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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37

Evaluation of High Temperature Plastics as a Ceramic Replacement

This report describes the 2015-2017 fiscal year research efforts to evaluate high temperature plastics as replacement materials for ceramics in electrical contact assemblies. The main objective of this work was to assess the feasibility of replacing existing high-price ceramic inserts with a polymeric material. Current ceramic parts are expensive due to machining costs and can suffer brittle failure. Therefore, replacing the ceramic with a more cost-effective material — in this case a plastic — is highly desirable. Not only are plastics easier to process, but they can also eliminate final tooling and are less brittle than ceramics. This effort used a three-phase approach: selection of appropriate materials determined by a comprehensive literature review, performance of an initial thermal stability screening, understanding of aging behavior under normal and off-normal conditions, and evaluation of performance at elevated temperatures. Two polymers were determined to meet the desired criteria: polybenzimidazole, and Vespel® SP-1 polyimide. Polymer derived ceramics may also be useful but will require further development of molding capabilities that were beyond the scope of this program.

36 MATERIALS SCIENCE↗

Modular Growth and Nucleation Formulations in Modular Plasticity Models

Recent investigations like the second and third Sandia Fracture Challenges have characterized and demonstrated the performance of a variety of failure techniques and models. These surveys have considered a wide breadth of models encapsulating both general failure criteria as well as those focusing on pore nucleation and growth. Extensive reviews exist on both topics. The former category generally consists of classic models like the Johnson-Cook or Wilkins criteria. These models were recently added to modular plasticity models in the Library of Advanced Materials for Engineering (LAME) as criteria for use with element death capabilities. The latter category was not treated in that effort. There exists a large class of failure models based on predicting the evolution of pores and failure associated with such microstructures. While the exact mechanisms and corresponding impact on the macroscale behavior remain an active area of research, a large suite of formulations have been proposed combining different features of both pore nucleation and subsequent growth. The most famous of these are based on the popular Gurson model of pore growth derived via micromechanical analysis assuming a plastically incompressible matrix. Numerous other models exist for both growth and nucleation and the Cocks-Ashby growth and Horstemeyer-Gokhale nucleation models have been used successfully in recent Sandia Fracture Challenges. This specific combination is colloquially referred to as the "BCJ-failure model as it has been frequently used with the Bammann-Chisea-Johnson plasticity model.

36 MATERIALS SCIENCE↗

Failure Formulations in Modular Plasticity Models

Computational prediction of ductile failure remains a challenging and important problem as demonstrated by the recent Sandia Fracture Challenges. In addition to emphasizing the complexity of such problems, the variety of solution strategies also highlighted the number of possible approaches to this problem. A common engineering approach for such efforts is to use a failure model in conjunction with element deletion. In the second Sandia Fracture Challenge, for instance, nine of the fourteen teams used some form of element deletion. For such schemes, a critical decision pertains to the selection of the appropriate failure model; of which many may be found in the literature (see the review of Corona and Reedlunn). The variety may also be observed in the aforementioned second Sandia Fracture Challenge in which at least eight different failure criteria are listed for the nine element deletion based approaches. The selection of the appropriate failure model is a difficult challenge depending on the material being considered and such criteria can variously depend on stress state (i.e. triaxiality, Lode angle) and loading conditions (i.e. strain rate, temperature). Separate implementations of each criteria with different plasticity models can be a repetitive and cumbersome process which may limit available models for an engineering analyst. To mitigate this issue, an effort was pursued to flexibly implement failure models in which different failure models could be specified and utilized within the same elastic-plastic constitutive routine by simply changing the input syntax. Similarly, the same models are implemented across a suite of elastic-plastic formulations enabling consistent definitions. As will be discussed later, a specific "modular failure" model is also implemented which allows for the selection or specification of different dependencies depending on the current need. At this stage, this effort is limited to defining failure models; progression/damage evolution in the constitutive model is not treated and left to future efforts.

42 ENGINEERING↗

Enhancing Plastic Recycling Through Nano-Scale Structure Analysis in Custom Block Copolymer Filaments (Rev.1)

As plastic production continues to increase, new methods to combat plastic waste are needed. This paper explores upcycling, a way to increase the utility or value of waste plastic. This can be done using block copolymers as compatibilizers. Block copolymers are made of two immiscible polymer blocks that phase separate on the nanoscale, forming small structures. The orientation of these nano-scale structures influences mechanical properties, and we show that orientation can be controlled by directional 3D (three dimensional) printing. Using small-angle X-ray scattering (SAXS), we analyze block copolymer filaments extruded at varying speeds. The SAXS data provide a baseline understanding of nano-scale structure in these unique filaments for future use in 3D printing experiments.

36 MATERIALS SCIENCE↗

From Plastic Waste to Fuel: Pyrolysis and Gasification of Polyethylene for Hydrogen Production

Thermochemical conversion processes offer promising solutions to address the plastic pollution crisis by transforming plastic waste into valuable products, notably hydrogen. In this study, thermal pyrolysis and steam gasification of polyethylene (PE), the most abundantly produced plastic waste, are investigated in a drop tube reactor system. Various process parameters, namely temperature, residence time, and feedstock composition, are evaluated to establish their correlations with reaction performance. Coal refuse, obtained from discarded thickener underflow in coal processing, is introduced as a co-feedstock for gasification to enhance PE handling and examine synergistic effects on product distribution, particularly H2 yield and syngas quality. Furthermore, the potential of low-cost, environmentally friendly catalysts (i.e., iron oxides, coal ash) for tar reforming is explored.

Natesakhawat, Sittichai↗

Demonstrating the Feasibility of Biomass Pyrolysis Liquid, Coal, Plastic Oil Mixtures for Entrained Flow Gasification

There is interest in co-gasifying coal, biomass and plastic. An attractive alternative is to do that in a pressurized entrained-flow gasifier, technology that has been used for coal gasification for decades. The approach taken in this study is to liquefy biomass through fast pyrolysis and to liquefy waste plastic by thermal decomposition. The liquids form the basis of a slurry that also includes coal particles. In this work, several different compositions of coal-bioliquid-plastic oil slurries were prepared and evaluated for viscosity and settling properties. Suitable composition ranges were identified and are highlighted in the presentation.

Hughey, Logan↗

Development of a Liquid Bridge Model for Particle Agglomeration and Defluidization in Plastic Pyrolysis

Molten plastic that forms during the pyrolysis of plastic or municipal solid waste feedstock can lead to particle agglomeration. A liquid bridge model is developed in MFiX-DEM and validated against a cold flow experiment with glass beads coated with silicone oil. The liquid bridge model is then extended to support an evolving liquid layer thickness for pyrolysis applications. The extended model is used to study the sensitivity of the pyrolysis reactor to solids holdup, flow conditions, and plastic properties.

Banerjee, Subhodeep↗

Microenvironmental Signals and Biochemical Information Processing: Cooperative Determinants of Intratumoral Plasticity and Heterogeneity

Intra-tumor cellular heterogeneity is a major challenge in cancer therapy. Tumors are composed of multiple phenotypic subpopulations that vary in their ability to initiate metastatic tumors and in their sensitivity to chemotherapy. In many cases, cells can transition between these subpopulations, not by genetic mutation, but instead through reversible changes in signal transduction or gene expression programs. This plasticity begins at the level of the microenvironment where local autocrine and paracrine signals, exosomes, tumor–stroma interactions, and extracellular matrix (ECM) composition create a signaling landscape that varies over space and time. The integration of this complex array of signals engages signaling pathways that control gene expression. The resulting modulation of gene expression programs causes individual cells to sample a wide array of phenotypic states that support tumor growth, dissemination, and therapeutic resistance. In this review, we discuss how information flows dynamically within the microenvironmental landscape to inform cell state decisions and to create intra-tumoral heterogeneity. We address the role of plasticity in the acquisition of transient and prolonged drug resistant states and discuss how targeted pharmacological modification of the signaling landscape may be able to constrain phenotypic plasticity, leading to improved treatment responses.

59 BASIC BIOLOGICAL SCIENCES↗

Real-Time Observation of Nanoscale Kink Band Mediated Plasticity in Ion-Irradiated Graphite: An In Situ TEM Study

Graphite IG-110 is a synthetic polycrystalline material used as a neutron moderator in reactors. Graphite is inherently brittle and is known to exhibit a further increase in brittleness due to radiation damage at room temperature. To understand the irradiation effects on pre-existing defects and their overall influence on external load, micropillar compression tests were performed using in situ nanoindentation in the Transmission Electron Microscopy (TEM) for both pristine and ion-irradiated samples. While pristine specimens showed brittle and subsequent catastrophic failure, the 2.8 MeV Au2+ ion (fluence of 4.378 × 1014 cm−2) irradiated specimens sustained extensive plasticity at room temperature without failure. In situ TEM characterization showed nucleation of nanoscale kink band structures at numerous sites, where the localized plasticity appeared to close the defects and cracks while allowing large average strain. We propose that compressive mechanical stress due to dimensional change during ion irradiation transforms buckled basal layers in graphite into kink bands. The externally applied load during the micropillar tests proliferates the nucleation and motion of kink bands to accommodate the large plastic strain. The inherent non-uniformity of graphite microstructure promotes such strain localization, making kink bands the predominant mechanism behind unprecedented toughness in an otherwise brittle material.

36 MATERIALS SCIENCE↗

A numerical study of reversible plasticity using continuum dislocation mechanics

In this contribution, an elasto-viscoplastic fast Fourier transform-based (EVPFFT) numerical implementation of the Mesoscale Field Dislocation Mechanics (MFDM) formulation, called MFDM-EVPFFT, is applied to study the reversible plastic behavior of periodic two-phase crystalline composites with an elasto-viscoplastic plastic matrix and a purely elastic second phase. Additionally, periodic laminate microstructures of this kind with different periods (i.e. sizes) are considered to examine the size dependence of the Bauschinger effect and hardening during cyclic loading. Comparisons with classic composite effects obtained with conventional crystal plasticity are discussed. Specifically, the MFDM-EVPFFT results shed light on the hardening mechanisms due to piling-up/unpiling-up of geometrically-necessary dislocations (GND) during reverse loading.

36 MATERIALS SCIENCE↗

Plastic films for reflective surfaces reproduced from masters

Accurate reproduction in plastic of the surface of the optical master to which a reflective finish may be applied is done by using backing from any suitable material to which cured plastic will adhere tightly. Plastics used for reflectors should be of the thermosetting or catalytically hardened type.

Source record↗

Void growth in an elastic-plastic medium.

The uniaxial deformation of an elastic-plastic medium containing a doubly periodic square array of circular cylindrical voids is studied under plane-strain conditions. Both the effects of geometrical nonlinearities resulting from large deformation and physical nonlinearities arising from plastic material behavior are included in formulating the problem. A variational principle is used as the basis for implementing a finite-element solution. Results are obtained for the change in void shape and size under increasing overall strain, the overall tensile behavior of the material with voids, and the development of the plastic zone about a void.

Needleman, A.↗

Plane elasto-plastic analysis of v-notched plate under bending by boundary integral equation method

A method of solution is presented, which, when applied to the elasto-plastic analysis of plates having a v-notch on one edge and subjected to pure bending, will produce stress and strain fields in much greater detail than presently available. Application of the boundary integral equation method results in two coupled Fredholm-type integral equations, subject to prescribed boundary conditions. These equations are replaced by a system of simultaneous algebraic equations and solved by a successive approximation method employing Prandtl-Reuss incremental plasticity relations. The method is first applied to number of elasto-static problems and the results compared with available solutions. Good agreement is obtained in all cases. The elasto-plastic analysis provides detailed stress and strain distributions for several cases of plates with various notch angles and notch depths. A strain hardening material is assumed and both plane strain and plane stress conditions are considered.

Rzasnicki, W.↗

Plasticity and the crack opening displacement in shells.

The plastic deformations and the crack opening displacement, delta, in cylindrical shells with an axial or circumferential crack and spherical shells with a meridional crack are considered. It is assumed that outside the perturbation zone of the crack the shell is subjected to uniform membrane loads perpendicular to the crack. The plastic strip model is used to calculate the plastic zone size. The crack opening displacement is calculated as the crack surface displacement at the crack tips by using the conventional superposition technique. In cylindrical shells with an axial crack the crack surface displacement perpendicular to the shell surface (i.e., the bulging) is also evaluated. The results are applied to a set of existing experimental data on the fracture of cylindrical shells. The tentative conclusion is that in dealing with the fracture of thin-walled structures, among various fracture models delta = constant appears to be the most satisfactory criterion.

Erdogan, F.↗

The use of COD and plastic instability in crack propagation and arrest in shells

The initiation, growth, and possible arrest of fracture in cylindrical shells containing initial defects are dealt with. For those defects which may be approximated by a part-through semi-elliptic surface crack which is sufficiently shallow so that part of the net ligament in the plane of the crack is still elastic, the existing flat plate solution is modified to take into account the shell curvature effect as well as the effect of the thickness and the small scale plastic deformations. The problem of large defects is then considered under the assumptions that the defect may be approximated by a relatively deep meridional part-through surface crack and the net ligament through the shell wall is fully yielded. The results given are based on an 8th order bending theory of shallow shells using a conventional plastic strip model to account for the plastic deformations around the crack border.

Erdogan, F.↗

Finite element formulations for problems of large elastic-plastic deformation

An Eulerian finite element formulation is presented for problems of large elastic-plastic flow. The method is based on Hill's variational principle for incremental deformations, and is suited to isotropically hardening Prandtl-Reuss materials. The formulation is given in a manner which allows any conventional finite element program, for "small strain" elasticplastic analysis, to be simply and rigorously adapted to problems involving arbitrary amounts of deformation and arbitrary levels of stress in comparison to plastic deformation moduli. The method is applied to a necking bifurcation analysis of a bar in plane-strain tension. A unified general formulation of finite element equations, both Lagrangian and Eulerian, for large deformations, with arbitrary choice of the conjugate stress and strain measures, and a discussion is given of other proposed formulations for elastic-plastic finite element analysis at large strain.

Mcmeeking, R. M.↗

Plastic intensity factors for cracked plates subjected to biaxial loading

An elastic-plastic analysis is performed for an infinite plate under plane stress conditions which contains a finite line crack and is subjected to biaxial loading. In the large scale yielding range, the amplitude of the dominant singularity at the crack tip, the plastic stress (or strain) intensity factor, is found to depend on the magnitude of loading parallel to the crack direction. The predicted value for the fracture initiation stress which is based on a plastic intensity factor fracture criterion, increases under lateral, tensile loading. Compressive loading parallel to the crack has the opposite effect on the fracture initiation stress.

Hilton, P. D.↗