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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36

Covariant Quantum Error-Correcting Codes with Metrological Entanglement Advantage

Here, we show that a subset of the basis for the irreducible representations of a tensor-product SU(2) rotation forms a covariant approximate quantum error-correcting code with transversal U(1) logical gates. Generalizing previous work on “thermodynamic codes” to general local spin and different irreducible representations using only properties of the angular momentum algebra, we obtain bounds on the code inaccuracy under generic noise on any known 𝑑 sites, under independent and identically distributed noise, and under heralded 𝑑-local erasures. We demonstrate that this family of codes protects a probe state with quantum Fisher information surpassing the standard quantum limit when the sensing parameter couples to the generator of the U(1) logical gate.

quantum error correction↗

The NASA ACTIVATE Mission

The NASA Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE) conducted 162 joint flights with two aircraft over the northwest Atlantic to study aerosol–cloud interactions (ACIs), which represent the largest uncertainty in estimating total anthropogenic radiative forcing. The combination of a high-flying King Air and low-flying HU-25 Falcon, equipped with remote sensing and in situ instruments, characterized trace gases, aerosol particles, clouds, and meteorological variables with data collected nearly simultaneously below, within, and above marine boundary layer (MBL) clouds. Flights spanning warm and cold seasons across 3 years (2020–22) provided a broad range of conditions associated with aerosol particles, cloud properties (including particle size and phase), and meteorology, ideally suited for robust ACI calculations and assessing how well models simulate a wide range of MBL clouds from stratiform to cumulus. ACTIVATE data suggest that drivers of cloud droplet number concentration N d , including aerosol particles and MBL dynamics, vary between winter and summer months with a stronger potential to convert aerosol particles into cloud droplets in winter. Models of varying complexity not only highlight some skills in simulating winter and summer cloud types but also identify challenges that still need to be addressed such as treatment of turbulence, wet scavenging, and mesoscale organization. Remote sensing advances range from new retrieval methods for N d , cloud phase classification, vertically resolved aerosol and cloud condensation nuclei number concentration, and ocean surface wind speed. This work describes these scientific and technological advances along with efforts in outreach and open data science.

aerosol indirect effect↗

The underappreciated importance of solar radiation in constraining spring phenology of temperate ecosystems in the Northern and Eastern United States

Spring phenology of temperate ecosystems is highly sensitive to climate change, generating various impacts on many important terrestrial surface biophysical processes. Although various prognostic models relying on environmental variables of temperature and photoperiod have been developed for spring phenology, comprehensive ecosystem-scale evaluations over large landscapes and long-time periods remain lacking. Further, environmental variables other than temperature and photoperiod might also importantly constrain spring phenology modelling but remain under-investigation. To address these issues, we leveraged around 20-years datasets of environmental variables (from Daymet and GLDAS products) and the spring phenology metric (i.e., the greenup date) respectively derived from MODIS and PhenoCams across 108 sites in the Northern and Eastern United States. We firstly cross-compared MODIS-derived greenup date with official PhenoCams product with high accuracy (R 2 = 0.70). Then, we evaluated the three prognostic models (i.e., Growing Degree Date (GDD), Sequential (SEQ) and optimality-based (OPT)) with MODIS-derived spring phenology, assessed the model residuals and their associations with soil moisture, rainfall, and solar radiation, and revised the two photoperiod-relevant models (SEQ, OPT) by replacing the daylength variable with solar radiation, which was found to contribute the most to model residuals. We found that 1) all models demonstrated good capability in characterizing spring phenology, with OPT performing the best (RMSE = 8.04 ± 5.05 days), followed by SEQ (RMSE = 10.57 ± 7.77 days) and GDD (RMSE = 10.84 ± 8.42 days), 2) all models displayed high model residuals showing tight correlation with solar radiation (r = 0.45–0.75), and 3) the revised models that included solar radiation significantly performed better with an RMSE reduction by 22.08%. Such results are likely because solar radiation better constrains early growing season plant photosynthesis than photoperiod, supporting the hypothesis of spring phenology as an adaptive strategy to maximize photosynthetic carbon gain (approximated by solar radiation) while minimizing frost damage risk (captured by temperature). Collectively, our study here reveals the underappreciated importance of solar radiation in constraining spring phenology of temperate ecosystems, and suggests ways to improve spring phenology modelling and other phenology-related ecological processes.

54 ENVIRONMENTAL SCIENCES↗

A biomimetic eye with a hemispherical perovskite nanowire array retina

Human eyes possess exceptional image-sensing characteristics such as an extremely wide field of view, high resolution and sensitivity with low aberration1. Biomimetic eyes with such characteristics are highly desirable, especially in robotics and visual prostheses. However, the spherical shape and the retina of the biological eye pose an enormous fabrication challenge for biomimetic devices2,3. In this paper, we present an electrochemical eye with a hemispherical retina made of a high-density array of nanowires mimicking the photoreceptors on a human retina. The device design has a high degree of structural similarity to a human eye with the potential to achieve high imaging resolution when individual nanowires are electrically addressed. Additionally, we demonstrate the image-sensing function of our biomimetic device by reconstructing the optical patterns projected onto the device. This work may lead to biomimetic photosensing devices that could find use in a wide spectrum of technological applications.

42 ENGINEERING↗

Spatiotemporal evolution of emission and absorption signatures in a laser-produced plasma

Here we report spatiotemporal evolution of emission and absorption signatures of Al species in a nanosecond (ns) laser-produced plasma (LPP). The plasmas were generated from an Inconel target, which contained ~0:4 wt. % Al, using 1064 nm, ≈6 ns full width half maximum pulses from an Nd:YAG laser at an Ar cover gas pressure of ≈34 Torr. The temporal distributions of the Al I (394.4 nm) transition were collected from various spatial points within the plasma employing time-of-flight (TOF) emission and laser absorption spectroscopy, and they provide kinetics of the excited state and ground state population of the selected transition. The emission and absorption signatures showed multiple peaks in their temporal profiles, although they appeared at different spatial locations and times after the plasma onset. The absorption temporal profiles showed an early time signature representing shock wave propagation into the ambient gas. We also used emission and absorption spectral features for measuring various physical properties of the plasma. The absorption spectral profiles are utilized for measuring linewidths, column density, and kinetic temperature, while emission spectra were used to measure excitation temperature. A comparison between excitation and kinetic temperature was made at various spatial points in the plasma. Our results highlight that the TOF measurements provide a resourceful tool for showing the spatiotemporal LPP dynamics with higher spatial and temporal resolution than is possible with spectral measurements but are difficult to interpret without additional information on excitation temperatures and linewidths. The combination of absorption and emission TOF and spectral measurements thus provides a more complete picture of LPP spatiotemporal dynamics than is possible using any one technique alone.

(140.3440) Laser-induced breakdown, (280.4788) Opt↗

Technical Characterization and Benefit Evaluation of 5G-Enabled Grid Data Transport and Applications

This report summarizes the Year 1 work of Pacific Northwest National Laboratory’s (PNNL’s) 5G Fabricated Resource and Asset Management Encompassment for energy infrastructure (Energy FRAME) project funded by the Department of Energy Office of Science’s Advanced Scientific Computing Research Program. 5G is a breakthrough technology that enables a fully mobile and connected society, and a 5G-enabled digital continuum will be one of the critical foundations for a clean energy economy and grid modernization. In collaboration with PNNL’s Advanced Wireless Communication team and Center for Advanced Technology Evaluation team, the project team has been evaluating the system performance of 5G testbeds in the PNNL 5G Innovation Studio, and has formulated a co-simulation test case of power system transmission, distribution, and communication (T&D&C) networks considering 5G technology and high penetration of distributed energy resources. The methodology developed in the 5G Energy FRAME project can be customized to fit different future grid scenarios to evaluate multiple (dynamic) configurations (computing, sensing, communication, environment) for different stakeholders. In summary, our main technical highlights in project Year 1 are as follows: 1) Technical characterization of 5G standalone architectures, 2) Formulation of co-simulation test case of T&D&C networks embedded with 5G, 3) Initial benefit evaluation of 5G communication platform for grid use cases, and 4) Additional extended discussions on edge computing, artificial intelligence and machine learning, and high-performance computing and cloud computing adoptions. In addition, a collection of system performance data is shared through the publicly available weblink, https://www.pnnl.gov/projects/5g-energy-frame/publications

24 POWER TRANSMISSION AND DISTRIBUTION↗

Hydraulic fracture characterization by integrating multidisciplinary data from the Hydraulic Fracturing Test Site 2 (HFTS-2)

Various technologies have traditionally been used to monitor and describe hydraulic fractures from different perspectives. This work demonstrates the value of data integration for hydraulic fracture characterization when multiple data resources are available. The Hydraulic Fracturing Test Site 2 (HFTS 2) is a hydraulic fracturing research project in the Delaware Basin with multiple surveillance techniques including fiber optics sensing, microseismic, pressure/temperature gauges, etc. We integrated the multidisciplinary data from the HFTS-2 to characterize hydraulic fractures. The integrated data revealed interesting fracture propagation features including layering, vertical propagation affected by pore pressure gradient, and different microseismic activities due to difference in-situ conditions. Furthermore, these findings can be insightful for understanding hydraulic fracture propagation. The comparison among multiple surveillance data also helps us to evaluate the roles of various surveillance technologies and provides us experience to make informative decisions depending on different monitoring objectives.

58 GEOSCIENCES↗

Making sense of uncertain nuclear data

At its core, and in an imperfect world, the scientific method relies heavily on the concept of uncertain knowledge. Understanding the nature and magnitude of our lack of knowledge on nuclear data has important ramifications on a wide range of nuclear technologies that encompass defense, energy, medicine, astrophysics, among others. Over the span of a long and fruitful carrier, Dr. Massimo Salvatores has made significant contributions to the fields of nuclear reactor physics, nuclear data, and uncertainty quantification and propagation. Advances in machine learning techniques and computational capabilities are enabling a new level of confidence in our ability to predict key nuclear metrics as well as their associated uncertainties across many applications. Here this short article reviews some of those concepts with an eye towards developing a new paradigm to provide nuclear data libraries of benefit to various applications.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Rapid Sensing to Facilitate Purification of Rare Earth Element-Containing Process Streams Produced Through Membrane-Assisted Solvent Extraction

The development of an economically competitive domestic supply of rare earth elements and yttrium (REY) is necessary for our nation’s economic growth and national security. The achievement of a secure domestic supply of REY requires not only the development of effective processes for recovery of REY from naturally occurring materials and/or recycled products, but also the development of downstream processes for the ultimate production of high-REY content solids. An impediment to the development of such processes is the scarcity of analytical methods that provide rapid determination of the process stream compositions. In this work, a membrane-based extraction process was used to selectively recover REYs from a dilute solution in the presence of much higher concentrations of Ca and Al. In tandem, the use of a portable spectrometer equipped with an immobilized zinc adeninate benzene tricarboxylate metal-organic framework sensing material makes possible the rapid detection of the presence of ppm concentrations of Tb and Eu in both weakly acidic and strongly acidic process streams within minutes. A solvent extraction processing time of 15-60 min maximized REY selectivity over gangue ions while achieving up to 80% REY and minimal gangue ion recovery. Taken together, these experiments highlight not only an innovative method for REY purification but also the importance of inexpensive, portable characterization methods for near real-time analysis of REY content.

Membrane-assisted solvent extraction↗

Ultra-Low SWaP CO 2 Sensing for Demand Control Ventilation (Final Report)

In this project PARC and Energy ETC aimed to develop an ultra-low cost, size, weight, and power (SWaP) printed CO 2 sensor system for occupancy detection to enable Demand Control Ventilation (DCV) on a per-room basis. The CO 2 sensor technology is based on the temperature variation when CO 2 reversibly physisorbs to a highly conductive and high surface area sorbent surface, and is compatible with integration with PARC innovations in printed sensors and flexible electronics, for which PARC is a globally leading research center. The printed CO 2 sensor itself is designed to be compatible with PARC’s “peel-and-stick” platform of ultra-low power, low-cost, distributed sensors, and to facilitate real-time DCV based on overall indoor air quality (IAQ). Previously, PARC has developed flexible hybrid electronics (FHE) compatible materials to measure humidity, temperature, light, strain, and gases such as carbon monoxide, methane, ammonia, and hydrogen sulfide. Through this project, PARC developed FHE-compatible materials to measure CO 2 . Thus, with one <$15 FHE “peel-and-stick” based sensor node, a building management system (BMS) will be able to capture a complete picture of the indoor environment. This includes IAQ, light, temperature, and other comfort factors that impact building operations. Combined with optimized DCV, this low-cost sensor capability can be a key enabler of annual primary energy savings of ~ 0.3-0.4 Quad in commercial buildings while ensuring healthy IAQ. Energy ETC is a leader in supplier-agnostic BMS deployments and will design the commissioning and deployment procedures to maximize system interoperability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Superconducting quasiparticle-amplifying transmon: A qubit-based sensor for meV-scale phonons and single terahertz photons

With great interest from the quantum computing community, an immense amount of R&D effort has been invested into improving superconducting qubits. The technologies developed for the design and fabrication of these qubits can be directly applied to applications for ultralow-threshold particle detectors, e.g., low-mass dark matter and far-infrared photon sensing. We propose a novel energy-resolving sensor based on the transmon qubit architecture combined with a signal-enhancing superconducting quasiparticle amplification stage. We refer to these sensors as SQUATs: superconducting quasiparticle-amplifying transmons. We detail the operating principle and design of this new sensor and predict that, with minimal R&D effort, solid-state-based detectors patterned with these sensors can achieve sensitivity to single terahertz photons, and sensitivity to 1 meV phonons in the detector absorber substrate on the microsecond timescale. Published by the American Physical Society 2024

47 OTHER INSTRUMENTATION↗

Robust Optical Sensor Technology for Real-Time Monitoring of Solid Oxide Fuel Cells with High Spatial Resolutions

This SOFC core technology development program will develop an integrated fiber optical sensor technology to perform real-time and high-resolution measurements in both planar and tubular fuel cells and fuel cell assembly to monitor operations and structural changes of SOFCs. The new fiber sensing solution can monitor hundreds of points in the 3D fuel cell structures with 5-mm spatial resolutions using one single optical fiber.

30 DIRECT ENERGY CONVERSION↗

All-aerosol-jet-printed highly sensitive and selective polyaniline-based ammonia sensors: a route toward low-cost, low-power gas detection

In this work, we report the design and scalable fabrication of a low-cost and low-power polyaniline-based (PANI) ammonia (NH3) gas sensor on polyimide (PI) substrates using additive manufacturing techniques. The silver interdigitated electrode (IDE) arrays and conducting polymer films are printed onto PI using a direct-write technology of aerosol-jet printing. Morphological characteristics are examined by scanning electron microscopy and energy-dispersive X-ray analysis which reveal homogeneously printed PANI film on the IDE platform. The gas sensing performance is evaluated in the analytical early leak detection range of 5–1000 ppm NH3 in air as a function of both thermal (23 °C, 50 °C, 80 °C) and relative humidity (RH = 0%, 30%, 50%) exposures. The sensor exhibits sensitivity down to 5 ppm NH3 with a sub-ppm detection limit and good repeatability. We observe rapid NH3 detection at 0% RH with very extended times for equilibration and recovery. However, at both 30 and 50% RH, the room temperature response and recovery times are reduced to only about 1 min and 5 min, respectively. Experiments also reveal good sensitivity toward the analyte even at higher operating temperatures. Present results merit the practical application of aerosol-jet-printed, low-power sensors for industrial applications where low-level hazardous gas detection is essential.

36 MATERIALS SCIENCE↗

Nickel(II) Metal Complexes as Optically Addressable Qubit Candidates

The inherent atomic level structural control of synthetic chemistry enables the creation of qubits, the base units of a quantum information science system, designed for a target application. For quantum sensing applications, enabling optical read-out of spin in tunable molecular systems, akin to defect-based systems, would be transformative. This approach would bring together molecular tunability with optical read-out technology. In theory, nickel ions in octahedral symmetry meet all the criteria for optical readout of spin. Yet, to the best of our knowledge, there are no pulse EPR studies on Ni 2+ molecules. We identified two compounds featuring highly symmetric Ni 2+ centers, thereby engendering weak zero-field splitting to enable EPR addressability:[Ni(phen) 3 ](BF 4 ) 2 (1) and [Ni(pyr 3 ) 2 ](BF 4 ) 2 (2) (phen = 1,10-phenanthroline; pyr 3 = tris-2-pyridyl-methane). Crucially, these complexes feature the requisite strong field ligands to enable emission for optical addressability. We extracted axial zero-field splitting parameters of D = +0.9 cm –1 and +2.7 cm –1 for 1 and 2, respectively, enabling pulse EPR measurements. Both compounds produce emission at λ max = 938–944 nm. Furthermore, the aggregate of these results expands the catalogue of qubit materials to Ni 2+ -based compounds and offers a future pathway for optical readout of these molecules.

36 MATERIALS SCIENCE↗

Sensing Electrical Networks Securely & Economically (SENSE)

The growing adoption of distributed energy resources (DERs) like battery energy storage systems and roof top solar/PV and the rapid penetration of electric vehicles (EVs), the electric grid is undergoing a major transformation with elevated stress on legacy grid assets. Despite a lot of expenditure to address these challenges, both in dollars and manpower, utilities have not been able to receive the value that was promised. The gains have been most visible at the transmission and substation level, especially where the main objective was improving operational and economic efficiency for the utility. Improving visibility and control at a few select points enhances the existing and established paradigm of centralized command and control. With changing load patterns, load types and the overall transition to an “active grid”, the centralized control and coordination paradigm gets challenged. To address the challenges, a new architecture and mechanism is needed, one that supports decentralized control and decision making, extracting value streams at the grid edge, particularly as the changes are fueled by transitions occurring in the distribution system. To address this, a communications and data processing platform, “GAMMA” was developed and demonstrated through the project. At the heart of the platform, are distributed, intelligent edge nodes with sensing and compute capabilities, that can record and analyze information locally. They are embedded in sensors and actuators specific to different distribution system applications. Phase 1 of the project focused on developing novel sensor technology that can be used for monitoring utility pole top distribution transformers. The sensors were designed with the objective of being low-cost, communicating with the GAMMA cloud using novel “delay-tolerant” networking using Bluetooth and a secure mobile application. They were non-intrusive in nature so that they can be installed quickly in the field, resulting in overall low cost of deployment and operations. Following the successful completion of Phase 1, the team manufactured 100 units for a field demonstration in Phase 2. The field demonstration was carried out on two real feeder systems with the local utility partner. In total, 100 sensors were installed and operated over a period of 6 months in the state of Georgia. The platform is operational end to end, with the cloud infrastructure deployed on a distributed, serverless environment that can serve multiple data streams, an analytics engine and a portal to securely view the data from multiple assets. The data collected through the GAMMA Mobile Phone app showcased the viability of the novel delay tolerant networking architecture, and the data processing algorithms developed through the course of the project, were successful in extracting important information about the overall network, improving the utility’s visibility and situational awareness in the distribution feeder.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Perception Testing in Fog for Autonomous Flight

As the path towards Urban Air Mobility (UAM) continues to take shape, there are outstanding technical challenges to achieving safe and effective air transportation operations under this new paradigm. To inform and guide technology development for UAM, NASA is investigating the current state-of-the-art in key technology areas including traffic management, detect-and-avoid, and autonomy. In support of this effort, a new perception testbed was developed at NASA Ames Research Center to collect data from an array of sensing systems representative of those that could be found on a future UAM vehicle. This testbed, featuring a Light-Detection-and-Ranging (LIDAR) instrument, a long-wave infrared sensor, and a visible spectrum camera was deployed for a multiday test campaign in the Fog Chamber at Sandia National Laboratories (SNL), in Albuquerque, New Mexico. During the test campaign, fog conditions were created for tests with targets including a human, a resolution chart, and a small unmanned aerial vehicle (sUAV). Here, this paper describes in detail, the developed perception testbed, the experimental setup in the fog chamber, the resulting data, and presents an initial result from analysis of the data with the evaluation of methods to increase contrast through filtering techniques.

aeronautics↗