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Topics discussed include: Cosmochemical fractionations, Chondritic meteorites and their components, Jet flows: Formation and thermal processing of solids in protoplanetary disks, A Search for Solar-System processing signatures in presolar grains, Experimental study of iron metal condensation, The chondrite types and their origins, Spinel-rich spherules from murchison, etc.
Understanding fluid behavior in microgravity environments is essential to further development of cryogenic storage in space environments. The Zero Boil Off Tank (ZBOT) experiment was designed to investigate two-phase pressurization and depressurization of a tank in a microgravity environment. The test fluid was the refrigerant Perfluoro-normal-Pentane (PNP). Thermal modeling for the ZBOT model was conducted using Thermal Desktop and SINDA/FLUINT. The temperature distribution within the fluid of the tank is of particular interest. This particular work is centered on ascertaining the thermal behavior of the refrigerant in order to build more complete models of fluid in microgravity. Separate cases were run modeling experiments that were conducted both on the ground and on the International Space Station (ISS) to compare 1g and microgravity environments. The microgravity modeling cases consisted of a fluid lump representing the vapor ullage suspended in a solid to represent the liquid. Mass flow between the liquid and vapor was modeled using the Schrage equation for mass flow. Initial results indicate that the pressure rise and temperature increase within the fluid closely align with the experimental data by matching initial conditions of the experiment. This work is ongoing and will yield further insights into the thermal behavior of fluid mixing in microgravity.
A finite volume-based network flow modeling tool, Generalized Fluid System Simulation Program (GFSSP), was used to simulate the no-vent filling of a cryogenic tank with a thermodynamic vent system assisted injector. The tank was discretized into nodes in the radial and axial directions to calculate two-dimensional axisymmetric flow with heat transfer between the solid wall and fluid. The nodes are connected by branches where momentum equations are solved to calculate the flowrates. The mass and energy conservation equations and the equation of state are solved to calculate pressure, temperature, and resident mass at the nodes. The energy conservation equations at the solid nodes were solved to calculate the temperature of the solid wall. The system of equations was solved by a combination of successive substitution and simultaneous Newton-Raphson method. The numerical model accounts for a) different regimes of pool boiling heat transfer, b) condensation of vapor around the spray droplets, c) condensation of vapor at the interface of the cooled injector and ullage, and d) condensation at the liquid-vapor interphase. The numerical predictions of tank pressure, filling rate, and wall temperatures were compared with the test data. The paper also presents the effect of nodal discretization by comparing the results of the 1D and 2D models and examines the effect of the droplet diameter on tank filling.
A finite volume-based network flow modeling tool, Generalized Fluid System Simulation Program (GFSSP), was used to simulate the no-vent filling of a cryogenic tank with a thermodynamic vent system assisted injector. The tank was discretized into nodes in the radial and axial directions to calculate two-dimensional axisymmetric flow with heat transfer between the solid wall and fluid. The nodes are connected by branches where momentum equations are solved to calculate the flowrates. The mass and energy conservation equations and the equation of state are solved to calculate pressure, temperature, and resident mass at the nodes. The energy conservation equations at the solid nodes were solved to calculate the temperature of the solid wall. The system of equations was solved by a combination of successive substitution and simultaneous Newton-Raphson method. The numerical model accounts for a) different regimes of pool boiling heat transfer, b) condensation of vapor around the spray droplets, c) condensation of vapor at the interface of the cooled injector and ullage, and d) condensation at the liquid-vapor interphase. The numerical predictions of tank pressure, filling rate, and wall temperatures were compared with the test data. The paper also presents the effect of nodal discretization by comparing the results of the 1D and 2D models and examines the effect of the droplet diameter on tank filling.
An Integrated Refrigeration and Storage (IRAS) experimental system called the Ground Operations and Demonstration Unit for Liquid Hydrogen (GODU-LH2) demonstrated the ability store cryogens in a zero boiloff (ZBO) process, and to densify liquid hydrogen by reducing the temperature and pressure down to the triple point resulting in solidification. The incompressible Navier-Stokes was utilized to simulate ZBO, densification, and solidification of liquid hydrogen (LH2) in the IRAS tank. The simulations were performed using a commercially available Computational Fluid Dynamics (CFD) pressure-based mass and momentum flow model and an enthalpy-porosity energy model. Results demonstrated the simulation’s ability to predict time-dependent flow and temperature fields and solid-liquid phase locations for hydrogen during ZBO, densification, and solidification. The simulations showed good agreement with experimental data, with errors within acceptable ranges for temperature and pressure predictions, provided detailed insights into natural convection and solid-liquid phase change dynamics. These findings are critical for the design of future cryogenic fluid management systems.
A heat transport analysis which considers forced convective fluid flow induced by the motion of a continuous solid ribbon over a melt has been done for horizontal ribbon growth. A model has been developed which treats both 'active' and 'passive' cooling at the ribbon surface. The results show that heat flow from the melt requires active cooling in the region of the leading growth edge or growth tip. Steady-state liquid-solid interface shape is analyzed and numerical results are given for steady-state pulling of silicon ribbon.
Nanofluid electrodes with high loading of active solid materials have significant potential as high energy density flow battery electrolytes; however, two key criteria need to be met: they must have a manageable viscosity for pumping and simultaneously exhibit good electrochemical activity. A typical dispersion of nickel hydroxide nanoparticles (~100 nm) is limited to 5–10 wt.% of solids, above which it has a paste-like consistency, incompatible with flow applications. We report on the successful formulation of stable dispersions of a nano-scale nickel hydroxide cathode (β-Ni(OH) 2 ) with up to 60 wt.% of solids and low viscosity (32 cP at 25 °C), utilizing a surface graft of small organic molecules. The fraction of grafting moiety is less than 3 wt.% of the nanoparticle weight, and its presence is crucial for the colloidal stability and low viscosity of suspensions. Electrochemical testing of the pristine and modified β-Ni(OH) 2 nanoparticles in the form of solid casted electrodes were found to be comparable with the latter exhibiting a maximum discharge capacity of ~237 mAh/g over 50 consecutive charge–discharge cycles, close to the theoretical capacity of 289 mAh/g.
The feasibility of using the Rayleigh scattering technique for molecular density imaging of the free-stream flow field in the Langley 0.3-Meter Transonic Cryogenic Tunnel has been experimentally demonstrated. The Rayleigh scattering was viewed with a near-backward geometry with a frequency-doubled output from a diode-pumped CW Nd:YAG laser and an intensified charge-coupled device camera. Measurements performed in the range of free-stream densities from 3 x 10(exp 25) to 24 x 10(exp 25) molecules/cu m indicate that the observed relative Rayleigh signal levels are approximately linear with flow field density. The absolute signal levels agree (within approx. 30 percent) with the expected signal levels computed based on the well-known quantities of flow field density, Rayleigh scattering cross section for N2, solid angle of collection, transmission of the optics, and the independently calibrated camera sensitivity. These results show that the flow field in this facility is primarily molecular (i.e., not contaminated by clusters) and that Rayleigh scattering is a viable technique for quantitative nonintrusive diagnostics in this facility.
Techniques yielding simultaneous, multiple point measurements of velocity in reacting or nonreacting flow fields have the potential to significantly impact basic and applied studies of fluid mechanics. Several candidate schemes which could provide such measurement capability were investigated. The concepts utilize laser sources which lead to scattered light which can be monitored by a film based camera or a multielement solid state camera. Velocity measurements in supersonic flows using a novel Doppler modulated fluorescence concept are presented.
Materials with tunable thermal properties enable on-demand control of temperature and heat flow, which is an integral component in the development of solid-state refrigeration, energy scavenging, and thermal circuits. Although gap-based and liquid-based thermal switches that work on the basis of mechanical movements have been an effective approach to control the flow of heat in the devices, their complex mechanisms impose considerable costs in latency, expense, and power consumption. As a consequence, materials that have multiple solid-state phases with distinct thermal properties are appealing for thermal management due to their simplicity, fast switching, and compactness. Thus, an ideal thermal switch should operate near or above room temperature, have a simple trigger mechanism, and offer a quick and large on/off switching ratio. In this study, we experimentally demonstrate that manipulating phonon scattering rates can switch the thermal conductivity of antiferroelectric PbZrO 3 bidirectionally by –10% and +25% upon applying electrical and thermal excitation, respectively. Our approach takes advantage of two separate phase transformations in PbZrO 3 that alter the phonon scattering rate in different manners. In this study, we demonstrate that PbZrO 3 can serve as a fast (<1 second), repeatable, simple trigger, and reliable thermal switch with a net switching ratio of nearly 38% from ~1.20 to ~1.65 W m –1 K –1 .
Policies embracing circular economy concepts have taken hold in national legislation around the world. As the number of governments and organizations adopting circular economy policies increases, so does the need for accurate and timely measurement of material resource flows. Since many countries do not have access to centrally reported municipal solid waste (MSW) data, estimation and modeling are critical in evaluating circular economy policy effectiveness. The purpose of this paper is to examine three modeling approaches estimating national MSW data in the United States, including industry-based material flow analysis, waste-extended input-output modeling, and aggregated regional waste reporting. We establish five criteria to guide the analysis through the context of policy monitoring (data quality, flow totality, update frequency, sensitivity to disruption, and product granularity) and use these criteria to analyze and score each model. We then use a literature search to identify five, internationally-implemented options for circular economy policy and determine the data and modeling components that are most helpful in evaluating policy effectiveness. Finally, we provide a crosswalk of the model scores and policy needs to inform the suitability of model selection by policy type. We found that data quality and update frequency are identified as critical components for evaluating circular economy policies within the models evaluated, and can both be fulfilled by aggregated regional waste reporting. Flow totality, sensitivity to disruption, and product granularity requirements vary by both model and policy types. While none of the evaluated models satisfy the combination of requirements for any of the five policies, industry-based material flow analysis offers flow totality for extended producer responsibility, landfill bans, and recycling rate target policies that typically require it. Here, the waste-extended input-output model can provide disruption sensitivity and product granularity as needed for policies like minimum recycled content and market restrictions. Policy developers in areas where strong centralized data collection is not an option should design policy action(s) with modeling tradeoffs in mind, including the potential hybridization of modeling approaches that may provide the most accurate national MSW estimates.
Am implicit/explicit procedure for the solution of problems of two-dimensional steady compressible viscous high-speed flows is presented. In the vicinity of solid walls, a grid which need only exhibit structure in the normal direction is employed while, away from this region, the grid is totally unstructured. The implicit form of the algorithm is used near solid walls, with the grid structure being utilized in an equation solution approach, based upon line relaxation. The explicit form of the algorithm is used elsewhere. Grid adaptation is achieved by means of adaptive remeshing. To illustrate the performance of the proposed method, problems of shock-boundary layer interaction and flow over a simulated forebody at high Mach number are included.
Fluid-flow restrictor has degree of restriction easily and accurately controlled during manufacture. Restrictor's flow channel is machined square thread around a solid slug which is shrink-fitted to cylindrical case. One end of case is closed, open end capped, and both ends tapped for tube fittings for fluid flow.
In response to the budget environment and to expand on the International Space Station (ISS) Fluids and Combustion Facility (FCF) Combustion Integrated Rack (CIR), common hardware approach, the NASA Combustion Science Program shifted focus in 1999 from single investigator PI (Principal Investigator)-specific hardware to multi-user 'Minifacilities'. These mini-facilities would take the CIR common hardware philosophy to the next level. The approach that was developed re-arranged all the investigations in the program into sub-fields of research. Then common requirements within these subfields were used to develop a common system that would then be complemented by a few PI-specific components. The sub-fields of research selected were droplet combustion, solids and fire safety, and gaseous fuels. From these research areas three mini-facilities have sprung: the Multi-user Droplet Combustion Apparatus (MDCA) for droplet research, Flow Enclosure for Novel Investigations in Combustion of Solids (FEANICS) for solids and fire safety, and the Multi-user Gaseous Fuels Apparatus (MGFA) for gaseous fuels. These mini-facilities will develop common Chamber Insert Assemblies (CIA) and diagnostics for the respective investigators complementing the capability provided by CIR. Presently there are four investigators for MDCA, six for FEANICS, and four for MGFA. The goal of these multi-user facilities is to drive the cost per PI down after the initial development investment is made. Each of these mini-facilities will become a fixture of future Combustion Science NASA Research Announcements (NRAs), enabling investigators to propose against an existing capability. Additionally, an investigation is provided the opportunity to enhance the existing capability to bridge the gap between the capability and their specific science requirements. This multi-user development approach will enable the Combustion Science Program to drive cost per investigation down while drastically reducing the time required to go from selection to space flight.
A novel freeze desalination technology is presented for purification of water produced from various industrial processes, including oil and gas extraction. The main innovative idea is introducing a water-immiscible intermediate-cold-liquid (ICL) medium which absorbs the cold from a refrigeration cycle and transfers it to a freezing chamber where it is mixed with brine. The cold ICL enters the freezing chamber at temperatures between -10°C to -30°C. Precooled brine in injected into the freezing chamber and pure water freezes out of the brine upon mixing with the ICL. The rate of freezing inside the chamber is controlled by adjusting the flow rate of the cold ICL relative to the inlet brine. Both eutectic freeze and non-eutectic freezing are possible by controlling the temperature of the freezing chamber. The solid-liquid slurry created in the freezing chamber flows to a filter separation unit after passing through a separation column. The ice crystals are separated from the liquid by a rotary filter device. The collected ice is rinsed by a centrifugal unit. The rinsed ice is melted to produce fresh water. The developed technology resolves the issues common to current freeze-desalination systems while offering superior heat transfer performance ascribed to direct-contact between the cooling medium and the brine in addition to producing solid salt and pure water. The system operates under atmospheric pressure. The low operation temperature minimizes the corrosion issues common in systems exposed to brine. Also, due to the low operating temperature, there are no concerns about evaporation of volatile organics from the produced water during the treatment. The developed technology effectively eliminates the use of chemicals for pretreatment of brine. The system can be constructed from commercially available components. Extensive testing using a lab-scale prototype by using synthetic brine and actual produced water with TDS values from 50,000 ppm to 300,000 ppm showed that freshwater could be achieved with relatively small dependency on the quality of the input brine. The quality of the treated water was found to be mainly a function of the duration of the centrifugal process. Treated water with TDS as low as 200 ppm could be achieved in the tests. Thermo-economic modeling coupled with system level thermochemical process model were developed for prediction of the LCOW. The LCOW was predicted to be $\$$0.50 to $\$$0.90 per barrel of produced water. The potential markets for deployment of the technology are the oil and gas, in-land thermoelectric powerplants, RO desalination plants, and mining industry.
Friction Stir Welding (FSW) is a solid state welding process that exhibits characteristics similar to traditional metal cutting processes. The plastic deformation that occurs during friction stir welding is due to the superposition of three flow fields: a primary rotation of a radially symmetric solid plug of metal surrounding the pin tool, a secondary uniform translation, and a tertiary ring vortex flow (smoke rings) surrounding the tool. If the metal sticks to the tool, the plug surface extends down into the metal from the outer edge of the tool shoulder, decreases in diameter like a funnel, and closes up beneath the pin. Since its invention, ten years have gone by and still very little is known about the physics of the friction stir welding process. In this experiment, an H13 steel weld tool (shoulder diameter, 0.797 in; pin diameter, 0.312 in; and pin length, 0.2506 in) was used to weld three 0.255 in thick plates. The deformation behavior during friction stir welding was investigated by metallographically preparing a plan view sections of the weldment and taking Vickers hardness test in the key-hole region.
A tip section of a delta wing having an NACA 0004-65 airfoil section and a 600 leading-edge sweepback was equipped with a porous leading-edge section through which hot gas was 'bled for anti-icing. Heating rates for anti-icing were determined for a wide range of icing conditions. The effects of gas flow through the porous leading-edge section on airfoil pressure distribution and drag in dry air were investigated. The drag increase caused by an ice formation on the unheated airfoil was measured for several icing conditions. Experimental porous surface- to free-stream convective heat-transfer coefficients were obtained in dry air and compared with theory. Adequate icing protection was obtained at all icing conditions investigated. Savings in total gas-flow rate up to 42 percent may be obtained with no loss in anti-icing effectiveness by sealing half the upper-surface porous area. Gas flow through the leading-edge section had no appreciable effect on airfoil pressure distribution. The airfoil section drag increased slightly (5-percent average) with gas flow through the porous surface. A heavy glaze-ice formation produced after 10 minutes of icing caused an increase in section drag coefficient of 240 percent. Experimental convective heat-transfer coefficients obtained with hot-gas flow through the porous area in dry air and turbulent flow were 20 to 30 percent lower than the theoretical values for a solid surface under similar conditions. The transition region from laminar to turbulent flow moved forward as the ratio of gas velocity through the porous surface to air-stream velocity was increased.
The application of hypersonic flow simulation tools to realistic flight scenarios will require the coupling of multiple physical effects to the baseline fluid dynamics. Such multiphysics effects can include the aerooelastic response of the airframe or engine components, dynamic transport of atmospheric particles, the deformation of solid-fluid interfaces that can ablate, pyrolyze, or erode, as well as a host of other processes, all of which are governed by unique sets of physical equations and models. Coupling multiple (and potentially disparate) physics solvers to a robust compressible flow solver poses additional challenges related to the stability, performance and scalability of the combined solver. The choices made during the software design process can therefore lead to a variation in simulation efficiency across different computer architectures. In this paper, we will consider two representative multiphysics hypersonic flow scenarios: the interaction of solid particulates with the flow field created by a hypersonic lifting body and the aerooelastic deformation of a model airframe under high-Mach-number flow conditions. For these simulations we explore the behavior of several hypersonic simulation tools, including Kestrel, FUN3D, US3D, and JENRE multiphysics framework, on several high performance computing systems containing various CPU and GPU architectures.