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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS1959

Lubricating Properties of Lead-Monoxide-Base Coatings of Various Compositions at Temperatures to 1250 F

A number of ceramic coatings of different compositions containing lead monoxide (PbO) were studied to determine their relative merits as dry-film lubricants. Lead monoxide is known to be an effective solid lubricant at elevated temperatures, and this oxide was the main component in all compositions studied. Friction and wear properties were determined at temperatures from 750 to 1250 F, at a sliding velocity of 430 feet per minute, and at a normal load of 1 kilogram. In all of the coatings, PbO was the component primarily responsible for the lubricating properties. Oxides other than PbO had an indirect effect on lubrication by influencing such properties as adhesion, hardness, vitrifying or glaze-forming tendency, melting or softening point, and chemical stability of the coatings. Notable among these oxides were magnetite (Fe3O4.), which had generally a beneficial influence on ceramic- to-metal adhesion, and silica (SiO2), which inhibited the oxidation of PbO and enhanced the tendency for glaze formation on the sliding surfaces. Several of the compositions studied provided protection against metal-to-metal adhesive wear, galling, or seizure at test temperatures from 750 to 1250 F. Coating friction coefficients ranged from 0.20 to 0.37 at 75 F but were around 0.08 to 0.20 at temperatures of 1250 F.

Sliney, Harold E.↗
NASA NTRS2000

Silicon-Based Ceramic-Matrix Composites for Advanced Turbine Engines: Some Degradation Issues

SiC/BN/SiC composites are designed to take advantage of the high specific strengths and moduli of non-oxide ceramics, and their excellent resistance to creep, chemical attack, and oxidation, while circumventing the brittleness inherent in ceramics. Hence, these composites have the potential to take turbine engines of the future to higher operating temperatures than is achievable with metal alloys. However, these composites remain developmental and more work needs to be done to optimize processing techniques. This paper highlights the lingering issue of pest degradation in these materials and shows that it results from vestiges of processing steps and can thus be minimized or eliminated.

Thomas-Ogbuji, Linus U. J.↗
NASA NTRS2000

Ground-Based Measurements of Stratospheric Composition from Mt. Barcroft, California

The MkIV is an FTIR spectrometer designed and built at JPL in the 1980's for remote sensing the composition of the Earth's atmosphere by solar absorption spectrometry. Optically, MkIV is very similar to the JPL ATMOS instrument, which flew three times on the Space Shuttle. Both use double-passed configurations with a KBr beamsplitter and compensator, in order to cover the mid-infrared. The main advantage of the MkIV is that it uses two detectors in parallel, a HgCdTe photoconductor for the long wavelengths and an InSb photodiode for the short wavelengths, allowing the entire 650 to 5650/cm region to be measured simultaneously. At a 10 kHz sampling rate, each 130 cm OPD interferogram takes 3 minutes to acquire. This paper describes how the MkIV instrument was adapted for remote operation from the Barcroft site, where the harsh winter conditions make access difficult. Some of the main technical challenges will be discussed including, (i) operation from solar panels and batteries, (ii) cooling the detectors with LN2, (iii) instrument control and monitoring over a cellular phone, and (iv) data storage, processing and analysis. Finally, MkIV spectra measured from Barcroft are compared with those measured from JPL to highlight the advantages of the higher altitude site.

Toon, G. C.↗
NASA NTRS2001

A Component-based Programming Model for Composite, Distributed Applications

The nature of scientific programming is evolving to larger, composite applications that are composed of smaller element applications. These composite applications are more frequently being targeted for distributed, heterogeneous networks of computers. They are most likely programmed by a group of developers. Software component technology and computational frameworks are being proposed and developed to meet the programming requirements of these new applications. Historically, programming systems have had a hard time being accepted by the scientific programming community. In this paper, a programming model is outlined that attempts to organize the software component concepts and fundamental programming entities into programming abstractions that will be better understood by the application developers. The programming model is designed to support computational frameworks that manage many of the tedious programming details, but also that allow sufficient programmer control to design an accurate, high-performance application.

Eidson, Thomas M.↗
NASA NTRS2001

The Seyfert-Starburst Connection in X-rays: Results and Implications - 2

We present the results of X-ray imaging and spectroscopic analysis of a sample of Seyfert 2 galaxies that contain starbursts, based on their optical and UV characteristics. These composite galaxies exhibit extended, soft, thermal X-ray emission, which we attribute to their starburst components. Comparing their X-ray and far-infrared properties with ordinary Seyfert and starburst galaxies, we identify the spectral characteristics of their various intrinsic emission sources. The observed far-infrared emission of the composite galaxies may be associated almost exclusively with star formation, rather than the active nucleus. The ratio of the hard X-ray luminosity to the far-infrared and [O III] (lambda)5007 luminosity distinguishes most of these composite galaxies from "pure" Seyfert 2 galaxies, while their total observed hard X-ray luminosity distinguishes them from "pure" starbursts. The hard nuclear X-ray source is generally heavily absorbed (N(sub H) greater than 10(exp 23)/sq cm) in the composite galaxies. Based on these results, we suggest that the interstellar medium of the nuclear starburst is a significant source of absorption. The majority of the sample are located in groups or are interacting with other galaxies, which may trigger the starburst or allow rapid mass infall to the central black hole or both. We conclude that starbursts are energetically important in a significant fraction of active galaxies and that starbursts and active galactic nuclei may be part of a common evolutionary sequence.

Levenson, N. A.↗
NASA NTRS2013

Multi-Scale CNT-Based Reinforcing Polymer Matrix Composites for Lightweight Structures

Reinforcing critical areas in carbon polymer matrix composites (PMCs), also known as fiber reinforced composites (FRCs), is advantageous for structural durability. Since carbon nanotubes (CNTs) have extremely high tensile strength, they can be used as a functional additive to enhance the mechanical properties of FRCs. However, CNTs are not readily dispersible in the polymer matrix, which leads to lower than theoretically predicted improvement in mechanical, thermal, and electrical properties of CNT composites. The inability to align CNTs in a polymer matrix is also a known issue. The feasibility of incorporating aligned CNTs into an FRC was demonstrated using a novel, yet commercially viable nanofiber approach, termed NRMs (nanofiber-reinforcing mats). The NRM concept of reinforcement allows for a convenient and safe means of incorporating CNTs into FRC structural components specifically where they are needed during the fabrication process. NRMs, fabricated through a novel and scalable process, were incorporated into FRC test panels using layup and vacuum bagging techniques, where alternating layers of the NRM and carbon prepreg were used to form the reinforced FRC structure. Control FRC test panel coupons were also fabricated in the same manner, but comprised of only carbon prepreg. The FRC coupons were machined to size and tested for flexural, tensile, and compression properties. This effort demonstrated that FRC structures can be fabricated using the NRM concept, with an increased average load at break during flexural testing versus that of the control. The NASA applications for the developed technologies are for lightweight structures for in-space and launch vehicles. In addition, the developed technologies would find use in NASA aerospace applications such as rockets, aircraft, aircraft/spacecraft propulsion systems, and supporting facilities. The reinforcing aspect of the technology will allow for more efficient joining of fiber composite parts, thus offering additional weight savings. More robust structures capable of withstanding micrometeoroid and space debris impacts will be possible with the enhanced mechanical properties imparted by the aligned CNTs incorporated into the fiber composite structure, as well as the potential for improved electrical and thermal properties. The materials fabrication approach developed in the present effort is a platform for customer applications where additional reinforcement is required or would be beneficial, especially in FRC structures and component parts. Depending upon the specific customer application, the NRM could be tailored to the specific matrix resin and desired property enhancement.

Eberly, Daniel↗
NASA NTRS2021

First Comet Observations with NIRSPEC-2 at Keck: Outgassing Sources of Parent Volatiles and Abundances Based on Alternative Taxonomic Compositional Baselines in 46P/Wirtanen

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets and whether systematic differences exist in the release of these species compared to H2O and CH3OH. Abundances of volatiles are reported relative to H2O, as traditionally done, as well as C2H6. While not unique, the choice of C2H6 demonstrates the value of extending the chemical taxonomy of parent volatiles in comets toward additional compositional "baselines" and, importantly, closer integration between coma abundances and the underlying volatile associations as revealed by spatial distributions. Our findings on composition and sources of outgassing include information relevant to future evaluations of 46P/Wirtanen as a prospective spacecraft target.

Boncho P. Bonev↗
DOE OSTI2020

Durable polymer-aerogel based superhydrophobic coatings: a composite material

Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140° and a contact angle hysteresis of less than about 1°. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

Kissel, David J.↗
DOE OSTI2023

CO2 Sorption in Aminopolymer-Based Direct Air Capture Composites Through Fluorescent Detection

Aminopolymer-mesoporous oxide composites are becoming widely recognized for their ability to adsorb CO2 directly from the air. However, a better fundamental understanding of the nature of these materials under different environmental operating conditions will be necessary before they become ubiquitous in industrial direct air capture (DAC) systems. For example, gas diffusion in general is coupled with polymer segmental mobility in these composites; diffusion is therefore affected by interactions of the polymer with the pore wall of the mesoporous oxide, by the relative humidity of the air, and by electrostatic crosslinks that develop as a function of CO2 sorption. Disentangling these and additional complicated effects in order to better optimize operating conditions is a major challenge for the field. Here, we present a method for quantifying the adsorption of CO2 and moisture in a polyethylenimine (PEI) - Al2O3 composite using infrared sensing while we simultaneously monitor polymer mobility with a fluorescent probe molecule doped into the composite. Both the fluorescence intensity and shape of the emission spectra are strongly dependent on the mobility of the supporting medium. We monitor the polymer mobility and CO2 adsorption kinetics across a series of different relative humidities (RH) with this technique, and we observed that the relative difference between polymer mobility and sorption kinetics from one RH to the next are quite dramatic. We interpret these results and discuss how they can be used to inform the design of more efficient DAC systems for real-world operating conditions.

carbon capture↗
NASA NTRS1985

The influence of cobalt, tantalum, and tungsten on the elevated temperature mechanical properties of single crystal nickel-base superalloys

The influence of composition on the tensile and creep strength of 001-line oriented nickel-base superalloy single crystals at temperatures near 1000 C was investigated. Cobalt, tantalum, and tungsten concentrations were varied according to a matrix of compositions based on the single crystal version of MAR-M247. For alloys with the baseline refractory metal level of 3 wt pct Ta and 10 wt pct W, decreases in Co level from 10 to 0 wt pct resulted in increased tensile and creep strength. Substitution of 2 wt pct W for 3 wt pct Ta resulted in decreased creep life at high stresses, but improved life at low stresses. Substitution of Ni for Ta caused large reductions in tensile strength and creep resistance, and corresponding increases in ductility. For these alloys with low Ta-plus-W totals, strength was independent of Co level. The effects of composition on properties were related to the microstructural features of the alloys. In general, high creep strength was associated with high levels of gamma-prime volume fraction, gamma-gamma-prime lattice mismatch, and solid solution hardening.

Nathal, M. V.↗
DOE OSTI2021

Compounds for central reactivation of organophosphorus-based compound-inhibited acetylcholinesterase and/or inactivation of organophosphorus-based acetylcholinesterase inhibitors and related compositions methods and systems for making and using them

Described herein are oxime compounds capable of inactivating OP-based AChE inhibitors, crossing the blood brain barrier (BBB), and/or reactivation of OP-inhibited acetylcholinesterase (AChE) and related methods, systems and compositions for inactivation of one or more OP-based AChE inhibitors, therapeutic and/or prophylactic treatment of an individual, and/or decomposition of OP-based AChE inhibitors for decontamination.

Valdez, Carlos A.↗
NASA NTRS2001

Reliability Analysis and Reliability-Based Design Optimization of Circular Composite Cylinders Under Axial Compression

This report describes the preliminary results of an investigation on component reliability analysis and reliability-based design optimization of thin-walled circular composite cylinders with average diameter and average length of 15 inches. Structural reliability is based on axial buckling strength of the cylinder. Both Monte Carlo simulation and First Order Reliability Method are considered for reliability analysis with the latter incorporated into the reliability-based structural optimization problem. To improve the efficiency of reliability sensitivity analysis and design optimization solution, the buckling strength of the cylinder is estimated using a second-order response surface model. The sensitivity of the reliability index with respect to the mean and standard deviation of each random variable is calculated and compared. The reliability index is found to be extremely sensitive to the applied load and elastic modulus of the material in the fiber direction. The cylinder diameter was found to have the third highest impact on the reliability index. Also the uncertainty in the applied load, captured by examining different values for its coefficient of variation, is found to have a large influence on cylinder reliability. The optimization problem for minimum weight is solved subject to a design constraint on element reliability index. The methodology, solution procedure and optimization results are included in this report.

Rais-Rohani, Masoud↗