Search NASA⌕ Search

SEARCH · Search NASA

Results for “sample activation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 649 records · Page 36

Radiation Induced Degradation of White Thermal Control Paint

This paper details a comparison analysis of the Zinc Oxide pigmented white thermal control paints Z-93 and Z-93P. Both paints were simultaneously exposed to combined space environmental effects and analyzed using an in-vacuum reflectance technique. The dose applied to the paints was approximately equivalent to 5 years in a geosynchronous orbit. This comparison analysis showed that Z-93P is an acceptable substitute for Z-93. Irradiated samples of Z-93 and Z-93P were subjected to additional exposures of ultraviolet (UV) radiation and analyzed using the in-vacuum reflectance technique to investigate UV activated reflectance recovery. Both samples showed minimal UV activated reflectanc6 recovery after an additional 190 Equivalent Sun Hour (ESH) exposure. Reflectance response utilizing nitrogen as a repressurizing gas instead of air was also investigated. This investigation found the rates of reflectance recovery when repressurized with nitrogen are slower than when repressurized with air.

Edwards, D. L.↗

POLYCYCLIC AROMATIC HYDROCARBONS, IONIZED GAS, AND MOLECULAR HYDROGEN IN BRIGHTEST CLUSTER GALAXIES OF COOL-CORE CLUSTERS OF GALAXIES

We present measurements of 5-25 {mu}m emission features of brightest cluster galaxies (BCGs) with strong optical emission lines in a sample of nine cool-core clusters of galaxies observed with the Infrared Spectrograph on board the Spitzer Space Telescope. These systems provide a view of dusty molecular gas and star formation, surrounded by dense, X-ray-emitting intracluster gas. Past work has shown that BCGs in cool-core clusters may host powerful radio sources, luminous optical emission-line systems, and excess UV, while BCGs in other clusters never show this activity. In this sample, we detect polycyclic aromatic hydrocarbons (PAHs), extremely luminous, rotationally excited molecular hydrogen line emission, forbidden line emission from ionized gas ([Ne II] and [Ne III]), and infrared continuum emission from warm dust and cool stars. We show here that these BCGs exhibit more luminous forbidden neon and H{sub 2} rotational line emission than star-forming galaxies with similar total infrared luminosities, as well as somewhat higher ratios of 70 {mu}m/24 {mu}m luminosities. Our analysis suggests that while star formation processes dominate the heating of the dust and PAHs, a heating process consistent with suprathermal electron heating from the hot gas, distinct from star formation, is heating the molecular gas and contributing to the heating of the ionized gas in the galaxies. The survival of PAHs and dust suggests that dusty gas is somehow shielded from significant interaction with the X-ray gas.

79 ASTRONOMY AND ASTROPHYSICS↗

Studies of thin films of Ti- Zr -V as non-evaporable getter films prepared by RF sputtering

Non-Evaporable Getter (NEG) films of the Ti-Zr-V prepared on stainless steel substrates by Radio Frequency sputtering. To observe its getter behavior at the lowest activation temperature, the sample is heated continuously at different temperatures (100 Degree-Sign C, 150 Degree-Sign C, 200 Degree-Sign C and 250 Degree-Sign C) for 2 hours. The changes of the surface chemical composition at different temperaturesare analyzed by using XPS and SEM (Scanning Electron Microscopy) techniques. The volume elemental composition of the film has been measured by energy dispersive X-ray spectroscopy (EDX). The in-situ XPS measurements of the activated getter films show the disappearance of the superficial oxide layer through the variation in the oxygen stoichiometry during thermal activation. Results of these studies show that the deposited films of Ti-Zr-V could be used as NEG to produce extreme high vacuum.

36 MATERIALS SCIENCE↗

Morphology induced photo-degradation study of low temperature, chemically derived ZnO/SnO{sub 2} heterostructure

Rational construction of heterostructure is a key pathway to pursue highly active photocatalysts that also offers prospects to explore the relationship between structural aspect and photocatalytic efficiency. Here, we adopted a two-step wet chemical protocol for decoration of ZnO nanowires with SnO{sub 2} nanoclusters. ZnO nanowires were prepared by one pot ambient conditioned synthesis from commercial zinc powder. In sequence, synthesized ZnO nanowires were engineered with varying quantity SnO{sub 2} nanoclusters via low temperature hydrothermal method. Environmental remediation through catalytic activity of the samples was inspected taking two dyes having different ionic character (Methyl Orange and Rhodamine B) under UV irradiation where the optimized hybrid displayed better performance than mono component oxides. Enhancement in catalytic performance could be enlightened by the heterostructure formation at the ZnO/SnO{sub 2} interface which in turns prolonged photogenerated carrier separation and extend the photo response range. Furthermore, the photocatalysis performance by heterostructure could be recycled for several times without noticeable decrease in their catalytic activity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Development and Comparison of Purgeable Mercury Values in SRR Samples Measured by SRNL and Eurofins FGS

Savannah River Remediation (SRR) requested the development of mercury speciation capabilities at the Savannah River National Laboratory (SRNL) to support the Liquid Waste Operations at SRS. As part of that method development, SRR requested that SRNL Analytical Development (AD) compare their results with those obtained from their outside contract laboratory, Eurofins Frontier Global Sciences (FGS). This document reports on this method development work as well as the comparative analyses conducted between the two laboratories. Development, optimization, and validation were undertaken at SRNL to produce a method for the species-specific analysis of dissolved gaseous mercury (DGM) in samples from SRR. It was determined that DGM present in SRR samples represented a combination of various soluble and volatile mercury species- and is thus referred to in this document as purgeable mercury. A method has been developed and analytically validated for the analysis of purgeable mercury in caustic nuclear waste. Using multivariate optimization method, purge flow rate was determined to be highly correlated with increased response (p=0.023). Total recovery of spiked purgeable mercury from deionized water was 99.4 ±10.6% and 91.6 ±14.9% from spiked high-activity tank waste samples. Calibration, by external calibration and standard addition calibration, maintained a mean accuracy of 101 ±5% and 99.9 ±1.7%, respectively. This method represents a decrease in sample handling and processing over currently standard methods and represents a more amenable method for purgeable mercury analysis in liquid nuclear waste.1 An interlaboratory comparison was performed between SRNL and Eurofins FGS in the co-analysis of three quarterly Tank 50 samples. Two samples demonstrated no statistically significant difference (p=0.271, p=0.0811), with one sample biased 30% low to a statistically significant degree (p=0.0432). Large mean uncertainty was present in the results reported by both laboratories (±15% and 40% from SRNL and Eurofins), with no significant difference observed in uncertainty (p=0.934). Across all co-analyzed samples, no significantly difference was observed in precision (p=0.205) or reported values (p=0.352) between SRNL and Eurofins. These results indicate that SRNL-AD may provide data to the customer of statistically similar quality.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Nevada National Security Site Integrated Groundwater Sampling Plan, Revision 1

The purpose is to provide a comprehensive, integrated approach for collecting and analyzing groundwater samples to meet the needs and objectives of the DOE/EM Nevada Program’s UGTA Activity. Implementation of this Plan will provide high-quality data required by the UGTA Activity for ensuring public protection in an efficient and cost-effective manner. The Plan is designed to ensure compliance with the UGTA Quality Assurance Plan (QAP) (NNSA/NFO, 2015); Federal Facility Agreement and Consent Order (FFACO) (1996, as amended); and DOE Order 458.1, Radiation Protection of the Public and the Environment (DOE, 2013). The Plan’s scope comprises sample collection and analysis requirements relevant to assessing both the extent of groundwater contamination from underground nuclear testing and impact of testing on water quality in downgradient communities. This Plan identifies locations to be sampled by CAU and location type, sampling frequencies, sample collection methodologies, and the constituents to be analyzed. In addition, the Plan defines data collection criteria such as well purging, detection levels, and accuracy requirements/recommendations; identifies reporting and data management requirements; and provides a process to ensure coordination between NNSS groundwater sampling programs for sampling analytes of interest to UGTA. Information used in the Plan development—including the rationale for selection of wells, sampling frequency, and the analytical suite—is discussed under separate cover (N-I, 2014) and is not reproduced herein. This Plan does not address compliance for those wells involved in a permitted activity. Sampling and analysis requirements associated with these wells are described in their respective permits and are discussed in NNSS environmental reports (see Section 5.2). In addition, sampling for UGTA CAUs that are in the Closure Report (CR) stage are not included in this Plan. Sampling requirements for these CAUs are described in the CR. Frenchman Flat is currently the only UGTA CAU in the CR stage. Sampling requirements for this CAU are described in Underground Test Area (UGTA) Closure Report for Corrective Action Unit 98: Frenchman Flat Nevada National Security Site, Nevada (NNSA/NFO, 2016).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Temporal, Spatial, and Diurnal Patterns in Avian Activity at the Shuttle Landing Facility, John F. Kennedy Space Center, Florida, USA

Spatial and temporal patterns in bird abundance within the five-mile airspace at the Shuttle Landing Facility (SLF) on John F. Kennedy Space Center (KSC), Florida, USA were investigated for purposes of quantifying Bird Aircraft Strike Hazards (BASH). The airspace is surrounded by the Merritt Island National Wildlife Refuge (MINWR) which provides habitat for approximately 331 resident and migratory bird species. Potential bird strike hazards were greatest around sunrise and sunset for most avian taxonomic groups, including wading birds, most raptors, pelicans, gulls/terns, shorebirds, and passerines. Turkey Vultures and Black Vultures were identified as a primary threat to aircraft operations and were represented in 33% of the samples. Diurnal vulture activity varied seasonally with the development of air thermals in the airspace surrounding the SLF. Variation in the presence and abundance of migratory species was shown for American Robins, swallows, and several species of shorebirds. Analyses of bird activities provides for planning of avionics operations during periods of low-dsk and allows for risk minimization measures during periods of high-risk.

Larson, Vickie L.↗

Aluminum-26 activities in meteorites

Al-26 activities for 686 Antarctic meteorites and 46 non-Antarctic meteorites are reported. The data set includes new results for 253 Antarctic and 5 non-Antarctic meteorites. Most of the Antarctic specimens were collected from the Allan Hills region, but specimens from other regions were measured as well. The non-Antarctic specimens include freshly fallen meteorites, in which short-lived radionuclides (e.g., Na-22, Mn-54, Co-57, etc.) were also measured. The data were analyzed for terrestrial age distributions, identification of samples with unusual activities, pairing of specimens, and comparisons of Antarctic and non-Antarctic activity distributions.

Wacker, J. F.↗

A LOCAL BASELINE OF THE BLACK HOLE MASS SCALING RELATIONS FOR ACTIVE GALAXIES. I. METHODOLOGY AND RESULTS OF PILOT STUDY

We present high-quality Keck/LRIS long-slit spectroscopy of a pilot sample of 25 local active galaxies selected from the SDSS (0.02 {<=}z {<=} 0.1; M{sub BH}>10{sup 7} M{sub sun}) to study the relations between black hole mass (M{sub BH}) and host-galaxy properties. We determine stellar kinematics of the host galaxy, deriving stellar-velocity dispersion profiles and rotation curves from three spectral regions (including CaH and K, MgIb triplet, and Ca II triplet). In addition, we perform surface photometry on SDSS images, using a newly developed code for joint multi-band analysis. BH masses are estimated from the width of the H{beta} emission line and the host-galaxy free 5100 A active galactic nucleus (AGN) luminosity. Combining results from spectroscopy and imaging allows us to study four M{sub BH} scaling relations: M{sub BH}-{sigma}, M{sub BH}-L{sub sph}, M{sub BH}-M{sub sph,*}, and M{sub BH}-M{sub sph,dyn}. We find the following results. First, stellar-velocity dispersions determined from aperture spectra (e.g., SDSS fiber spectra or unresolved data from distant galaxies) can be biased, depending on aperture size, AGN contamination, and host-galaxy morphology. However, such a bias cannot explain the offset seen in the M{sub BH}-{sigma} relation at higher redshifts. Second, while the CaT region is the cleanest to determine stellar-velocity dispersions, both the MgIb region, corrected for Fe II emission, and the CaHK region, although often swamped by the AGN power-law continuum and emission lines, can give results accurate to within a few percent. Third, the M{sub BH} scaling relations of our pilot sample agree in slope and scatter with those of other local active and inactive galaxies. In the next papers of the series we will quantify the scaling relations, exploiting the full sample of {approx}100 objects.

79 ASTRONOMY AND ASTROPHYSICS↗

Handbook: Collecting Groundwater Samples from Monitoring Wells in Frenchman Flat, CAU 98

Frenchman Flat basin on the Nevada National Security Site (NNSS) contains Corrective Action Unit (CAU) 98, which is comprised of ten underground nuclear test locations. Environmental management of these test locations is part of the Underground Test Area (UGTA) Activity conducted by the U.S. Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended) with the U.S. Department of Defense (DOD) and the State of Nevada. A Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) has been approved for CAU 98 (DOE, 2011). The CADD/CAP reports on the Corrective Action Investigation that was conducted for the CAU, which included characterization and modeling. It also presents the recommended corrective actions to address the objective of protecting human health and the environment. The recommended corrective action alternative is “Closure in Place with Modeling, Monitoring, and Institutional Controls.” The role of monitoring is to verify that Contaminants of Concern (COCs) have not exceeded the Safe Drinking Water Act (SDWA) limits (Code of Federal Regulations, 2014) at the regulatory boundary, to ensure that institutional controls are adequate, and to monitor for changed conditions that could affect the closure conditions. The long-term closure monitoring program will be planned and implemented as part of the Closure Report stage after activities specified in the CADD/CAP are complete. Groundwater at the NNSS has been monitored for decades through a variety of programs. Current activities were recently consolidated in an NNSS Integrated Sampling Plan (DOE, 2014). Although monitoring directed by the plan is not intended to meet the FFACO long-term monitoring requirements for a CAU (which will be defined in the Closure Report), the objective to ensure public health protection is similar. It is expected that data collected in accordance with the plan will support the transition to long-term monitoring at each CAU. The sampling plan is designed to ensure that monitoring activities occur in compliance with the UGTA Quality Assurance Plan (DOE, 2012). The sampling plan should be referenced for Quality Assurance (QA) elements and procedures governing sampling activities. The NNSS Integrated Sampling Plan specifies the groundwater monitoring that will occur in CAU 98 until the long-term monitoring program is approved in the Closure Report. The plan specifies the wells that must be monitored and categorizes them by their sampling objective with the associated analytical requirements and frequency. Possible sample collection methods and required standard operating procedures are also presented. The intent of this handbook is to augment the NNSS Integrated Sampling Plan by providing well-specific details for the sampling professional implementing the Sampling Plan in CAU 98, Frenchman Flat. This handbook includes each CAU 98 well designated for sampling in the NNSS Integrated Sampling Plan. The following information is provided in the individual well sections: 1. The purpose of sampling. 2. A physical description of the well. 3. The chemical characteristics of the formation water. 4. Recommended protocols for purging and sampling. The well-specific information has been gathered from numerous historical and current sources cited in each section, but two particularly valuable resources merit special mention. These are the USGS NNSS website (http://nevada.usgs.gov/doe_nv/ntsarea5.cfm) and the UGTA Field Operations website (https://ugta.nv.doe.gov/sites/Field%20Operations/default.aspx). 2 Land surface elevation and measuring point for water level measurements in Frenchman Flat were a focus during CAU investigations (see Appendix B, Attachment 1 in Navarro-Intera, 2014). Both websites listed above provide information on the accepted datum for each well. A summary is found on the home page for the well on the USGS website. Additional information is available through a link in the “Available Data” section to an “MP diagram” with a photo annotated with the datum information. On the UGTA Field Operations well page, the same information is in the “Wellhead Diagram” link. Well RNM-2s does not have an annotated photo at this time. All of the CAU 98 monitoring wells are located within Area 5 of Frenchman Flat, with the exception of ER-11-2 in Area 11 (Figure 1). The wells are clustered in two areas: the northern area (Figure 2) and the central area (Figure 3). Each well is discussed below in geographic order from north to south as follows: ER-11-2, ER-5-3 shallow piezometer, ER-5-3-2, ER-5-5, RNM-1, RNM-2s, and UE-5n.

(1996↗

Accretion disc sizes from continuum reverberation mapping of AGN selected from the ZTF survey

ABSTRACT We present the accretion disc-size estimates for a sample of 19 active galactic nuclei (AGNs) using the optical g-, r-, and i-band light curves obtained from the Zwicky Transient Facility survey. All the AGNs have reliable supermassive black hole (SMBH) mass estimates based on previous reverberation mapping measurements. The multiband light curves are cross-correlated, and the reverberation lag is estimated using the Interpolated Cross-Correlation Function method and the Bayesian method using the javelin code. As expected from the disc-reprocessing arguments, the g − r band lags are shorter than the g − i band lags for this sample. The interband lags for all, but five sources, are larger than the sizes predicted from the standard Shakura Sunyaev (SS) analytical model. We fit the light curves directly using a thin disc model implemented through the javelin code to get the accretion disc sizes. The disc sizes obtained using this model are on an average 3.9 times larger than the prediction based on the SS disc model. We find a weak correlation between the disc sizes and the known physical parameters, namely the luminosity and the SMBH mass. In the near future, a large sample of AGNs covering broader ranges of luminosity and SMBH mass from large photometric surveys would be helpful in a better understanding of the structure and physics of the accretion disc.

Jha, Vivek Kumar (ORCID:0000000232776335)↗

Controllable preparation of flower-like brookite TiO{sub 2} nanostructures via one-step hydrothermal method

Highlights: • Flower-like brookite TiO{sub 2} structures were prepared by hydrothermal method. • PVP not only acted as a dispersant but also stabilized the layered structure. • The resulted brookite TiO{sub 2} showed high photocatalytic activity under UV irradiation. - Abstract: Flower-like brookite TiO{sub 2} nanostructures were controllable prepared by a one-step hydrothermal method by changing experimental conditions, such as hydrothermal temperature, reaction time and the amount of polyvinylpyrrolidone. The photocatalytic activities of the samples were investigated by degradation of methylene blue (MB) in aqueous solution under UV light irradiation. It was found that the formation of brookite TiO{sub 2} nanostructures with various morphologies could be well controlled by the adjustment of hydrothermal temperature, reaction time and the amount of surfactant, and the morphology of the products changed from spindle-like structures to flower-like structures with the increase of hydrothermal temperature, reaction time and the amount of surfactant. The photocatalytic tests indicate that the flower-like brookite TiO{sub 2} nanostructures shows high photocatalytic activity in degradation of methylene blue (MB) under UV light irradiation. The formation mechanism of flower-like brookite TiO{sub 2} nanostructures was also discussed in detail based on the above investigations.

36 MATERIALS SCIENCE↗

Extending ROSAT Light Curves of Ecliptic Pole AGN Formation and Galaxy Evolution

In collaboration with UCLA graduate student Fred Baganoff, Professor Malkan has obtained the longest continuous light curves ever available for a large sample (# = 60) of active galactic nuclei. This was accomplished by using the ROSATAII-Sky Survey, which covered the ecliptic pole regions once every 9O-minute orbit. Using this Astrophysics Data Processing grant from NASA, we extended these light curves by combining the RASS data with pointed observations over the next several years of operation of the ROSAT PSPC. This lengthens the baselines of about half of the light curves from a few months up to a few years. The proportion of AGN showing variability increases substantially with this improvement. In fact most AGN in this representative sample are now shown to be significantly variable in the X-rays. We are also able to say something about the amplitudes of variability on timescales from days to years, with more detail than previously has been possible. We have also identified some dependence of the X-ray variability properties on a) the luminosity of the AGN; and b) The presence of a "Blazar" nucleus. By extending the ROSAT light curves, we are also able to learn more about the correlation of X-ray and optical emission on longer time-scales. It appears to be very weak, at best.

Malkan, Matthew A.↗

Radiation Quality Effects on Transcriptome Profiles in 3-d Cultures After Particle Irradiation

In this work, we evaluate the differential effects of low- and high-LET radiation on 3-D organotypic cultures in order to investigate radiation quality impacts on gene expression and cellular responses. Reducing uncertainties in current risk models requires new knowledge on the fundamental differences in biological responses (the so-called radiation quality effects) triggered by heavy ion particle radiation versus low-LET radiation associated with Earth-based exposures. We are utilizing novel 3-D organotypic human tissue models that provide a format for study of human cells within a realistic tissue framework, thereby bridging the gap between 2-D monolayer culture and animal models for risk extrapolation to humans. To identify biological pathway signatures unique to heavy ion particle exposure, functional gene set enrichment analysis (GSEA) was used with whole transcriptome profiling. GSEA has been used extensively as a method to garner biological information in a variety of model systems but has not been commonly used to analyze radiation effects. It is a powerful approach for assessing the functional significance of radiation quality-dependent changes from datasets where the changes are subtle but broad, and where single gene based analysis using rankings of fold-change may not reveal important biological information. We identified 45 statistically significant gene sets at 0.05 q-value cutoff, including 14 gene sets common to gamma and titanium irradiation, 19 gene sets specific to gamma irradiation, and 12 titanium-specific gene sets. Common gene sets largely align with DNA damage, cell cycle, early immune response, and inflammatory cytokine pathway activation. The top gene set enriched for the gamma- and titanium-irradiated samples involved KRAS pathway activation and genes activated in TNF-treated cells, respectively. Another difference noted for the high-LET samples was an apparent enrichment in gene sets involved in cycle cycle/mitotic control. It is plausible that the enrichment in these particular pathways results from the complex DNA damage resulting from high-LET exposure where repair processes are not completed during the same time scale as the less complex damage resulting from low-LET radiation.

Patel, Z. S.↗

The SOUX AGN sample: optical/UV/X-ray SEDs and the nature of the disc

We use the SOUX sample of ~700 active galactic nucleus (AGN) to form average optical-ultraviolet (UV)-X-rays spectral energy distributions (SEDs) on a two-dimensional (2D) grid of M BH and L 2500 . We compare these with the predictions of a new AGN SED model, qsosed, which includes prescriptions for both hot and warm Comptonization regions as well as an outer standard disc. This predicts the overall SED fairly well for 7.5 < log(M BH /M ⊙ ) < 9.0 over a wide range in L/L Edd , but at higher masses the outer disc spectra in the model are far too cool to match the data. We create optical-UV composites from the entire Sloan Digital Sky Survey sample and use these to show that the mismatch is due to there being no significant change in spectral shape of the optical-UV continuum across several decades of M BH at constant luminosity. We show for the first time that this cannot be matched by standard disc models with high black hole spin. These apparently fit, but are not self-consistent as they do not include the General Relativistic effects for the emission to reach the observer. At high spin, increased gravitational redshift compensates for almost all of the higher temperature emission from the smaller inner disc radii. The data do not match the predictions made by any current accretion flow model. Either the disc is completely covered by a warm Comptonization layer whose properties change systematically with L/L Edd , or the accretion flow structure is fundamentally different to that of the standard disc models.

79 ASTRONOMY AND ASTROPHYSICS↗

Pt-TiO{sub 2} microspheres with exposed {001} facets for degradation of formaldehyde in air: Formation mechanism and enhanced visible light photocatalytic activity

Highlights: • TiO{sub 2} microspheres with exposed {001} facets were successfully synthesized. • Pt-TiO{sub 2} catalyst combined the properties of Pt nanoparticles and TiO{sub 2} {001} facet. • The catalyst exhibited an enhanced visible-light photocatalytic activity. • The formation mechanism of TiO{sub 2} microspheres with exposed {001} facets was studied. - Abstract: In this study, TiO{sub 2} microspheres with exposed {001} facets were successfully synthesized by a low-temperature hydrothermal method without using any organic solvents as morphology controlling agent. Furthermore, an active Pt-TiO{sub 2} catalyst was prepared by impregnation and deposition-precipitation methods with reduction processes. The photocatalytic activity of the samples was evaluated by degradation of formaldehyde in air under visible light irradiation at room temperature. After modification with Pt, the optical absorption property of the Pt-TiO{sub 2} microspheres was extended to visible light range. More importantly, the Pt-TiO{sub 2} microspheres exhibited excellent photocatalytic performance for formaldehyde degradation under visible light irradiation, being superior to pure TiO{sub 2} microspheres and even Pt-P25. The formation mechanism of the TiO{sub 2} microspheres with exposed {001} facets was studied. Moreover, the proper photocatalytic mechanism was also proposed. This work provided new insight into the improvement of photocatalytic activity by special high-energy facet exposing and noble metal depositing.

36 MATERIALS SCIENCE↗

THE PREVALENCE OF NARROW OPTICAL Fe II EMISSION LINES IN TYPE 1 ACTIVE GALACTIC NUCLEI

From detailed spectral analysis of a large sample of low-redshift active galactic nuclei (AGNs) selected from the Sloan Digital Sky Survey, we demonstrate-statistically for the first time-that narrow optical Fe II emission lines, both permitted and forbidden, are prevalent in type 1 AGNs. Remarkably, these optical lines are completely absent in type 2 AGNs, across a wide luminosity range, from Seyfert 2 galaxies to type 2 quasars. We suggest that the narrow Fe II-emitting gas is confined to a disk-like geometry in the innermost regions of the narrow-line region on physical scales smaller than the obscuring torus.

79 ASTRONOMY AND ASTROPHYSICS↗

Cross sections for proton-induced reactions on Pd isotopes at energies relevant for the {gamma} process

Proton-activation reactions on natural and enriched palladium samples were investigated via the activation technique in the energy range of E{sub p}=2.75-9 MeV, close to the upper end of the respective Gamow window of the {gamma} process. We have determined cross sections for {sup 102}Pd(p, {gamma}){sup 103}Ag, {sup 104}Pd(p, {gamma}){sup 105}Ag, and {sup 105}Pd(p, n){sup 105}Ag, as well as partial cross sections of {sup 104}Pd(p, n){sup 104}Ag{sup g}, {sup 105}Pd(p, {gamma}){sup 106}Ag{sup m}, {sup 106}Pd(p, n){sup 106}Ag{sup m}, and {sup 110}Pd(p, n){sup 110}Ag{sup m} with uncertainties between 3% and 15% for constraining theoretical Hauser-Feshbach rates and for direct use in {gamma}-process calculations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗