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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36

Theoretical investigation of flutter of two-dimensional flat panels with one surface exposed to supersonic potential flow

A Rayleigh type analysis involving chosen modes of the panel as degrees of freedom is used to treat the flutter of a two-dimensional flat panel supported at its leading and trailing edges and subjected to a middle-plane tensile force. The panel has a supersonic stream passing over its upper surface and still air below. The aerodynamic forces due to the supersonic stream are obtained from the theory for linearized two-dimensional unsteady flow and the forces due to the still air are obtained from acoustical theory. In order to study the effect of increasing the number of modes in the analysis, two and then four modes are employed. The modes used are the first four natural modes of the panel in a vacuum with no tensile force acting. The analysis includes these variables: Mach number, structural damping, tensile force, density of the still air, and edge fixity (clamped and pinned). For certain combinations of these variables, stability boundaries are obtained which can be used to determine the panel thickness required to prevent flutter for any panel material and altitude.

Nelson, Herbert C↗

Gravitational lensing effects in a time-variable cosmological 'constant' cosmology

A scalar field phi with a potential V(phi) varies as phi exp -alpha(alpha is greater than 0) has an energy density, behaving like that of a time-variable cosmological 'constant', that redshifts less rapidly than the energy densities of radiation and matter, and so might contribute significantly to the present energy density. We compute, in this spatially flat cosmology, the gravitational lensing optical depth, and the expected lens redshift distribution for fixed source redshift. We find, for the values of alpha of about 4 and baryonic density parameter Omega of about 0.2 consistent with the classical cosmological tests, that the optical depth is significantly smaller than that in a constant-Lambda model with the same Omega. We also find that the redshift of the maximum of the lens distribution falls between that in the constant-Lambda model and that in the Einstein-de Sitter model.

Ratra, Bharat↗

On the radio variability of V410 Tauri

The radio flux density of the star V410 Tauri has been monitored at 6 and 2 cm wavelengths at monthly intervals over a one-year period with the VLA. In contrast to earlier observations, the radio emission was typically at the level of roughly 1 mJy with flat or negative spectral indices. No large radio 'flare' events were detected. However, a periodicity analysis of the quiescent data shows statistically significant evidence for a modulation of the radio emission, with a period of 0.933 days, or one-half the optical period reported by Vrba, et al. (1988). If the modulation is real, it would imply that (1) the radio emission is produced either in localized zones on two opposite hemispheres of the star, or in a single, presumably high-latitude, structure that remains visible for an entire rotation period; (2) this zone or zones must be comparable to the stellar radius in size; (3) the energy spectrum of the radiating electrons is stable over long times (greater than 1 yr) but the absolute intensity level in the quiescent state may vary by factors of a few; and (4) the emission solid angle varies with viewing angle of the emission zone. It is suggested that gyrosynchrotron radiation from closed-loop magnetic structures may be responsible for the quasisteady low-level radio emission reported here. A geometric model for the radio emission structure may explain qualitatively the modulation of the radio emission. By analogy with the premain-sequence star DoAr 21, this same physical mechanism may produce both the 'quiescent' and 'flaring' radio emission. The monitoring results suggest that strong radio outbursts, such as were previously observed for V410 Tau, are relatively rare.

Bieging, John H.↗

Application of Box-Behnken design in optimizing product properties of supercritical methanol co -liquefaction of rice straw and linear low-density polyethylene

We report co-processing of plastic and biomass wastes to produce high-quality fuel has been attracting considerable interest in energy recovery. This work employed Box-Behnken Design (BBD) to optimize yield and properties of oil from supercritical methanol (scMeOH) co-liquefaction of rice straw (RS) and linear low-density polyethylene (LLDPE). Three independent variables of reaction temperature (270, 300, and 330°C), holding time (60, 90, and 120 mins), and RS/LLDPE mass ratio (0.15, 0.50, and 0.85) were selected for experiments. A maximum oil yield of 34.17 wt% was achieved at 303°C, 96 mins, and RS/LLDPE ratio of 0.59 according to BBD. Temperature and RS/LLDPE ratio dominated the oil yield and synergistic effects during co-liquefaction, whereas time was an insignificant factor. Optimum oil from co-liquefaction contained substantial hydrocarbons content of 32.91% compared to that from single RS-derived oil of 7.77%. Solid product obtained at the optimum condition could be used as solid fuel, due to its relatively high HHV of 43.08 MJ/kg compared to the other solid fuels (13.90–32.14 MJ/kg). This work provides a deep understanding of the co-processing of solid biomass and plastic wastes.

09 BIOMASS FUELS↗

A retrospective review of von Neumann’s analysis of hidden variables in quantum mechanics

This article reviews the history of J. von Neumann’s analysis of hidden variables in quantum mechanics and the subsequent analysis by others. In his book The Mathematical Foundations of Quantum Mechanics , published in 1932, von Neumann performed an analysis of the consequences of introducing hidden parameters (hidden variables) into quantum mechanics. He arrived at two principal conclusions: first, hidden variables cannot be incorporated into the existing theory of quantum mechanics without major modifications, and second, if they did exist, the theory would have already failed in situations where it has been successfully applied. This analysis has been taken as an “incorrect proof” against the existence of hidden variables, possibly due to a mistranslation of the German word prufen . von Neumann’s so-called proof isn’t even wrong as such a proof does not exist, but it is an examination of the limitations imposed by internal consistency of the Hilbert space formulation of the theory. One of the earliest attempts to eliminate uncertainty, by D. Bohm, requires a major modification of quantum mechanics (observables are not represented by Hermitian operators), which supports von Neumann’s first principal conclusion. However, testing the Bohm theory requires constructing a physically impossible initial state. As such, the theory has no experimental consequences, so W. Pauli referred to it as an “uncashable check”. As there are no observable consequences, the Bohm theory is possibly a counterexample to von Neumann’s second conclusion that hidden variables in particular would have already led to a failure of the theory.

density matrix↗

Probabilistic structural analysis methods for improving Space Shuttle engine reliability

Probabilistic structural analysis methods are particularly useful in the design and analysis of critical structural components and systems that operate in very severe and uncertain environments. These methods have recently found application in space propulsion systems to improve the structural reliability of Space Shuttle Main Engine (SSME) components. A computer program, NESSUS, based on a deterministic finite-element program and a method of probabilistic analysis (fast probability integration) provides probabilistic structural analysis for selected SSME components. While computationally efficient, it considers both correlated and nonnormal random variables as well as an implicit functional relationship between independent and dependent variables. The program is used to determine the response of a nickel-based superalloy SSME turbopump blade. Results include blade tip displacement statistics due to the variability in blade thickness, modulus of elasticity, Poisson's ratio or density. Modulus of elasticity significantly contributed to blade tip variability while Poisson's ratio did not. Thus, a rational method for choosing parameters to be modeled as random is provided.

Boyce, L.↗

Estimating canopy fuel characteristics for predicting crown fire potential in common forest types of the Atlantic Coastal Plain, USA

We computed four stand-level canopy stratum variables important for crown fire modelling – canopy cover, stand height, canopy base height and canopy bulk density – from forest inventory data. We modelled the relationship between the canopy variables and a set of common inventory parameters – site index, stem density, basal area, stand age or stand height – and number of prescribed burns. We used a logistic model to estimate canopy cover, a linear model to estimate the other canopy variables, and the information theoretic approach for model selection. Coefficients of determination across five forest groups were 0.72–0.91 for stand height, 0.36–0.83 for canopy base height, 0.39–0.80 for canopy cover, and 0.63–0.78 for canopy bulk density. We assessed crown fire potential (1) for several sets of environmental conditions in all seasons, and (2) with increasing age, density and number of prescribed burns using our modelled canopy bulk density and canopy base height variables and local weather data to populate the Crown Fire Initiation and Spread model. Results indicated that passive crown fire is possible in any season in Atlantic coastal plain pine stands with heavy surface fuel loads and active crown fire is most probable in infrequently burned, dense stands at low fuel moistures.

Forestry↗

An Evaluation of Antarctica as a Calibration Target for Passive Microwave Satellite Missions with Climate Data Record Applications

Passive microwave remote sensing at L-band (1.4 GHz) is sensitive to soil moisture and sea surface salinity, both important climate variables. Science studies involving these variables can now take advantage of new satellite L-band observations. The first mission with regular global passive microwave observations at L-band is the European Space Agency's Soil Moisture and Ocean Salinity (SMOS), launched November, 2009. A second mission, NASA's Aquarius, was launched June, 201 I. A third mission, NASA's Soil Moisture Active Passive (SMAP) is scheduled to launch in 2014. Together, these three missions may provide a decade-long data record-provided that they are intercalibrated. The intercalibration is best performed at the radiance (brightness temperature) level, and Antarctica is proving to be a key calibration target. However, Antarctica has thus far not been fully characterized as a potential target. This paper will present evaluations of Antarctica as a microwave calibration target for the above satellite missions. Preliminary analyses have identified likely target areas, such as the vicinity of Dome-C and larger areas within East Antarctica. Physical sources of temporal and spatial variability of polar firn are key to assessing calibration uncertainty. These sources include spatial variability of accumulation rate, compaction, surface characteristics (dunes, micro-topography), wind patterns, and vertical profiles of density and temperature. Using primarily SMOS data, variability is being empirically characterized and attempts are being made to attribute observed variability to physical sources. One expected outcome of these studies is the potential discovery of techniques for remotely sensing--over all of Antarctica-parameters such as surface temperature.

Kim, Edward↗

An Evaluation of Antarctica as a Calibration Target for Passive Microwave Satellite Missions

Passive microwave remote sensing at L-band (1.4 GHz) is sensitive to soil moisture and sea surface salinity, both important climate variables. Science studies involving these variables can now take advantage of new satellite L-band observations. The first mission with regular global passive microwave observations at L-band is the European Space Agency's Soil Moisture and Ocean Salinity (SMOS), launched November, 2009. A second mission, NASA's Aquarius, was launched June, 201l. A third mission, NASA's Soil Moisture Active Passive (SMAP) is scheduled to launch in 2014. Together, these three missions may provide a decade-long data record -- provided that they are intercalibrated. The intercalibration is best performed at the radiance (brightness temperature) level, and Antarctica is proving to be a key calibration target. However, Antarctica has thus far not been fully characterized as a potential target. This paper will present evaluations of Antarctica as a microwave calibration target for the above satellite missions. Preliminary analyses have identified likely target areas, such as the vicinity of Dome-C and larger areas within East Antarctica. Physical sources of temporal and spatial variability of polar firn are key to assessing calibration uncertainty. These sources include spatial variability of accumulation rate, compaction, surface characteristics (dunes, micro-topography), wind patterns, and vertical profiles of density and temperature. Using primarily SMOS data, variability is being empirically characterized and attempts are being made to attribute observed variability to physical sources. One expected outcome of these studies is the potential discovery of techniques for remotely sensing--over all of Antarctica--parameters such as surface temperature.

Kim, Edward↗

Multiscale topology optimization using neural network surrogate models

In this study, we are concerned with optimization of macroscale elastic structures that are designed utilizing spatially varying microscale metamaterials. The macroscale optimization is accomplished using gradient-based nonlinear topological optimization. But instead of using density as the optimization decision variable, the decision variables are the multiple parameters that define the local microscale metamaterial. This is accomplished using single layer feedforward Gaussian basis function networks as a surrogate models of the elastic response of the microscale metamaterial. The surrogate models are trained using highly resolved continuum finite element simulations of the microscale metamaterials and hence are significantly more accurate than analytical models e.g. classical beam theory. Because the derivative of the surrogate model is important for sensitivity analysis of the macroscale topology optimization, a neural network training procedure based on the Sobolev norm is described. Since the SIMP method is not appropriate for spatially varying lattices, an alternative method is developed to enable creation of void regions. Lastly, the efficacy of this approach is demonstrated via several examples in which the optimal graded metamaterial outperforms a traditional solid structure.

42 ENGINEERING↗

An adaptive Hessian approximated stochastic gradient MCMC method

Bayesian approaches have been successfully integrated into training deep neural networks. One popular family is stochastic gradient Markov chain Monte Carlo methods (SG-MCMC), which have gained increasing interest due to their ability to handle large datasets and the potential to avoid overfitting. Although standard SG-MCMC methods have shown great performance in a variety of problems, they may be inefficient when the random variables in the target posterior densities have scale differences or are highly correlated. Here, we present an adaptive Hessian approximated stochastic gradient MCMC method to incorporate local geometric information while sampling from the posterior. The idea is to apply stochastic approximation (SA) to sequentially update a preconditioning matrix at each iteration. The preconditioner possesses second-order information and can guide the random walk of a sampler efficiently. Instead of computing and saving the full Hessian of the log posterior, we use limited memory of the samples and their stochastic gradients to approximate the inverse Hessian-vector multiplication in the updating formula. Moreover, by smoothly optimizing the preconditioning matrix via SA, our proposed algorithm can asymptotically converge to the target distribution with a controllable bias under mild conditions. To reduce the training and testing computational burden, we adopt a magnitude-based weight pruning method to enforce the sparsity of the network. Our method is user-friendly and demonstrates better learning results compared to standard SG-MCMC updating rules. The approximation of inverse Hessian alleviates storage and computational complexities for large dimensional models. Numerical experiments are performed on several problems, including sampling from 2D correlated distribution, synthetic regression problems, and learning the numerical solutions of heterogeneous elliptic PDE. The numerical results demonstrate great improvement in both the convergence rate and accuracy.

97 MATHEMATICS AND COMPUTING↗

Local Chain Dynamics in Sequence-Controlled Polymers as a Tunable Handle for Rare Earth Sequestration

Chain dynamics govern the intricate behaviors of proteins, underpinning functions such as catalysis, recognition, and stimulus response, and are an increasingly appreciated aspect of structure–function relationships. Analogously, manipulating chain dynamics and structure in abiotic polymers via sequence control is an exciting, yet underexplored, strategy for improving material functions. In this work, we report a systematic study relating the sequence of polymeric sequestrants to their structure and dynamics, as well as to their binding affinity and selectivity for model substrates, rare earth elements (REEs). A series of sequence-controlled polymers with metal chelating, solubilizing, and structure forming monomers was synthesized via multiblock polymerization, yielding compositionally identical polymers with spectroscopically resolved domains and distinct morphologies. Using a combination of small-angle X-ray scattering and 19 F NMR relaxometry measurements, we connected differences in polymer structure and dynamics to polymer sequence variables such as the patchiness (density) of the structure forming monomer and the location of the chelating monomer. Furthermore, we found that, relative to calcium, all polymers in the series collapse more and have slower dynamics when binding REEs (lanthanum and lutetium) , though the extent of these effects were sequence-dependent and localized to specific domains within the polymer. Notably, sequence-controlled polymers that exhibited the largest conformational and dynamic changes upon binding REEs also bound REEs with the greatest affinity and modest selectivity. Collectively, these results correlate monomer patterning with dynamics, morphology, and REE binding performance en route to the development of efficient and selective macromolecular chelators.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pulsed Electrolysis Promotes Catalyst Activity in Dilute CO 2 Streams

Industrial CO 2 streams vary widely in composition, from pure to as low as 3%, posing challenges for purification or direct conversion. Electrochemical reduction offers a route for converting dilute CO 2 streams but faces severe mass transport limitations. This study demonstrates that pulsed electrolysis effectively overcomes these limitations, enhancing CO 2 electroreduction across variable feed compositions and current densities, particularly at low CO 2 concentrations and high current densities. At 25% CO 2 and 400 mA cm −2 , pulsing improved selectivity from 25.6 to 78.6%, production rate from 13.7 to 21.0 mol m −2 h −1 , and energy productivity from 0.77 to 2.59 mol kWh −1 . A dynamic, multiphysics continuum model confirms a 64% increase in CO 2 concentration within the catalyst layer during pulsing, resolving the transient chemical microenvironment. These findings establish pulsed electrolysis as a viable strategy for converting dilute industrial CO 2 streams into valuable feedstocks, bypassing costly pre-separation.

Orfali, Dania Muhieddine [New York University (NYU↗

Turbulence statistical analysis of the L-H transition and RMPs in KSTAR

Here, we investigate the turbulence statistics associated with low-to-high confinement (L-H) transitions and externally applied resonant magnetic perturbations (RMPs) in KSTAR. Time-series fluctuations of electron density n e , electron temperature T e , and the time derivative of the poloidal magnetic field dB θ /dt (Mirnov coils) are analysed using information-geometric measures (information rate Γ and information length $\mathcal{L}$ = ∫ Γ dt), together with kurtosis κ and variance σ 2 . In low-density upper single-null plasmas (n e ~ 1.2 x 10 19 m -3 ), a ~80 kHz magnetic mode coupling n e , T e , dB θ /dt and emerges prior to the L-H transition and persists into the edge-localised modes H-mode. Edge-localised RMPs (ERMPs) suppress this coherent mode but enhance intermittency, producing frequent bursts that abruptly reshape the time-dependent probability density functions (PDFs) and generate large spikes in Γ (with smaller changes in κ), signalling ERMP-driven departures from quasi-stationarity. The impact of ERMPs on background fluctuation levels depends on density, radial location, and the fluctuating variable itself ($\tilde{n}$, $\tilde{T}$, $\dot{B}$ θ ), whereas $\mathcal{L}$ provides a robust, regime-agnostic measure of cumulative statistical reorganisation and spatial decorrelation. In particular, at low density we observe weaker coupling between $\tilde{n}$ and $\tilde{T}$, along with a tendency toward decreased radial correlation-most clearly for $\tilde{T}$-under ERMPs. Overall, information geometry cleanly captures intermittent events, quantifies non-equilibrium PDF evolution, and offers a compact, cross-diagnostic metric for assessing resonant magnetic perturbation effects on edge transport and correlation across densities, radial locations, and confinement states.

Kim, Eun-jin [Coventry Univ. (United Kingdom); Seo↗

Refining fast calorimeter simulations with a Schrödinger Bridge

Machine learning-based simulations, especially calorimeter simulations, are promising tools for approximating the precision of classical high energy physics simulations with a fraction of the generation time. Nearly all methods proposed so far learn neural networks that map a random variable with a known probability density, like a Gaussian, to realistic-looking events. In many cases, physics events are not close to Gaussian and so these neural networks have to learn a highly complex function. We study an alternative approach: Schrödinger bridge Quality Improvement via Refinement of Existing Lightweight Simulations (SQuIRELS). SQuIRELS leverages the power of diffusion-based neural networks and Schrödinger bridges to map between samples where the probability density is not known explicitly. We apply SQuIRELS to the task of refining a classical fast simulation to approximate a full classical simulation. On simulated calorimeter events, we find that SQuIRELS is able to reproduce highly non-trivial features of the full simulation with a fraction of the generation time.

Calorimeter methods↗

Distributionally Robust Variational Quantum Algorithms With Shifted Noise

Given their potential to demonstrate near-term quantum advantage, variational quantum algorithms (VQAs) have been extensively studied. Although numerous techniques have been developed for VQA parameter optimization, it remains a significant challenge. A practical issue is the high sensitivity of quantum noise to environmental changes, and its propensity to shift in real time. This presents a critical problem as an optimized VQA ansatz may not perform effectively under a different noise environment. For the first time, we explore how to optimize VQA parameters to be robust against unknown shifted noise. We model the noise level as a random variable with an unknown probability density function (PDF), and we assume that the PDF may shift within an uncertainty set. This assumption guides us to formulate a distributionally robust optimization problem, with the goal of finding parameters that maintain effectiveness under shifted noise. We utilize a distributionally robust Bayesian optimization solver for our proposed formulation. This provides numerical evidence in both the Quantum Approximate Optimization Algorithm (QAOA) and the Variational Quantum Eigensolver (VQE) with hardware-efficient ansatz, indicating that we can identify parameters that perform more robustly under shifted noise. We regard this work as the first step towards improving the reliability of VQAs influenced by real-time noise.

97 MATHEMATICS AND COMPUTING↗

The Shape and Density Evolution of Snow Aggregates

Abstract Snow aggregates evolve into a variety of observed shapes and densities. Despite this diversity, models and observational studies employ fractal or Euclidean geometric measures that are assumed universal for all aggregates. This work therefore seeks to improve understanding and representation of snow aggregate geometry and its evolution by characterizing distributions of both observed and Monte Carlo–generated aggregates. Two separate datasets of best-fit ellipsoid estimates derived from Multi-Angle Snowflake Camera (MASC) observations suggest the use of a bivariate beta distribution model for capturing aggregate shapes. Product moments of this model capture shape effects to within 4% of observations. This mathematical model is used along with Monte Carlo simulated aggregates to study how combinations of monomer properties affect aggregate shape evolution. Plate aggregates of any aspect ratio produce a consistent ellipsoid shape evolution whereas thin column aggregates evolve to become more spherical. Thin column aggregates yield fractal dimensions much less than the often-assumed value of 2.0. Ellipsoid densities and fractal analogs of density (lacunarity) are much more variable depending on combinations of monomer size and shape. Simple mathematical scaling relationships can explain the persistent triaxial ellipsoid shapes that appear in both observed and modeled aggregates. Overall, both simulations and observations prove aggregates are rarely oblate. Therefore, the use of the proposed bivariate ellipsoid distribution in models will allow for similar-sized aggregates to exhibit a realistic dispersion of masses and fall speeds.

54 ENVIRONMENTAL SCIENCES↗