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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Design of a three-layer antireflection coating for high efficiency indium phosphide solar cells using a chemical oxide as first layer

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 mu m of the surface of the illuminated cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally a grown oxide as opposed to a deposited one, will cause a significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, we demonstrate the effectiveness of using a chemically grown thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3-layer AR coating for thermally diffused p+n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p+ emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as an efficient antireflective layer yielding a measured record high AMO open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface. We show that it is possible to design a three-layer AR coating for a thermally diffused InP solar cell using the In(PO3)3 grown oxide as the first layer and Al2O3 and MgF2 as the second and third layers respectively, so as to yield an overall theoretical reflectance of less than 2%. Since chemical oxides are readily grown on III-V semiconductors materials, the technique of using the grown oxide layer to both passivate the surface as well as serve as the first of a multilayer AR coating should work well for all III-V compound-based solar cells.

Moulot, Jacques↗
NASA NTRS1995

Design of a Three-Layer Antireflection Coating for High Efficiency Indium Phosphide Solar Cells Using a Chemical Oxide as First Layer

It is well known that the behavior of III-V compound based solar cells is largely controlled by their surface, since the majority of light generated carriers (63% for GaAs and 79% for InP) are created within 0.2 microns of the illuminated surface of the cell. Consequently, the always observed high surface recombination velocity (SRV) on these cells is a serious limiting factor for their high efficiency performance, especially for those with the p-n junction made by either thermal diffusion or ion implantation. A good surface passivation layer, ideally, a grown oxide as opposed to a deposited one, will cause a significant reduction in the SRV without adding interface problems, thus improving the performance of III-V compound based solar cells. Another significant benefit to the overall performance of the solar cells can be achieved by a substantial reduction of their large surface optical reflection by the use of a well designed antireflection (AR) coating. In this paper, we demonstrate the effectiveness of using a chemically grown, thermally and chemically stable oxide, not only for surface passivation but also as an integral part of a 3- layer AR coating for thermally diffused p(+)n InP solar cells. A phosphorus-rich interfacial oxide, In(PO3)3, is grown at the surface of the p(+) emitter using an etchant based on HNO3, o-H3PO4 and H2O2. This oxide has the unique properties of passivating the surface as well as serving as a fairly efficient antireflective layer yielding a measured record high AM0, 25 C, open-circuit voltage of 890.3 mV on a thermally diffused InP(Cd,S) solar cell. Unlike conventional single layer AR coatings such as ZnS, Sb2O3, SiO or double layer AR coatings such as ZnS/MgF2 deposited by e-beam or resistive evaporation, this oxide preserves the stoichiometry of the InP surface. We show that it is possible to design a three-layer AR coating for a thermally diffused InP solar cell using the In(PO3)3 grown oxide as the first layer and Al2O3, MgF2 or ZnS, MgF2 as the second and third layers respectively, so as to yield an overall theoretical reflectance of less than 2%. Since chemical oxides are readily grown on III-V semiconductor materials, the technique of using the grown oxide layer to both passivate the surface as well as serve as the first of a multilayer AR coating, should work well for essentially all III-V compound-based solar cells.

Moulot, Jacques↗
NASA NTRS1979

Development of Surfaces Optically Suitable for Flat Solar Panels

A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

Source record↗
NASA NTRS1972

Review of results in infrared space astronomy.

Some stars, in particular, T Tauri stars, have substantial IR excesses at 10 microns. It is now understood that the long wavelength radiation comes from a shell of dust which surrounds the star and absorbs the stellar radiation. Part of the mass which is lost from supergiants is condensed into solid particles which remain in the stellar environment and provide the excess IR radiation. The most intense far-infrared object outside the solar system is the galactic center. Diffuse galactic IR objects include extended regions of gas and dust surrounding very hot young stars and regions of gas and dust surrounding cooler stars. Other subjects considered include IR galaxies and cosmic radiation.

Hoffmann, W. F.↗
NASA NTRS1975

Operational performance of a low cost, air mass 2 solar simulator

Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.

Yass, K.↗
NASA NTRS1975

Cosmic-ray streaming and anisotropies

The paper is concerned with the differential current densities and anisotropies that exist in the interplanetary cosmic-ray gas, and in particular with a correct formulation and simple interpretation of the momentum equation that describes these on a local basis. Two examples of the use of this equation in the interpretation of previous data are given. It is demonstrated that in interplanetary space, the electric-field drifts and convective flow parallel to the magnetic field of cosmic-ray particles combine as a simple convective flow with the solar wind, and that there exist diffusive currents and transverse gradient drift currents. Thus direct reference to the interplanetary electric-field drifts is eliminated, and the study of steady-state and transient cosmic-ray anisotropies is both more systematic and simpler.

Forman, M. A.↗
NASA NTRS1975

Development of a high efficiency thin silicon solar cell

Variations in temperatures used in experimental processing and their effect on the resulting solar cell performance parameters were investigated. Diffusion temperature variation results in a fairly distinct optimum cell performance for diffusion temperatures in the immediate vicinity of 850 C. An additional effort was also devoted to redesign of the matallization gridline pattern for both minimum light blockage and minimum fill factor alteration due to series resistance. Efforts on improvement of tantalum oxide antireflection coatings were undertaken. Fifty 2 cm x 2 cm cells having a range of thicknesses have been submitted as the first sample group. These cells were processed under conditions tentatively identified during this first contractual quarter's experiments as being optimal for resulting cell performance.

Lindmayer, J.↗
NASA NTRS1981

Evaluation of an evacuated-tube liquid solar collector

Indoor and outdoor thermal performances of collectors are compared in report. Tests conducted on indoor solar simulator with data from both diffuse and specular reflectors are presented graphically and in tables. Comparisons with previous data for prototype show effects of improved mainfold.

Source record↗
NASA NTRS1985

Vacuum MOCVD fabrication of high efficience cells

Vacuum metal-organic-chemical-vapor-deposition (MOCVD) is a new fabrication process with improved safety and easier scalability due to its metal rather than glass construction and its uniform multiport gas injection system. It uses source materials more efficiently than other methods because the vacuum molecular flow conditions allow the high sticking coefficient reactants to reach the substrates as undeflected molecular beams and the hot chamber walls cause the low sticking coefficient reactants to bounce off the walls and interact with the substrates many times. This high source utilization reduces the materials costs power device and substantially decreases the amounts of toxic materials that must be handled as process effluents. The molecular beams allow precise growth control. With improved source purifications, vacuum MOCVD has provided p GaAs layers with 10-micron minority carrier diffusion lengths and GaAs and GaAsSb solar cells with 20% AMO efficiencies at 59X and 99X sunlight concentration ratios. Mechanical stacking has been identified as the quickest, most direct and logical path to stacked multiple-junction solar cells that perform better than the best single-junction devices. The mechanical stack is configured for immediate use in solar arrays and allows interconnections that improve the system end-of-life performance in space.

Partain, L. D.↗
NASA NTRS1985

Continual LDEF program

The long-duration-exposure-facility (LDEF) experiment underway as of November 1985 is presented in drawings, diagrams, photographs, and tables and briefly characterized. The 57 LDEF experiments include studies of diffusion crystal growth; photovoltaic degradation of solar cells; thermal-coating performance; heat pipes; and cosmic-ray effects on seeds, spores, and eggs. Also included are answers to questions about LDEF retrieval posed at the conference.

Jones, James L.↗
NASA NTRS1992

The Objective Double Crystal Spectrometer

The solar corona, supernova remnants, the hot diffuse interstellar gas in the Galaxy, galactic halos, and the hot intracluster gas in rich clusters of galaxies, are examples of extended astrophysical plasmas which emit line-rich spectra in the X-ray spectral range from 1.5 to 25 A. These phenomena represent a significant fraction of the baryonic matter in the universe. The study of the composition, structure and dynamics of these astrophysical plasmas requires observations with both high spectral and spatial resolution simultaneously. The Objective Double Crystal Spectrometer, coupled with a grazing incidence X-ray telescope, represents a stigmatic instrument which is highly efficient for the study of such sources. We describe the configuration and performance (spatial resolution, spectral resolution and efficiency) of the Objective Double Crystal spectrometer.

Walker, Arthur B. C., Jr.↗
NASA NTRS1994

Diurnal heating and cloudiness in the NCAR Community Climate Model (CCM2)

In this paper, the authors assess the suitability of the heating fileds in the latest version of the National Center for Atmospheric Research (NCAR) Community Climate Model (CCM2) for modeling the thermal forcing of atmospheric tides. Accordingly, diurnal variations of the surface pressure, outgoing longwave radiation (OLR), cloudiness, and precipitation are examined in the CCM2. The fields of radiative, sensible, and latent heating are similarly analyzed. These results are subjectively compared with available data. Equatorial diurnal surface pressure tides are fairly well simulated by CCM2. The model successfully reproduces the semidiurnal surface pressure tides; however, this may result in part from reflection of wave energy at the upper boundary. The CCM2 large-scale diurnal OLR is generally consistent with observations. The moist-convective scheme in the model is able to reproduce the diurnally varying cloudiness and precipitation patterns associated with land-sea contrasts; however, the amplitudes of CCM2 diurnal continental convective cloudiness are weaker than observations. The CCM2 boundary-layer sensible heating is consistent with a very limited set of observations, and with estimates obtained from simple models of diffusive heating. Although the CCM2 tropospheric solar radiative heating is similar in magnitude to previous estimates, there are substantial differences in the vertical structures. A definitive assessment of the validity of the CCM2 diurnal cycle is precluded by the lack of detailed observations and the limitations of our CCM2 sample. Nevertheless, the authors conclude that the global-scale components of the CCM2 diurnal heating are useful proxies for the true diurnal forcing of the tides.

Lieberman, Ruth S.↗
NASA NTRS1998

On the Origin of Chaos in the Asteroid Belt

We consider the effect of gravitational perturbations from Jupiter on the dynamics of asteroids, when Jupiter is itself perturbed by Saturn. The presence of Saturn introduces a number of additional frequencies into Jupiters orbit. These frequencies in turn produce chaos in narrow regions on either side of the chaotic zones associated with the mean motion resonances between the asteroids and Jupiter. The resonant arguments of these three-body resonances contain the longitudes of Jupiter and the asteroid together with either the secular frequency 9-6, or the longitude of Saturn. Resonances involving the longitude of Saturn are analogs of the Laplace resonance in the Jovian satellite system. We show that many three-body resonances involving the longitude of Saturn are chaotic. We give simple expressions for the width of the chaotic region and the associated Lyapunov time. In some cases the chaos can produce a diffusive growth in the 4 eccentricity of the asteroid that leads to ejection of the asteroid on times shorter than the age of the solar system. We give simple estimates for the diffusion time. Finally, we present the results of numerical integrations testing the theory.

Murray, N.↗
NASA NTRS2017

Exospheric Escape: A Parametrical Study

The study of exospheres can help us understand the long-term loss of volatiles from planetary bodies due to interactions of planets, satellites, and small bodies with the interplanetary medium, solar radiation, and internal forces including diffusion and outgassing. Recent evidence for water and OH on the Moon has spurred interest in processes involving chemistry and sequestration of volatile species at the poles and in voids. In recent years, NASA has sent spacecraft to asteroids including Vesta and Ceres, and ESA sent Rosetta to comet 67P/Churyumov-Gerasimenko and the asteroids Lutetia and Steins. Japan's Hayabusa spacecraft returned a sample from asteroid Itakowa, and OSIRIS-REX will return a sample from a primitive asteroid, Bennu, to Earth. In a surface-bounded exosphere, the gases are derived from the surface and thus reflect the composition of the body's regolith, although not in a one-to-one ratio. Observation of an escaping exosphere, termed a corona, is challenging. We have therefore embarked on a parametrical study of exospheres as a function of mass of the exospheric species, mass of the primary body and source velocity distribution, specifically thermal (Maxwell-Boltzmann) and sputtering. The goal is to provide a quick look to determine under what conditions and for what mass of the primary body the species of interest are expected to be bound or escaping and to quickly estimate the observability of exospheric species. This work does not provide a comprehensive model but rather serves as a starting point for further study. These parameters will be useful for mission planning as well as for students beginning a study of planetary exospheres.

Volatilels↗