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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36

Integration of Nuclear Material Accounting Data and Process Monitoring Data for Improvement on Detection Probability in Safeguarding Electrochemical Processing Facilities (Final Technical Report)

The KAERI advanced spent fuel conditioning process (ACP) process is a critical component of the US- South Korean nuclear cooperation and the following “123 Agreement.” Its development has received considerable attention in both countries. The ACP is an electrochemical processing (pyroprocessing) that recycles over 96% of the used nuclear fuel (UNF). It is also intrinsically proliferation-resistant in theory. In normal operation, the U/TRU product is very hot radiologically. In addition, the Cm provides a high level of spontaneous neutrons, making the product unsuitable for weapon use. However, as pointed in some study, “the need for safeguards to protect against the diversion and misuse of separated plutonium applies essentially equally to all grades of plutonium.” As pointed by many studies, the well-established traditional Nuclear Material Accounting (NMA) approach cannot be directly applied to electrochemical processing because of the lack of an input accountability tank, the non-continuous material flow, and the unsatisfactory level of confidence in sampling methods. Therefore, nuclear safeguards remain a grand challenge in the developing of commercial electrochemical separations facilities, especially around the heart of such facilities, the electrorefiner (ER) systems. In contrast to NMA data, process monitoring (PM) data is normally an indirect measurement of the SNM and is acquired much more frequently. In a broad sense, PM includes monitoring by various types of equipment, e.g. radiation detectors, cameras, voltage, current sensors. Because it is already being collected by the operator, the additional cost to safeguards is low. It has long been believed that PM data can supplement NMA data and help improve safeguards, although the benefits are hard to quantify. The U.S. DOE’s Material Protection, Accounting, and Control Technology (MPACT) campaign has made substantial investments into innovative PM sensor technology and predictive model development for real- or near real-time measurement and prediction of molten salt density and level, salt composition and actinide concentration especially Pu, the cell voltage, and the cell current to supplement traditional NMA. For aqueous-based reprocessing facilities, it is reported that PM, integrated with traditional NMA, have a high detection probability for specific diversions. For electrochemical reprocessing, preliminary studies have shown that PM data can support traditional NMA in various ways by providing a basis to estimate some of the in-processing nuclear material inventories. Despite early success, further studies on fusion of PM data and NMA data are still needed, which is the goal of this proposed work.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An experimental database of cell performance for vanadium redox flow battery

The continual growth in energy demand has resulted in the deployment of renewable energy generators to reduce the impact of fossil fuel dependence. However, these generators often suffer from intermittency and require energy storage when there is over-generation and the subsequent release of this stored energy at high demand. One promising energy storage technology which can provide a solution to improve energy management and grid stability, is the redox flow battery. Among the numerous flow battery systems, vanadium redox flow battery is the most iconic solution to large scale energy storage, giving a more efficient link between energy production, especially from renewables, and energy demand. The aim of the current database is to characterize the performance of the cell design and to provide training/validation data for physical model or data-driven model. The database includes hundreds of experimental cell performance data of vanadium redox flow battery with various current densities for multiple charge-discharge cycles. All the cell parameters, chemical parameters, material parameters, operation parameters and thermodynamic parameters of the cell system are listed. Coulomb, voltaic and energy efficiencies are also provided. The database will be helpful for researchers in the field of redox flow batteries.

Gao, Peiyuan↗

Rates of elementary reactions - Measurement and applications

Techniques used for characterizing elementary chemical reaction kinetics are explored. Flash- or laser-photolysis (FP) involves producing reactive species on the psec time scale and monitoring the changes spectroscopically. In the discharge flow (DF) method, reactive species are produced continuously in a flow of an inert gas containing the reactants. FP avoids surface and transport effects, while DF allows several reactions to be studied in different regions of one flow. Transport and surface boundary layer models are defined for DF calculations and sample calculations are carried out to illustrate the difficulties inherent in theoretically defining the rate constants for elementary reactions. Applications of the models thus far derived in atmospheric science and combustion studies are discussed.

Kaufman, F.↗

Terrestrial Analogue Studies from ISRO’s Venus Mission Perspective: Polarimetric Radar Properties of Hawaiian Lava Flows

Detection of present and past volcanism on Venus is one of the major goals of the proposed ISRO’s Venus orbiter mission. The S-band, high-resolution (40 m/pixel) fully Polarimetric Synthetic Aperture Radar (PolSAR) instrument on this mission [1] may have the capabilities to detect volcanism within the mission lifetime using repeated PolSAR imagery, and possibly SAR Interferometry (InSAR, experimental mode). The global mapping efforts of Venus by Magellan mission has enabled comprehensive mapping of lava flows and indicated that Venus has an extensive history of volcanism, the ages of which are largely unknown (e.g. [2]). While Magellan radar emissivity data (e.g. [3, 4]) and Near Infrared emissivity data from VIRTIS [5] suggested the occurrence of recent episodes of volcanic activity (e.g. Maat Mons and Ganis Chasma), as well as the presence of stratigraphically young lava flows (e.g. Idunn Mons), measuring changes in radar backscatter amplitude alone to identify lava flows has many challenges. Although very large changes in the shape of the terrain can be observed in radar backscatter amplitude changes (e.g. [6]), smaller, or relatively flat lava flows are difficult to detect. Previous terrestrial studies suggest that PolSAR and InSAR techniques are very effective for mapping lava flows (e.g. [7-9]), and can be used when changes cannot be distinguished in radar backscatter images. We use the unvegetated lava flows on Hawaiʻi island as a terrestrial analogue to study Venus lava flows for the following reasons: (a) It is extensively studied at several wavelengths commonly used in remote sensing studies (including PolSAR and InSAR methods); and (b) it is a volcanically active area with new lava flows frequently covering older emplaced flows. To investigate the surface roughness, texture, and fine-grained mantling associated with Mauna Loa and Kilauea lava flows, we utilize C- and L-band PolSAR datasets obtained from RISAT-1A (EOS-4) and ALOS PALSAR missions respectively. In particular, we will use the quad-polarized backscatter and polarimetric parameters to characterize the texture of the terrestrial lava flows to understand whether the Venus crust is continuously disrupted during flow emplacement. While some previous studies (e.g. [10, 11]) suggested that surface roughness of most of the Venus flows is comparable to that of terrestrial pāhoehoe flows, other studies indicated that fractal dimensions of some large lava flows on Venus imply high eruption rates which favour the formation of a’a flows (e.g. [12]). We will also analyse the terrestrial flows for the presence/absence of pyroclastic mantling as radar-bright diffuse deposits near the summit regions of some coronae on Venus have been proposed to be young pyroclastics, and possible evidence of a renewed epoch of mantle volcanism that taps into deeper volatiles [13]. A recent study using EOS-4 RISAT-1 data of a part of fresh Mauna Loa lava flows (2022 eruption) emphasizes the ability of fully polarimetric SAR data to understand the diversity of physical properties (e.g. texture and morphology) associated with them (Sreejith et al. 2024); and we will apply similar methods to the PolSAR data obtained from ISRO’s Venus mission for our proposed objectives.

Sriram S Bhiravarasu↗

Equations, tables, and charts for compressible flow

This report, which is a revision and extension of NACA-TN-1428, presents a compilation of equations, tables, and charts useful in the analysis of high-speed flow of a compressible fluid. The equations provide relations for continuous one-dimensional flow, normal and oblique shock waves, and Prandtl-Meyer expansions for both perfect and imperfect gases. The tables present useful dimensionless ratios for continuous one-dimensional flow and for normal shock waves as functions of Mach number for air considered as a perfect gas. One series of charts presents the characteristics of the flow of air (considered a perfect gas) for oblique shock waves and for cones in a supersonic air stream. A second series shows the effects of caloric imperfections on continuous one-dimensional flow and on the flow through normal and oblique shock waves. (author)

Source record↗

Eigenmodes of Ducted Flows With Radially-Dependent Axial and Swirl Velocity Components

This report characterizes the sets of small disturbances possible in cylindrical and annular ducts with mean flow whose axial and tangential components vary arbitrarily with radius. The linearized equations of motion are presented and discussed, and then exponential forms for the axial, circumferential, and time dependencies of any unsteady disturbances are assumed. The resultant equations form a generalized eigenvalue problem, the solution of which yields the axial wavenumbers and radial mode shapes of the unsteady disturbances. Two numerical discretizations are applied to the system of equations: (1) a spectral collocation technique based on Chebyshev polynomial expansions on the Gauss-Lobatto points, and (2) second and fourth order finite differences on uniform grids. The discretized equations are solved using a standard eigensystem package employing the QR algorithm. The eigenvalues fall into two primary categories: a discrete set (analogous to the acoustic modes found in uniform mean flows) and a continuous band (analogous to convected disturbances in uniform mean flows) where the phase velocities of the disturbances correspond to the local mean flow velocities. Sample mode shapes and eigensystem distributions are presented for both sheared axial and swirling flows. The physics of swirling flows is examined with reference to hydrodynamic stability and completeness of the eigensystem expansions. The effect of assuming exponential dependence in the axial direction is discussed.

Kousen, Kenneth A.↗

A Data-Driven Nonparametric Approach for Probabilistic Load-Margin Assessment Considering Wind Power Penetration

A modern power system is characterized by an increasing penetration of wind power, which results in large uncertainties in its states. These uncertainties must be quantified properly; otherwise, the system security may be threatened. Facing this challenge, here we propose a cost-effective, data-driven approach to assessing a power system's load margin probabilistically. Using actual wind data, a kernel density estimator is applied to infer the nonparametric wind speed distributions, which are further merged into the framework of a vine copula. The latter enables us to simulate complex multivariate and highly dependent model inputs with a variety of bivariate copulae that precisely represent the tail dependence in the correlated samples. Furthermore, to reduce the prohibitive computational time of traditional Monte-Carlo simulations that process a large amount of samples, we propose to use a nonparametric, Gaussian-process-emulator-based reduced-order model to replace the original complicated continuation power-flow model through a Bayesian-learning framework. To accelerate the convergence rate of this Bayesian algorithm, a truncated polynomial chaos surrogate, which serves as a highly efficient, parametric Bayesian prior, is developed. This emulator allows us to execute the time-consuming continuation power-flow solver at the sampled values with a negligible computational cost. Results of simulations that are performed on several test systems reveal the impressive performance of the proposed method in the probabilistic load-margin assessment.

17 WIND ENERGY↗

Detection of small molecules with a flow immunosensor

We describe the development of an easy-to-use sensor with widespread applications for detecting small molecules. The flow immunosensor can analyze discrete samples in under one minute or continuously monitor a flowing stream for the presence of specific analytes. This detection system is extremely specific, and achieves a level of sensitivity which meets or exceeds the detection limits reported for rival assays. Because the system is also compact, transportable, and automated, it has the potential to impact diverse areas. For example, the flow immunosensor has successfully detected drugs of abuse and explosives, and may well address many of the needs of the environmental community with respect to continuous monitoring for pollutants. Efforts are underway to engineer a portable device in the field.

Kusterbeck, Anne W.↗

Effects of Particle Mixing and Gravitational Settling on Charge Transport in Carbon Flow-Electrode Cells

Flowable carbon slurries are actively studied and under development for charge transport in various electrochemical systems including flow capacitors, capacitive deionization cells, semi-solid flow batteries, and lithium extraction. However, much less is known about in operando slurry flow dynamics and their corresponding effect on charge transport. We performed an experimental study of mixing and settling dynamics of slurry electrodes within an electrochemical flow cell during continuous operations. The electrochemical cell consisted of two horizontal co-flowing channels, separated by a cation-exchange membrane (CEM). Here we used high-speed optical imaging of planes parallel to gravity and simultaneous electrochemical measurements. At low flow rates, dense yet dynamic particle beds formed on the bottom electrode in each channel, which unexpectedly yielded the highest currents. This approach enables the operation of the flow cell at low system-average particle concentrations while leveraging gravity-driven particle settling to locally enhance carbon concentrations precisely at the current collector sites. Conversely, high flow rates were characterized by thin particle beds and well-mixed particle flows. In the latter case, the electrodes in closest proximity (located on either side of the CEM) achieved a current higher than the other electrode pairs. The observations have implications for slurry control and electrode designs in electrochemical systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Non-Stationary Power System Forced Oscillation Analysis using Synchrosqueezing Transform

Non-stationary forced oscillations (FOs) have been observed in power system operations. However, most detection methods assume that the frequency of FOs is stationary. In this paper, we present a methodology for the analysis of nonstationary FOs. Firstly, Fourier synchrosqueezing transform (FSST) is used to provide a concentrated time-frequency representation of the signals that allows identification and retrieval of non-stationary signal components. To continue, the Dissipating Energy Flow (DEF) method is applied to the extracted components to locate the source of forced oscillations. The methodology is tested using simulated as well as real PMU data. In conclusion, the results show that the proposed FSST-based signal decomposition provides a systematic framework for the application of DEF Method to non-stationary FOs.

42 ENGINEERING↗

Pulsed laminar falling films in vertical tubes: Maintaining a continuous liquid film with reduced film thickness

Falling-liquid-film heat transfer is important to a wide variety of industrial applications, including two-phase thermosyphons, falling-film evaporators in the food industry, heat exchangers in fuel-ethanol processing, and the chemical service industry. Particularly for laminar falling films, the heat transfer increases as the film thickness decreases, hence it is desirable to keep the films as thin as possible. This article presents a periodically-pulsed flow concept to reduce the average mass flow inside a vertical tube. The technique provides thinner films than can be achieved with continuous flow. A drainage model is adopted to predict the film thickness as a function of flow rate and location along the tube. The concept is confirmed experimentally by measuring the film thickness in real time in a circular tube using a laser-based absorption technique. A new heat-transfer-based film continuity measurement is also integrated into the optical film measurement setup. Water at ambient temperature and pressure is used for this work. Film thickness reductions of up to 60%, and liquid-film volume-flow reductions of up to 80% compared to the minimum continuous-flow film have been obtained. The time-varying film thickness profile can also be controlled to a limited extent, which may be of interest for process industries.

42 ENGINEERING↗

Intermittent Flow Regimes in a Transonic Fan Airfoil Cascade

A study was conducted in the NASA Glenn Research Center linear cascade on the intermittent flow on the suction surface of an airfoil section from the tip region of a modern low aspect ratio fan blade. Experimental results revealed that, at a large incidence angle, a range of transonic inlet Mach numbers exist where the leading-edge shock-wave pattern was unstable. Flush mounted high frequency response pressure transducers indicated large local jumps in the pressure in the leading edge area, which generates large intermittent loading on the blade leading edge. These measurements suggest that for an inlet Mach number between 0.9 and 1.0 the flow is bi-stable, randomly switching between subsonic and supersonic flows. Hence, it appears that the change in overall flow conditions in the transonic region is based on the frequency of switching between two stable flow states rather than on the continuous increase of the flow velocity. To date, this flow behavior has only been observed in a linear transonic cascade. Further research is necessary to confirm this phenomenon occurs in actual transonic fans and is not the byproduct of an endwall restricted linear cascade.

Lepicovsky, J.↗

Unified approach for incompressible flows

An unified approach for solving both compressible and incompressible flows was investigated in this study. The difference in CFD code development between incompressible and compressible flows is due to the mathematical characteristics. However, if one can modify the continuity equation for incompressible flows by introducing pseudocompressibility, the governing equations for incompressible flows would have the same mathematical characters as compressible flows. The application of a compressible flow code to solve incompressible flows becomes feasible. Among numerical algorithms developed for compressible flows, the Centered Total Variation Diminishing (CTVD) schemes possess better mathematical properties to damp out the spurious oscillations while providing high-order accuracy for high speed flows. It leads us to believe that CTVD schemes can equally well solve incompressible flows. In this study, the governing equations for incompressible flows include the continuity equation and momentum equations. The continuity equation is modified by adding a time-derivative of the pressure term containing the artificial compressibility. The modified continuity equation together with the unsteady momentum equations forms a hyperbolic-parabolic type of time-dependent system of equations. The continuity equation is modified by adding a time-derivative of the pressure term containing the artificial compressibility. The modified continuity equation together with the unsteady momentum equations forms a hyperbolic-parabolic type of time-dependent system of equations. Thus, the CTVD schemes can be implemented. In addition, the boundary conditions including physical and numerical boundary conditions must be properly specified to obtain accurate solution. The CFD code for this research is currently in progress. Flow past a circular cylinder will be used for numerical experiments to determine the accuracy and efficiency of the code before applying this code to more specific applications.

Chang, Tyne-Hsien↗

Physics-Guided Continual Learning for Predicting Emerging Aqueous Organic Redox Flow Battery Material Performance

Aqueous organic redox flow batteries (AORFBs) have gained popularity in renewable energy storage due to their low cost, environmental friendliness and scalability. The rapid discovery of aqueous soluble organic (ASO) redox-active materials necessitates efficient machine learning surrogates for predicting battery performance. The physics-guided continual learning (PGCL) method proposed in this study can incrementally learn data from new ASO electrolytes while addressing catastrophic forgetting issues in conventional machine learning. Using a AORFB database with a thousand potential materials generated by a 780 $\text{cm}^2$ interdigitated cell model, PGCL incorporates AORFB physics to optimize the continual learning task formation and training strategies to retain previously learned battery material knowledge. Finally, the trained PGCL demonstrates its capability in assessing emerging ASO materials within the established parameter space when evaluated with the dihydroxyphenazine isomers.

25 ENERGY STORAGE↗

Modified ICED-ALE method for astrogeophysical plasma flows

The Implicit-Continuous-Eulerian-Difference Mesh-Arbitrary-Lagrangian-Eulerian (ICED-ALE) algorithm of Brackbill and Pracht (1973) is modified for the study of astrophysical plasma flows in which dynamical effects are important. In the present study the general-energy-conservation law is directly applied to the iteration process, with the total (kinetic-, specific-internal-, and magnetic-) energy density being obtained implicitly at the end of the process. An example is computed in which the convergence speed of the latter method is substantially faster than that of the former. The initializing calculation, or explicit phase, in which the electric current density, magnetic diffusion of field, energy augmentation, and zero-order approximation of the flow velocity are given, is described. Consideration is given to the iteration process, or implicit phase, from which the exact Lagrangian solution for energy density, velocity, and a magnetic field is obtained.

Wu, S. T.↗

Effect of wall suction on the stability of compressible subsonic flows over smooth two-dimensional backward-facing steps

The effect of suction on the stability of compressible flows over backward-facing steps is investigated. Mach numbers up to 0.8 are considered. The results show that continuous suction stabilizes the flow outside the separation bubble, but it destabilizes the flow inside it. Nevertheless, the overall N factor decreases as the suction level increases due to the considerable reduction of the separation bubble. For the same suction flow rate, properly distributed suction strips stabilize the flow more than continuous suction. The size of the separation bubble, and hence its effect on the instability can be considerably reduced by placing strips with high suction velocities in the separation region.

Al-Maaitah, Ayman A.↗

Periodicity and chaos from switched flow systems - Contrasting examples of discretely controlled continuous systems

We analyze two examples of the discrete control of a continuous variable system. These examples exhibit what may be regarded as the two extremes of complexity of the closed-loop behavior: one is eventually periodic, the other is chaotic. Our examples are derived from sampled deterministic flow models. These are of interest in their own right but have also been used as models for certain aspects of manufacturing systems. In each case, we give a precise characterization of the closed-loop behavior.

Chase, Christopher↗