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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Local structure effects of carbon-doping on the phase change material Ge 2 Sb 2 Te 5

Ge 2 Sb 2 Te 5 is used in phase change memory, a nonvolatile memory technology, due to its phase change properties. The primary advantage of phase change memory over the state-of-the-art (flash memory) is its simple and small device geometry, which allows for denser nodes and lower power consumption. In phase change memory, resistive heating induces fast switching between the high resistance amorphous and low resistance crystalline phases, corresponding to storage of low and high digital states, respectively. However, the instability of the amorphous phase of Ge 2 Sb 2 Te 5 presents issues with processing and long-term data storage; such issues can be resolved by C doping, which stabilizes the amorphous phase and raises the crystallization temperature. To better understand the local structural effects of C doping on Ge 2 Sb 2 Te 5 , in situ Ge K-edge X-ray absorption spectroscopy measurements were taken during heating of films with various C doping concentrations. Here, the range of structural transformation temperatures derived from X-ray absorption near-edge structure analysis across the C doping series proved narrower than crystallization temperatures reported in similar in situ X-ray diffraction experiments, which may reflect changes in local structure that precede long-range ordering during crystallization. In addition, rigorous extended X-ray absorption fine structure fitting across and between temperature series revealed effects of C doping on the rigidity of Ge–Te bonds at low (2 at% and 4 at%) C concentrations.

Langhout, John D.↗
DOE OSTI2024

Iron Carbonyl Complexes of [2.2.2]Hericene as a Rigid Tris(1,3-diene) Ligand

Hericene is an unusual hexaolefin consisting of three 1,3-diene units located on a rigid bicyclo [2.2.2]octane framework that restricts the geometrical relationships of metal atoms bonded to these olefinic units. In order to explore possible effects of this rigidity limiting metal–metal interaction in polynuclear derivatives possibly stabilizing coordinatively unsaturated species, the structures and energetics of the hericene iron carbonyl complexes (hericene)Fem(CO)n (m = 1, n = 3; m = 2, n = 6, 5; m = 3, n = 9, 8) have been investigated by density functional theory. The lowest-energy (hericene)Fem(CO)3m (m = 1, 2, 3) structures have the cavities of the hericene ligand filled with a single Fe(CO)3 moiety bonded to a 1,3-diolefin unit. Such species have been synthesized by the reaction of Fe2(CO)9 with hericene. For the (hericene)Fe2(CO)5 system, the lowest energy structures are singlet structures with an Fe(CO)3 unit bonded to a 1,3-diene unit in one hericene cavity and an Fe(CO)2 unit in another hericene cavity bonded to three C=C double bonds from two 1,3-diene units. Higher energy (hericene)Fe2(CO)5 structures include a structure in which a single hericene cavity contains a Fe2(CO)4(µ-CO) moiety with each iron atom bonded to a 1,3-diene unit. In addition, both singlet and triplet (hericene)Fe2(CO)5 structures are found in which an Fe(CO)3 moiety and an Fe(CO)2 moiety located in separate hericene cavities are each bonded to a 1,3-diene unit. The lowest-energy (hericene)Fe3(CO)8 structures have two hericene cavities containing Fe(CO)3 moieties fully bonded to 1,3-diene units and a third hericene cavity containing an Fe(CO)2 moiety fully bonded to a 1,3-diene unit.

Luo, Jinfeng↗
NASA NTRS1972

Polymeric binder for explosives

Chemical reaction for producing a polymer which can be mixed with explosives to produce a rigid material is discussed. Physical and chemical properties of polymers are described and chemical structure of the polymer is illustrated.

Bissell, E. R.↗
NASA NTRS1973

Aeroelastic analysis of sounding rocket vehicles.

Rigid-body stability analysis can be extended to treat aeroelastic effects by allowing the structure to deflect under airloads as a simple beam. Linear aerodynamics and the bent shape then define the airloads. The resulting equations are indeterminant but can be manipulated to show the basic aeroelastic effects of flexibility, dynamic pressure, and angle of attack. The FLMD quasi-static program can solve these equations by iteration and compute stability for a specific vehicle/payload combination. Given the proper distributed inputs for the instant of time investigated, the FLMD predicts the center of pressure and related parameters, such as static margin.

Meyers, S. C.↗
NASA NTRS1975

The effect of ring distortions on buckling of blunt conical shells

A rigorous analytical study of cones stiffened by many thin-gage, open-section rings is presented. The results are compared with data previously obtained from uniform pressure tests of the Viking mission flight aeroshell and of the Viking structural prototype aeroshells. A conventional analysis, in which the rings are modeled as discrete rigid cross sections, is shown to lead to large, unconservative strength predictions. A more sophisticated technique of modeling the rings as shell branches leads to much more realistic strength predictions and more accurately predicts the failure modes. It is also shown that if a small initial imperfection proportional to the shape of the buckling mode is assumed, the critical buckling modes from analysis and test are in agreement. However, the reduction in buckling strength from the perfect-shell predictions is small.

Heard, W. L., Jr.↗
NASA NTRS1978

Dynamic analysis using superelements for a large helicopter model

Using superelements (substructures), modal and frequency response analysis was performed for a large model of the Advanced Attack Helicopter developed for the U.S. Army. Whiffletree concept was employed so that the residual structure along with the various superelements could be represented as beam-like structures for economical and accurate dynamic analysis. A very large DMAP alter to the rigid format was developed so that the modal analysis, the frequency response, and the strain energy in each component could be computed in the same run.

Patel, M. P.↗
NASA NTRS1979

Rigidity of lattice domes

The means of ensuring total rigidity of lattice domes, using comparison with solid shells of 1-3 layers are discussed. Irregularities of manufacture, processing, and other factors are considered, as they relate to diminution of rigidity. The discussion uses the concepts of upper and lower critical loads on the structure in question.

Savelyev, V. A.↗
NASA NTRS1980

Buckling of axially compressed conical shells

The buckling of a truncated elastic conical shell subjected to an axial compression is a classical problem in shell structures. The paper reinvestigates the buckling of an axially compressed truncated conical shell with rigid bulkheads. Two improvements are achieved. First, the condition that the total horizontal displacement must vanish due to rigid bulkhead and axisymmetry is treated as a constraint. This constraint is incorporated into the system through the use of the Lagrange multiplier; then the variational method is used to derive a complete set of boundary conditions for conical shells. Second, the stability is evaluated in the deformed state using the asymptotic solutions of the pair of Donnell-type equations for axisymmetric configuration. The results indicate that the buckling strength of conical shells depends mainly on the condition of the smaller end. In addition to the vertex angle, the distance ratio plays, at least, an equally important role.

Chang, C.-H.↗
NASA NTRS1986

A model for the biological precipitation of Precambrian iron-formation

A biological model for the precipitation of Precambrian iron formations is presented. Assuming an oxygen deficient atmosphere and water column to allow sufficient Fe solubility, it is proposed that local oxidizing environments, produced biologically, led to precipitation of iron formations. It is further suggested that spheroidal structures about 30 mm in diameter, which are widespread in low grade cherty rion formations, are relict forms of the organic walled microfossil Eosphaera tylerii. The presence of these structures suggests that the organism may have had a siliceous test, which allowed sufficient rigidity for accumulation and preservation. The model involves precipitation of ferric hydrates by oxidation of iron in the photic zone by a variety of photosynthetic organisms. Silica may have formed in the frustules of silica secreting organisms, including Eosphaera tylerii. Iron formates formed, therefore, by a sediment rain of biologically produced ferric hydrates and silica and other organic material. Siderite and hematite formed diagenetically on basin floors, and subsequent metamorphism produced magnetite and iron silicates.

Laberge, G. L.↗
NASA NTRS1986

Anisotropic responses to motion toward and away from the eye

When a rigid object moves toward the eye, it is usually perceived as being rigid. However, in the case of motion away from the eye, the motion and structure of the object are perceived nonveridically, with the percept tending to reflect the nonrigid transformations that are present in the retinal image. This difference in response to motion to and from the observer was quantified in an experiment using wire-frame computer-generated boxes which moved toward and away from the eye. Two theoretical systems are developed by which uniform three-dimensional velocity can be recovered from an expansion pattern of nonuniform velocity vectors. It is proposed that the human visual system uses two similar systems for processing motion in depth. The mechanism used for motion away from the eye produces perceptual errors because it is not suited to objects with a depth component.

Perrone, John A.↗
NASA NTRS1988

Microplate and shear zone models for oceanic spreading center reorganizations

The kinematics of rift propagation and the resulting goemetries of various tectonic elements for two plates is reviewed with no overlap zone. The formation and evolution of overlap regions using schematic models is discussed. The models are scaled in space and time to approximate the Easter plate, but are simplified to emphasize key elements. The tectonic evolution of overlap regions which act as rigid microplates and shear zones is discussed, and the use of relative motion and structural data to discriminate between the two types of models is investigated. The effect of propagation rate and rise time on the size, shape, and deformation of the overlap region is demonstrated.

Engeln, Joseph F.↗
NASA NTRS1988

Experimental verification of a large flexible manipulator

A large experimental lightweight manipulator would be useful for material handling, for welding, or for ultrasonic inspection of a large structure, such as an airframe. The flexible parallel link mechanism is designed for high rigidity without increasing weight. This constrained system is analyzed by singular value decomposition of the constraint Jacobian matrix. A verification of the modeling using the assumed mode method is presented. Eigenvalues and eigenvectors of the linearized model are compared to the measured system natural frequencies and their associated mode shapes. The modeling results for large motions are compared to the time response data from the experiments. The hydraulic actuator is verified.

Lee, Jac Won↗
NASA NTRS1989

Conceptual design of a self-deployable, high performance parabolic concentrator for advanced solar-dynamic power systems

A summary is presented of the concentrator conceptual design work performed under a NASA-funded project. The design study centers around two basic efforts: conceptual design of a self-deploying, high-performance parabolic concentrator; and materials selection for a lightweight, shape-stable concentrator. The primary structural material selected for the concentrator is PEEK/carbon fiber composite. The deployment concept utilizes rigid gore-shaped reflective panels. The assembled concentrator takes a circular shape with a void in the center. The deployable solar concentrator concept is applicable to a range of solar dynamic power systems of 25 kWe to more than 75 kWe.

Dehne, Hans Joachim↗
NASA NTRS1990

Probabilistic structural analysis by extremum methods

The objective is to demonstrate discrete extremum methods of structural analysis as a tool for structural system reliability evaluation. Specifically, linear and multiobjective linear programming models for analysis of rigid plastic frames under proportional and multiparametric loadings, respectively, are considered. Kinematic and static approaches for analysis form a primal-dual pair in each of these models and have a polyhedral format. Duality relations link extreme points and hyperplanes of these polyhedra and lead naturally to dual methods for system reliability evaluation.

Nafday, Avinash M.↗
NASA NTRS1991

A recursive approach to the equations of motion for the maneuvering and control of flexible multi-body systems

Interest lies in a mathematical formulation capable of accommodating the problem of maneuvering a space structure consisting of a chain of articulated flexible substructures. Simultaneously, any perturbations from the 'rigid body' maneuvering and any elastic vibration must be suppressed. The equations of motion for flexible bodies undergoing rigid body motions and elastic vibrations can be obtained conveniently by means of Lagrange's equations in terms of quasi-coordinates. The advantage of this approach is that it yields equations in terms of body axes, which are the same axes that are used to express the control forces and torques. The equations of motion are nonlinear hybrid differential quations. The partial differential equations can be discretized (in space) by means of the finite element method or the classical Rayleigh-Ritz method. The result is a set of nonlinear ordinary differential equations of high order. The nonlinearity can be traced to the rigid body motions and the high order to the elastic vibration. Elastic motions tend to be small when compared with rigid body motions.

Kwak, Moon K.↗
NASA NTRS1991

Dynamic dissipative compensator design for large space structures

Control system design is considered for attitude control and vibration suppression of flexible space structures. The problem addressed is that of controlling both the zero-frequency rigid-body modes and the elastic modes. Model-based compensators, which employ observers tuned to the plant parameters, are first investigated. Such compensators are shown to generally exhibit high sensitivity to the knowledge of the parameters, especially the elastic mode frequencies. To overcome this problem a class of dynamic dissipative compensators is next proposed, which robustly stabilize the plant in the presence of unmodeled dynamics and parametric uncertainties. An analytical proof of robust stability is given, and a method of implementing the controller as a strictly proper compensator is given. Methods of designing such controllers to obtain optimal performance and robust stability are presented. Numerical and experimental results of application of the methods are presented, which indicate that dynamic dissipative controllers can simultaneously provide excellent performance and robustness.

Joshi, S. M.↗
NASA NTRS1992

Foldable Large Reflectors

Reflector deployed from cylindrical package about one-fifth as wide. Large paraboloidal, otherwise curved, or flat reflectors automatically deployable from, and retractable into, compact packages, according to proposal. Reflecting surfaces consist of rigid panels, stacked in compact packages along with deployment mechanisms becoming parts of supporting structures upon deployment.

Mikulas, Martin M., Jr.↗
NASA NTRS1992

On the coupling between a supersonic boundary layer and a flexible surface

The coupling between a two-dimensional, supersonic, laminar boundary layer and a flexible surface is studied using direct numerical computations of the Navier-Stokes equations coupled with the plate equation. The flexible surface is forced to vibrate by plane acoustic waves at normal incidence emanated by a sound source located on the side of the flexible surface opposite to the boundary layer. The effect of the source excitation frequency on the surface vibration and boundary layer stability is analyzed. We find that, for frequencies near the fifth natural frequency of the surface or lower, large disturbances are introduced in the boundary layer which may alter its stability characteristics. The interaction between a stable two-dimensional disturbance of Tollmien-Schlichting (TS) type with the vibrating surface is also studied. We find that the disturbance level is higher over the vrating flexible surface than that obtained when the surface is rig id, which indicates a strong coupling between flow and structure. However, in the absence of the sound source the disturbance level over the rigid and flexible surfaces are identical. This result is due to the high frequency of the TS disturbance which does not couple with the flexible surface.

Frendi, Abdelkader↗