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NASA NTRS2010

Application of Reflected Global Navigation Satellite System (GNSS-R) Signals in the Estimation of Sea Roughness Effects in Microwave Radiometry

In February-March 2009 NASA JPL conducted an airborne field campaign using the Passive Active L-band System (PALS) and the Ku-band Polarimetric Scatterometer (PolSCAT) collecting measurements of brightness temperature and near surface wind speeds. Flights were conducted over a region of expected high-speed winds in the Atlantic Ocean, for the purposes of algorithm development for salinity retrievals. Wind speeds encountered were in the range of 5 to 25 m/s during the two weeks deployment. The NASA-Langley GPS delay-mapping receiver (DMR) was also flown to collect GPS signals reflected from the ocean surface and generate post-correlation power vs. delay measurements. This data was used to estimate ocean surface roughness and a strong correlation with brightness temperature was found. Initial results suggest that reflected GPS signals, using small low-power instruments, will provide an additional source of data for correcting brightness temperature measurements for the purpose of sea surface salinity retrievals.

Voo, Justin K.↗
NASA NTRS2009

MODIS Observations of Enhanced Clear Sky Reflectance Near Clouds

Several recent studies have found that the brightness of clear sky systematically increases near clouds. Understanding this increase is important both for a correct interpretation of observations and for improving our knowledge of aerosol-cloud interactions. However, while the studies suggested several processes to explain the increase, the significance of each process is yet to be determined. This study examines one of the suggested processes three-dimensional (3-D) radiative interactions between clouds and their surroundings by analyzing a large dataset of MODIS (Moderate Resolution Imaging Spectroradiometer) observations over the Northeast Atlantic Ocean. The results indicate that 3-D effects are responsible for a large portion of the observed increase, which extends to about 15 km away from clouds and is stronger (i) at shorter wavelengths (ii) near optically thicker clouds and (iii) near illuminated cloud sides. This implies that it is important to account for 3-D radiative effects in the interpretation of solar reflectance measurements over clear regions in the vicinity of clouds.

Varnai, Tamas↗
NASA NTRS2010

Re-Evaluating the Role of the Saharan Air Layer in Atlantic Tropical Cyclogenesis and Evolution

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air frequently present over the tropical Atlantic Ocean, has long been appreciated. The nature of its impact on hurricanes remains unclear, however, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. Most research in recent years has emphasized the potential negative impacts of the SAL, but is this emphasis justified? The potential negative impacts of the SAL include 1) vertical wind shear associated with the African easterly jet; 2) warm air aloft, which increases thermodynamic stability at the base of the SAL; and 3) dry air, which produces cold downdrafts. Multiple NASA satellite data sets and NCEP global analyses are used to characterize the SAL's properties and evolution in relation to tropical cyclones and to evaluate these potential negative influences. The results suggest that the negative influences of the SAL have been significantly over-emphasized, in part because of several false assumptions about the structure and role of the SAL.

Braun, Scott A.↗
NASA NTRS2010

The Invigoration of Deep Convective Clouds Over the Atlantic: Aerosol Effect, Meteorology or Retrieval Artifact?

Associations between cloud properties and aerosol loading are frequently observed in products derived from satellite measurements. These observed trends between clouds and aerosol optical depth suggest aerosol modification of cloud dynamics, yet there are uncertainties involved in satellite retrievals that have the potential to lead to incorrect conclusions. Two of the most challenging problems are addressed here: the potential for retrieved aerosol optical depth to be cloud-contaminated, and as a result, artificially correlated with cloud parameters; and the potential for correlations between aerosol and cloud parameters to be erroneously considered to be causal. Here these issues are tackled directly by studying the effects of the aerosol on convective clouds in the tropical Atlantic Ocean using satellite remote sensing, a chemical transport model, and a reanalysis of meteorological fields. Results show that there is a robust positive correlation between cloud fraction or cloud top height and the aerosol optical depth, regardless of whether a stringent filtering of aerosol measurements in the vicinity of clouds is applied, or not. These same positive correlations emerge when replacing the observed aerosol field with that derived from a chemical transport model. Model-reanalysis data is used to address the causality question by providing meteorological context for the satellite observations. A correlation exercise between the full suite of meteorological fields derived from model reanalysis and satellite-derived cloud fields shows that observed cloud top height and cloud fraction correlate best with model pressure updraft velocity and relative humidity. Observed aerosol optical depth does correlate with meteorological parameters but usually different parameters from those that correlate with observed cloud fields. The result is a near-orthogonal influence of aerosol and meteorological fields on cloud top height and cloud fraction. The results strengthen the case that the aerosol does play a role in invigorating convective clouds.

Koren, Ilan↗
NASA NTRS2010

Combined Aircraft and Satellite-Derived Storm Electric Current and Lightning Rates Measurements and Implications for the Global Electric Circuit

Using rotating vane electric field mills and Gerdien capacitors, we measured the electric field profile and conductivity during 850 overflights of electrified shower clouds and thunderstorms spanning regions including the Southeastern United States, the Western Atlantic Ocean, the Gulf of Mexico, Central America and adjacent oceans, Central Brazil, and the South Pacific. The overflights include storms over land and ocean, with and without lightning, and with positive and negative fields above the storms. The measurements were made with the NASA ER-2 and the Altus-II high altitude aircrafts. Peak electric fields, with lightning transients removed, ranged from -1.0 kV/m to 16 kV/m, with a mean value of 0.9 kV/m. The median peak field was 0.29 kV/m. Integrating our electric field and conductivity data, we determined total conduction currents and flash rates for each overpass. With knowledge of the storm location (land or ocean) and type (with or without lightning), we determine the mean currents by location and type. The mean current for ocean storms with lightning is 1.6 A while the mean current for land storms with lightning is 1.0 A. The mean current for oceanic storms without lightning (i.e., electrified shower clouds) is 0.39 A and the mean current for land storms without lightning is 0.13 A. Thus, on average, land storms with or without lightning have about half the mean current as their corresponding oceanic storm counterparts. Over three-quarters (78%) of the land storms had detectable lightning, while less than half (43%) of the oceanic storms had lightning. We did not find any significant regional or latitudinal based patterns in our total conduction currents. By combining the aircraft derived storm currents and flash rates with diurnal lightning statistics derived from the Lightning Imaging Sensor (LIS) and Optical Transient Detector (OTD) low Earth orbiting satellites, we reproduce the diurnal variation in the global electric circuit (i.e., the Carnegie curve) to within 4% for all but two short periods of time. This excellent agreement with the Carnegie curve was obtained without any tuning or adjustment of the satellite or aircraft data. Given our data and assumptions, mean contributions to the global electric circuit are 0.7 kA (ocean) and 1.1 kA (land) from lightning-producing storms, and 0.22 kA (ocean) and 0.04 (land) from electrified shower clouds, resulting in a mean total conduction current estimate for the global electric circuit of 2.0 kA. Breaking the results down into mean storm counts reveals 1100 for land storms with lightning, 530 for ocean storms without lightning, 390 for ocean storms with lightning, and 330 for land storms without lightning.

Mach, Douglas M.↗
NASA NTRS2010

Remote Sensing of Radiative and Microphysical Properties of Clouds During TC (sup 4): Results from MAS, MASTER, MODIS, and MISR

The Moderate Resolution Imaging Spectroradiometer (MODIS) Airborne Simulator (MAS) and MODIS/Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Airborne Simulator (MASTER) were used to obtain measurements of the bidirectional reflectance and brightness temperature of clouds at 50 discrete wavelengths between 0.47 and 14.2 microns (12.9 microns for MASTER). These observations were obtained from the NASA ER-2 aircraft as part of the Tropical Composition, Cloud and Climate Coupling (TC4) experiment conducted over Central America and surrounding Pacific and Atlantic Oceans between 17 July and 8 August 2007. Multispectral images in eleven distinct bands were used to derive a confidence in clear sky (or alternatively the probability Of cloud) over land and ocean ecosystems. Based on the results of individual tests run as part of the cloud mask, an algorithm was developed to estimate the phase of the clouds (liquid water, ice, or undetermined phase). The cloud optical thickness and effective radius were derived for both liquid water and ice clouds that were detected during each flight, using a nearly identical algorithm to that implemented operationally to process MODIS Cloud data from the Aqua and Terra satellites (Collection 5). This analysis shows that the cloud mask developed for operational use on MODIS, and tested using MAS and MASTER data in TC(sup 4), is quite capable of distinguishing both liquid water and ice clouds during daytime conditions over both land and ocean. The cloud optical thickness and effective radius retrievals use five distinct bands of the MAS (or MASTER), and these results were compared with nearly simultaneous retrievals of marine liquid water clouds from MODIS on the Terra spacecraft. Finally, this MODIS-based algorithm was adapted to Multiangle Imaging SpectroRadiometer (MISR) data to infer the cloud optical thickness Of liquid water clouds from MISR. Results of this analysis are compared and contrasted.

King, Michael D.↗
NASA NTRS2009

An Analysis of Moisture Fluxes into the Gulf of California

This study examines the nature of episodes of enhanced warm-season moisture flux into the Gulf of California. Both spatial structure and primary time scales of the fluxes are examined using the 40-yr ECMWF Re-Analysis data for the period 1980-2001. The analysis approach consists of a compositing technique that is keyed on the low-level moisture fluxes into the Gulf of California. The results show that the fluxes have a rich spectrum of temporal variability, with periods of enhanced transport over the gulf linked to African easterly waves on subweekly (3-8 day) time scales, the Madden-Julian oscillation (MJO) at intraseasonal time scales (20-90 day), and intermediate (10-15 day) time-scale disturbances that appear to originate primarily in the Caribbean Sea-western Atlantic Ocean. In the case of the MJO, enhanced low-level westerlies and large-scale rising motion provide an environment that favors large-scale cyclonic development near the west coast of Central America that, over the course of about 2 weeks, expands northward along the coast eventually reaching the mouth of the Gulf of California where it acts to enhance the southerly moisture flux in that region. On a larger scale, the development includes a northward shift in the eastern Pacific ITCZ, enhanced precipitation over much of Mexico and the southwestern United States, and enhanced southerly/southeasterly fluxes from the Gulf of Mexico into Mexico and the southwestern and central United States. In the case of the easterly waves, the systems that reach Mexico appear to redevelop/reorganize on the Pacific coast and then move rapidly to the northwest to contribute to the moisture flux into the Gulf of California. The most intense fluxes into the gulf on these time scales appear to be synchronized with a midlatitude short-wave trough over the U.S. West Coast and enhanced low-level southerly fluxes over the U.S. Great Plains. The intermediate (10-15 day) time-scale systems have zonal wavelengths roughly twice that of the easterly waves, and their initiation appears to be linked to an extratropical U.S. East Coast ridge and associated northeasterly winds that extend well into the Caribbean Sea during their development phase. The short (3-8 day) and, to a lesser extent, the intermediate (10-15 day) time-scale fluxes tend to be enhanced when the convectively active phase of the MJO is situated over the Americas.

Wu, Man-Li C.↗
NASA NTRS2011

Using High-Resolution Forward Model Simulations of Ideal Atmospheric Tracers to Assess the Spatial Information Content of Inverse CO2 Flux Estimates

Attribution of observed atmospheric carbon concentrations to emissions on the country, state or city level is often inferred using "inversion" techniques. Such computations are often performed using advanced mathematical techniques, such as synthesis inversion or four-dimensional variational analysis, that invoke tracing observed atmospheric concentrations backwards through a transport model to a source region. It is, to date, not well understood how well such techniques can represent fine spatial (and temporal) structure in the inverted flux fields. This question is addressed using forward-model computations with idealized tracers emitted at the surface in a large number of grid boxes over selected regions and examining how distinctly these emitted tracers can be detected downstream. Initial results show that tracers emitted in half-degree grid boxes over a large region of the Eastern USA cannot be distinguished from each other, even at short distances over the Atlantic Ocean, when they are emitted in grid boxes separated by less than five degrees of latitude - especially when only total-column observations are available. A large number of forward model simulations, with varying meteorological conditions, are used to assess how distinctly three types observations (total column, upper tropospheric column, and surface mixing ratio) can separate emissions from different sources. Inferences inverse modeling and source attribution will be drawn.

Pawson, Steven↗
NASA NTRS2011

Detecting Corrosion Under Paint and Insulation

Corrosion is a major concern at the Kennedy Space Center in Florida due to the proximity of the center to the Atlantic Ocean and to salt water lagoons. High humidity, salt fogs, and ocean breezes, provide an ideal environment in which painted steel structures become corroded. Maintenance of painted steel structures is a never-ending process.

Bastin, Gary L.↗
NASA NTRS2011

Global Electric Circuit Implications of Combined Aircraft Storm Electric Current Measurements and Satellite-Based Diurnal Lightning Statistics

Using rotating vane electric field mills and Gerdien capacitors, we measured the electric field profile and conductivity during 850 overflights of thunderstorms and electrified shower clouds (ESCs) spanning regions including the Southeastern United States, the Western Atlantic Ocean, the Gulf of Mexico, Central America and adjacent oceans, Central Brazil, and the South Pacific. The overflights include storms over land and ocean, and with positive and negative fields above the storms. Over three-quarters (78%) of the land storms had detectable lightning, while less than half (43%) of the oceanic storms had lightning. Integrating our electric field and conductivity data, we determined total conduction currents and flash rates for each overpass. With knowledge of the storm location (land or ocean) and type (with or without lightning), we determine the mean currents by location and type. The mean current for ocean thunderstorms is 1.7 A while the mean current for land thunderstorms is 1.0 A. The mean current for ocean ESCs 0.41 A and the mean current for land ESCs is 0.13 A. We did not find any significant regional or latitudinal based patterns in our total conduction currents. By combining the aircraft derived storm currents and flash rates with diurnal flash rate statistics derived from the Lightning Imaging Sensor (LIS) and Optical Transient Detector (OTD) low Earth orbiting satellites, we reproduce the diurnal variation in the global electric circuit (i.e., the Carnegie curve) to within 4% for all but two short periods of time. The agreement with the Carnegie curve was obtained without any tuning or adjustment of the satellite or aircraft data. Given our data and assumptions, mean contributions to the global electric circuit are 1.1 kA (land) and 0.7 kA (ocean) from thunderstorms, and 0.22 kA (ocean) and 0.04 (land) from ESCs, resulting in a mean total conduction current estimate for the global electric circuit of 2.0 kA. Mean storm counts are 1100 for land thunderstorms, 530 for ocean ESCs, 390 for ocean thunderstorms, and 330 for land ESCs.

Mach, Douglas M.↗
NASA NTRS2009

Smoke Above Clouds

Aerosols in the atmosphere alter the radiative balance of the Earth by reflecting or absorbing solar radiation. Spaceborne measurements of clouds and aerosols advected over the southeastern Atlantic Ocean indicate that the greater the cloud cover below the aerosols, the more likely the aerosols are to heat the planet.

Remer, Lorraine A.↗
NASA NTRS2011

Using OMI Observations to Measure Aerosol Absorption of Biomass Burning Aerosols Above Clouds

The presence of absorbing aerosol layers above clouds is unambiguously detected by the TOMS/OMI UV Aerosol Index (AI) that uses satellite observations at two near-UV channels. A sensitivity study using radiative transfer calculations shows that the AI signal of resulting from the presence of aerosols above clouds is mainly driven by the aerosol absorption optical depth and the optical depth of the underlying cloud. Based on these results, an inversion algorithm has been developed to retrieve the aerosol optical depth (AOD) of aerosol layers above clouds. In this presentation we will discuss the sensitivity analysis, describe the retrieval approach, and present results of applications of the retrieval method to OMI observations over the South Atlantic Ocean. Preliminary error analyses, to be discussed, indicate that the AOD can be underestimated (up to -30%) or overestimated (up to 60%) depending on algorithmic assumptions.

Torres, Omar↗
NASA NTRS2006

Forecasting of Storm-Surge Floods Using ADCIRC and Optimized DEMs

Increasing the accuracy of storm-surge flood forecasts is essential for improving preparedness for hurricanes and other severe storms and, in particular, for optimizing evacuation scenarios. An interactive database, developed by WorldWinds, Inc., contains atlases of storm-surge flood levels for the Louisiana/Mississippi gulf coast region. These atlases were developed to improve forecasting of flooding along the coastline and estuaries and in adjacent inland areas. Storm-surge heights depend on a complex interaction of several factors, including: storm size, central minimum pressure, forward speed of motion, bottom topography near the point of landfall, astronomical tides, and, most importantly, maximum wind speed. The information in the atlases was generated in over 100 computational simulations, partly by use of a parallel-processing version of the ADvanced CIRCulation (ADCIRC) model. ADCIRC is a nonlinear computational model of hydrodynamics, developed by the U.S. Army Corps of Engineers and the US Navy, as a family of two- and three-dimensional finite-element-based codes. It affords a capability for simulating tidal circulation and storm-surge propagation over very large computational domains, while simultaneously providing high-resolution output in areas of complex shoreline and bathymetry. The ADCIRC finite-element grid for this project covered the Gulf of Mexico and contiguous basins, extending into the deep Atlantic Ocean with progressively higher resolution approaching the study area. The advantage of using ADCIRC over other storm-surge models, such as SLOSH, is that input conditions can include all or part of wind stress, tides, wave stress, and river discharge, which serve to make the model output more accurate. To keep the computational load manageable, this work was conducted using only the wind stress, calculated by using historical data from Hurricane Camille, as the input condition for the model. Hurricane storm-surge simulations were performed on an eight-node Linux computer cluster. Each node contained dual 2-GHz processors, 2GB of memory, and a 40GB hard drive. The digital elevation model (DEM) for this region was specified using a combination of Navy data (over water), NOAA data (for the coastline), and optimized Interferometric Synthetic Aperture Radar data (over land). This high-resolution topographical data of the Mississippi coastal region provided the ADCIRC model with improved input with which to calculate improved storm-surge forecasts.

Valenti, Elizabeth↗
NASA NTRS2009

Sensitivity of Boreal-Summer Circulation and Precipitation to Atmospheric Aerosols in Selected Regions: The Americas - Part 2

Aerosol perturbations over selected land regions are imposed in Version-4 of the Goddard Earth Observing System (GEOS-4) general circulation model (GCM) to assess the influence of increasing aerosol concentrations on regional circulation patterns and precipitation in four selected regions: India, Africa, and North and South America. Part 1 of this paper addresses the responses to aerosol perturbations in India and Africa. This paper presents the same for aerosol perturbations over the Americas. GEOS-4 is forced with prescribed aerosols based on climatological data, which interact with clouds using a prognostic scheme for cloud microphysics including aerosol nucleation of water and ice cloud hydrometeors. In clear-sky conditions the aerosols interact with radiation. Thus the model includes comprehensive physics describing the aerosol direct and indirect effects on climate (hereafter ADE and AIE respectively). Each simulation is started from analyzed initial conditions for 1 May and was integrated through June-July-August of each of the six years: 1982 1987 to provide a 6-ensemble set. Results are presented for the difference between simulations with double the climatological aerosol concentration and one-half the climatological aerosol concentration for three experiments: two where the ADE and AIE are applied separately and one in which both the ADE and AIE are applied. The ADE and AIE both yield reductions in net radiation at the top of the atmosphere and surface while the direct absorption of shortwave radiation contributes a net radiative heating in the atmosphere. A large net heating of the atmosphere is also apparent over the subtropical North Atlantic Ocean that is attributable to the large aerosol perturbation imposed over Africa. This atmospheric warming and the depression of the surface pressure over North America contribute to a northward shift of the inter-Tropical Convergence Zone over northern America, an increase in precipitation over Central America and the Caribbean, and an enhancement of convergence in the North American monsoon region.

Wilcox, E. M.↗
NASA NTRS2011

The Impact of Rise of the Andes and Amazon Landscape Evolution on Diversification of Lowland terra-firme Forest Birds

Since the 19th Century, the unmatched biological diversity of Amazonia has stimulated a diverse set of hypotheses accounting for patterns of species diversity and distribution in mega-diverse tropical environments. Unfortunately, the evidence supporting particular hypotheses to date is at best described as ambiguous, and no generalizations have emerged yet, mostly due to the lack of comprehensive comparative phylogeographic studies with thorough trans-Amazonian sampling of lineages. Here we report on spatial and temporal patterns of diversification estimated from mitochondrial gene trees for 31 lineages of birds associated with upland terra-firme forest, the dominant habitat in modern lowland Amazonia. The results confirm the pervasive role of Amazonian rivers as primary barriers separating sister lineages of birds, and a protracted spatio-temporal pattern of diversification, with a gradual reduction of earlier (1st and 2nd) and older (> 2 mya) splits associated with each lineage in an eastward direction. (The easternmost tributaries of the Amazon, the Xingu and Tocantins Rivers, are not associated with any splits older than > 2 mya). For the suboscine passerines, maximum-likelihood estimates of rates of diversification point to an overall constant rate over the past 5 my (up to a significant downturn at 300,000 y ago). This "younging-eastward" pattern may have an abiotic explanation related to landscape evolution. Triggered by a new pulse of Andean uplift, it has been proposed that modern Amazon basin landscapes may have evolved successively eastward, away from the mountain chain, starting approximately 10 mya. This process was likely based on the deposition of vast fluvial sediment masses, known as megafans, that may have extended progressively and in series eastward from Andean sources. This process plausibly explains the progressive extinction of original Pebas wetland of western-central Amazonia by the present fluvial landsurfaces of a more terra-firme type. The youngest landsurfaces thus lie furthest from the mountains. In this scenario major drainages were also reoriented in wholesale fashion away from a northerly orientation generally towards the east and an Atlantic Ocean outlet. The advance of megafans is best seen by the location of axial rivers such as the Orinoco and Mamore which lie against the cratonic margins furthest from the Andes, at the distal ends of major megafan ramparts. More importantly, other major river courses in western-central Amazonia will have been established at progressively younger dates with distance eastward. If this landscape-sequence scenario is accurate, it parallels the progressive younging of the passerine lineages. The bird DNA data appears to confirm strongly the pervasive role of Amazonian rivers--as primary barriers separating sister lineages of birds, and thus probably as facilitaters of bird speciation. We show for the first time that a general spatio-temporal pattern of diversification for terra-firme lineages in the Amazon is associated with rivers ("younging-eastward"), and furthermore parallels a specific scenario of regional drainage evolution.

Aleixo, Alexandre↗
NASA NTRS2004

Manned Spacecraft Landing and Recovery

As recent history has tragically demonstrated, a successful space mission is not complete until the crew has safely returned to earth and has been successfully recovered. It is noted that a safe return to earth does not guarantee a successful recovery. The focus of this presentation will be a discussion of the ground operation assets involved in a successful recovery. The author's experience in land and water-based recovery of crewed vehicles and flight hardware at Kennedy Space Center (KSC), Edwards Air Force Base, international landing sites, and the Atlantic Ocean provides for some unique insight into this topic. He has participated in many aspects of Space Shuttle landing and recovery operations including activation of Transatlantic Abort Landing (TAL) sites and Emergency Landing Sites (ELS) as an Operations Test Director, execution of post landing convoy operations as an Orbiter Move Director, Operations Test Director, and Landing and Recovery Director, and recovery of solid rocket boosters, frustum and their parachutes 140 miles offshore in a wide range of sea states as a Retrieval Diver/Engineer. The recovery operations for the Mercury, Gemini, and Apollo were similar from a landing and recovery perspective in th t they all were capsules with limited "flying" capability and had a planned End of Mission (EOM) in an ocean with a descent slowed by parachutes. The general process was to deploy swim teams via helicopters to prepare the capsule for recovery and assist with crew extraction when required. The capsule was then hoisted onto the deck of a naval vessel. This approach required the extensive use and deployment of military assets to support the primary landing zone as well as alternate and contingency locations. The Russian Soyuz capsule also has limited "flying" capability; however, the planned EOM is terrestrial. In addition to use of parachutes to slow the reentry descent, soft-landing rockets on the bottom of the vehicle are employed to cushion the landing. The recovery forces are deployed via helicopters and the capsule is transported by a specialized all-terrain vehicle. The Space Shuttle Orbiter landing and recovery process is considerably different. The added lift capability and maneuverability allow the Orbiter to land at an exact location/runway for a nominal EOM. This allows for a timely response of recovery/contingency rescue forces, centralized staging of personnel and equipment, and assured access by ground vehicles. The well defined landing zone also provides for far more options when selecting landing sites for EOM and emergency returns and the relatively large cross-range capability increases the number of landing opportunities at the preferred sites.

Hammel, Don↗
NASA NTRS2004

Electrochemical Impedance Spectroscopy of Alloys in a Simulated Space Shuttle Launch Environment

Type 304L stainless steel (304L SS) tubing is currently used in various supply lines that service the Orbiter at NASA's John F. Kennedy Space Center Launch Pads in Florida (USA). The atmosphere at the Space Shuffle launch site is very corrosive due to a combination of factors, such as the proximity of the Atlantic Ocean and the concentrated hydrochloric acid produced by the fuel combustion reaction in the solid rocket boosters. The acidic chloride environment is aggressive to most metals and causes severe pitting in many of the common stainless steel alloys such as 304L SS. Stainless steel tubing is susceptible to pitting corrosion that can cause cracking and rupture of both high-pressure gas and fluid systems. Outages in the systems where failures occur can impact the normal operation of the shuttle and launch schedules. The use of a more corrosion resistant tubing alloy for launch pad applications would greatly reduce the probability of failure, improve safety, lessen maintenance costs, and reduce downtime. A study which included ten alloys was undertaken to find a more corrosion resistant material to replace the existing 304L SS tubing. The study included atmospheric exposure at NASA's John F. Kennedy Space Center outdoor corrosion test site near the launch pads and electrochemical measurements in the laboratory which included DC techniques and electrochemical impedance spectroscopy (EIS). This paper presents the results from EIS measurements on three of the alloys: AL6XN (UN N08367), 254SMO (UNS S32l54), and 304L SS (UNS S30403). Type 304L SS was included in the study as a control. The alloys were tested in three electrolyte solutions which consisted of neutral 3.55% NaC1, 3.55% NaCl in O.1N HC1, and 3.55% NaCl in 1.ON HC1. The solutions were chosen to simulate environments that were expected to be less, similar, and more aggressive, respectively, than those present at the Space Shuttle launch pads. The results from the EIS measurements were analyzed to evaluate the corrosion susceptibility of the alloys and to predict the long-term corrosion performance of the subject materials. The results from the EIS measurements for the three alloys indicated that the higher-alloyed 254SMO and AL6XN exhibited a significantly improved resistance to corrosion than the 304L SS as the concentration of hydrochloric acid in the 3.55% NaC1 solution was increased. The polarization resistance values obtained from the EIS measurements were consistent with those from linear polarization measurements, and were indicative of the actual long-term corrosion performance of the alloys during a two-year atmospheric exposure study.

Calle, L. M.↗
NASA NTRS2004

Role of EIS in Materials and Coatings Selection for NASA's Launch Facilities

Corrosion studies began at NASA's John F. Kennedy Space Center (KSC) in 1966, during the Gemini/Apollo Programs, with the evaluation of long-term anti-corrosion coatings for carbon steel structures. NASAIKSC's Atmospheric Exposure Test Site was established at that time on the beach near the launch pad. In the years that followed, numerous studies at the site have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. The atmosphere at the launch pad is highly corrosive due to the proximity of the Atlantic Ocean, high heat from rocket exhaust, and since the introduction of the Space Shuttle, the acidic combustion products of the Solid Rocket Boosters (SRBs). Currently, NASAIKSC maintains about $2 billion worth of unique equipment and facilities, not including the orbiters, each valued at about $1.8 billion. Among the items: two launch complexes, two crawler transporters, three mobile launch platforms, and specialized testing equipment. Atmospheric exposure provides very valuable data but it takes a long time and relies on human visual inspection. NASA Technical Standard for Protective Coatings requires 18 months of good performance at the Atmospheric Exposure Test Site for preliminary approval and continued good performance for 5 years for final approval of a coating system. The use of electrochemical impedance spectroscopy (EIS) was introduced at KSC in 1989 as a supplement to the traditional dc electrochemical techniques and atmospheric exposure studies. This paper presents and overview of several projects in which EIS was used in order to select materials and coatings to be used at NASA's launch facilities [1-2].

Calle, Luz Marina↗