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At least 649 records · Page 36

Generic HLW Repository In Bedded Salt In Germany: Emplacement Technologies and Repository Designs - 18288

In Germany, a new site selection act for a repository for HLW and SNF entered into force in July 2013 and was amended in spring 2017 [1]. It stipulates that the safety of repository systems for heat-generating radioactive waste and spent nuclear fuel in different host rock formations be compared. This requires that generic repository concepts and adequate safety- and safety demonstration concepts for all potential host rock formations in Germany (salt, clay and crystalline rock) exist. For several decades, development of disposal concepts and safety analyses for a repository in a salt dome was prioritized while repository concepts for clay and crystalline rock have been taken into account for two decades only. So far, bedded salt formations have not been the subject of comparative investigations. Thus, in summer 2015, the Federal Ministry for Economic Affairs and Energy (BMWi) launched the R and D project KOSINA to develop repository designs and carry out safety analyses for different emplacement alternatives in a generic bedded salt formation and a generic salt pillow. KOSINA is an acronym for 'Concept development for a generic repository for heat-generating waste in bedded salt formations in Germany as well as development and testing of a safety and demonstration concept'. Together with its partners BGR, GRS, and IfG, DBE Technology GmbH has successfully carried out an almost three years lasting scientific programme, which will be concluded in April 2018. The core areas of the programme are the development of generic geologic models, including derivation of model parameters, the development of a safety and safety demonstration concept, the development of technical repository designs for four different emplacement alternatives, the analysis of geomechanical integrity, the evaluation of operational safety as well as the analysis of radiological consequences. An interim report, which compiles the basic data of the waste inventory, the repository design requirements, the data basis for geologic model developments, and the outline of a safety and safety demonstration concept, was already published in February 2016. The main achievements of the R and D project KOSINA are the development of four different repository designs, two per each generic geologic model (flat-bedded salt, salt pillow) based on thermomechanical calculations. This includes the implementation of a safety concept that provides containment of the radioactive materials with regard to the technical designs of waste packages, transport and emplacement technologies, and backfilling and sealing concepts. Furthermore, the integrity of the geologic barriers could be demonstrated for all four repository designs, and the long-term predictions showed no radiological releases during the demonstration period of one million years. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Upgrading the JET Remote Handling System - 18356

The Joint European Torus (JET) has employed advanced remote-maintenance techniques for over three decades to avoid exposing humans to a potentially hazardous environment and to develop techniques for future power-generating fusion reactors where environments will be too hazardous for any manned maintenance. As a unique application of robotics, virtual reality and operations management systems, JET's remote handling unit, now a part of RACE, has driven the state-of-the-art with each upgrade programme in its history. This conference paper presents the current capabilities of the JET remote handling system, and the future capabilities being delivered by its latest upgrade programme, which makes use of cutting edge advances. RACE (Remote Applications in Challenging Environments) aims to shape the technologies being developed for JET in such a way that they will have wider applications, such as in nuclear decommissioning. (authors)

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Delivering Business Benefit to UK Decommissioning through Collaborative Innovation - Approach and Technologies - 18539

The UK's nuclear energy programme, dating from the post-war years, has left a mixed legacy to the country: numerous prototype reactors, fuel-manufacturing plants, research centres, reprocessing plants and 11 power stations. The Sellafield site in west Cumbria houses more than 200 nuclear facilities and 1,000 buildings, making it one of the world's most complex environmental decommissioning challenges. Many 'never-done-before' projects are under way, which require substantial levels of R and D and innovative engineering approaches. One of the Nuclear Decommissioning Authority's (NDA) responsibilities is to ensure that the right level of R and D is carried out to enable progress on delivering the full decommissioning programme. Since 2010, NDA has been collaborating with Innovate UK, the UK government's innovation agency, to engage the supply chain and develop innovative technologies and services to support the NDA's mission and the growing international nuclear decommissioning market. The paper will provide an overview of the approach (e.g. open calls, briefing events, independent assessment, technology showcases) and the associated benefits (e.g. attracting new ideas, end-user engagement, increased supply chain collaboration). The paper also highlights selected technologies developed through the process. (authors)

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Development of an Alternative Approach to Demonstrating Environmental Performance in the UK - 19354

European basic safety standards require that exposure of humans to the potentially harmful effects of ionising radiation are optimised so that they are as low as reasonably achievable, taking account of economic and societal factors. In the United Kingdom the responsibility for ensuring that exposures to humans are optimised is split between two regulatory functions. The Office of Nuclear Regulation regulates exposures to workers in all scenarios and to members of the public in the event of an accident. Environmental regulators in each of the four nations comprising the United Kingdom regulate exposures to members of the public from normal operations. Since the early 1990's, all permissions granted to nuclear sites in the UK for the discharge/disposal of radioactive waste to the environment have contained conditions requiring holders to demonstrate that they minimise the generation of radioactive waste, apply appropriate abatement and discharge/dispose of it in a way that minimises impacts on members of the public and the environment. For many years, the industry standard for providing this demonstration, which was heavily influenced by regulatory expectations and feedback, was to undertake one or a series of multi-attribute decision assessments (MADA). Wood's team of environmental specialists has been involved in undertaking such MADA studies for many years. Since the mid-2000's, our team has become increasingly aware of some of the limitations of undertaking MADA to demonstrate environmental performance for large scale new nuclear build projects and, in particular, the next generation of new nuclear power stations that are being planned and implemented in the UK. We have collaborated with the vendors of reactor technologies, the prospective/owner operators of new nuclear power stations and the developers of new facilities on existing sites to develop an alternative approach to demonstrating environmental performance. Our alternative approach comprises three main pillars which are summarised as: - Evolution - benefit from progressive improvements, operational experience and recent permitting activities. Our alternative approach uses the claim, argument, evidence approach which is commonly used for nuclear safety cases and which allows us to 'tell the story' of how environmental performance has been achieved. We have successfully deployed this approach for all new nuclear power stations proposed in the UK. - Integration - ensure that optimisation is integrated into the project programme and forms part of the 'big picture'. Our alternative approach allows environmental performance to be managed better throughout the life cycle of the project and ensures that our outputs are 'living' documents and do not 'sit on the shelf'. We have successfully demonstrated how this can be applied during rationalisation of major schemes and significant design changes on nuclear new build projects. - Opportunity - identify the best time to deliver elements of the programme. Our alternative approach aims to minimise the overall time, trouble and costs associated with demonstrating environmental performance by ensuring that decisions are made at the time when they offer greatest benefit and by minimising unnecessary rework. Our advice has helped to reduce the project costs and minimise delays associated with regulatory queries and interventions. This paper describes the journey that we have taken with our clients in developing our alternative approach to demonstrating environmental performance. We explain the UK regulatory context and explore the need for change. We present a number of case studies related to new nuclear power stations and other new facilities on existing nuclear sites that demonstrate the successful application of our alternative approach. We provide examples of how we have successfully implemented the outputs of our alternative approach into project and corporate management arrangements. Finally, we examine feedback from clients, regulators and other interested parties to propose future refinements. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Durability of Containers for the Disposal of Radioactive Waste - Swiss and Belgian R and D Studies - 19392

In this paper, we present a summary of the results from research and development (R and D) studies associated with the durability of steel-based disposal canisters for high-level waste (HLW) and spent nuclear fuel (SNF), focusing on experimental studies carried out in support of the Swiss and Belgian disposal programmes. We present the results of laboratory studies carried out for periods of the order of ten to twenty years, and compare them with more recent observations from in situ experiments carried out at the Mont Terri and Grimsel underground laboratories. For the Belgian programme, which is currently envisaging relatively high gamma dose rates outside the steel overpack, we also show the results of studies focusing on gamma radiation at dose rates compatible with those expected in the disposal system. These studies show how, in bentonite systems, corrosion rates decrease to values lower than 1 μm year{sup -1} after an initial period. In the case of cement-based systems, corrosion rates lower than 0.1 μm year{sup -1} are typically observed, with modest effects of gamma irradiation. (authors)

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A Systematic Evidence Based Performance Approach to Regulation of Nuclear Sites in England and Wales - 20058

The Environment Agency for England has developed a systematic evidence-based approach to pursue our strategic environmental objectives for the regulation of nuclear sites. We use an annual evidence review process to ensure effective and efficient targeting of limited resources to achieve those objectives. Over the last 8 years, we have been developing and refining this approach to ensure risk-based and value driven regulation. The approach comprises nuclear site and nuclear sector review processes known as Site Environment Review (SER) and Nuclear Environment Review (NER). This approach complements our regulation of nuclear site permit holders under the Environmental Permitting Regulations (EPR). We deliver our regulation of nuclear sites in England and Wales alongside the Office for Nuclear Regulation. The SER process involves the lead regulator for each nuclear site assessing the permit holder's environmental performance across 14 themes, set within the context of the site's main activities and associated waste disposals. Our themes include environmental leadership, resources and climate change, radioactive waste management, facility management and decommissioning, groundwater, and environmental radiological protection. We use evidence from site inspections and working within our subject matter groups to grade current and predicted future environmental performance. We are particularly interested in sustainability and the application of Best Available Techniques (BAT) to prevent the creation, and minimise the disposal, of radioactive wastes. We use risk analysis (strengths, weaknesses, threats and opportunities) to examine performance against our strategic environmental objectives, which are set out, in our 5-year Nuclear Delivery Plan (NDP). The output supports the targeting of our resources at each nuclear site. We consult the relevant permit holders on the SER priorities and use their feedback to refine our plans. We expect all permit holders to take account of our priorities when considering their own programmes of work, objectives and plans. The NER process brings together what we learn and achieve through regulation across the sector. It provides input to planning priorities, supported by qualitative and semi-quantitative evidence. It covers the 28 nuclear sites in England and Wales and spans the same 14 environmental themes. During the process we collate, compile and summarise evidence from the SERs and other sources such as inspection reports and evidence from our other nuclear work programmes. The output is the NER annual report. This provides a snapshot of the status of the nuclear sector and gives insights to enable us to regulate more efficiently and effectively. It also takes account of cross-cutting issues and risks such as changes in international standards, domestic policy, regulatory framework, domestic standards and guidance, learning from experience such as incidents, events and good practice, and innovation, research and development. It provides graphics that illustrate the grading of environmental performance for the nuclear sector across the fourteen environmental themes. This analysis allows benchmarking of nuclear site's environmental performance and the visualisation provides a convenient comparison of performance across themes, sites, and over time. We use this intelligence to inform our investment in training and development of our staff, and our cross-cutting engagement on strategic issues with government, the Nuclear Decommissioning Authority (NDA) and other corporate organisations. Adopting this approach can provide benefits with organisational reputation, stakeholder participation and ensuring value from the public investment. This paper describes the history of the SER/NER process, a selection of outputs from the process and ideas for improvement. The paper will be of interest to other regulators and organisations across the world that are interested in supporting continuous improvement. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Complexity and error potential of digital I and C - 135

Utilization of digital I and C for application in nuclear power plants led to a growing discussion on how to create methods for a probabilistic evaluation on such systems. Issues arise on the one hand due to a lack of commonly accepted models for quantitative evaluation of availability and reliability and on the other hand due to the integration of such models into the evaluation of reliability of an overall system. Nevertheless programmable and even more complex systems are implemented to satisfy growing functionality requirements. Therefore the question for a method to evaluate the reliability of systems based on software or on programmable logic became even more urgent. The approach described is based on the commonly accepted assumption that more complex designs are less reliable. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A new international standard on cybersecurity for nuclear power plants: IEC 62645 - cybersecurity requirements - 161

This paper provides an overview of the IEC 62645, an actual standard by the International Electrotechnical Commission (IEC) focused on the issue of requirements for computer security programmes and system development processes to prevent and/or minimize the impact of cyber attacks against computer-based I and C systems. Developed since 2009 and published end of 2014, the standard is intended to be used for changing or establishing new security programmes for I and C systems of operating and new Nuclear Power Plants (NPP). This paper also presents the key issues being considered in the new revision to IEC 62645, currently in process. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Development and application of FPGA-based logic controller - 357

The control systems of nuclear power plants contain many components which are becoming obsolete at an increasing rate. Nowadays maintenance for analog-based protection systems may be difficult as analog parts become obsolete or hard to obtain. Various studies have been conducted to address this control system hardware obsolescence issue. Those control systems of nuclear power plants have been replaced with modern digital control systems such as the programmable logic controller (PLC) and the distributed control system (DCS). The central processing unit (CPU)- based platforms such as the PLC and the DCS require an operating system (OS) and application software, and thus they might result in a common-cause failure when a problem occurs in the operating system or application software. The field programmable gate array (FPGA) is highlighted as an alternative to the conventional protection or control systems. This paper presents the development of an FPGA-based logic controller (FLC) and a diverse protection system (DPS) with the FLC platform. Protection functions for the DPS were implemented in FPGAs without any CPU or OS. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Going from Closed to Open and Then Back Again: How to Keep a Level Head

Nuclear Energy is a mature, reliable low carbon technology with a secure and abundant fuel source and is an essential contributor to the energy mix. The UK has a long history of using nuclear energy and has a long standing world class expertise in the recycling of used nuclear fuel with three generations of industrial scale reprocessing plant operating on the Sellafield site, as well as the Thorp Miniature Pilot Plant in the 1980's, and a vibrant, internationally recognised R and D capability at the National Nuclear Laboratory (NNL). However, the reprocessing plants at Sellafield are both scheduled to finish around 2020 with Thorp and Magnox plants moving to post operational clean out (POCO). This will move the UK from a closed fuel cycle to an open one. Within the UK a decision has been made to refresh the current nuclear energy plants to at least replacement of the existing nuclear fleet. This will mean the building of new nuclear power plant to ensure energy production of 16 GWe per annum. With the closure of the UK's reprocessing plants, these new nuclear power plants will operate on an open fuel cycle with long term storage of used fuel followed by disposal. However it is also recognised that this may not be enough and as such expansion scenarios ranging from 16 to 75 GWe nuclear energy production are being considered through the development of a UK Road map. Within these energy scenarios, a variety of options are being evaluated including electricity generation only, electricity generation plus heat, open versus closed fuel cycles, Generation III versus Generation IV systems and combinations of the above. What is clear is that the deciding factor on the type and mix of any energy programme will not be on technology choice alone. Instead a complex mix of Government policy, relative cost of nuclear power, market decisions and public opinion will influence the rate and direction of growth of any future energy programme. At the ANS Winter Meeting 2013 a number of these techniques were presented. What was clear from the fuel cycle scenario modelling was the requirement for the utilisation of a closed fuel cycle to enable the expansion beyond 16 GWe. It is therefore a necessity for the UK to keep options open for a potential return to a closed fuel cycle in the future. The requirement to maintain the skills and capabilities to do so will be an essential part of any future nuclear strategy. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The development of criticality response materials - 14282

The Sellafield nuclear facility in the UK comprises a highly complex suite of plants and processes. This in turn demands a consistent and high performance from Emergency Response teams and management in order to demonstrate readiness to respond and combat any nuclear emergency. In order to continue to improve such readiness, a comprehensive programme of development has been undertaken by the Licensee. The programme spans the totality of the emergency response cycle which is resolved into three broad areas: Preparedness; Response; Building Specific File. Within these broad categories the focus of the materials changes from broad and general materials in the preparedness section to actual scenario specific materials in the Building Specific Files Sellafield Ltd. provided the scope of work for the totality of the criticality response materials, known collectively as Criticality Accident Response Data (CARD). The UK National Nuclear Laboratory (NNL) was challenged to technically underpin, develop and present the information in a format and layout that would satisfy the requirements of consistency, brevity, simplicity and relevance. One of the key areas targeted for improvement, and the focus of this paper, was the criticality accident response information that sits within the Building Specific File. At this level of the emergency response cycle by necessity the information must be detailed and specific and enable the emergency responder to understand the problem and assist in formulating a recovery plan. One of the key challenges faced by NNL and discussed in this paper was how to provide the emergency responder with the greatest amount of relevant information in the simplest form. NNL solved this problem by presenting the information in a 'four-block' format which includes a common set of information in textual and diagrammatic form. This paper presents on overview of the criticality accident specific four-blocker, highlights the problems encountered and focuses on the new and innovative materials developed. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Modbus RTU for Embedded Cyber Secure Inverter Controller

The Modbus communication protocol is a widely adopted communication standard in industrial control systems. This communication protocol is known for being reliable and straightforward to implement while being versatile in terms of its operating parameters while supporting multiple formats over various hardware infrastructures and architectures. Many intelligent devices such as Programmable Logic Controllers (PLCs), Human-Machine Interfaces (HMIs), Internet-of-Things (IoT), and various Operational Technologies (OT) utilize Modbus for their communication systems. These types of systems must communicate with each other through a standardized and central communication process. To support the integration of these modular systems, a Field-Programmable Gate Array (FPGA) can act as an embedded central routing fabric for this communication to take place. Embedded systems are versatile enough to interface with various devices and systems to accomplish various goals. Additionally, embedded systems require relatively small physical designs to minimize the required resources to facilitate the intended application by providing low-level system access. This minimization of system resources goes hand in hand with reducing the financial cost of a proposed solution or system. As remotely collaborating researchers often use FPGAs to prototype designs that are required to have a method for data transmission among systems, it is imperative to provide a baseline standard for communications among devices and systems. A typical method of implementing the Modbus RTU communication protocol in an embedded environment is using integrated logic architectures within the FPGA called “Intellectual Property (IP) cores.” IP cores can be designed using integrated logic or circuit designs to function as an embedded processor. These IP cores can then perform the required computational actions to support the Modbus RTU communication protocol by utilizing high-level programming languages such as the C programming language. The hardware description language of Very High-Speed Integrated Circuit Hardware Description Language (VHDL) allows for the control of real hardware at the logic gate and signal level. These logic gates and signals can be designed and controlled to perform desired actions based on the system design. Programming an FPGA using VHDL allows an individual to access the lowest abstraction level of the system during FPGA development. This level of abstraction is referred to as the register-transfer level (RTL), which gives access to manipulating values and variables at the register level. This register-level manipulation provides precision over creating the logical circuit within the FPGA, thus minimizing the required code to perform desired operations. The Modbus RTU communication protocol can be implemented within an FPGA using VHDL programming to establish a standardized and embedded serial communication pathway. This implementation provides a standardized communication protocol to streamline research efforts among researchers, thus increasing the efficiency of research efforts. Additionally, this Modbus RTU implementation requires fewer resources when compared to typical communication protocol implementations that utilize an IP core, reducing the hardware requirement for effective research efforts.

communication↗

Towards Automated Generation of Chiplet-Based Systems

The Software Defined Architectures (SODA) Synthesizer is an open-source compiler-based tool able to automatically generate domain-specialized systems targeting Application- Specific Integrated Circuits (ASICs) or Field Programmable Gate Arrays (FPGAs) starting from high-level programming. SODA is composed of a high-level frontend, SODA-OPT, which leverages the multilevel intermediate representation (MLIR) framework to interface with productive programming tools (e.g., machine learning frameworks), identify kernels suitable for acceleration, and perform high-level optimizations, and of a state-of-the-art high-level synthesis backend, Bambu from the PandA framework, to generate custom accelerators. One specific application of the SODA Synthesizer is the generation of accelerators to enable ultra-low latency inference and control on autonomous systems for scientific discovery (e.g., electron microscopes, sensors in particle accelerators, etc.). This talk will discuss ongoing work on the SODA synthesizer to enable no-human-in-the-loop generation and design space exploration of the chiplets for highly specialized artificial intelligence accelerators. Connecting these highly specialized chiplets to general-purpose cores or programmable accelerators will allow to quickly deploy autonomous systems for scientific discovery.

Limaye, Ankur M.↗

Expanding the physics reach of DUNE in the near and far detectors

The Deep Underground Neutrino Experiment (DUNE) is a next-generation long-baseline neutrino oscillation experiment. Its primary goal is the determination of the neutrino mass hierarchy and the CP-violating phase. The DUNE physics programme also includes the detection of astrophysical neutrinos and the search for beyond the Standard Model (BSM) phenomena. DUNE will consist of a near detector (ND) complex placed at Fermilab, and a modular Liquid Argon Time Projection Chamber (LArTPC) far detector (FD) to be built in the Sanford Underground Research Facility (SURF), approximately 1300 km away from the neutrino production point. This thesis describes three different projects within DUNE. First, a novel strategy to improve the triggering capabilities of the DUNE FD is proposed. It uses matched filters to enhance the production of online hits across all charge collection planes. Next, the possibility of detecting neutrinos coming from dark matter (DM) annihilations in the Sun with the FD is explored. The complementarity of DUNE to this kind of DM searches is shown. Finally, the simulation and reconstruction framework of ND-GAr, the gas argon ND proposed for Phase II of DUNE, is presented. A number of additions to this are described, particularly focused on the development of the particle identification (PID) capabilities of the detector. These are then used to perform the first event selection studies with an end-to-end simulation in ND-GAr, in particular the selection of pion exclusive samples in $\nu_{\mu}$ CC interactions. All three of these projects share the common goal of enhancing the physics programme of DUNE.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Tubulin Double Helix: Lateral and Longitudinal Curvature Changes of Tubulin Protofilament

By virtue of their native structures, tubulin dimers are protein building blocks that are naturally pre-programmed to assemble into cytoskeletal polymers known as microtubules (MTs). Here we demonstrate polycation-directed (i.e. electrostatically tunable) assembly of tubulins through tubulin protofilament conformational changes in the longitudinal and lateral directions, creating novel tubulin double helices and various tubular architectures. Synchrotron small angle X-ray scattering and transmission electron microscopy reveal a remarkable range of nanoscale assembly structures: single- and double-layered double-helix tubulin tubules. The phase transitions from MTs into the new assemblies are dependent on the size and concentration of polycations. Two characteristic scales that determine the number of observed phases are the size of polycation compared to the size of tubulin (≈4 nm) and MT diameter (≈25 nm). This work suggests the feasibility of “programmable breakdown” of protein nanotubes, tearing MTs into double-stranded tubulins and building up previously undiscovered nanostructures, by using polycations with scissor- and glue-like properties. Importantly, we define a new role of tubulins as two-dimensionally shape-controllable building blocks for novel supramolecular architectures. Furthermore, these findings provide insight into the design of protein-based functional materials, for example, as metallization templates for nanoscale electronic devices, kinesin motor-driving molecular screws, and anticancer drug delivery vehicles.

2D shape‐control↗

Lax-Oleinik-Type Formulas and Efficient Algorithms for Certain High-Dimensional Optimal Control Problems

Two of the main challenges in optimal control are solving problems with state-dependent running costs and developing efficient numerical solvers that are computationally tractable in high dimension. In this paper, we provide analytical solutions to certain optimal control problems whose running cost depends on the state variable and with constraints on the control. We also provide Lax-Oleinik-type representation formulas for the corresponding Hamilton-Jacobi partial differential equations with state-dependent Hamiltonians. Additionally, we present an efficient, grid-free numerical solver based on our representation formulas, which is shown to scale linearly with the state dimension, and thus, to overcome the curse of dimensionality. Using existing optimization methods and the min-plus technique, we extend our numerical solvers to address more general classes of convex and nonconvex initial costs. We demonstrate the capabilities of our numerical solvers using implementations on a central processing unit (CPU) and a field-programmable gate array (FPGA). In several cases, our FPGA implementation obtains over a 10 times speedup compared to the CPU, which demonstrates the promising performance boosts FPGAs can achieve. Furthermore, our numerical results show that our solvers have the potential to serve as a building block for solving broader classes of high-dimensional optimal control problems in real-time.

97 MATHEMATICS AND COMPUTING↗

Pulse discrimination with a Gaussian mixture model on an FPGA

A Gaussian Mixture Model (GMM) based machine learning algorithm has been applied to the problem of gamma/neutron pulse shape discrimination (PSD). The algorithm has been successfully implemented on a standard PC as well as a field programmable gate array (FPGA). We describe the GMM classifier and its implementation on these two different types of hardware. We compare the performance of the algorithm on these two platforms against each other, along with other standard techniques applied in PSD. Our results show that the FPGA-based GMM classifier outperforms the standard PSD techniques in terms of classification accuracy at low particle energy and executes more quickly than its CPU-based counterpart.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Ion Transport in Self-Assembled Peptoid Membranes with Carbon Nanotube Porin Channels

Artificial membranes that combine high ionic selectivity with mechanical robustness remain a key challenge for next-generation separation technologies. Here, we report ion transport measurements in biomimetic membranes composed of crystalline peptoid nanosheets co-assembled with carbon nanotube porins (CNTPs). Pure peptoid sheets formed defect-free, ion-impermeable membranes, which were then suspended over small SiN x nanopore apertures for ion transport measurements. Incorporation of CNTPs into the peptoid sheet matrix made these membranes ion permeable, with ion conductance values consistent with ion transport through individual and multiple carbon nanotube channels. In conclusion, the modularity and molecular order of peptoid membranes, combined with the exceptional conductance properties of CNTPs, position this platform as a versatile framework for assembling programmable, selective, and robust nanofluidic membranes that can bridge the performance gap between biological and synthetic membrane materials.

Biotechnology↗