feasibility, Storage Complex Feasibility, Site Characterization, and Permitting and Construction. Subject to availability of funds, a series of funding opportunity announcements (FOAs) are planned to accomplish this mission. This document describes a project that addresses DOE FOA-1584 Phase I: Integrated Carbon Capture and Storage (CCS) Pre-Feasibility. The objective of this project was to take the first step in developing an integrated commercial geologic CO 2 storage complex in the Northern Michigan Basin, herein referred to as the CarbonSAFE – Northern Michigan Basin (CS-NMB) storage complex. This includes demonstrating that the storage sites within the complex have the potential to store more than 50 million metric tons (MMT) of industrially-sourced CO 2 emissions safely, permanently and economically. To achieve the overall objective of the Phase I pre-feasibility study, FOA-1584 required three activities: • Perform a high-level technical sub-basinal evaluation to identify a potential storage complex with storage site(s), including a description of the geology and risks associated with the potential storage site; identify and evaluate potential CO 2 sources. • Develop a plan for the storage complex and storage site(s) including a strategy that would enable an integrated capture and storage project to be economically feasible and publicly acceptable. • Form a CCS coordination team capable of addressing regulatory, legislative, technical, public policy, commercial, financial, etc. challenges specific to commercial-scale deployment of the CO 2 storage project.

20 FOSSIL-FUELED POWER PLANTS↗

Improving turbine engine compressor performance retention through airfoil coatings

In order to evaluate the potential effectiveness of coatings in limiting erosive damage to compressor airfoils, an effort was initiated to evaluate candidate coatings for substrate alloys typically used in commercial engine high compressor blades. Laboratory and rig erosion testing of plasma deposited and diffusion coatings described in this paper have shown the potential of a two to four fold improvement in erosion life. The selective application of these coatings to approximately the outer third of the airfoil avoids coating the fatigue critical region of the blade, thus providing erosion resistance potentially without compromising the fatigue strength of the blade. Both the plasma and the diffusion coatings also offer the advantage of low initial cost and a multi-source production base.

Friedrich, L. A.↗

Geothermal potential of Harrat Rahat, Northern Arabian Shield: geological constraints

Arabian Shield offers a strong potential for geothermal energy. However, only a limited amount of exploration effort has taken place. Harrat Rahat is a recent volcanic area located along the Makkah-Madinah-Nafud volcanic line in western Saudi Arabia. This study is oriented to identify the geothermal potential of Harrat Rahat. The geologic data was collected and processed. Here, we focus on evaluating the potential sources of subsurface heat and groundwater. Subsurface heat is based on the age of erupted volcanoes and the expected volume of subsurface magma chambers. An analogy with an existing geothermal field in a similar setting as Mexico suggests that the faults and the coincident seismicity may be associated with higher permeability. It is concluded that Harrat Rahat is characterized by a good geothermal potential for future geothermal energy source production.

58 GEOSCIENCES↗

Human Health Risk Assessment Methods for PV (Part 2: Breakage Risks)

Photovoltaic (PV) modules are designed and tested for long-term durability in harsh outdoor environments, but a small percentage may break during installation or operation. Some industry stakeholders have expressed concerns regarding potential human exposure to hazardous materials should a PV module break in the field. To evaluate these concerns, screening-level risk assessment methods are presented that can estimate emissions that may occur when broken PV modules are exposed to rainwater, estimate the associated chemical concentrations in soil, groundwater and air, and finally compare these exposure-point concentrations to health-protective screening levels based on 1 x 10-6 cancer risk and hazard quotient of 1. The screening-level methods can be used to decide whether further evaluation of potential health risks is warranted. A few example scenarios demonstrate application of the methods. Specifically, this report presents an analysis of potential human health impacts associated with rainwater leaching from broken modules for two PV technologies, focusing on release of the highest-prioritized chemical element for each: lead (Pb) content in crystalline-silicon (c-Si) PV modules and cadmium (Cd) content in thin film cadmium telluride (CdTe) PV modules. The prioritization of these chemical elements for analysis is based on stakeholder interest. Because the methodology is chemical-specific, the risk assessment results for these chemicals cannot be directly generalized to other chemicals, although the risk assessment methodology can be applied to other chemicals.

14 SOLAR ENERGY↗

Aquifer Injection Modeling (AIM) Toolbox User Guide

The Aquifer Injection Modeling Toolbox (“AIM Toolbox”) software was developed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Environmental Protection Agency’s (EPA) to provide a collection of analytical solutions suitable for evaluating the potential extent of the area impacted by subsurface injection operations. Subsurface injection operations are regulated under the EPA’s Underground Injection Control (UIC) program and are typically related to oil/gas development, waste disposal, or subsurface mining or storage. The analytical algorithms provided in the AIM Toolbox each have different approaches/assumptions/focus with respect to the nature and processes in subsurface and the nature of the injection operations. Collectively the set of analysis algorithms provides a broader evaluation of the area that can potentially be impacted by an injection operation. By providing estimates for the injectate plume extent, the software supports technical aspects of planning, evaluation, and overseeing injection activities. That is, the results help assess when further regulatory controls (e.g., monitoring, reporting) may be required and, in the case of disposal into an underground source of drinking water, the extent of the impacted area would require exemption from protection under the Safe Drinking Water Act. The AIM Toolbox software is available as a single-page web application, providing an interface to provide the necessary inputs, and both chart and map panes for visualizing the results. This User Guide describes the AIM Toolbox software, information required, user interactions, and the underlying basis of the calculations.

54 ENVIRONMENTAL SCIENCES↗

Aquifer Injection Modeling (AIM) Toolbox User Guide

The Aquifer Injection Modeling Toolbox (“AIM Toolbox”) software was developed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Environmental Protection Agency’s (EPA) to provide a collection of analytical solutions suitable for evaluating the potential extent of the area impacted by subsurface injection operations. Subsurface injection operations are regulated under the EPA’s Underground Injection Control (UIC) program and are typically related to oil/gas development, waste disposal, or subsurface mining or storage. The analytical algorithms provided in the AIM Toolbox each have different approaches/assumptions/focus with respect to the nature and processes in subsurface and the nature of the injection operations. Collectively the set of analysis algorithms provides a broader evaluation of the area that can potentially be impacted by an injection operation. By providing estimates for the injectate plume extent, the software supports technical aspects of planning, evaluation, and overseeing injection activities. That is, the results help assess when further regulatory controls (e.g., monitoring, reporting) may be required and, in the case of disposal into an underground source of drinking water, the extent of the impacted area would require exemption from protection under the Safe Drinking Water Act. The AIM Toolbox software is available as a single-page web application, providing an interface to provide the necessary inputs, and both chart and map panes for visualizing the results. This User Guide describes the AIM Toolbox software, information required, user interactions, and the underlying basis of the calculations.

58 GEOSCIENCES↗

The Impact of Current and Future Polar Orbiting Satellite Data on Numerical Weather Prediction at NASA/GSFC

The lack of adequate observational data continues to be recognized as a major factor limiting both atmospheric research and numerical prediction on a variety of temporal and spatial scales. Since the advent of meteorological satellites in the 1960's, a considerable research effort has been directed toward the design of space-borne meteorological sensors, the development of optimal methods for the utilization of these data, (and an assessment of the influence of existing satellite data and the potential influence of future satellite observations on numerical weather prediction. This has included both Observing System Experiments (OSEs) and Observing System Simulation Experiments (OSSEs). OSEs are conducted to evaluate the impact of specific observations or classes of observations on analyses and forecasts. While OSEs are performed with existing data, OSSEs are conducted to evaluate the potential for future observing systems to improve-NWP, as well as to evaluate trade-offs in observing system design, and to develop and test improved methods for data assimilation. At the conference, results from OSEs to evaluate satellite data sets that have recently become available to the global observing system, such as AIRS and Seawinds, and results from OSSEs to determine the potential impact of space-based lidar winds will be presented.

Atlas, Robert↗

Niagara Falls Storage Site - Interim Waste Containment Structure - 16199

The Niagara Falls Storage Site (NFSS) is a 77.3-hectare (ha) (191-acre) property that is owned by the United States Government and located in the township of Lewiston, Niagara County, New York. The NFSS is part of the former Lake Ontario Ordnance Works (LOOW) that was used by the War Department beginning in 1942 for the production of trinitrotoluene (TNT). During the 1940's and 1950's, the Manhattan Engineer District and the Atomic Energy Commission brought various radioactive wastes and uranium processing byproducts (residues) resulting from our nation's atomic energy program to the LOOW for storage. Site operations caused soil, sediment, and groundwater contamination that lead to several remedial actions, which culminated in the construction of the Interim Waste Containment Structure (IWCS) on the NFSS. The U.S. Army Corps of Engineers (USACE)-Buffalo District is the lead Federal agency for Formerly Utilized Sites Remedial Action Program (FUSRAP) remediation of the NFSS. As the lead agency, USACE is conducting a remedial investigation/feasibility study (RI/FS) pursuant to the protocols set forth in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). CERCLA activities at the NFSS have transitioned from the site RI activities to the FS evaluation of potential remediation alternatives. USACE recognizes the need to implement a focused CERCLA FS process and, therefore, has established three separate operable units (OUs) for NFSS: the IWCS OU, the Balance of Plant (BOP) OU [i.e., all on-site areas outside the boundary of the IWCS], and the Groundwater OU. This paper will discuss the following: - Provide background information on the NFSS including the nature of the materials within the IWCS. - Explain the steps of the CERCLA and associated processes the Formerly Utilized Sites Remedial Action Program (FUSRAP) employs. - Describe the OUs for the NFSS property and the subunit designations used in the FS evaluations for the IWCS OU. - Provide the current project status within the CERCLA framework and path forward for all OUs and Vicinity Properties (VPs). Identify the Applicable or Relevant and Appropriate Requirements (ARARs) preferred by USACE and the regulatory agencies and explain the differences between the two positions. - Provide the comparative evaluation of the remedial alternatives assessed in the FS. - Identify the justifications for the USACE - Buffalo District selecting the preferred remedial alternative within the Proposed Plan. The remedial action objectives for the IWCS OU are designed to provide short- and long-term protection of human health and the environment. CERCLA requires that any action taken be protective of human health and the environment as well as be compliant with identified ARARs. USACE evaluated 'No Action' and four potential remedial alternatives for the IWCS OU that ranged from leaving all of the wastes in-place and installing a final cover to partial and full removal of the contents. The four alternatives met the remedial action objectives defined identified for the IWCS OU. In accordance with the statutory requirements of CERCLA Section 121, remedial alternatives must comply with two threshold criteria, overall protection of human health and the environment and compliance with ARARs, in order to be carried forward for further evaluation. If a remedial alternative meets the threshold criteria, it is evaluated against the following five balancing criteria: - Long-term effectiveness and permanence; - Reduction in toxicity, mobility, or volume through treatment; - Short-term effectiveness; - Implementability; and, - Cost. The Feasibility Study evaluation led to the preferred remedial alternative selection and this will be the focus of this paper. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone–Alkylthiocarbamate Metal Complexes

A series of hybrid ligands (H 2 L 1 –H 2 L 3 ) derived from 4-methyl-3-thiosemicarbazide and hydrazinecarbothioic acid O-alkyl esters were synthesized and characterized by NMR. The ligands were chelated with copper (4–6), nickel (7–9), and zinc (10–12) and characterized by spectroscopy, electrochemistry, and single crystal X-ray crystallography. The chelated metals displayed substantial anodic shifts in the Cu II/I reduction potential of ~160 mV relative to their bis(thiosemicarbazone) analogues. The metal chelates 4–12 were evaluated for potential anticancer activity by MTT assays, and selected results were confirmed by clonogenic and trypan blue assays. The copper derivatives 4 and 6 were found to have potent and cancer-selective antiproliferative effects, with GI 50 values less than 100 nM in A549 lung adenocarcinoma cells compared with at least 20-fold less activity in IMR90 nonmalignant lung fibroblasts. In comparison, the nickel complexes were much less active and had little cancer-selectivity. Varying by ligand, the zinc complexes were less potent or had comparable activity compared to that of the corresponding copper complex. UV–visible spectroscopy indicated that zinc complex 10 was transmetalated in the presence of equimolar copper, whereas nickel complex 7 was not. Copper complexes 4 and 6 were also assessed in the NCI60 screen and were found to have cytotoxic activity against most solid tumor cell lines. In MTT assays, 4 and 6 were substantially more active against A549 cancer cells than Cu(ATSM) and were more cancer-selective (for A549 compared to IMR-90) than Cu(GTSM). Finally, our results suggest that hybrid thiosemicarbazone–alkylthiocarbamate copper complexes have potential for development as new anticancer agents.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessing the Solar Photovoltaic (PV) Potential in Puerto Rican Brownfields and Reservoirs: Detailed Results and Methodology Annex [Slides]

This is the technical annex for "Assessing the Solar Photovoltaic (PV) Potential in Puerto Rican Brownfields and Reservoirs." This study by the National Renewable Energy Laboratory (NREL) evaluates the potential for solar photovoltaic (PV) development on brownfields and reservoirs in Puerto Rico. Redeveloping these sites offers significant benefits, such as expanding energy infrastructure, supporting environmental remediation, and enhancing community revitalization. The study identifies up to 3.3 gigawatts (GW) of solar PV capacity, including 213 megawatts (MW) on closed landfills, 1-2.5 GW on contaminated sites, 78 MW on decommissioned plants, 21-50 MW on transmission line rights-of-way, and 636 MW on waterbodies for floating PV. This research highlights the strategic importance of investments and regulatory support to achieve Puerto Rico's goal of 100% clean energy by 2050.

14 SOLAR ENERGY↗

Vapor Phase Catalytic Ammonia Reduction

This paper discusses the development of a Vapor Phase Catalytic Ammonia Reduction (VPCAR) teststand and the results of an experimental program designed to evaluate the potential of the technology as a water purification process. In the experimental program the technology is evaluated based upon product water purity, water recovery rate, and power consumption. The experimental work demonstrates that the technology produces high purity product water and attains high water recovery rates at a relatively high specific power consumption. The experimental program was conducted in 3 phases. In phase I an Igepon(TM) soap and water mixture was used to evaluate the performance of an innovative Wiped-Film Rotating-Disk evaporator and associated demister. In phase II a phenol-water solution was used to evaluate the performance of the high temperature catalytic oxidation reactor. In phase III a urine analog was used to evaluate the performance of the combined distillation/oxidation functions of the processor.

Flynn, Michael T.↗

High speed turboprops for executive aircraft, potential and recent test results

Four high speed propeller models were designed and tested in an 8x6 foot wind tunnel in order to evaluate the potential of advanced propeller technology. Results from these tests show that the combination of: increased blade number, aerodynamically integrated propeller/nacelles, reduced blade thickness, spinner area ruling, and blade sweep are important in achieving high propeller efficiency at the high cruise speeds.

Mikkelson, D. C.↗

Potential of GPM IMERG Precipitation Estimates to Monitor Natural Disaster Triggers in Urban Areas: the Case of Rio deJaneiro, Brazil

Extreme rainfall can be a catastrophic trigger for natural disaster events at urban scales. However, there remains large uncertainties as to how satellite precipitation can identify these triggers at a city scale. The objective of this study is to evaluate the potential of satellite-based rainfall estimates to monitor natural disaster triggers in urban areas. Rainfall estimates from the Global Precipitation Measurement (GPM) mission are evaluated over the city of Rio de Janeiro, Brazil, where urban floods and landslides occur periodically as a result of extreme rainfall events. Two rainfall products derived from the Integrated Multi-satellite Retrievals for GPM (IMERG), the IMERG Early and IMERG Final products, are integrated into the Noah Multi-Parameterization (Noah-MP) land surface model in order to simulate the spatial and temporal dynamics of two key hydrometeorological disaster triggers across the city over the wet seasons during 2001-2019. Here, total runoff (TR) and rootzone soil moisture (RZSM) are considered as flood and landslide triggers, respectively. Ground-based observations at 33 pluviometric stations are interpolated, and the resulting rainfall fields are used in an in-situ precipitation-based simulation, considered as the reference for evaluating the IMERG-driven simulations. The evaluation is performed during the wet seasons (November-April), when average rainfall over the city is 4.4mm/day. Results show that IMERG products show low spatial variability at the city scale, generally overestimate rainfall rates by 12-35%, and impacts on TR and RZSM vary spatially mostly as a function of land cover and soil types. Results based on statistical and categorical metrics show that IMERG skill in detecting extreme events is moderate, with IMERG Final performing slightly better for most metrics. By analyzing two recent storms, we observe that IMERG detects mostly hourly extreme events, but underestimates rainfall rates, resulting in underestimated TR and RZSM. An evaluation of normalized time series using percentiles shows that both satellite products have significantly improved skill in detecting extreme events when compared to the evaluation using absolute values, indicating that IMERG precipitation could be potentially used as a predictor for natural disasters in urban areas.

IMERG↗

Opportunities for increasing CO 2 storage in deep, saline formations by active reservoir management and treatment of extracted formation water: Case study at the GreenGen IGCC facility, Tianjin, PR China

Carbon capture, utilization and storage (CCUS) seeks beneficial applications for CO 2 recovered from fossil fuel combustion. This study evaluated the potential for removing formation water to create additional storage capacity for CO 2 , while simultaneously treating the produced water for beneficial use. Furthermore, the process would control pressures within the target formation, lessen the risk of caprock failure, and better control the movement of CO 2 within that formation. The project plans to highlight the method of using individual wells to produce formation water prior to injecting CO 2 as an efficient means of managing reservoir pressure. Because the pressure drawdown resulting from pre-injection formation water production will inversely correlate with pressure buildup resulting from CO 2 injection, it can be proactively used to estimate CO 2 storage capacity and to plan well-field operations. The project studied the GreenGen site in Tianjin, China where Huaneng Corporation is capturing CO 2 at a coal fired IGCC power plant. Known as the Tianjin Enhanced Water Recovery (EWR) project, local rock units were evaluated for CO 2 storage potential and produced water treatment options were then developed. Average treatment cost for produced water with a cooling water treatment goal ranged from 2.27 to 2.96 US$/m 3 (recovery 95.25%), and for a boiler water treatment goal ranged from 2.37 to 3.18 US$/m 3 (recovery 92.78%). Importance analysis indicated that water quality parameters and transportation are significant cost factors as the injection-extraction system is managed over time. Our study found that in a broad sense, active reservoir management in the context of CCUS/EWR is technically feasible. In addition, criteria for evaluating suitable vs. unsuitable reservoir properties, reservoir storage (caprock) integrity, a recommended injection/withdrawal strategy and cost estimates for water treatment and reservoir management are proposed.

54 ENVIRONMENTAL SCIENCES↗

A method and tool to determine the colorimetric and photobiological properties of light transmitted through glass and other optical materials

Here we describe a framework and provides a computational tool to characterize the color quality and biological potential of light that is transmitted through glass and other optical materials. The IES TM-30 framework and Excel computation tool were adapted to evaluate color quality, with measures from CIE S 026, UL 24480, and the WELL Building Standard v2 added to evaluate biological potential. The user selects a pre-transmittance spectral power distribution (SPD), such as for a CIE D-Series Illuminant, Planckian radiation, electric lamp, or measurement of daylight at a building site. The tool allows a user to populate a database with spectral data for glazing or other optical materials, comprising spectral transmission and the spectral reflectance of both sides. The user creates a unit with one, two, or three panes of glazing or other optical materials, and the tool calculates the composite spectral transmittance accounting for reflections between materials. The tool computes the transmitted SPD, then determines colorimetric and photobiological outputs using the transmitted SPD as the test source. Glass, window, and skylight manufacturers can employ the tool to optimize glazing spectral transmission to achieve intentional colorimetric and photobiological performance with transmitted light. Electric lighting manufacturers, designers, and researchers can use the tool to evaluate the impact of glazing units and other optical materials on the color quality and biological potential of transmitted light.

36 MATERIALS SCIENCE↗