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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Shape memory behavior and recovery force of 4D printed textile functional composites

Four-dimensional (4D) printing of multi-directionally reinforced preforms has tremendous potential for the development of next generation functional composites by using the capabilities of 3D printing technology, 3D textile preform design, and polymer shape memory behavior. This paper demonstrates the shape memory behavior and recovery force of 4D printed circular braided tube preforms and their silicone elastomer matrix composites. The preforms were printed by fused deposition modeling using the shape memory polymer (SMP), polylactic acid (PLA). The effects of braiding angle, tube wall thickness, and shape recovery temperature on the shape memory behavior of 4D printed tube preforms and their silicone elastomer matrix composites have been characterized. Measurements of shape recovery forces of the preform and composite were conducted using dynamic mechanical analysis (DMA). The braided microstructural parameters and shape recovery temperature have a significant effect on the preform shape memory behavior. The introduction of the silicone elastomer matrix greatly enhances the shape recovery force, shape recovery ratio, as well as radial compressive failure load of the 4D printed preform/silicone elastomer matrix composite. Finally, building on these results, a potential application for 4D printed textile functional composites is presented.

42 ENGINEERING↗
DOE OSTI2020

A comparative reactivity study of 1-alkene fuels from ethylene to 1-heptene

In this work, a comparative reactivity study of 1-alkene fuels from ethylene to 1-heptene has been performed using ignition delay time (IDT) measurements from both a high-pressure shock tube and a rapid compression machine, at an equivalence ratio of 1.0 in ‘air’, at a pressure of 30 atm in the temperature range of 600–1300 K. At low temperatures (< 950 K), the results show that 1-alkenes with longer carbon chains show higher fuel reactivity, with 1-pentene being the first fuel to show negative temperature coefficient (NTC) behavior followed by 1-hexene and 1-heptene. At high temperatures (> 950 K), the experimental results show that all of the fuels except propene show very similar fuel reactivity, with the IDTs of propene being approximately four times longer than for all of the other 1-alkenes. To analyze the experimental results, a chemistry mechanism has been developed using consistent rate constants for these alkenes. At 650 K, flux analyses show that hydroxyl radicals add to the double bond, followed by addition to molecular oxygen producing hydroxy-alkylperoxy radicals, which can proceed via the Waddington mechanism or alternate internal H-atom isomerizations in chain branching similar to those for alkanes. We have found that the major chain propagation reaction pathways that compete with chain branching pathyways mainly produce hydroxyl rather than hydroperoxyl radicals, which explains the less pronounced NTC behavior for larger 1-alkenes compared to their corresponding alkanes. At 1200 K, flux analyses show that the accumulation of hydroperoxyl radicals is important for the auto-ignition of 1-alkenes from propene to 1-heptene. The rate of production of hydroperoxyl radicals for 1-alkenes from 1-butene to 1-heptene is higher than that for propene, which is due to the longer carbon chain facilitating hydroperoxyl radical formation via more efficient reaction pathways. This is the major reason that propene presents lower fuel reactivity than the other 1-alkenes at high temperatures.

1-Alkene↗
DOE OSTI2022

Impact of bulk-edge coupling on observation of anyonic braiding statistics in quantum Hall interferometers

Abstract Quantum Hall interferometers have been used to probe fractional charge and statistics of quasiparticles. We present measurements of a small Fabry–Perot interferometer in which the electrostatic coupling constants which affect interferometer behavior can be determined experimentally. Near the center of the ν = 1/3 state this device exhibits Aharonov–Bohm interference interrupted by a few discrete phase jumps, and Φ 0 oscillations at higher and lower magnetic fields, consistent with theoretical predictions for detection of anyonic statistics. We estimate the electrostatic parameters K I and K I L by two methods: using the ratio of oscillation periods in compressible versus incompressible regions, and from finite-bias conductance measurements. We find that the extracted K I and K I L can account for the deviation of the phase jumps from the theoretical anyonic phase θ a = 2 π /3. At integer states, we find that K I and K I L can account for the Aharonov–Bohm and Coulomb-dominated behavior of different edge states.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2013

A measurement of the turbulence-driven density distribution in a non-star-forming molecular cloud

Molecular clouds are supersonically turbulent. This turbulence governs the initial mass function and the star formation rate. In order to understand the details of star formation, it is therefore essential to understand the properties of turbulence, in particular the probability distribution of density in turbulent clouds. We present H{sub 2}CO volume density measurements of a non-star-forming cloud along the line of sight toward W49A. We use these measurements in conjunction with total mass estimates from {sup 13}CO to infer the shape of the density probability distribution function. This method is complementary to measurements of turbulence via the column density distribution and should be applicable to any molecular cloud with detected CO. We show that turbulence in this cloud is probably compressively driven, with a compressive-to-total Mach number ratio b=M{sub C}/M>0.4. We measure the standard deviation of the density distribution, constraining it to the range 1.5 < σ {sub s} < 1.9, assuming that the density is lognormally distributed. This measurement represents an essential input into star formation laws. The method of averaging over different excitation conditions to produce a model of emission from a turbulent cloud is generally applicable to optically thin line observations.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1983

Performance of a quantitative study of instability-related delamination growth

An experimental program was conducted to quantify instability-induced imbedded delamination growth. Static tests on double cantilever beam (DCB) specimens yielded the critical mode 1 strain energy release rate (G sub 1 C) for T300/5208 graphite/epoxy. Static tests on mixed mode cracked lap shear (CLS) specimens, and a nonlinear finite element analysis (NFEA) of the CLS specimen to separate mode 1 and mode 2 effects, yielded the critical mode 2 strain energy release rate (G sub 2 C) for T300/5208. Constant amplitude fatigue tests on DCB and CLS specimens, along with the NFEA results on CLS specimens, quantified mode 1 and mode 2 contributions to delamination growth rate. Fatigue tests were conducted at a frequency (omega) of 10 Hertz, maintaining the minimum to maximum cyclic load ratio (R) at 0.05. Static compression and constant amplitude compression fatigue tests were also conducted on specimens with imbedded through the width (ITTW) delaminations. Kapton imbeddments were located below 3, 4 or 6 plies in a 64-ply laminate, during layup, to simulate ITTW delaminations.

Ramkumar, R. L.↗
NASA NTRS1951

Theoretical Investigation of Submerged Inlets at Low Speeds

The general characteristics of the flow field in a submerged air inlet are investigated by theoretical, wind-tunnel, and visual-flow studies. Equations are developed for calculating the laminar and turbulent boundary-layer growth along the ramp floor for parallel, divergent, and convergent ramp walls, and a general equation is derived relating the boundary-layer pressure losses to the boundary-layer thickness. It is demonstrated that the growth of the boundary layer on the floor of the divergent-ramp inlet is retarded and that a vortex pair is generated in such an inlet. Functional relationships are established between the pressure losses in the vortices and the geometry of the inlet. A general discussion of the boundary layer and vortex formations is included, in which variations of the various losses and of the incremental external drag with mass-flow ratio are considered. Effects of compressibility are also discussed.

Sacks, Alvin H.↗
NASA NTRS1992

Advanced ramjet concepts program

Uniquely advantageous features, on both the performance and weight sides of the ledger, can be achieved through synergistic design integration of airbreathing and rocket technologies in the development of advanced orbital space transport propulsion systems of the combined cycle type. In the context of well understood advanced airbreathing and liquid rocket propulsion principles and practices, this precept of synergism is advanced mainly through six rather specific examples. These range from the detailed component level to the overall vehicle system level as follows: using jet compression; achieving a high area ratio rocket nozzle; ameliorating gas generator cycle rocket system deficiencies; using the in-duct special rocket thrust chamber assembly as the principal scramjet fuel injection operation; using the unstowed, covered fan as a duct closure for effecting high area ratio rocket mode operation; and creating a unique airbreathing rocket system via the onboard, cryogenic hydrogen induced air liquefaction process.

Leingang, J. L.↗
NASA NTRS1992

The elastic and yield behavior of polyethylene tubes subjected to biaxial loadings

The elastic and yield response of extruded thin-walled high-density polyethylene tubes with a density in the range of 0.961 to 0.964 gm/cu cm was investigated. Material properties in the axial and hoop directions were measured, and the tubes were found to be mildly transversely isotropic. The yield response was pressure sensitive, and was well predicted using the pressure-modified Hill criterion using a compressive to tensile yield strength ratio of 1:12.

Tuttle, M. E.↗
NASA NTRS1949

Critical combinations of shear and direct axial stress for curved rectangular panels

A solution is presented for the problem of the buckling of curved rectangular panels subjected to combined shear and direct axial stress. Charts giving theoretical critical combinations of shear and direct axial stress are presented for panels having five different length-width ratios. Because the actual critical compressive stress of rectangular panels having substantial curvature is known to be much lower than the theoretical value, a semiempirical method of analysis of curved panels subjected to combined shear and direct axial stress is presented for use in design. (author

PLATES - STRESSES, SHEARING CURVED↗
NASA NTRS1951

Stability of the cylindrical shell of variable curvature

This report is a first attempt to devise a calculation method for representing the buckling behavior of cylindrical shells of variable curvature. The problem occurs, for instance, in dimensioning wing noses, the stability of which is decisively influenced by the variability of curvature. The calculation is made possible by simplifying the stability equations (permissible for the shell of small curvature) and by assuming that the curvature 1/R as a function of the arc lengths can be represented by a very few Fourier terms. The formulas for the special case of an ellipse-like half oval with an axis ratio 1/3 ?= e ?= 1 under compression in longitudinal direction,shear, and a combination of shear and compression were evaluated. However, the results can also be applied approximately to an unsymmetrical oval-shell segment under compression, shear, and bending so that the numerical values contained in the diagrams 10 to 12 represent directly dimensioning data for the wing nose.

LOADS AND STRESSES, STRUCTURAL - BENDING↗
NASA NTRS1993

Humidity effects on soluble core mechanical and thermal properties (polyvinyl alcohol/microballoon composite) type CG extendospheres, volume 2

This document constitutes the final report for the study of humidity effects and loading rate on soluble core (PVA/MB composite material) mechanical and thermal properties under Contract No. 100345. This report describes test results procedures employed, and any unusual occurrences or specific observations associated with this test program. The primary objective of this work was to determine if cured soluble core filler material regains its tensile and compressive strength after exposure to high humidity conditions and following a drying cycle. Secondary objectives include measurements of tensile and compressive modulus, and Poisson's ratio, and coefficient of thermal expansion (CTE) for various moisture exposure states. A third objective was to compare the mechanical and thermal properties of the composite using 'SG' and 'CG' type extendospheres. The proposed facility for the manufacture of soluble cores at the Yellow Creek site incorporates no capability for the control of humidity. Recent physical property tests performed with the soluble core filler material showed that prolonged exposure to high humidity significantly degradates in strength. The purpose of these tests is to determine if the product, process or facility designs require modification to avoid imparting a high risk condition to the ASRM.

Source record↗
NASA NTRS2005

Characterization of Ice for Return-to-Flight of the Space Shuttle: Soft Ice - Part 2

In support of characterizing ice debris for return-to-flight (RTF) of NASA's space shuttle, we have determined the microstructure, density and compressive strength (at -10 C at approximately 0.3 per second) of porous or soft ice that was produced from both atmospheric water and consolidated snow. The study showed that the atmospheric material was generally composed of a mixture of very fine (0.1 to 0.3 millimeters) and coarser (5 to 10 millimeter) grains, plus air bubbles distributed preferentially within the more finely-grained part of the microstructure. The snow ice was composed of even finer grains (approximately 0.05 millimeters) and contained more pores. Correspondingly, the snow ice was of lower density than the atmospheric ice and both materials were significantly less dense than hard ice. The atmospheric ice was stronger (approximately 3.8 MPa) than the snow ice (approximately 1.9 MPa), but weaker by a factor of 2 to 5 than pore-free hard ice deformed under the same conditions. Zero Values are given for Young's modulus, compressive strength and Poisson's ratio that can be used for modeling soft ice from the external tank (ET).

Schulson, Erland M.↗
DOE OSTI2014

Development of A High Performance Cold Climate Heat Pump

The primary goals of the proposed project were to develop, test, and evaluate a high performance and cost-effective vapor compression air-source heat pump for use in cold climate regions. Vapor compression heat pumps are a proven technology, and have been used for many years to meet heating requirements for buildings in residential, commercial, and industrial applications. However, in climate regions that experience very low outdoor ambient temperatures both the heating capacity and coefficient of performance (COP) of traditional air-source vapor compression heat pumps drops dramatically with a decrease in the outdoor air temperature. The efficiency of heat pumping equipment has improved substantially over the past 20 years; however, the efficiencies of the highest rated equipment on the market are approaching practical limits that cannot be surpassed without modifications to the basic cycle and possibly the use of additional hardware. In this report, three technologies to improve the efficiency of vapor compression systems are described. These are a) vapor injected compression, b) oil flooded compression and c) hybrid flow control of the evaporator. Compressor prototypes for both, oil flooded and vapor injected compression were developed by Emerson Climate Technologies. For the oil flooded compressor, the oil injection port location was optimized and an internal oil separator was added using several design iterations. After initial testing at Emerson Climate Technologies, further testing was done at Purdue University, and compressor models were developed. These models were then integrated into a system model to determine the achievable improvement of seasonal energy efficiency (SEER) for Minneapolis (Minnesota) climate. For the oil flooded compression, a 34% improvement in seasonal energy efficiency was found while a 21% improvement in seasonal energy efficiency ratio was found for the vapor injected compression. It was found that one benefit of both tested compression technologies is a lower discharge temperature, which allows for continued operation at lower ambient temperatures. A bin analysis of the vapor injected prototype cold climate heat pump predicts a 6% improvement in HSPF for Minneapolis. This improvement is mainly a result of the increased capacity of the system for active vapor injection. For the oil flooded system, a slightly larger performance improvement is predicted, in this case mostly caused by an increase in heating COP. Based on an economic analysis of these results, the maximum additional cost of the system changes, for the Minneapolis location, are $\$430$ for the vapor injected system and $\$391$ for the oil flooded system. These estimates assume that a 3-year simple payback period is accepted by the customer. For the hybrid flow control of evaporators, a new type of balancing valve was developed together with Emerson Climate technologies to reduce the cost of the control scheme. In contrast to conventional stepper motor valves, this valve requires less cables and can be driven by a cheaper output circuit on the control board. The correct valve size was determined in a dedicated test stand in several design iterations. The performance benefits of the hybrid control of the evaporator coil were determined for clean coil conditions as well as with partial blockage of the air inlet grille and under frosting conditions. For clean coil conditions, the benefits in terms of COP and capacity are negligible. However, significant benefits were noted for severely air-maldistributed operating conditions. For the H2-test, the maximum COP improvement of 17% along with a capacity improvement of nearly 40% was observed. Overall, the hybrid control scheme leads to a significant amount of performance improvement, if the air inlet conditions to the evaporator are maldistributed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Influence of magnesia-to-phosphate molar ratio on microstructures, mechanical properties and thermal conductivity of magnesium potassium phosphate cement paste with large water-to-solid ratio

This paper describes the influence of the magnesia-to-phosphate (M/P) molar ratios ranging from 4 to 12, on the properties and microstructures of magnesium potassium phosphate cement (MKPC) pastes with a large water-to-solid ratio (w/s) of 0.50. The setting behavior, compressive strength, tensile bonding strength and thermal conductivity of the MKPC pastes, were investigated. The results show that an increase in the M/P ratio can slow down the setting reaction, and clearly degrade the mechanical strengths, but clearly improve the thermal conductivity of MKPC pastes. Furthermore, micro-characterizations including X-ray diffraction, scanning electron microscopy and thermogravimetric analysis, on the MKPC pastes reveal that a lower M/P ratio can facilitate better crystallization of the resultant magnesium potassium phosphate hexahydrate (MKP) and a denser microstructure. Moreover, strong linear correlations are found between the mechanical strengths and the MKP-to-space ratio, and between thermal conductivity and the volume ratio of the unreacted magnesia to the MKP. - Highlights: • Increase of M/P molar ratio causes clear mechanical degradations on MKPC pastes. • Thermal conductivity of MKPC pastes is improved with increase of M/P molar ratio. • Lower M/P ratio leads to better MKP crystallization and denser microstructure. • Strengths of MKPC pastes are linearly correlated to the MKP-to-space ratios. • Thermal conductivity is affected by the volume ratio of unreacted magnesia to MKP.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Autoignition response of n -butanol and its blend with primary reference fuel constituents of gasoline.

We study the influence of blending n-butanol on the ignition delay times of n -heptane and iso-octane, the primary reference fuels for gasoline. The ignition delay times are measured using a rapid compression machine, with an emphasis on the low-to-intermediate temperature conditions. The experiments are conducted at equivalence ratios of 0.4 and 1.0, for a compressed pressure of 20 bar, with the temperatures at the end of compression ranging from 613 K to 979 K. The effect of n -butanol addition on the development of the two-stage ignition characteristics for the two primary reference fuels is also examined. The experimental results are compared to predictions obtained using a detailed chemical kinetic mechanism, which has been obtained by a systematic merger of previously reported base models for the combustion of the individual fuel constituents. In conclusion, a sensitivity analysis on the base, and the merged models, is also performed to understand the dependence of autoignition delay times on the model parameters.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2014

Novel concepts for the compression of large volumes of carbon dioxide-phase III

In the effort to reduce the release of CO 2 greenhouse gases to the atmosphere, sequestration of CO 2 from Integrated Gasification Combined Cycle (IGCC) and Oxy-Fuel power plants is being pursued. This approach, however, requires significant compression power to boost the pressure to typical pipeline levels. The penalty can be as high as 8-12% on a typical IGCC plant. The goal of this research is to reduce this penalty through novel compression concepts and integration with existing IGCC processes. The primary objective of the study of novel CO 2 compression concepts is to reliably boost the pressure of CO 2 to pipeline pressures with the minimal amount of energy required. Fundamental thermodynamics were studied to explore pressure rise in both liquid and gaseous states. For gaseous compression, the project investigated novel methods to compress CO 2 while removing the heat of compression internal to the compressor. The highpressure ratio, due to the delivery pressure of the CO 2 for enhanced oil recovery, results in significant heat of compression. Since less energy is required to boost the pressure of a cooler gas stream, both upstream and inter-stage cooling is desirable. While isothermal compression has been utilized in some services, it has not been optimized for the IGCC environment. Phase I of this project determined the optimum compressor configuration and developed technology concepts for internal heat removal. Other compression options using liquefied CO 2 and cryogenic pumping were explored as well. Preliminary analysis indicated up to a 35% reduction in power is possible with the new concepts being considered. In the Phase II program, two experimental test rigs were developed to investigate the two concepts further. A new pump loop facility was constructed to qualify a cryogenic turbopump for use on liquid CO 2 . Also, an internally cooled compressor diaphragm was developed and tested in a closed loop compressor facility using CO 2 . Both test programs successfully demonstrated good performance and mechanical behavior. In Phase III, a pilot compression plant consisting of a multi-stage centrifugal compressor with cooled diaphragm technology has been designed, constructed, and tested. Comparative testing of adiabatic and cooled tests at equivalent inlet conditions shows that the cooled diaphragms reduce power consumption by 3-8% when the compressor is operated as a back-to-back unit and by up to 9% when operated as a straight-though compressor with no intercooler. The power savings, heat exchanger effectiveness, and temperature drops for the cooled diaphragm were all slightly higher than predicted values but showed the same trends.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Striated nozzle flow with small radius of curvature ratio throats

A theory is presented that makes it possible to apply one-dimensional techniques to compressible striated nozzle flow with small radius of curvature ratio throats. The throat plane solution is shown to approximate the two-dimensional axisymmetric flowfield and can be used for analyzing the throat plane in converging-diverging type nozzles with striated flow for radius of curvature throat ratios down to 0.25.

Norton, D. J.↗