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At least 667 records · Page 37

Ejection of atoms and molecules from Io by plasma-ion impact

The directions and energy distributions of neutral atoms and molecules ejected from Io are modeled analytically. The particles are emitted from the Io exosphere by collisions of incident plasma ions. Some of the Io atmosphere is attributed to particles sputtered off the surface by incoming plasma ions, while other departing particles originate at the top of volcanic plumes. Account is taken of the thermal motion of incident plasma and Io's gravitational field when calculating the distribution of the ejected particles. The distributions associated with each type of ejection force are projected to be different and highly dependent on the inclusion of realistic cross-sections. Attention is focused on Na-rich species and defining ejection processes which can be verified with ground-based observations. It is, however, concluded that no particles are ejected directly from the surface by Jean's escape.

Sieveka, E. M.↗

International Cosmic Ray Conference, 13th, University of Denver, Denver, Colo., August 17-30, 1973, Proceedings. Volumes 1 & 2

Topics discussed include diffuse gamma rays, gamma ray sources (in particular, the Crab Nebula and Crab Pulsar), X-ray sources, isotopic and nuclear composition, spectra of nuclei, searches for antinuclei, studies of VH and VVH nuclei, measurements of electrons and positrons, the spectra of high-energy electrons, cosmic gamma rays, cosmic ray sources, interplanetary radial gradients, the theory and observation of electron modulation, short-period cosmic ray intensity variations, atmospheric and coupling effects on neutron monitors and muon telescopes, secondary particles and photons in the atmosphere, harmonics of diurnal variations, geomagnetic effects and cutoffs, planetary and interplanetary effects, solar particle access observations, long-term cosmic ray intensity modulation by solar activity and interplanetary effects, Forbush decreases, modulation and anisotropy of low-energy particles, the theory and models of solar particle propagation, solar flare particle composition, and relativistic solar particles. Individual items are announced in this issue.

Source record↗

Solar He-3: Information from nuclear reactions in flares

Information on solar He-3 from nuclear reactions in flares was considered. Consideration was also given to the development of models for these reactions as well as the abundance of He-3 in the photosphere. Data show that abundances may be explained by nuclear reactions of flare acceleration protons and alpha particles with the ambient atmosphere, provided that various assumptions are made on the directionality of the interacting beams and acceleration of the particles after production.

Ramaty, R.↗

Estimating mass-absorption cross-section of ambient black carbon aerosols: theoretical, empirical, and machine learning models

The mass-absorption cross-section of black carbon (MAC BC ) is an essential parameter to link the atmospheric concentration of black carbon (BC) with its radiative forcing. When a direct calculation of MAC BC based on observations of aerosol light absorption and BC mass concentration is impossible, we rely on modeling and simulations to estimate MAC BC , but currently, there is no consensus model that can be relied on for accurate predictions across all atmospheric environments when BC particles have different coating thicknesses. Here, we applied five MAC BC prediction models (including three light scattering theories, an empirical model based on observations of particle mass concentrations, and a machine learning model developed in our previous work) to aerosols from three Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) field campaigns. While many studies have found that increasing the complexity of the models helps to constrain biases of the estimated MAC BC , our effort is to evaluate the models based on the criteria of simplicity and accuracy. We find that our machine learning model (support vector machine for regression, SVM) generally performs well across all DOE ARM field campaign data, while the accuracy of core-shell Mie theory depends on the bias correction algorithm applied to filter-based light absorption data. Generally, the empirical model for internally-mixed particles that we considered tends to over-predict MAC BC , while Mie theory for externally-mixed particles tends to under-predict MAC BC . An examination of the influence of coating material on BC cores suggests that the performance of our current SVM model is degraded when the BC is thickly-coated (e.g., it has undergone aging and mixing with other materials in the atmosphere).

54 ENVIRONMENTAL SCIENCES↗

Laboratory investigations of the aerosols in the stratosphere of Titan

Results of experiments in which particles were produced from UV photolysis of C2H2, C2H4, or HCN, separately or in mixtures, modeling Titan's upper atmosphere, are presented. The particles were collected on disks and examined by Scanning Electron Microscopy (SEM). Measurements of particle sizes and shapes and of aggregation were determined from the SEM photographs.

Scattergood, Thomas W.↗

Characterization of carbonaceous aerosols during TRACER-CAT

Absorbing aerosols (AA) have an important impact on the global radiation budget and cloud properties. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which coatings in general, and water uptake especially, alters absorption by AA particles and how this depends on particle composition. We deployed new and existing experimental tools during the Tracking Aerosol Convection Interactions Experiment (TRACER) campaign in Houston, TX as part of the Carbonaceous Aerosols Thrust (CAT) to provide detailed characterization of aerosol optical, chemical, and physical properties. Our TRACER-CAT measurements complemented and expanded on the planned TRACER instrumentation, allowing for more detailed characterization of aerosol properties of relevance to cloud development (a core focus of TRACER), such as the composition of particles that can act as cloud condensation nuclei, than would otherwise be available. Our measurements have allowed for assessment of the relationship(s) between AA optical properties (with a focus on absorption) and the chemical and physical characteristics (including the mixing state of black carbon (BC) containing particles). These field observations occurred in collaboration with Los Alamos National Laboratory in summer 2022 during the TRACER intensive operating period. The instrumentation we co-deployed provided for measurement of (i) multi-wavelength dry aerosol absorption, scattering, and extinction, (ii) the size-dependent composition and abundance of sub-micron aerosol, differentiating between those particles that do and do not contain BC, (iii) BC-specific concentrations and size distributions, (iv) particle size, and (v) the first field measurements at an ARM site of the influence of RH on multi-wavelength absorption by ambient AA. We have leveraged the natural variability of the atmosphere and of aerosol sources in the Houston region to (i) specifically disentangle contributions to light absorption from BC, absorbing organic carbon (brown carbon), and coatings on BC, (ii) characterize the mixing state of BC and assess the factors that give rise to compositional differences between BC-containing and BC-free aerosol, and (iii) establish how water uptake influences absorption and how any such effect depends on particle composition and BC mixing state. Overall, our study contributed to the mission of the Atmospheric System Research program in multiple ways. Through the deployment of complementary, advanced instrumentation for characterization of a wide range of aerosol properties our work helped to maximize the scientific impact of the TRACER campaign. Our work also allowed for development of new insights into the relationship(s) between aerosol composition, hygroscopicity, and the mixing state of BC with aerosol optical properties. Through this, our work has provided knowledge that can improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES↗

The meteorology of Jupiter

From the point of view of meteorology the most important differences between Jupiter and the earth are related to the fact that Jupiter has an appreciable internal energy source and probably lacks a solid surface. The composition and vertical structure of the Jovian atmosphere is considered along with the composition of Jovian cloud particles, turbulence in Jupiter's atmosphere, data on the horizontal structure and motions of the atmosphere, and questions related to the longevity of Jupiter's clouds. Attention is given to the barotropic characteristics of Jupiter's atmosphere, the radiation balance in the atmosphere of the earth and of Jupiter, and studies of the Great Red Spot.

Ingersoll, A. P.↗

OCS, stratospheric aerosols and climate

The carbonyl sulfide budget in the atmosphere is examined, and the effects of stratospheric sulfate aerosol particles, formed in part from atmospheric carbonyl sulfate, on global climate are considered. From tropospheric measurements of carbon disulfide and the rate constant for the conversion of carbon disulfide to carbonyl sulfide, it is estimated that five Tg of carbonyl sulfide/year could be generated from carbon disulfide in the atmosphere. Direct sources of OCS include the refining and combustion of fossil fuels (1 Tg/year), natural and agricultural fires (0.2 to 0.3 Tg/year), and soils (0.5 Tg/year), yielding a total influx of from 1 to 10 Tg/year, up to 50% of which may be anthropogenic. Considerations of carbonyl sulfide sinks and concentrations indicate an atmospheric lifetime of one year, with OCS the major atmospheric sulfur compound. It is estimated that a ten-fold increase in atmospheric carbonyl sulfide would cause an optical depth perturbation comparable to that of a modest volcanic eruption, leading to an average global surface temperature decrease of 0.1 K, in addition to a possible greenhouse effect.

Turco, R. P.↗

Space Launch Vehicle Transient Particle Redistribution Modeling and Implications for Optically Sensitive Payloads

The performance of contamination sensitive components—such as optical components—can be degraded by particulate matter depositing on the surfaces. Particles can accumulate during manufacturing, handling and operation. For a space-based system, particles can shed from the fairing and redistribute onto sensitive surfaces during launch. An engineering modeling approach has been developed for modeling particle migration during launch. The approach involves particle detachment from the fairing, particle transport through the venting atmosphere inside the fairing, and attachment to the receiving surface. Particle size and amounts on the fairing surface can be modeled using distributions from standards, such as IEST-STD-CC1246E, as well as from empirical data obtained from tape lifts. Surface interactions are modeled using theoretical as well as empirical data. Commercial computational fluid dynamics codes are used to calculate the gas flow in the fairing during depressurization during launch. This approach not only provides insight into particle redistribution during launch but also can be used to establish fairing cleanliness requirements.

Brieda, Lubos↗

Cratering on Titan: A Pre-Cassini Perspective

The NASA-ESA Cassini mission, comprising a formidably instrumented orbiter and parachute-borne probe to be launched this October, promises to reveal a crater population on Titan that has been heretofore hidden by atmospheric haze. This population on the largest remaining unexplored surface in the solar system will be invaluable in comparative planetological studies, since it introduces evidence of the atmospheric effects of cratering on an icy satellite. Here, I highlight some impact features we may hope to find and could devote some modeling effort toward. Titan in a Nutshell: Radius= 2575 km. Density= 1880 kg/cubic m consistent with rock-ice composition. Surface pressure = 1.5 bar. Surface gravity = 1.35 m/square s Atmosphere -94% N2 6% CH, Surface temperature = 94K Tropopause temperature = 70K at 40 km alt. Probable liquid hydrocarbon deposits exist on or near the surface.Titan in a Nutshell: Radius= 2575 km. Density= 1880 kg/cubic m consistent with rock-ice composition. Surface pressure = 1.5 bar. Surface gravity = 1.35 m/square s; Atmosphere about 94% N2 6% CH, Surface temperature = 94K Tropopause temperature = 70K at 40 km alt. Probable liquid hydrocarbon deposits exist on or near the surface. Titan is comparable to Callisto and Ganymede for strength/gravity, Mars/Earth/Venus for atmospheric interaction, and Hyperion, Rhea, and Iapetus for impactor distribution. The leading/trailing asymmetry of crater density from heliocentric impactors is expected to be about 5-6, in the absence of resurfacing. Any Saturnocentric impactor population is likely to alter this. In particular the impact disruption of Hyperion is noted; because of the 3:4 orbital resonance with Titan, fragments from the proto-Hyperion breakup would have rapidly accreted onto Titan. Titan's resurfacing history is of course unknown. The disruption of impactors into fragments that individually create small craters is expected to occur. A crude estimate suggests a maximum separation of about 2 km (compared with 4 km on Venus, or 0.5 km on Earth). Crater chains are unlikely on Titan, since impactors must pass close enough to Saturn to be tidally disrupted; as a result, they would suffer aerodynamic disruption. Crater counting on adjacent satellites gives densities of about 200 per 10 (exp 6) square km for 20-km-diameter craters. However, the presence of a thick atmosphere leads to atmospheric shielding, depleting the relative abundance of small craters. This has been evaluated by models, and the relative abundance of small craters may be due to a diagnostic atmospheric collapse. A number of radar-dark "splotches" have been detected on Venus; these have been attributed to the interaction of the surface with the atmospheric shockwave produced by the Tunguska-like explosion of a bolide in the atmosphere. Simple analogy suggests that similar features might occur on Titan, but the shocked mass density (which controls the momentum coupling between the surface and the shockwave) of Titan's cold N2 atmosphere is about 20x smaller than that of Venus's hot CO2 atmosphere. Unless ice is much more easily turned to rubble than is rock, such features seem less probable on Titan. When the energy deposited by an impact forms a fireball with an equilibrate greater than one scale height, the fireball expands upward and can distribute ejecta. on ballistic exoatmospheric trajectories. On Venus this process is believed to be responsible for the parabolic features; the interaction of various-sized particles falling through the atmosphere with the zonal wind field winnows the particles to form a parabolic deposit. Although such a process is possible on Titan, the large scale height at higher altitudes would make it more difficult. Comparison with craters on other icy satellites suggests that craters on Titan will be fairly shallow (depth/diameter about 0.1) and craters greater than 10 km in diameter will have central peaks or domed bases, perhaps with central pits. The formation of ejecta. blankets may involve the atmosphere in a significant way, both by restraining the expansion of the ejecta cloud and by influencing the thermal history of the ejecta. Compared with Venus, Titan's atmosphere will chill an impact melt somewhat quickly, so the long ejecta flows seen on Venus seem less likely, detailed modeling needs to be performed to determine the impact melt production. Crater topography on Titan may be highlighted by the influence of liquids forming crater lakes. Craters with central peaks will typically form ring-shaped lakes, although horseshoe-shaped takes may be common; domed craters with central pits may even form bullseye lakes with islands with central ponds. If liquids have covered a substantial part of Titan's surface for a substantial period, hydroblemes and tsunami deposits may be common.

Lorenz, R. D.↗

Direct measurement of small particle growth and aging at SGP

Atmospheric aerosols influence climate directly by scattering and absorbing solar radiation and indirectly through their influence on the reflectivity and lifetime of clouds. But that influence is limited to only those particles large enough to efficiently interact with solar radiation (diameter, D p ≳ 100 nm) and/or to form cloud droplets at typical atmospheric supersaturations (D p ≳ 50 nm). Many cloud condensation nuclei (CCN) originate as ~1 nm nucleated particles that must grow to those threshold sizes before being lost to coagulation with larger particles. Though there is consensus that new particle formation and growth contributes significantly to total CCN concentrations, different groups using different models and assumptions have arrived at diverse estimates.

54 ENVIRONMENTAL SCIENCES↗

On Lidar Sounding of the Atmosphere to Estimate Static and Dynamic Characteristics of Aerosol Inhomogeneities

1. A possible application of intensity fluctuations of a pulse light signal reflected by atmospheric aerosols is analyzed by the correlation method to evaluate static (medium sizes, shape) and dynamic (speed and direction of movement, lifetime) characteristics of aerosol inhomogeneities. The aerosol inhomogeneities are assumed to be expanded, pressed, disintegrated and originated constantly in accordance with random laws, the set of inhomogeneities as a whole traveling together with air masses and having predominant movement in wind direction. It is shown that the characteristics of aerosol inhomogeneities considered can be expressed by the coefficients of the correlation function expansion of the reflected signal fluctuation intensity in Tailor series. 2/ Correlation systems for evaluating static and dynamic characteristics of driving objects can be divided into two types according to the kind and quantity of used information: the systems with coordinates of the information removal "points" to be fixed in space, and the systems with a parallel simultaneous information removal at discrete moments of time. The systems for determination of wind direction considered in are the examples of the first type system. However, the operating information removal for two points is insufficient to estimate completely static and dynamic characteristics of inhomogenities, their quantity ought to be increased up to three of them for two-dimensional problem and up to four of them for three-dimensional problem as it is usually done in the ionospheric studies. The second type systems are used for the investigation of a medium shape and speed of the clouds according to photographs made from satellites. These systems are also used for solution of navigation problems. The use of optical quantum generators with a scanning beam is seen to increase greatly the working information removal in comparison with the first type systems. Nevertheless, scanning rate is not sufficient sometimes in order· to consider a general picture of aerosol inhomogeneities to be stationary. In this connection the use of the systems of second type treatment becomes a matter of essential difficulty. 3. Aerosol inhomogeneities simulation has been carried out on the basis of the digital computer experiments with the aim of estimating static and dynamic characteristics of inhomogeneities by an optical beam in the atmosphere at different scanning procedures. The dependence of determination accuracy of these characteristics on the type of chosen laws of aerosol particle distribution in the atmosphere, the parameters of inhomogeneities geometry, their speed and the law of scanning have been obtained.

Zuev, V. E.↗

Airborne particle monitoring by electrostatic precipitation

For qualitative analysis of atmospheric particulates by microscopy, the sampling device should preserve the particles in the state existing at the moment of capture. A collector is described that uses electrostatic precipitation to capture and disperse specimens on various substrates for direct insertion into microscopes. Sampling runs in various atmospheres are described. Micrographs are presented to show particle morphology and distribution on the substrates. Chemical identification by X-ray energy probe and electron diffraction is illustrated.

Robinson, J. C.↗

Multimodal Chemical Characterization of Brown Carbon in Atmosphere and Snowpack during SAIL Field Campaign Report

The main goal of this field project was to characterize the chemical and physical properties of light-absorbing particles (LAP) present in the atmosphere and snowpack. The specific field efforts included: 1) online measurement and sampling of light-absorbing particles using a Magee Scientific model AE33 aethalometer (AE33) and a time-resolved aerosol collector (TRAC); and 2) sampling of snowpack during observed events of LAP deposition on snow, confirmed by onsite U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility measurements and meteorological data. The ongoing research objectives of our follow-up sample and data analysis include: 1) Characterization of aerosol regimes and sources, identifying particle-type populations, mixing states, and atmospheric transformations based on correlative analysis of our detailed chemical imaging and chemical characterization measurements and real-time records from the second ARM Mobile Facility (AMF2) and other instruments available from the Surface Atmosphere Integrated Field Laboratory (SAIL) experiment; 2) Assessment of the optical and chemical properties of snowpack deposits to investigate how aerosol deposition influences snowpack lifetime.

54 ENVIRONMENTAL SCIENCES↗

Detection of Aerosols at Microbar Pressures in an Exoplanet Atmosphere

The formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra; however observational evidence of aerosols in the low-pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at ~1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with the Space Telescope Imaging Spectrograph and Wide Field Camera 3 instruments on the Hubble Space Telescope. The transmission spectrum shows a wavelength-dependent slope induced by aerosol scattering that covers 11 scale heights of spectral modulation. Drawing on the extensive studies of haze in our solar system, we model the transmission spectrum based on a scaled version of Jupiter’s haze-density profile to show that the WASP-69b transmission spectrum can be produced by scattering from an approximately constant density of particles extending throughout the atmospheric column from 40 millibar to microbar pressures. These results are consistent with theoretical expectations based on microphysics of the aerosol particles that have suggested haze can exist at microbar pressures in exoplanet atmospheres.

47 OTHER INSTRUMENTATION↗

Quantifying the Diversity of an Atmospheric Aerosol Population in an Arctic Oil Field on a Single‐Particle Level

As the Arctic rapidly warms, sea ice extent is decreasing and oil and gas extraction activities are expanding. Local combustion emissions affect the Arctic atmospheric aerosol chemical mixing state (the distribution of chemical species across the aerosol population), which impacts climate-relevant properties. Bulk and single-particle measurements of submicron aerosols were conducted at Oliktok Point, Alaska within the North Slope of Alaska oil fields. In this work, we quantify aerosol diversity using online single-particle mass spectrometry data (32,880 individual particles), offline single-particle microscopy data (20,912 individual particles), and online bulk aerosol mass spectrometry and aethalometer data. This method was used to derive individual particle mass fractions for both refractory and non-refractory material within distinct particle types. Single-particle, average single-particle, and bulk population diversities (D i , D α , D γ , respectively) and mixing state indices (χ) were calculated for the data set. Calculated D i values were generally low (2.2 ± 0.6), as individual particle masses were dominated by a few chemical species of interest. Aged aerosol particles (those internally mixed with nitrate and/or sulfate) exhibited higher D i values (>3) compared to recently emitted (fresh) aerosol particles. During oil field plume periods, D α values approached three due to the abundance of diesel combustion particles, which were rich in sulfate, black carbon, and organic aerosol. Overall, the submicron aerosol population within the Arctic oil fields was found to be relatively externally mixed (χ < 50%), due to the constant local emissions within oil fields combining with background aerosol and locally emitted sea spray aerosol at the coastal site.

Wu, J.↗