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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36

Advanced Control Surface Seal Development for Future Space Vehicles

NASA's Glenn Research Center (GRC) has been developing advanced high temperature structural seals since the late 1980s and is currently developing seals for future space vehicles as part of the Next Generation Launch Technology (NGLT) program. This includes control surface seals that seal the edges and hinge lines of movable flaps and elevons on future reentry vehicles. In these applications, the seals must operate at temperatures above 2000 F in an oxidizing environment, limit hot gas leakage to protect underlying structures, endure high temperature scrubbing against rough surfaces, and remain flexible and resilient enough to stay in contact with sealing surfaces for multiple heating and loading cycles. For this study, three seal designs were compared against the baseline spring tube seal through a series of compression tests at room temperature and 2000 F and flow tests at room temperature. In addition, canted coil springs were tested as preloaders behind the seals at room temperature to assess their potential for improving resiliency. Addition of these preloader elements resulted in significant increases in resiliency compared to seals by themselves and surpassed the performance of the baseline seal at room temperature. Flow tests demonstrated that the seal candidates with engineered cores had lower leakage rates than the baseline spring tube design. However, then the seals were placed on the preloader elements, the flow rates were higher as the seals were not compressed as much and therefore were not able to fill the groove as well. High temperature tests were also conducted to assess the compatability of seal fabrics against cermaic matrix composite (CMC) panels anticipated for use in next generation launch vehicles. These evaluations demonstrated potential bonding issues between the Nextel fabrics and CMC candidates.

DeMange, Jeffrey J.↗

Advanced Oxide Material Systems for 1650 C Thermal/Environmental Barrier Coating Applications

Advanced thermal and environmental barrier coatings (TEBCs) are being developed for low-emission SiC/SiC ceramic matrix composite (CMC) combustor and vane applications to extend the CMC liner and vane temperature capability to 1650 C (3000 F) in oxidizing and water-vapor-containing combustion environments. The advanced 1650 C TEBC system is required to have a better high-temperature stability, lower thermal conductivity, and more resistance to sintering and thermal stress than current coating systems under engine high-heat-flux and severe thermal cycling conditions. In this report, the thermal conductivity and water vapor stability of selected candidate hafnia-, pyrochlore- and magnetoplumbite-based TEBC materials are evaluated. The effects of dopants on the materials properties are also discussed. The test results have been used to downselect the TEBC materials and help demonstrate the feasibility of advanced 1650 C coatings with long-term thermal cycling durability.

Zhu, Dong-Ming↗

Refining Microstructures in Additively Manufactured Al/Cu Gradients Through TiB 2 Inclusions

Here, the additive manufacture of compositionally graded Al/Cu parts by laser engineered net shaping (LENS) is demonstrated. The use of a blue light build laser enabled deposition on a Cu substrate. The thermal gradient and rapid solidification inherent to selective laser melting enabled mass transport of Cu up to 4 mm from a Cu substrate through a pure Al deposition, providing a means of producing gradients with finer step sizes than the printed layer thicknesses. Divorcing gradient continuity from layer or particle size makes LENS a potentially enabling technology for the manufacture of graded density impactors for ramp compression experiments. Printing graded structures with pure Al, however, was prevented by the growth of Al 2 Cu 3 dendrites and acicular grains amid a matrix of Al 2 Cu. A combination of adding TiB 2 grain refining powder and actively varying print layer composition suppressed the dendritic growth mode and produced an equiaxed microstructure in a compositionally graded part. Material phase was characterized for crystal structure and nanoindentation hardness to enable a discussion of phase evolution in the rapidly solidifying melt pool of a LENS print.

36 MATERIALS SCIENCE↗

Technical Challenges for Next Generation Liquid Rocket Engine Nozzles

Next generation launch and propulsion systems face significant challenges of providing increased performance at lower cost with shorter development cycles. The use of existing materials in new application areas and the development and application of "advanced" material systems are enabling for the achievement of these aggressive goals. An area which offers substantial opportunity to decrease liquid rocket engine systems weight, and thus provide a measure of increased performance, is the nozzle. This presentation will examine the technical issues and showstoppers limiting the application of alternate materials to liquid rocket engine nozzles and identify the key material systems which have the potential for high payoff relative to the forcing functions of cost and performance (weight). Existing nozzle material development projects will be cited and opportunities for future joint partnerships to address these materials and processes challenges will be addressed. The presentation will include overviews of activities in low cost ablative nozzles, ceramic matrix composite cooled and uncooled nozzles, and advanced metallics.

Clinton, R. G., Jr.↗

Torque Limit for Bolted Joint For Composites: Experimentation - Part B

Today, aerospace quality composite parts are generally made from either a unidirectional tape or a fabric prepreg form depending on the application. The matrix material, typically epoxy because of it dimensional stability, is pre-impregnated onto the fibers to ensure uniform distribution. Both of these composite forms are finding themselves used in applications where a joint is required. Two widely used joint methods are the classic mechanically fastened joint, and the contemporary bonded joint; however, the mechanically fastened joint is most commonly used by design engineers. A major portion of the research up-to-date about bolted composite joints has dealt with the inplane static load capacity. This work has helped to spawn standards dealing with filled-hole static joint strength. Other research has clearly shown that the clamp-up load in the mechanical fastener significantly affects the joint strength in a beneficial manner by reducing the bearing strength dependence of the composite laminate. One author reported a maximum increase in joint strength of 28%. This finding has helped to improve the reliability and efficiency of the joint in a composite structure.

Kostreva, Kristian M.↗

Effect of plasma treatment on LMPAEK/CF tape and composites manufactured by automated tape placement (ATP)

Automated tape placement (ATP) process is widely used in aerospace for its advanced process control and multi-axis capabilities but faces issues like limited choice of materials and suboptimal tape consolidation. This study investigates air plasma treatment on ATP carbon fiber thermoplastic feedstock tape to address these challenges. The effects on low melt Polyaryletherketone/carbon fiber unidirectional tape (LMPAEK/CF UD tape) were analyzed. Treated and untreated tapes were used to fabricate composites and evaluated for physical, thermal, mechanical, and interfacial properties. Atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) analyses revealed surface roughness changes (on LMPAEK), extent of oxidation, and the presence of hydroxyl/carboxyl groups. Composites from plasma-treated tapes showed a 7.6% increase in tensile strength, 8% in tensile modulus, 18% in flexural strength, and 8.3% in flexural modulus. Further, the interlaminar shear strength improved by 18.7%. Failure analysis showed untreated composites failed via inter-ply and fiber-matrix delamination, while treated composites experienced matrix cracking and fiber breakage. This study highlights atmospheric plasma treatment as a solution to ATP’s limitations, significantly enhancing LMPAEK/CF UD tape composites’ properties.

36 MATERIALS SCIENCE↗

Application of Gr/PMR-15 to commercial aircraft

Following from early experience with polyimides on the SST program and Shuttle aft flap studies the Boeing Company is now working on collaborative programs with its principal nacelle suppliers to pursue the development of Gr/PMR-15 nacelle components. Two programs are currently in effect. The first program is directed specifically towards the flight test and service evaluation at the earliest possible date of a 747 nacelle core cowl structure. The second program seeks to firmly establish the producibility and cost of a 757 thrust reverser C duct in a production environment. The near term objectives of these programs include: (1) the comparison of estimated cost and weight of Gr/PMR-15 versus metal structure, (2) the engine test of representative composite structure, (3) the preliminary design and analysis of the C duct structure, and (4) the preparation of cost data and time schedules for the development and producibility program. In addition to powerplant structure, the propulsion ducting system has shown to be a strong candidate for Gr/PMR-15 application. Currently, the Boeing 747 Organization is evaluating the use of PMR-15 matrix composites to replace nearly 800 lbs of titanium ducting per airplane.

Postlewaite, J.↗

Special Issue: Environmental Barrier Coatings

The global increase in air travel will require commercial vehicles to be more efficient than ever before. Advanced turbine hot section materials are a key technology required to keep fuel consumption and emission to a minimum. Ceramic matrix composites (CMCs) are the most promising material to revolutionize turbine hot section materials because of their excellent high‐temperature properties. Rapid surface recession due to volatilization by water vapor is the Achilles heel of CMCs. Environmental barrier coatings (EBCs), which protect CMCs from water vapor, is an enabling technology for CMCs. The first CMC component entered into service in 2016 in a commercial engine, and more CMC components are scheduled to follow within the next few years. One of the most difficult challenges to CMC components is EBC durability because failure of EBC leads to a rapid reduction in CMC component life. Novel EBC chemistries, creative EBC designs, and robust processes are required to meet EBC durability challenges. Engine-relevant testing, characterization, and lifing methods need to be developed to improve EBC reliability. The aim of this Special Issue is to present recent advances in EBC technology to address current EBC challenges.

EBC, CMC, Oxidation, Volatility, CMAS, Thermomecha↗

NASA Glenn Research Center UEET (Ultra-Efficient Engine Technology) Program: Agenda and Abstracts

Topics discussed include: UEET Overview; Technology Benefits; Emissions Overview; P&W Low Emissions Combustor Development; GE Low Emissions Combustor Development; Rolls-Royce Low Emissions Combustor Development; Honeywell Low Emissions Combustor Development; NASA Multipoint LDI Development; Stanford Activities In Concepts for Advanced Gas Turbine Combustors; Large Eddy Simulation (LES) of Gas Turbine Combustion; NASA National Combustion Code Simulations; Materials Overview; Thermal Barrier Coatings for Airfoil Applications; Disk Alloy Development; Turbine Blade Alloy; Ceramic Matrix Composite (CMC) Materials Development; Ceramic Matrix Composite (CMC) Materials Characterization; Environmental Barrier Coatings (EBC) for Ceramic Matrix Composite (CMC) Materials; Ceramic Matrix Composite Vane Rig Testing and Design; Ultra-High Temperature Ceramic (UHTC) Development; Lightweight Structures; NPARC Alliance; Technology Transfer and Commercialization; and Turbomachinery Overview; etc.

Manthey, Lri↗

A Progressive Damage Methodology for Residual Strength Predictions of Center-Crack Tension Composite Panels

An investigation of translaminate fracture and a progressive damage methodology was conducted to evaluate and develop a residual strength prediction capability for laminated composites with through penetration notches. This is relevant to the damage tolerance of an aircraft fuselage that might suffer an in-flight accident such as an uncontained engine failure. An experimental characterization of several composite materials systems revealed an R-curve type of behavior. Fractographic examinations led to the postulate that this crack growth resistance could be due to fiber bridging, defined here as fractured fibers of one ply bridged by intact fibers of an adjacent ply. The progressive damage methodology is currently capable of predicting the initiation and growth of matrix cracks and fiber fracture. Using two difference fiber failure criteria, residual strength was predicted for different size panel widths and notch lengths. A ply discount fiber failure criterion yielded extremely conservative results while an elastic-perfectly plastic fiber failure criterion showed that the fiber bridging concept is valid for predicting residual strength for tensile dominated failure loads. Furthermore, the R-curves predicted by the model using the elastic-perfectly plastic fiber criterion compared very well with the experimental R-curves.

Coats, Timothy William↗

Isolating the Electrocatalytic Activity of a Confined NiFe Motif within Zirconium Phosphate

Unique classes of active-site motifs are needed for improved electrocatalysis. Herein, the activity of a new catalyst motif is engineered and isolated for the oxygen evolution reaction (OER) created by nickel–iron transition metal electrocatalysts confined within a layered zirconium phosphate matrix. It is found that with optimal intercalation, confined NiFe catalysts have an order of magnitude improved mass activity compared to more conventional surface-adsorbed systems in 0.1 m KOH. Interestingly, the confined environments within the layered structure also stabilize Fe-rich compositions (90%) with exceptional mass activity compared to known Fe-rich OER catalysts. Through controls and by grafting inert molecules to the outer surface, it is evidenced that the intercalated Ni/Fe species stay within the interlayer during catalysis and serve as the active site. After determining a possible structure (wycherproofite), density functional theory is shown to correlate with the observed experimental compositional trends. It is further demonstrated that the improved activity of this motif is correlated to the Fe and water content/composition within the confined space. This work highlights the catalytic enhancement possibilities available through zirconium phosphate and isolates the activity from the intercalated species versus surface/edge ones, thus opening new avenues to develop and understand catalysts within unique nanoscale chemical environments.

36 MATERIALS SCIENCE↗

Nanotechnology Concepts at MSFC: Engineering Directorate

Nanotechnology is the art and science of building materials and devices at the ultimate level of finesse: atom by atom. Our nation's space program has needs for miniaturization of components, minimization of weight and maximization of performance, and nanotechnology will help us get there. MSFC - Engineering Directorate (ED) is committed to developing nanotechnology that will enable MSFC missions in space transportation, space science and space optics manufacturing. MSFC-ED has a dedicated group of technologists who are currently developing high pay-off nanotechnology concepts. This poster presentation will outline some of the concepts being developed at this time including, nanophase structural materials, carbon nanotube reinforced metal and polymer matrix composites, nanotube temperature sensors and aerogels. The poster will outline these concepts and discuss associated technical challenges in turning these concepts into real components and systems.

Bhat, Biliyar↗

Processing-Related Issues for the Design and Lifing of SiC/SiC Hot-Section Components

For successful SiC/SiC engine components, numerous process steps related to the fiber, fiber architecture, interphase coating, and matrix need to be optimized. Under recent NASA-sponsored programs, it was determined that many of these steps in their initial approach were inadequate, resulting in less than optimum thermostructural and life properties for the as-fabricated components. This presentation will briefly review many of these process issues, the key composite properties they degrade, their underlying mechanisms, and current process remedies developed by NASA and others.

DiCarlo, J.↗

The effect of differential mineral shrinkage on crack formation and network geometry

Rock, concrete, and other engineered materials are often composed of several minerals that change volumetrically in response to variations in the moisture content of the local environment. Such differential shrinkage is caused by varying shrinkage rates between mineral compositions during dehydration. Using both 3D X-ray imaging of geo-architected samples and peridynamic (PD) numerical simulations, we show that the spatial distribution of the clay affects the crack network geometry with distributed clay particles yielding the most complex crack networks and percent damage (99.56%), along with a 60% reduction in material strength. We also demonstrate that crack formation, growth, coalescence, and distribution during dehydration, are controlled by the differential shrinkage rates between a highly shrinkable clay and a homogeneous mortar matrix. Sensitivity tests performed with the PD models show a clay shrinkage parameter of 0.4 yields considerable damage, and reductions in the parameter can result in a significant reduction in fracturing and an increase in material strength. Additionally, isolated clay inclusions induced localized fracturing predominantly due to debonding between the clay and matrix. These insights indicate differential shrinkage is a source of potential failure in natural and engineered barriers used to sequester anthropogenic waste.

58 GEOSCIENCES↗

Factors Affecting Fiber Design and Selection for Advanced Ceramic Composites

Structural Ceramic Matrix Composites (CMC) have the potential for application in the hot sections of a variety of advanced propulsion and power systems. It is therefore necessary to have a general understanding of the key properties of CMC and Reinforcing Fibers. This need is complicated by the wide variety of application conditions and structural requirements for which CMC's will be used, and the proprietary concerns of the design engineers. CMC's, to be successful, must display properties which are competitive with the currently used high temperature structural materials: (i.e., Iron and Nickel based superalloys, tough monolithic ceramics, and carbon/carbon composites.) Structural CMC offers several areas of competition: (1) performance, (i.e., strength and strength retention, creep resistance, and thermal conductivity), (2) reliability (i.e., environmental durability, and damage tolerance) and (3) processing (i.e., capability for varying sizes and shapes, and cost effective fabrication). The presentation further discusses, and illustrates with fiber and CMC data the key fiber properties and processes which strongly affect each CMC area of competition. The presentation further discusses the current knowledge of the important factors which control the key fiber properties. A design guidelines for the optimum fiber characteristics is developed, and the currently available fibers are compared against those guidelines.

DiCarlo, James A.↗

An Engineering Approach to Analyze Damage Initiation Modes in Tapered Composite Structures

In this work an engineering approach is demonstrated for analyzing damage initiation modes in tapered composite structures. The analysis methodology includes simulation of the non-linear static response of tapered composite structures under static tension loads to predict the location of interfacial delamination initiation. Furthermore, the developed methodology provides a strength-based criterion to assess whether damage initiation will occur in the inter-laminar delamination or intra-laminar matrix cracking mode. Based on the results of the analysis, a tapered composite structure is fabricated and tested under displacement-controlled quasi-static tension loading. The damage initiation location captured experimentally is compared with the analysis towards achieving preliminary qualitative validation. The linear stiffness of the tapered composite structure is predicted within 15% of the experimental average thereby achieving preliminary quantitative validation.

Rao, Prabhakar M.↗

An Engineering Approach to Analyze Damage Initiation Modes in Tapered Composite Structures

In this work an engineering approach is demonstrated for analyzing damage initiation modes in tapered composite structures. The analysis methodology includes simulation of the non-linear static response of tapered composite structures under static tension loads to predict the location of interfacial delamination initiation. Furthermore, the developed methodology provides a strength-based criterion to assess whether damage initiation will occur in the inter-laminar delamination or intra-laminar matrix cracking mode. Based on the results of the analysis, a tapered composite structure is fabricated and tested under displacement-controlled quasi-static tension loading. The damage initiation location captured experimentally is compared with the analysis towards achieving preliminary qualitative validation. The linear stiffness of the tapered composite structure is predicted within 15% of the experimental average thereby achieving preliminary quantitative validation.

Prabhakar M Rao↗

Thermostructural analysis of simulated cowl lips

Three dimensional finite element analyses using MSC/NASTRAN and MARC are performed to predict the thermal and structural response of various cooling schemes under high heat loads. Steady state heat transfer analyses and elastic stress analyses are performed using MSC/NASTRAN. Elastic/plastic analyses are done using MARC. To help verify these analyses experimentally, a hydrogen-oxygen rocket engine was modified to use the exhaust stream as a high enthalpy, high heat flux source to evaluate various actively cooled, simulated cowl lip (leading edges) segments as well as flat structural segments. Cross flow and parallel flow cooling configurations were tested and analyzed using cooling fluids of water and gaseous hydrogen. In addition, various material types, including high conductivity copper, nickel, and a copper and graphite metal matrix composite were tested and compared.

Melis, Matthew E.↗