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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Cooling and deformation of sulfur flows

A simple one-dimensional cooling analysis is used to consider the cooling of a flow of pure sulfur on the Ionian surface by a combination of upward radiation and downward conduction, and some speculations on the nature of surface structures and optical properties for such a flow are made. It is concluded that surface folding caused by compressive stresses, crustal foundering due to tensile fracturing and density inversions, and local turbulence may result in regularly spaced surface ridges periodically interrupted by upwellings of liquid sulfur onto the frozen surface of the flow. The model suggests that although the color of the surface crust of a quickly quenched sulfur flow will not necessarily reflect the local internal temperature of the flow, diapiric upwellings and convection from beneath this crust should indicate the progressive cooling of the inner, more fluid zones of the flow.

Fink, J. H.↗
NASA NTRS1992

Deployable reflector antenna performance optimization using automated surface correction and array-feed compensation

Methods for increasing the electromagnetic (EM) performance of reflectors with rough surfaces were tested and evaluated. First, one quadrant of the 15-meter hoop-column antenna was retrofitted with computer-driven and controlled motors to allow automated adjustment of the reflector surface. The surface errors, measured with metric photogrammetry, were used in a previously verified computer code to calculate control motor adjustments. With this system, a rough antenna surface (rms of approximately 0.180 inch) was corrected in two iterations to approximately the structural surface smoothness limit of 0.060 inch rms. The antenna pattern and gain improved significantly as a result of these surface adjustments. The EM performance was evaluated with a computer program for distorted reflector antennas which had been previously verified with experimental data. Next, the effects of the surface distortions were compensated for in computer simulations by superimposing excitation from an array feed to maximize antenna performance relative to an undistorted reflector. Results showed that a 61-element array could produce EM performance improvements equal to surface adjustments. When both mechanical surface adjustment and feed compensation techniques were applied, the equivalent operating frequency increased from approximately 6 to 18 GHz.

Schroeder, Lyle C.↗
DOE OSTI2017

Anodes for Lithium-Ion Batteries Based on Type I Silicon Clathrate Ba 8 Al 16 Si 30 - Role of Processing on Surface Properties and Electrochemical Behavior

Type I silicon clathrates based on Ba 8 Al y Si 46- y (8 < y < 12) have been studied as potential anodes for lithium-ion batteries and display electrochemical properties that are distinct from those found in conventional silicon anodes. Processing steps such as ball-milling (typically used to reduce the particle size) and acid/base treatment (used to remove nonclathrate impurities) may modify the clathrate surface structure or introduce defects, which could affect the observed electrochemical properties. Here, we perform a systematic investigation of Ba 8 Al y Si 46- y clathrates with y ≈ 16, i.e, having a composition near Ba 8 Al 16 Si 30 , which perfectly satisfies the Zintl condition. The roles of ball-milling and acid/base treatment were investigated using electrochemical, X-ray diffraction, electron microscopy, X-ray photoelectron and Raman spectroscopy analysis. The results showed that acid/base treatment removed impurities from the synthesis, but also led to formation of a surface oxide layer that inhibited lithiation. Ball-milling could remove the surface oxide and result in the formation of an amorphous surface layer, with the observed charge storage capacity correlated with the thickness of this amorphous layer. According to the XRD and electrochemical analysis, all lithiation/delithiation processes are proposed to occur in single phase reactions at the surface with no discernible changes to the crystal structure in the bulk. Electrochemical impedance spectroscopy results suggest that the mechanism of lithiation is through surface-dominated, Faradaic processes. Lastly, this suggests that for off-stoichiometric clathrates, as we studied in our previous work, Li + insertion at defects or vacancies on the framework may be the origin of reversible Li cycling. However, for clathrates Ba 8 Al y Si 46- y with y ≈ 16, Li insertion in the structure is unfavorable and low capacities are observed unless amorphous surface layers are introduced by ball-milling.

25 ENERGY STORAGE↗
NASA NTRS1977

Experimental observations of the chemistry of the SiO2/Si interface

Changes in silicon surface preparation prior to thermal oxidation are shown to leave a signature by altering the final SiO2/Si interface structure. Surface analytical techniques, including XPS, static SIMS, ion milling, and newly developed wet-chemical profiling procedures are used to obtain detailed information on the chemical structure of the interface. The oxides are shown to be essentially SiO2 down to a narrow transitional interface layer (3-7 A). A number of discrete chemical species are observed in this interface layer, including different silicon bonds (e.g., C-, OH-, H-) and a range of oxidation states of silicon (0 to +4). The effect of surface preparation and the observed chemical species are correlated with oxide growth rate, surface-state density, and flatband shifts after irradiation.

Grunthaner, F. J.↗
DOE OSTI2015

Surface faceting and elemental diffusion behaviour at atomic scale for alloy nanoparticles during in situ annealing

The catalytic performance of nanoparticles is primarily determined by the precise nature of the surface and near-surface atomic configurations, which can be tailored by post-synthesis annealing effectively and straightforwardly. Understanding the complete dynamic response of surface structure and chemistry to thermal treatments at the atomic scale is imperative for the rational design of catalyst nanoparticles. Here, by tracking the same individual Pt 3 Co nanoparticles during in situ annealing in a scanning transmission electron microscope, we directly discern five distinct stages of surface elemental rearrangements in Pt 3 Co nanoparticles at the atomic scale: initial random (alloy) elemental distribution; surface platinum-skin-layer formation; nucleation of structurally ordered domains; ordered framework development and, finally, initiation of amorphization. Furthermore, a comprehensive interplay among phase evolution, surface faceting and elemental inter-diffusion is revealed, and supported by atomistic simulations. Furthermore, this work may pave the way towards designing catalysts through post-synthesis annealing for optimized catalytic performance.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Thermal Stability of Au Rhombic Dodecahedral Nanocrystals Can Be Greatly Enhanced by Coating Their Surface with an Ultrathin Shell of Pt

Rhombic dodecahedral nanocrystals have been considered particularly difficult to synthesize because they are enclosed by {110}, a low-index facet with the greatest surface energy. Recently, we demonstrated the use of seed-mediated growth for the facile and robust synthesis of Au rhombic dodecahedral nanocrystals (AuRD). While the unique shape and surface structure of AuRD are desirable for potential applications in plasmonics and catalysis, respectively, their high surface energy makes them highly susceptible to thermal degradation. Here we demonstrate that it is feasible to greatly improve the thermal stability with some sacrifice to the plasmonic properties of the original AuRD by coating their surface with an ultrathin shell made of Pt. Our in situ electron microscopy analysis indicates that the ultrathin Pt coating can increase the thermal stability from 60 up to 450 °C, a trend that is also supported by the results from a computational study.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Extraction of quantitative surface characteristics from AIRSAR data for Death Valley, California

Polarimetric Airborne Synthetic Aperture Radar (AIRSAR) data were collected for the Geologic Remote Sensing Field Experiment (GRSFE) over Death Valley, California, USA, in Sep. 1989. AIRSAR is a four-look, quad-polarization, three frequency instrument. It collects measurements at C-band (5.66 cm), L-band (23.98 cm), and P-band (68.13 cm), and has a GIFOV of 10 meters and a swath width of 12 kilometers. Because the radar measures at three wavelengths, different scales of surface roughness are measured. Also, dielectric constants can be calculated from the data. The AIRSAR data were calibrated using in-scene trihedral corner reflectors to remove cross-talk; and to calibrate the phase, amplitude, and co-channel gain imbalance. The calibration allows for the extraction of accurate values of rms surface roughness, dielectric constants, sigma(sub 0) backscatter, and polarization information. The radar data sets allow quantitative characterization of small scale surface structure of geologic units, providing information about the physical and chemical processes that control the surface morphology. Combining the quantitative information extracted from the radar data with other remotely sensed data sets allows discrimination, identification and mapping of geologic units that may be difficult to discern using conventional techniques.

Kierein-Young, K. S.↗
NASA NTRS2009

Detection of Rossby Waves in Multi-Parameters in Multi-Mission Satellite Observations and HYCOM Simulations in the Indian Ocean

Rossby waves are difficult to detect with in situ methods. However, as we show in this paper, they can be clearly identified in multi-parameters in multi-mission satellite observations of sea surface height (SSH), sea surface temperature (SST) and ocean color observations of chlorophyll-a (chl-a), as well as 1/12-deg global HYbrid Coordinate Ocean Model (HYCOM) simulations of SSH, SST and sea surface salinity (SSS) in the Indian Ocean. While the surface structure of Rossby waves can be elucidated from comparisons of the signal in different sea surface parameters, models are needed to gain direct information about how these waves affect the ocean at depth. The first three baroclinic modes of the Rossby waves are inferred from the Fast Fourier Transform (FFT), and two-dimensional Radon Transform (2D RT). At many latitudes the first and second baroclinic mode Rossby wave phase speeds from satellite observations and model parameters are identified.

SSH (SEA SURFACE HEIGHT)↗
NASA NTRS2000

The Structure of Ice Nanoclusters and Thin-films of Water Ice: Implications for Icy Grains in Cold Molecular Clouds

The cubic to hexagonal phase transformation in water ice (I(sub c) yields I(sub h)) is used to measure the extent to which surface structure and impurities control bulk properties. In pure crystalline (I(sub c)) water ice nanoclusters and in thin-films of impure water ice, I(sub c) yields I(sub h) occurs at lower temperatures than in thin-films of pure water ice. The disordered surface of the 20 nm diameter nanoclusters promotes transformations or reactions which would otherwise be kinetically hindered. Likewise, impurities such as methanol introduce defects into the ice network, thereby allowing sluggish structural transitions to proceed. Such surface-related phenomena play an important role in promoting chemical reactions on interstellar ice grains within cold molecular clouds, where the first organic compounds are formed.

Delzeit, Lance↗
DOE OSTI2023

Structural properties of aqueous grown polydopamine thin films determined by neutron reflectometry

Here, in this work, neutron reflectometry (NR) studies of the bio-mimetic polymer, polydopamine (PDA), deposited from differing initial concentrations of precursor material dopamine hydrochloride for a range of polymerization times, is reported. PDA can form a complex and highly versatile polymer film, with many structure studies having been performed previously, but a comprehensive structural determination of PDA by NR is lacking in the literature. It was found that simple box models were incapable of fully explaining the observed data, necessitating the use of a composite model consisting of the weighted average of both the 1 and 2 box models to fully capture the heterogeneous nature of the PDA film structure. Confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM) were performed to capture the surface structure and relative mechanical difference between the separate domains of the PDA. The CLSM results provide evidence that the PDA domains are larger than the coherent scattering length of a neutron used in these measurements, 10μm, supporting the need for a composite model. The AFM measurements show complex structure below the coherence length provide physical justification for the two box model. It was determined that film structure and quality are both heavily impacted by the initial concentration of dopamine hydrochloride and the polymerization time, giving confidence to the highly customizable nature of PDA as an adhesion promoting interface treatment in composite systems, such as plastic bonded explosives (PBX).

36 MATERIALS SCIENCE↗
DOE OSTI2017

Electronic Interactions of Size-Selected Oxide Clusters on Metallic and Thin Film Oxide Supports

The interfacial electronic structure of various size-selected metal oxide nanoclusters (M 3 O x ; M = Mo, Nb, Ti) on Cu(111) and a thin film of Cu 2 O supports were investigated in this paper by a combination of experimental methods and density functional theory (DFT). These systems explore electron transfer at the metal–metal oxide interface which can modify surface structure, metal oxidation states, and catalytic activity. Electron transfer was probed by measurements of surface dipoles derived from coverage dependent work function measurements using two-photon photoemission (2PPE) and metal core level binding energy spectra from X-ray photoelectron spectroscopy (XPS). The measured surface dipoles are negative for all clusters on Cu(111) and Cu 2 O/Cu(111), but those on the Cu 2 O surface are much larger in magnitude. In addition, sub-stoichiometric or “reduced” clusters exhibit smaller surface dipoles on both the Cu(111) and Cu 2 O surfaces. Negative surface dipoles for clusters on Cu(111) suggest Cu → cluster electron transfer, which is generally supported by DFT-calculated Bader charge distributions. For Cu 2 O/Cu(111), calculations of the surface electrostatic potentials show that the charge distributions associated with cluster adsorption structures or distortions at the cluster–Cu 2 O–Cu(111) interface are largely responsible for the observed negative surface dipoles. Changes observed in the XPS spectra for the Mo 3d, Nb 3d, and Ti 2p core levels of the clusters on Cu(111) and Cu 2 O/Cu(111) are interpreted with help from the calculated Bader charges and cluster adsorption structures, the latter providing information about the presence of inequivalent cation sites. Finally, the results presented in this work illustrate how the combined use of different experimental probes along with theoretical calculations can result in a more realistic picture of cluster–support interactions and bonding.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Planarizing Spalled GaAs(100) Surfaces by MOVPE Growth

III-V photovoltaic devices have demonstrated exceptional performance across various applications, with controlled crystal fracturing, known as controlled spalling, emerging as a promising method to reduce costs by enabling substrate reuse. Spalling GaAs(100) substrates, a commonly used substrate in III-V photovoltaics, results in faceted ridges that must be planarized to grow high-quality photovoltaic devices. Here, in this study, we demonstrate that a GaAs(100) wafer offcut toward [$0\bar{11}$] and spalled toward [$011$] can be efficiently planarized by growing C:GaAs by metal-organic vapor phase epitaxy (MOVPE) on the surface, with up to 95% of the nominally deposited material used to fill the valleys between ridges. We find that reducing the offcut to 2° enhances the planarizing capability of C:GaAs. A surface morphology model indicates that the density of surface dangling bonds significantly influences the growth evolution of undoped GaAs surfaces. In contrast, the model suggests that the effectiveness of C:GaAs as a smoothing layer stems from modifying the atomic surface structure and, consequently, the associated sticking coefficients of the facets, which can alter the evolution of surface morphology. Our findings provide guidelines for the epitaxial planarization of semiconductor surfaces and improve the understanding of MOVPE growth on nonplanar surfaces.

14 SOLAR ENERGY↗
DOE OSTI2015

Thermographic process monitoring in powderbed based additive manufacturing

Selective Laser Melting is utilized to build metallic parts directly from CAD-Data by solidification of thin powder layers through application of a fast scanning laser beam. In this study layerwise monitoring of the temperature distribution is used to gather information about the process stability and the resulting part quality. The heat distribution varies with different kinds of parameters including scan vector length, laser power, layer thickness and inter-part distance in the job layout which in turn influence the resulting part quality. By integration of an off-axis mounted uncooled thermal detector the solidification as well as the layer deposition are monitored and evaluated. Errors in the generation of new powder layers usually result in a locally varying layer thickness that may cause poor part quality. For effect quantification, the locally applied layer thickness is determined by evaluating the heat-up of the newly deposited powder. During the solidification process space and time-resolved data is used to characterize the zone of elevated temperatures and to derive locally varying heat dissipation properties. Potential quality indicators are evaluated and correlated to the resulting part quality: Thermal diffusivity is derived from a simplified heat dissipation model and evaluated for every pixel and cool-down phase of a layer. This allows the quantification of expected material homogeneity properties. Maximum temperature and time above certain temperatures are measured in order to detect hot spots or delamination issues that may cause a process breakdown. Furthermore, a method for quantification of sputter activity is presented. Since high sputter activity indicates unstable melt dynamics this can be used to identify parameter drifts, improper atmospheric conditions or material binding errors. The resulting surface structure after solidification complicates temperature determination on the one hand but enables the detection of potential surface defects on the other hand. These issues and proper key figures for thermographic monitoring of the Selective Laser Melting process are discussed in the paper. Even though microbolometric temperature measurement is limited to repetition rates in the Hz-regime and sub megapixel resolution, current results show the feasibility of process surveillance by thermography for a limited section of the building platform in a commercial system.

42 ENGINEERING↗
DOE OSTI2026

Lowering oxygen evolution overpotential via morphology control of NiO x nanocatalysts

NiO x nanocatalysts with two distinct morphologies, nano-spindles and nano-plates, were synthesized and evaluated for oxygen evolution reaction (OER) performance. Spindle-like NiO x was prepared via a hydrothermal reaction of nickel nitrate and urea with cetyltrimethylammonium bromide as a surfactant at 120 °C for 24 h, forming Ni(OH) 2 -based intermediates that were subsequently calcined at 300 °C for 3 h. In contrast, platelet-like Ni(OH) 2 nanocrystals were obtained using nickel(II) acetate and KOH at 180 °C for 24 h, followed by calcination at 400 °C or 500 °C for 4 h to yield NiO x nano-plates. The NiO x nano-spindles exhibited an OER overpotential of 395 mV at 10 mA/cm 2 , whereas the NiO x nano-plates annealed at 400 °C and 500 °C showed overpotentials of 565 mV and 474 mV at 10 mA/cm 2 , respectively. Structural characterization and X-ray photoemission spectroscopy indicate these differences arise from morphology-dependent surface structures that govern catalytic activity.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Scattering properties of Venus' surface

Radar backscatter functions Sigma-(carat)(sub 0)(phi) for incidence angles between 0 less than or equal to phi less than or equal to 4-10 deg were derived from Magellan altimetry radar echoes. The procedure includes constrained solution of a system of simultaneous equations for which the echo-spectrum and echo time profile are inputs. A practical and workable set of constraints was applied; optimization and improved results are expected as the analysis matures. The scattering functions yield information on small-scale surface structures (tens of centimeters to tens of meters) but averaged over hundreds of sq km. RMS surface slopes derived from fits of analytic functions to the Sigma-(carat)(sub 0)(phi) results were converted to map form and show patterns similar to those reported using other techniques. While all three forms are found on Venus, fit residuals imply that an exponential scattering function matches data better than either the Hagfors or Gaussian form in most areas, although the Hagfors function may be a better descriptor at some sites. Limited study of image data indicates that average backscatter cross section, and possibly its slope, can be derived at oblique angles (17 deg less than or equal to phi less than or equal to 45 deg). Offsets of the echo peak in altimetry spectra are surprisingly common and are loosely correlated with Venus topography, but no cause for this phenomenon was identified.

Tyler, G. L.↗
NASA NTRS2017

Surface Characterization of Carbon Fiber Reinforced Polymers by Picosecond Laser Induced Breakdown Spectroscopy

Adhesive bonding of composite materials requires reliable monitoring and detection of surface contaminants as part of a vigorous quality control process to assure robust and durable bonded structures. Surface treatment and effective monitoring prior to bonding are essential in order to obtain a surface which is free from contaminants that may lead to inferior bond quality. In this study, the focus is to advance the laser induced breakdown spectroscopy (LIBS) technique by using pulse energies below 100 μJ (μLIBS) for the detection of low levels of silicone contaminants in carbon fiber reinforced polymer (CFRP) composites. Various CFRP surface conditions were investigated by LIBS using ∼10 ps, 355 nm laser pulses with pulse energies below 30 μJ. Time-resolved analysis was conducted to optimize the gate delay and gate width for the detection of the C I emission line at 247.9 nm to monitor the epoxy resin matrix of CFRP composites and the Si I emission line at 288.2 nm for detection of silicone contaminants in CFRP. To study the surface sensitivity to silicone contamination, CFRP surfaces were coated with polydimethylsiloxane (PDMS), the active ingredient in many mold release agents. The presence of PDMS was studied by inspecting the Si I emission lines at 251.6 nm and 288.2 nm. The measured PDMS areal densities ranged from 0.15 to 2 μg/cm(sup 2). LIBS measurements were performed before and after laser surface ablation. The results demonstrate the successful detection of PDMS thin layers on CFRP using picosecond μLIBS.

Rodolfo Ledesma↗
DOE OSTI2015

Si{sub 3}N{sub 4} layers for the in-situ passivation of GaN-based HEMT structures

A method for the in situ passivation of GaN-based structures with silicon nitride in the growth chamber of a metal organic vapor phase epitaxy (MOVPE) reactor is described. The structural and electrical properties of the obtained layers are investigated. The in situ and ex situ passivation of transistor structures with silicon nitride in an electron-beam-evaporation device are compared. It is shown that ex situ passivation changes neither the initial carrier concentration nor the mobility. In situ passivation makes it possible to protect the structure surface against uncontrollable degradation upon the finishing of growth and extraction to atmosphere. In the in situ passivated structure, the carrier concentration increases and the mobility decreases. This effect should be taken into account when manufacturing passivated GaN-based transistor structures.

36 MATERIALS SCIENCE↗