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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1992

A preliminary study of the variability and magnitude of the flux of biogenic sulfur gases from a New Hampshire salt marsh

Salt marshes have highly variable spatial and temporal fluxes of hydrogen sulfide, carbonyl sulfide, methane thiol, dimethyl sulfide, and carbon disulfide (H2S, COS, MeSH, DMS, and CS2, respectively). This variability was tested at nine emission sites in a New Hampshire, USA salt marsh: three replicates in each of three vegetation zones, Spartina alterniflora, S. patens, and a transition zone. Three sites were sampled simultaneously, either within or across vegetation zones, using a dynamic flux chamber technique. Difficulties with calibration and field equipment resulted in fluxes with maximum absolute uncertainties of greater than plus or minus 200 percent. However, the relative uncertainty between subsequent samples was closer to plus or minus 20 percent. Chambers are expected to affect the natural flux of gases by altering the humidity, temperature, and composition of the gas inside the chamber. Summertime fluxes are highest for all gases except COS which demonstrated evidence of a springtime peak. A summertime background flux of 5 to 100 x 10(exp -9) g S/m(sup -2) min was observed for all gases, while S alternifora fluxes of MeSH and DMS were approximately 8 fold and approximately 100 fold higher than S. patens, respectively. DMS and MeSH fluxes were higher during the day than at night. Evidence of COS uptake by plants was observed. CS2 appeared to be the quantitatively least important sulfur gas emitted. Improved laboratory and sample collection techniques and further data collection in the field will yield information on the details of salt marsh variability, will improve estimates of the error associated with single flux measurements, and will allow a more accurate estimation of sulfur fluxes from salt marshes based on vegetation and area coverage data. Inability to control the temperature and humidity inside of the chamber remain significant problems with the chamber design.

Morrison, Michael Cope↗
NASA NTRS1993

Procedures for analysis of debris relative to Space Shuttle systems

Debris samples collected from various Space Shuttle systems have been submitted to the Microchemical Analysis Branch. This investigation was initiated to develop optimal techniques for the analysis of debris. Optical microscopy provides information about the morphology and size of crystallites, particle sizes, amorphous phases, glass phases, and poorly crystallized materials. Scanning electron microscopy with energy dispersive spectrometry is utilized for information on surface morphology and qualitative elemental content of debris. Analytical electron microscopy with wavelength dispersive spectrometry provides information on the quantitative elemental content of debris.

Kim, Hae Soo↗
NASA NTRS1993

Gas-grain simulation experiment module conceptual design and gas-grain simulation facility breadboard development

This report delineates the Option portion of the Phase A Gas-Grain Simulation Facility study. The conceptual design of a Gas-Grain Simulation Experiment Module (GGSEM) for Space Shuttle Middeck is discussed. In addition, a laboratory breadboard was developed during this study to develop a key function for the GGSEM and the GGSF, specifically, a solid particle cloud generating device. The breadboard design and test results are discussed and recommendations for further studies are included. The GGSEM is intended to fly on board a low earth orbit (LEO), manned platform. It will be used to perform a subset of the experiments planned for the GGSF for Space Station Freedom, as it can partially accommodate a number of the science experiments. The outcome of the experiments performed will provide an increased understanding of the operational requirements for the GGSF. The GGSEM will also act as a platform to accomplish technology development and proof-of-principle experiments for GGSF hardware, and to verify concepts and designs of hardware for GGSF. The GGSEM will allow assembled subsystems to be tested to verify facility level operation. The technology development that can be accommodated by the GGSEM includes: GGSF sample generation techniques, GGSF on-line diagnostics techniques, sample collection techniques, performance of various types of sensors for environmental monitoring, and some off-line diagnostics. Advantages and disadvantages of several LEO platforms available for GGSEM applications are identified and discussed. Several of the anticipated GGSF experiments require the deagglomeration and dispensing of dry solid particles into an experiment chamber. During the GGSF Phase A study, various techniques and devices available for the solid particle aerosol generator were reviewed. As a result of this review, solid particle deagglomeration and dispensing were identified as key undeveloped technologies in the GGSF design. A laboratory breadboard version of a solid particle generation system was developed and characterization tests performed. The breadboard hardware emulates the functions of the GGSF solid particle cloud generator in a ground laboratory environment, but with some modifications, can be used on other platforms.

Zamel, James M.↗
NASA NTRS1994

A mineralogical instrument for planetary applications

The mineralogy of a planetary surface can be used to identify the provenance of soil or sediment and reveal the volcanic, metamorphic and/or sedimentological history of a particular region. We have discussed elsewhere the applications and the instrument design of possible X-ray diffraction and X-ray fluorescence (XRD/XRF) devices for the mineralogical characterization of planetary surfaces. In this abstract we evaluate some aspects of sample-detector geometry and sample collection strategies.

Blake, David F.↗
NASA NTRS1994

Terrain modelling and motion planning for an autonomous exploration rover

To assess the feasibility of planetary exploration missions using rovers, the French national agency CNES, with a consortium of European laboratories and industrial concerns, has initiated the Eureka project, 'Illustration of an Autonomous Robot for the Exploration of Space' (IARES). IARES is a demonstrator composed of a rover and a ground station, linked by telemetry and telecommand. It is aimed at verifying, on earth, robotic concepts developed by the RISP group of French laboratories (LAAS, INRIA, CERT, LETI) to perform scientific missions such as autonomous terrain sample collecting over large areas. To cope with the actual needs of planet exploration, IARES suitability is assessed through constraints on limited bandwidth, time delay and on-board resources. This autonomy relies heavily on robust onboard trajectory generation capabilities. This paper presents the main functions of the IARES navigation sub-system and shows how they are combined to allow movement in Mars-like environments. Section 2 gives an overall description of the IARES system. Section 3 details the functions of the Navigation sub-system, and finally, section 4 illustrates with a simple example the use of these functions.

Richard, F.↗
NASA NTRS1993

Application of MAC-Europe AVIRIS data to the analysis of various alteration stages in the Landdmannalauger Hydrothermal Area (South Iceland)

In June 1991 extensive airborne remote sensing data-sets have been acquired over Iceland in the framework of the joint NASA/ESA Multisensor Airborne Campaign Europe (MAC-Europe). The study area is located within the Torfajokull central volcanic complex in South Iceland. This complex is composed by anomalously abundant rhyolitic acid volcanics, which underwent intensive hydrothermal alteration. Detailed studies of surface alteration of rhyolitic rocks in the area showed that all the major elements are leached as the rock is affected by complex mineralogical changes. Montmorillonite appears during the earliest stages of alteration. In the ultimate alteration product montmorillonite is absent and the rock consists mostly of amorphous silica, anatase, up to a volume of 50% kaolinite and variable amounts of native sulphur and pyrite. The case study presented shall endeavor to assess the potential of MAC-Europe AVIRIS and TMS data in determining a possible zonation of hydrothermal alteration in relationship to the active geo-thermal fields and structural features. To this end, the airborne data is analysed in comparison with laboratory spectral measurements of characteristics rock, soil, and vegetation samples collected in the study areaduring the summer of 1992. Various spectral mapping algorithms as well as unmixing approaches are tested and evaluated. Detailed geological and structural mapping as well as geochemical analysis of the main rock and soil types were performed to underpin the analysis of the airborne data.

Sommer, S.↗
NASA NTRS1993

Mineralogic variability of the Kelso Dunes, Mojave Desert, California derived from Thermal Infrared Multispectral Scanner (TIMS) data

Mineral identification and mapping of alluvial material using thermal infrared (TIR) remote sensing is extremely useful for tracking sediment transport, assessing the degree of weathering and locating sediment sources. As a result of the linear relation between a mineral's percentage in a given area (image pixel) and the depth of its diagnostic spectral features, TIR spectra can be deconvolved in order to ascertain mineralogic percentages. Typical complications such as vegetation, particle size and thermal shadowing are minimized upon examination of dunes. Actively saltating dunes contain little to no vegetation, are very well sorted and lack the thermal shadows that arise from rocky terrain. The primary focus of this work was to use the Kelso Dunes as a test location for an accuracy analysis of temperature/emissivity separation and linear unmixing algorithms. Accurate determination of ground temperature and component discrimination will become key products of future ASTER data. A decorrelation stretch of the TIMS image showed clear color variations within the active dunes. Samples collected from these color units were analyzed for mineralogy, grain size, and separated into endmembers. This analysis not only revealed that the dunes contained significant mineralogic variation, but were more immature (low quartz percentage) than previously reported. Unmixing of the TIMS data using the primary mineral endmembers produced unique variations within the dunes and may indicate near, rather than far, source locales for the dunes. The Kelso Dunes lie in the eastern Mojave Desert, California, approximately 95 km west of the Colorado River. The primary dune field is contained within a topographic basin bounded by the Providence, Granite Mountains, with the active region marked by three northeast trending linear ridges. Although active, the dunes appear to lie at an opposing regional wind boundary which produces little net movement of the crests. Previous studies have estimated the dunes range from 70% to 90% quartz mainly derived from a source 40 km to the west. The dune field is assumed to have formed in a much more arid climate than present, with the age of the deposit estimated at greater than 100,000 years.

Ramsey, Michael S.↗
NASA NTRS1991

Apollo 12: Pinpoint for Science

This video, using historical film footage, photography, and computer animation, describes the launch, flight, lunar landing and exploration, and return flight of Apollo 12, one of the manned lunar missions. The astronauts were Charles Conrad, Richard Gordon, and Allen Bean. Thirty-six seconds into the November 14, 1969 launch, the spacecraft was hit by lightning from the thunderstorm surrounding the launch site. In spite of this mishap, the vehicle and astronauts were not harmed and continued with their mission. The Yankee Clipper (command module) docked with the Intrepid (lunar module) and upon reaching the Moon, the Intrepid disconnected during lunar orbit and descended to the Moon's surface to a landing area previously marked by the Surveyor satellite. After lunar surface exploration, soil sample collection, satellite maintenance, and setting up various lunar surface monitoring equipment (a seismometer and two atmospheric monitors), the Intrepid launched back into lunar orbit, docked with the Yankee Clipper, and returned to Earth. There are both B/W and color photography and film footage, which includes the Earth launch, lunar orbit, descent and ascent of Intrepid on the Moon, return flight, atmospheric reentry, and recovery on the Earth, and ground to air and space communication is shown.

Source record↗
NASA NTRS1994

Global trends and annual releases of CCl3F and CCl2F2 estimated from ALE/GAGE and other measurements from July 1978 to June 1991

Thirteen years of Atmospheric Lifetime Experiment/Global Atmospheric Gases Experiment CCl3F and CCl2F2 measurements at five remote, surface, globally distributed sites are analyzed. Comparisons are made against shipboard measurements by the Scripps Institution of Oceanography (SIO) group and archived air samples collected at Cape Grim, Tasmania, since 1978. CCl3F in the lower troposphere was increasing at an average rate of 9.2 ppt/yr over the period July 1978 to June 1988. CCl2F2 was increasing at an average 17.3 ppt/yr in the lower troposphere over the same period. However, between July 1988 and June 1991 the increases of CCl3F and CCl2F2 in this region have averaged just 7.0 ppt/yr and 15.7 ppt/yr, respectively. The rate of increase has been decreasing 2.4 ppt/yr(exp 2) and 2.9 ppt/yr(exp 2) over this 3-year period. Based on a recent scenario of the global releases of these compounds and using the new calibration scale SIO 1993, the equilibrium lifetimes are estimated to be 44 +17/-10 and 180 +820/-81 years for CCl3F and CCl2F2, respectively. Using these lifetime estimates and a two-dimensional model, it is estimated that global releases of these two chlorofluorocarbons in 1990 were 249 +/- 28 x 10(exp 6) kg for CCl3F and 366 +/- 30 x 10(exp 6) kg for CCl2F2. It is also estimated that combined releases of these chlorofluorocarbons in 1990 were 21 +/- 5% less than those in 1986.

Cunnold, D. M.↗
NASA NTRS1994

Ecosystem and physiological controls over methane production in northern wetlands

Peat chemistry appears to exert primary control over methane production rates in the Canadian Northern Wetlands Study (NOWES) area. We determined laboratory methane production rate potentials in anaerobic slurries of samples collected from a transect of sites through the NOWES study area. We related methane production rates to indicators of resistance to microbial decay (peat C: N and lignin: N ratios) and experimentally manipulated substrate availability for methanogenesis using ethanol (EtOH) and plant litter. We also determined responses of methane production to pH and temperature. Methane production potentials declined along the gradient of sites from high rates in the coastal fens to low rates in the interior bogs and were generally highest in surface layers. Strong relationships between CH4 production potentials and peat chemistry suggested that methanogenesis was limited by fermentation rates. Methane production at ambient pH responded strongly to substrate additions in the circumneutral fens with narrow lignin: N and C: N ratios (delta CH4/delta EtOH = 0.9-2.3 mg/g) and weakly in the acidic bogs with wide C: N and lignin: N ratios (delta CH4/delta EtOH = -0.04-0.02 mg/g). Observed Q(sub 10) values ranged from 1.7 to 4.7 and generally increased with increasing substrate availability, suggesting that fermentation rates were limiting. Titration experiments generally demonstrated inhibition of methanogenesis by low pH. Our results suggest that the low rates of methane emission observed in interior bogs during NOWES likely resulted from pH and substrate quality limitation of the fermentation step in methane production and thus reflect intrinsically low methane production potentials. Low methane emission rates observed during NOWES will likely be observed in other northern wetland regions with similar vegetation chemistry.

Valentine, David W.↗
NASA NTRS1993

An intercomparison of aircraft instrumentation for tropospheric measurements of sulfur dioxide

As part of the NASA Tropospheric Chemistry Program, a series of field intercomparisons have been conducted to evaluate the state-of-the art for measuring key tropospheric species. One of the objectives of the third intercomparison campaign in this series, Chemical Instrumentation Test and Evaluation 3 (CITE 3), was to evaluate instrumentation for making reliable tropospheric aircraft measurements of sulfur dioxide, dimethyl sulfide, hydrogen sulfide, carbon disulfide, and carbonyl sulfide. This paper reports the results of the intercomparisons of five sulfur dioxide measurement methods ranging from filter techniques, in which samples collected in flight are returned to the laboratory for analyses (chemiluminescent or ion chromatographic), to near real-time, in-flight measurements via gas chromatographic, mass spectrometric, and chemiluminescent techniques. All techniques showed some tendency to track sizeable changes in ambient SO2 such as those associated with altitude changes. For SO2 mixing ratios in the range of 200 pptv to a few ppbv, agreement among the techniques varies from about 30% to several orders of magnitude, depending upon the pair of measurements intercompared. For SO2 mixing ratios less than 200 pptv, measurements from the techniques are uncorrelated. In general, observed differences in the measurement of standards do not account for the flight results. The CITE 3 results do not unambiguously identify one or more of the measurement techniques as providing valid or invalid SO2 measurements, but identify the range of 'potential' uncertainty in SO2 measurements reported by currently available instrumentation and as measured under realistic aircraft environments.

Gregory, Gerald L.↗
NASA NTRS1993

Atmospheric measurements of carbonyl sulfide, dimethyl sulfide, and carbon disulfide using the electron capture sulfur detector

Measurements of atmospheric dimethyl sulfide (DMS), carbonyl sulfide (COS), and carbon disulfide (CS2) were conducted over the Atlantic Ocean on board the NASA Electra aircraft during the Chemical Instrumentation Test and Evaluation (CITE 3) project using the electron capture sulfur detector (ECD-S). The system employed cryogenic preconcentration of air samples, gas chromatographic separation, catalytic fluorination, and electron capture detection. Samples collected for DMS analysis were scrubbed of oxidants with NaOH impregnated glass fiber filters to preconcentration. The detection limits (DL) of the system for COS, DMS, and CS2 were 5, 5, and 2 ppt, respectively. COS concentrations ranged from 404 to 603 ppt with a mean of 489 ppt for measurements over the North Atlantic Ocean (31 deg N to 41 deg N), and from 395 to 437 ppt with a mean of 419 ppt for measurements over the Tropical Atlantic Ocean (11 deg S to 2 deg N). DMS concentrations in the lower marine boundary layer, below 600-m altitude, ranged from below DL to 150 ppt from flights over the North Atlantic, and from 9 to 104 ppt over the Tropical Atlantic. CS2 concentrations ranged from below DL to 29 ppt over the North Atlantic. Almost all CS2 measurements over the Tropical Atlantic were below DL.

Johnson, James E.↗
NASA NTRS1995

Radon measurements aboard the Kuiper Airborne Observatory

We have carried out three (piggyback) radon-related projects aboard the KAO. The first, which was limited to upper tropospheric measurements while in level flight, revealed the systematic occurrence of unexpectedly high radon concentrations in this region of the atmosphere. The second project was an instrument development project, which led to the installation of an automatic radon measurement system aboard the NASA ER-2 High Altitude Research Aircraft. In the third, we installed a new system capable of collecting samples during the normal climb and descent of the KAO. The results obtained in these projects have resulted in significant contributions to our knowledge of atmospheric transport processes, and are currently playing a key role in the validation of global circulation and transport models.

Kritz, Mark A.↗
NASA NTRS1991

High-Moisture Diet for Laboratory Rats: Complete Blood Counts, Serum Biochemical Values, and Intestinal Enzyme Activity

Rats were fed an irradiated high-moisture diet (KSC-25) with or without access to a water bottle. Physiologic values were compared between these two groups and a group of rats fed a purified diet. Hematologic and serum biochemical values, urine specific gravity, and intestinal enzyme activities were determined from samples collected from the three groups of rats. Sprague Dawley rats (n=32) fed the irradiated high-moisture diet with or without a water bottle were the test animals. Rats (n=16) fed an irradiated purified diet and water provided via a water bottle were the control group. The purified diet formulation, modified AIN-76A, is a commonly used purified diet for laboratory rodents. All rats remained alert and healthy throughout the study. A comparison of the physiologic values of rats in this study with reported normal values indicated that all of the rats in the study were in good health. Significant differences (P less than 0.05) of the physiologic values from each rat group are reported.

Battles, August H.↗
NASA NTRS1997

Planetary and Primitive Object Strength Measurements and Sampling Apparatus

We present experimental data and a model for the low-velocity (subsonic, 0 - 1000 m/s) penetration of brittle materials by both solid and hollow (i.e., coring) penetrators. The experiments show that penetration is proportional to momentum/frontal area of the penetrator. Because of the buildup of a cap in front of blunt penetrators, the presence or absence of a streamlined or sharp front end usually has a negligible effect for impact into targets with strength. The model accurately predicts the dependence of penetration depth on the various parameters of the target-penetrator system, as well as the qualitative condition of the target material ingested by a corer. In particular, penetration depth is approximately inversely proportional to the static bearing strength of the target. The bulk density of the target material has only a small effect on penetration, whereas friction can be significant, especially at higher impact velocities, for consolidated materials. This trend is reversed for impacts into unconsolidated materials. The present results suggest that the depth of penetration is a good measure of the strength, but not the density, of a consolidated target. Both experiments and model results show that, if passage through the mouth of a coring penetrator requires initially porous target material to be compressed to less than 26% porosity, the sample collected by the corer will be highly fragmented. If the final porosity remains above 26%, then most materials, except cohesionless materials, such as dry sand, will be collected as a compressed slug of material.

Ahrens, Thomas J.↗
NASA NTRS1998

Thermal and evolved gas analyzer

The Thermal and Evolved Gas Analyzer (TEGA) instrument will perform calorimetry and evolved gas analysis on soil samples collected from the Martian surface. TEGA is one of three instruments, along with a robotic arm, that form the Mars Volatile and Climate Survey (MVACS) payload. The other instruments are a stereo surface imager, built by Peter Smith of the University of Arizona and a meteorological station, built by JPL. The MVACS lander will investigate a Martian landing site at approximately 70 deg south latitude. Launch will take place from Kennedy Space Center in January, 1999. The TEGA project started in February, 1996. In the intervening 24 months, a flight instrument concept has been designed, prototyped, built as an engineering model and flight model, and tested. The instrument performs laboratory-quality differential-scanning calorimetry (DSC) over the temperature range of Mars ambient to 1400K. Low-temperature volatiles (water and carbon dioxide ices) and the carbonates will be analyzed in this temperature range. Carbonates melt and evolve carbon dioxide at temperatures above 600 C. Evolved oxygen (down to a concentration of 1 ppm) is detected, and C02 and water vapor and the isotopic variations of C02 and water vapor are detected and their concentrations measured. The isotopic composition provides important tests of the theory of solar system formation.

Williams, M. S.↗
NASA NTRS1999

Nonmethane Hydrocarbon Measurements on the North Atlantic Flight Corridor During SONEX

Mixing ratios of nonmethane hydrocarbons (NMHCS) were not enhanced in whole air samples collected within the North Atlantic Flight Corridor (NAFC) during the fall of 1997. The investigation was conducted aboard NASA's DC-8 research aircraft, as part of the Subsonic Assessment-Ozone and Nitrogen Experiment (SONEX). NMHC enhancements were not detected within the general Organized Tracking System (OTS) of the NAFC, nor during two tail-chases of the DC-8's own exhaust. Because positive evidence of aircraft emissions was demonstrated by enhancements in both nitrogen oxides and condensation nuclei during SONEX, the NMHC results suggest that the commercial air traffic fleet operating in the North Atlantic region does not contribute significantly to NMHCs in the NAFC.

Simpson, I. J.↗
NASA NTRS1999

Search for Unique Organic Biomarkers in ALH84001

Four goals were outlined for this project. These were: [1] to reproduce the measurement of polycyclic aromatic hydrocarbons (PAHS) in ALH84001 with both a higher spatial resolution and sensitivity than has been previously reported; [2] to extend such measurements to include other members of the Martian SNC (Shergotties, Nahklites, and Chassigny) meteorite clan, in particular the Antarctic Martian meteorite EETA79001; [3] to address issues of potential organic contamination, because at present very little is known about the effect of terrestrial weathering in the Antarctic environment as it pertains to perturbing an indigenous organic distribution within a meteoritic matrix; and [4] to diversify the range of organic compounds studied to include species that can serve as unique biological markers - "molecular fossils" - derived from once living organisms. In order to achieve this, three specific goals were outlined for the funding period 06/01/97 to 02/28/98. They were: [1] to investigate the effects of terrestrial weathering and organic contamination of meteoritic samples collected from Antarctica; [2] to reproduce and extend upon the measurements of PAHs in ALH84001 with the aim of establishing or refuting the indigeneity of these species; and [3] to extend the analysis of organic compounds in ALH84001 and EETA79001 to address compounds that are considered to be more biologically relevant than PAHS. All three were successfully accomplished, as detailed in the previous performance report. In brief, however, the results achieved were to establish that the PAHs found in ALH84001 were indigenous and not due to contamination, and to determine that a novel and sensitive technique in meteoritic work, capillary zone electrophoresis (CE), could indeed detect amino acids, a potential class of biomarker.

Zare, Richard N.↗