Analysis of rocks by spectral infrared emission - 8 to 25 microns.
Normal emittance, reflectance and transmittance spectra of roughened rock and mineral surfaces from 8 to 25 micron wavelengths
ROCK↗
SEARCH · Search NASA
Results for “Spectrum analysis”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Lightwave-electronic harmonic frequency mixing
Electronic frequency mixers are fundamental building blocks of electronic systems. Harmonic frequency mixing in particular enables broadband electromagnetic signal analysis across octaves of spectrum using a single local oscillator. However, conventional harmonic frequency mixers do not operate beyond hundreds of gigahertz to a few terahertz. If extended to the petahertz scale in a compact and scalable form, harmonic mixers would enable field-resolved optical signal analysis spanning octaves of spectra in a monolithic device without the need for frequency conversion using nonlinear crystals. Here, we demonstrate lightwave-electronic harmonic frequency mixing beyond 0.350 PHz using plasmonic nanoantennas. We demonstrate that the mixing process enables complete, field-resolved detection of spectral content far outside that of the local oscillator, greatly extending the range of detectable frequencies compared to conventional heterodyning techniques. Our work has important implications for applications where optical signals of interest exhibit coherent femtosecond-scale dynamics spanning multiple harmonics.
Science & Technology - Other Topics↗
Understanding the Puzzling X-Ray Spectrum of the SO Galaxy NGC 4382; NGC 43819: Spectral Analysis of the Prototypical Early Merger and ASCA Observations of a Dynamically Young Elliptical: NGC 4125
We have analyzed the ASCA observations of NGC 4382, NGC 4038/9, NGC 4125 and produced papers for publication. NGC 4382 is one of the E and SO galaxies detected with the lowest X-ray to optical luminosity ratio. These galaxies have a peculiar X-ray (0.1-3 keV) spectrum, with a significant excess of counts in the lowest spectral channels (less than 1 keV) relative to the spectral count distributions of X-ray brihter E and SO galaxies. Analyzing the ROSAT PSPC observation of NGC 4382 it was unclear whether this soft excess was due to a real very soft component in a multi-component spectrum, or reflected an extremely low metal abundance in an isothermal hot gas. Our ASCA observations show that the low-abundance single-temperature model does not fit well to the X-ray spectrum, in agreement with our previous suggestions. A better explanation is a composite spectrum with a very soft component (0.3 keV) in addition to a harder (5 keV) component from X-ray binaries. In this model, the abundance cannot be constrained. More complex spectral models are also possible. The ASCA observations of The Antennae - (NGC4038/9) show that at least two spectral components are required to describe the emission-thermal emission from a plasma at 0.8 keV, and a component at higher energies. The hot gas contributes about half of the flux in the 0.5 to 6 keV band. If the column density to the higher energy component is greater than 2 x 10 (exp 21) per square centimeter, then the fitted abundance in the hot gas component is less than 0.2 solar. This low abundance is not expected for the hot interstellar medium in NGC4038/9 in which supernovae and star formation (expected to enrich and heat the gas) are ongoing. We do not detect any spatial variations in the spectrum. We relate these findings to data obtained by other satellites (Einstein, ROSAT) for this interacting galaxy pair. NGC4125's ASCA data was analyzed jointly with its Beppo-SAX observation. A hard component (kT /sim 4-10 keV) is observed together with a thermal component with line emission.
Fabbiano, Giuseppina↗
Amplitude Analysis of ωπ0 Photoproduction at GlueX
spectrum of light mesons produced from a linearly polarized photon beam. The production and decays of a light meson resonance X such as γp → Xp′ →ωπ0p′ can be modeled with polarized vector-pseudoscalar ampli- tudes, which can describe the contribution of individual amplitudes to the total measured intensity. The status of mass-independent fits to the ωπ0 mass spectrum over a wide range of mass and momentum transfer−twill be presented, with an emphasis on interactions with the b1(1235) meson. We will also present in parallel an analysis of moments of the angular dis- tributions for the same process, as a means of verifying the stability of the amplitude-based results. These results will help to improve the broader knowledge of light meson states and how they are produced.
Scheuer, Kevin [College of William and Mary, Willi↗
Gravitational-wave signal of a core-collapse supernova explosion of a 15M ⊙ star
In this paper we report on the gravitational-wave signal computed in the context of a three-dimensional simulation of a core-collapse supernova explosion of a 15 M ⊙ star. The simulation was performed with our neutrino hydrodynamics code chimera . We detail the gravitational wave strains as a function of time, for both polarizations, and discuss their physical origins. We also present the corresponding spectral signatures. Gravitational wave emission in our model has two key features: low-frequency emission (less than 200 Hz) emanates from the gain layer as a result of neutrino-driven convection and the standing accretion shock instability (SASI), and high-frequency emission (greater than 600 Hz) emanates from the proto–neutron star due to Ledoux convection within it. The high-frequency emission dominates the gravitational wave emission in our model and emanates largely from the convective layer itself, not from the convectively stable layer above it, due to convective overshoot. Moreover, the low-frequency emission emanates from the gain layer itself, not from the proto–neutron star, due to accretion onto it. We provide evidence of the SASI in our model and demonstrate that the peak of our low-frequency gravitational wave emission spectrum corresponds to it. Given its origin in the gain layer, we classify the SASI emission in our model as p-mode emission and assign a purely acoustic origin, not a vortical–acoustic origin, to it. We compare the results of our three-dimensional model analysis with those obtained from the model’s two-dimensional counterpart and find a significant reduction in the strain amplitudes in the former case, as well as significant reductions in all related quantities. Our dominant proto–neutron star gravitational wave emission is not well characterized by emission from surface g modes, complicating the relationship between peak frequencies observed and the mass and radius of the proto–neutron star expressed by analytic estimates under the assumption of surface g-mode emission. We present our frequency normalized characteristic strain along with the sensitivity curves of current- and next-generation gravitational wave detectors. This simple analysis indicates that the spectrum of gravitational wave emission between approximately 20 Hz and approximately 1 kHz, stemming from neutrino-driven convection, the SASI, accretion onto the proto–neutron star, and proto–neutron star convection, will be accessible for a Galactic event.
79 ASTRONOMY AND ASTROPHYSICS↗
Online Rapid Analysis of Laser Heterodyne Radiometer (LHR) Data Using the Planetary Spectrum Generator (PSG)
One of the biggest challenges in developing scientific instruments is not just the build and testing of an instrument, but the method for processing the data and producing a consistent, well characterized data product that can be confidently used by the public and scientific community. Raw data products are frequently an array of numbers that are a read-out of voltages. The challenge is to convert these arrays into meaningful information as well as remove noise and interferences. Because this can be a tedious and time-consuming, the goal is to automate the process so that data ca be processed rapidly and be available in real-time for event monitoring. Here we present a rapid analysis method for Laser Heterodyne Radiometer (LHR) data that can be used to analyze data taken from a range of LHR observation modes (column, limb, etc.). This online tool uses the versatile Planetary Spectrum Generator (PSG) and allows LHR users to quickly analyze their own data using a NASA Goddard Space Flight Center (GSFC) monitored capability to ensure quality and reproducibility in the data products. Background: Development of a miniaturized LHR (mini-LHR) as a ground instrument for measuring carbon dioxide (CO 2 ) and methane (CH 4 ) in the atmospheric column started in 2009 with the commercial availability of distributive feedback lasers (DFB) in wavelengths that could measure absorption of gases in the near-IR. As new DFB lasers, detectors and hardware emerged at different wavelengths, additional gases were added to the capability. The mini-LHR was adapted into an occultation-viewing CubeSat with Lawrence Livermore National Laboratory (LLNL) for observing CO 2 , CH 4 , and H 2 O in the limb and was launched in 2019. Other versions of the LHR technology have been designed for observation of water vapor in the lunar exosphere as well as observations of trace gases in planetary atmospheres and plumes from icy moons. The PSG is an online tool developed at GSFC that can be used for synthesizing Earth and planetary spectra (atmospheres and surfaces) over a broad range of wavelengths (0.1 μm to 100 mm) for any observatory, orbiter or lander. Spectra are simulated by combining several state-of-the-art radiative transfer models, spectroscopic databases, planetary databases, as well as modern-era retrospective analysis for research and applications, version 2 (MERRA-2) data set which provides meteorological inputs such as modeled surface pressure for calculating dry-air columns.
Emily Wilson↗
A Mercury Model of the Molly-G Fast Burst Reactor (FBR)
In order to design neutron irradiation experiments at a given nuclear reactor, one requires a representative neutron spectrum for the configuration of the reactor that will exist during the experiment. This usually implies modeling the operation of the reactor using a neutron transport code. Since the modeling of pulsed neutron reactors is quite complex, requiring coupled modeling of neutronics and thermo-structural response, the typical methodology employs analysis of the neutron spectrum which is obtained from a static keff calculation. While this time-independent Eigenfunction is not truly representative of that during a reactor pulse, we postulate that it is a reasonable representation for our purposes. The Nuclear Survivability (NS) Program at LLNL is considering fielding such experiments at the Molly-G (‘Molybdenum Godiva-II’) Fast Burst Reactor (FBR) at the White Sands Missile Range (WSMR). The goal of these experiments is to (a) test / proof / calibrate diagnostics, and (b) test the efficacy of neutron shield configurations, before fielding at other nuclear reactors, such as the Annular Core Research Reactor (ACRR) at SNL/NM. After attempting to secure either drawings or a copy of an existing MCNP model of the Molly-G FBR from various institutions, it was decided to develop a new model for use with the Mercury Monte Carlo transport code. The model described herein will be used to design these experiments.
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
Searching for Turbulent Spectra in Mutliple Spacecraft Observations
The subject of magnetohydrodynamic simulations in the 1980's, magnetic turbulence has reemerged as a favored explanation for the production of fast magnetic reconnection. Recent three-dimensional simulations reveal the formation of secondary islands that serve to shorten the current sheet and increase the accelerating electric field, while both simulations and observations witness electron holes whose collapse energizes electrons. However, little work has been done to investigate the presence of turbulent magnetic and electric field spectra in association with in situ reconnection observations in space. In this study we address this deficiency by analyzing the wavelength spectra of two reconnection events established by multiple spacecraft observations in previous publications. We apply a k-filtering analysis to determine the wave vectors. To optimize the quality of the k-filtering analysis and minimize aliasing, we select multi-spacecraft observations having optimal spacecraft tetrahedral geometry and dimensions that resolve wavelengths within the ion diffusion region. We have chosen one dayside and one nightside reconnection event each observed by the Cluster spacecraft. Spatial correlation between the reconnecting current sheet and a turbulent magnetic spectrum supports an association between turbulence and reconnection in space. The k-filtering method, a wavelet time-frequency spectrum, and a polarization analysis serve to identify wave modes associated with the turbulence. A calculation of the reconnection electric field based on the normal component of the reconnecting magnetic field provides an estimate of the reconnection rate.
Wendel, Deirdre E.↗
All-Particle Cosmic Ray Energy Spectrum Measured with 26 Icetop Stations
We report on a measurement of the cosmic ray energy spectrum with the IceTop air shower array, thesurface component of the IceCube Neutrino Observatory at the South Pole. The data used in this analysiswere taken between June and October, 2007, with 26 surface stations operational at that time, corresponding to about one third of the final array. The fiducial area used in this analysis was 0.122 square kilometers.The analysis investigated the energy spectrum from 1 to 100 PeV measured for three different zenithangle ranges between 0 and 46. Because of the isotropy of cosmic rays in this energy range the spectrafrom all zenith angle intervals have to agree. The cosmic-ray energy spectrum was determined under differentassumptions on the primary mass composition. Good agreement of spectra in the three zenithangle ranges was found for the assumption of pure proton and a simple two-component model. Forzenith angles theta less than 30 deg., where the mass dependence is smallest, the knee in the cosmic ray energy spectrumwas observed at about 4 PeV, with a spectral index above the knee of about -3.1. Moreover, an indicationof a flattening of the spectrum above 22 PeV was observed.
icetop↗
Dynamics of disordered mechanical systems with large connectivity, free probability theory, and quasi-Hermitian random matrices
Disordered mechanical systems with high connectivity represent a limit opposite to the more familiar case of disordered crystals. Individual ions in a crystal are subjected essentially to nearest-neighbor interactions. In contrast, the systems studied in this paper have all their degrees of freedom coupled to each other. Thus, the problem of linearized small oscillations of such systems involves two full positive-definite and non-commuting matrices, as opposed to the sparse matrices associated with disordered crystals. Consequently, the familiar methods for determining the averaged vibrational spectra of disordered crystals, introduced many years ago by Dyson and Schmidt, are inapplicable for highly connected disordered systems. In this paper we apply random matrix theory (RMT) to calculate the averaged vibrational spectra of such systems, in the limit of infinitely large system size. At the heart of our analysis lies a calculation of the average spectrum of the product of two positive definite random matrices by means of free probability theory techniques. We also show that this problem is intimately related with quasi-hermitian random matrix theory (QHRMT), which means that the ‘hamiltonian’ matrix is hermitian with respect to a non-trivial metric. This extends ordinary hermitian matrices, for which the metric is simply the unit matrix. The analytical results we obtain for the spectrum agree well with our numerical results. The latter also exhibit oscillations at the high-frequency band edge, which fit well the Airy kernel pattern. We also compute inverse participation ratios of the corresponding amplitude eigenvectors and demonstrate that they are all extended, in contrast with conventional disordered crystals. Finally, we compute the thermodynamic properties of the system from its spectrum of vibrations. In addition to matrix model analysis, we also study the vibrational spectra of various multi-segmented disordered pendula, as concrete realizations of highly connected mechanical systems. A universal feature of the density of vibration modes, common to both pendula and the matrix model, is that it tends to a non-zero constant at vanishing frequency.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
The far ultraviolet reflection spectrum of Uranus - Results from the Voyager encounter
The present analysis of the 1250-1700 A region Uranus spectrum obtained by Voyager's US spectrometer characterizes these observation results as due primarily to solar light reflected from an H2 Rayleigh and Raman scattering atmosphere with small but measurable hydrocarbon absorption. The hydrocarbon abundances obtained are substantially lower than those at comparable levels of the Saturn or Jupiter atmospheres; it is suggested, in one-dimensional terms, that this is due to diffusive separation, in conjunction with photochemical depletion caused by a very low eddy-diffusion coefficient. Strong latitudinal variations in the hydrocarbon abundances are suggested in the subsolar, polar stratosphere.
Yelle, Roger V.↗
Gamma-rays and neutrons as a probe of the proton spectrum during the solar flare of 1988 December 16
We have previously reported on high-energy gamma-rays and neutrons from the flare of 1988 December 16 detected by the Gamma-Ray Spectrometer on the SMM satellite. In this paper, we present results on gamma-ray lines seen by the same detector during this flare. Together, these measurements constitute a powerful probe of the proton spectrum that produces the flare neutrals. Analysis of the data suggests a Bessel-function proton spectrum with a shape parameter (alpha T) of 0.054 +/- 0.004 and the number of protons above 30 MeV equal to (9.0 +/- 0.9) x 10 exp 32. The number of neutrons detected from this flare is much smaller than what is predicted from an isotropic distribution of the protons, indicating that the distribution may be nonisotropic.
Dunphy, P. P.↗
Meeting Radiation Protection Requirements and Reducing Spacecraft Mass - A Multifunctional Materials Approach
Both crew and radio-sensitive systems, especially electronics must be protected from the effects of the space radiation environment. One method of mitigating this radiation exposure is to use passive-shielding materials. In previous vehicle designs such as the International Space Station (ISS), materials such as aluminum and polyethylene have been used as parasitic shielding to protect crew and electronics from exposure, but these designs add mass and decrease the amount of usable volume inside the vehicle. Thus, it is of interest to understand whether structural materials can also be designed to provide the radiation shielding capability needed for crew and electronics, while still providing weight savings and increased useable volume when compared against previous vehicle shielding designs. In this paper, we present calculations and analysis using the HZETRN (deterministic) and FLUKA (Monte Carlo) codes to investigate the radiation mitigation properties of these structural shielding materials, which includes graded-Z and composite materials. This work is also a follow-on to an earlier paper, that compared computational results for three radiation transport codes, HZETRN, HETC, and FLUKA, using the Feb. 1956 solar particle event (SPE) spectrum. In the following analysis, we consider the October 1989 Ground Level Enhanced (GLE) SPE as the input source term based on the Band function fitting method. Using HZETRN and FLUKA, parametric absorbed doses at the center of a hemispherical structure on the lunar surface are calculated for various thicknesses of graded-Z layups and an all-aluminum structure. HZETRN and FLUKA calculations are compared and are in reasonable (18% to 27%) agreement. Both codes are in agreement with respect to the predicted shielding material performance trends. The results from both HZETRN and FLUKA are analyzed and the radiation protection properties and potential weight savings of various materials and materials lay-ups are compared.
Atwell, William↗
Spatially Resolved Raman Spectroscopy of Thin Carbon Interphase in SiC Ceramic Matrix Composites
A dedicated analysis method is presented to extract the Raman spectrum of an interphase layer thinner than the laser spot size. We focused on spatial correlations between the contrast of optical micrographs and Raman hyperspectral data to predict the constituents of the mixed spectra measured near the interphase. By employing a mapping step size of 0.1 μm, the Raman spectrum of approximately 0.3-μm-thick carbon interphase in a SiC fiber-reinforced SiC matrix composite was extracted from data acquired with a theoretical spot size of about 0.7 μm. Notably, conventional chemometrics procedures were unable to isolate the interphase signal, instead producing a spectrum representing a mixture of interphase and matrix. This study used another composite with approximately 0.9-μm-thick interphase to validate the analysis method, enabling direct measurement of the interphase spectrum. The proposed Raman analysis method has advantages in specimen volume and turnaround time compared to traditional characterization methods, such as transmission electron microscopy. In conclusion, this study also evaluates the applicability of the analysis method to different composite materials and identifies key requirements of the measurements, including the ratio of interphase thickness to spot size and the homogeneity of the surrounding matrix.
ceramic matrix composite↗
Oscillations of red dwarfs in evolved low-mass binaries with neutron stars
We investigate a novel aspect of a problem related to the properties of low-mass binaries (LMBs) with millisecond pulsars: the pulsations of the red dwarf (donor) companion of the neutron star (NS). The illumination of the donor star by the pulsar's high-energy nonthermal radiation and relativistic wind may substantially affect its structure. We present a quantitative analysis of the oscillation spectrum of a red dwarf which has evolved in an LMB and has undergone the stage of evaporation. We calculate the p- and g-modes for red dwarfs with masses in the interval (0.2-0.6) stellar mass. For comparison, similar calculations are presented for zero age main-sequence (ZAMS) stars of the same masses. For less massive donor stars (approximately 0.2 stellar mass) the oscillation spectrum becomes quantitatively different from that of their ZAMS counterparts. The differnce is due to the fact that a ZAMS star of 0.2 stellar mass is fully convective, while the donor star in an LMB is expected to be far from thermal equilibrium and not fully convective. As a result, in contrast to a low-mass ZAMS star, a red dwarf of the same mass in an LMB allows the existence of g-modes. We also consider tidally forced g-modes, and perform a linear analysis of these oscillations for different degrees of nonsynchronism between the orbital and spin rotation of the red dwarf component. We demonstrate the existence of a series of reasonances for the low-order g-modes which may occur in LMBs at a late stage of their evolution. We discuss the possibility that these oscillations may trigger Roche lobe overflow and sudden mass loss by the donor star. Further implications of this effect for gamma- and X-ray burst phenomena are outlined.
Sarna, Marek J.↗
The nu(sub 2) and 2nu(sub 2) - nu(sub 2) bands of N-14 (16)O2: Electron Spin-Rotation and Hyperfine Contact Resonances in the (010) Vibrational State
High-resolution Fourier transform spectra covering the 720-9-10/ cm spectral region have been used to perform a reanalysis of the 2nu(sub 2) band ((010) - (000) vibrational transition) together with the first analysis of the nu(sub 2) - nu(sub 2) hot band of nitrogen dioxide ((020)-(010) vibrational transition). The high-quality spectra show that, for numerous nu(sub 2) lines, the hyperfine structure is easily observable in the case of resonances due to the hyperfine Fermi-type operator. By performing a full treatment of the spin-rotation and of the hyperfine operators, a near line list of the nu(sub 2) band (positions and intensities) has been generated, and it is in excellent agreement with the experimental spectrum. Also, a thorough analysis of the -2nu(sub 2) nu(sub 2) hot band has been performed leading to an extended set of new (020) spin-rotation levels, These levels, together with the (100), (020), (001) spin-rotation levels deduced previously from the analysis of thenu(sub 1), 2nu(sub 2), and nu(sub 3) cold bands performed in the 6.3 - to 7.5 microns spectral range were least-squares fitted, allowing one to derive a new set of vibrational band centers and rotational. spin-rotation, and interaction constants for the {(100)(020)(001)} interacting states of N-14(16)O2.
Perrin, A.↗
Applying Two-Dimensional Correlation Spectroscopy and Principal Component Analysis to Understand How Temperature Affects the Neptunium(V) Absorption Spectrum
The visible-near infrared (Vis-NIR) electronic absorption spectrum of neptunium(V) (NpO 2 + ) comprises numerous f-f electronic transitions with mostly undocumented temperature dependencies. The effect of temperature on the absorption spectrum of the pentavalent neptunyl dioxocation (NpO 2 + ) is an important factor to consider with spectrophotometric applications but has often been overlooked. Optical Vis-NIR absorption spectra (400–1700 nm) of Np(V) (0.017–0.89 M) in 1 M nitric acid were evaluated with varying temperatures (T = 10–80 °C). The intensity, position, and overall shape of the bands were sensitive to interactions with the solvent and coordination environment. Numerous temperature-induced isosbestic points were identified resulting from dynamic, overlapping peak shifts. Spectral variations were characterized using principal component analysis (PCA) and 2D correlation spectroscopy (COS). 2D-COS revealed that the absorption band near 1095 nm likely consists of two bands centered near 1087 and 1096 nm, which cannot be explained by current computational methods. 2D-COS analysis also provided an unambiguous assignment of unresolved peaks in the visible region for comparison with computational predictions. PCA was used to identify nonlinearity in the spectral response at elevated Np(V) concentrations ≥ 0.5 M. This unique experimental data and interpretation will foster a deeper understanding of the absorption spectra for complex actinyl ions.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Computational optimal transport for molecular spectra: The fully continuous case
Computational optimal transport is used to analyze the difference between pairs of continuous molecular spectra. It is demonstrated that transport distances which are derived from this approach may be a more appropriate measure of the difference between two continuous spectra than more familiar measures of distance under many common circumstances. Associated with the transport distances is the transport map which provides a detailed analysis of the difference between two molecular spectra and is a key component of our study of quantitative differences between two continuous spectra. The use of optimal transport for comparing molecular spectra is developed in detail here with a set of model spectra, so that the discussion is self-contained. The difference between the transport distance and more common definitions of distance is elucidated for some well-chosen examples and it is shown where transport distances may be very useful alternatives to standard definitions of distance. The transport distance between a theoretical and experimental electronic absorption spectrum for SO 2 is studied and it is shown how the theoretical spectrum can be modified to fit the experimental spectrum better adjusting the theoretical band origin and the resolution of the theoretical spectrum. In conclusion, this analysis includes the calculation of transport maps between the theoretical and experimental spectra suggesting future applications of the methodology.
74 ATOMIC AND MOLECULAR PHYSICS↗