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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37

Ethanol Electro-Oxidation on Ternary Platinum–Rhodium–Tin Nanocatalysts: Insights in the Atomic 3D Structure of the Active Catalytic Phase

Novel insights in the synthesis–structure–catalytic activity relationships of nanostructured trimetallic Pt–Rh–Sn electrocatalysts for the electrocatalytic oxidation of ethanol are reported. In particular, we identify a novel single-phase Rh-doped Pt–Sn Niggliite mineral phase as the source of catalytically active sites for ethanol oxidation; we discuss its morphology, composition, chemical surface state, and the detailed 3D atomic arrangement using high-energy (HE-XRD), atomic pair distribution function (PDF) analysis, and X-ray photoelectron spectroscopy (XPS). The intrinsic ethanol oxidation activity of the active Niggliite phase exceeded those of earlier reports, lending support to the notion that the atomic-scale neighborhood of Pt, Rh, and Sn is conducive to the emergence of active surface catalytic sites under reaction conditions. In situ mechanistic Fourier transform infrared (in situ FTIR) analysis confirms an active 12 electron oxidation reaction channel to CO 2 at electrode potentials as low as 450 mV/RHE, demonstrating the favorable efficiency of the PtRhSn Niggliite phase for C–C bond splitting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Vortex motion induced losses in tantalum resonators

Tantalum (Ta)-based superconducting circuits have been demonstrated to enable ultrahigh qubit quality factors (𝑄), motivating a careful study of the microscopic origin of the remaining losses that limit their performance. We have recently shown that the losses in Ta-based resonators are dominated by two-level systems at low microwave powers and millikelvin temperatures. We also observe that some devices exhibit loss that is exponentially activated at a lower temperature inconsistent with the superconducting critical temperature (T 𝑐 ) of the constituent film. Specifically, dc resistivity measurements show a T 𝑐 of over 4 K, while microwave measurements of resonators fabricated from these films show losses that increase exponentially with temperature with an activation energy as low as 0.3 K. Here, in this study, we present a comparative study of the structural and thermodynamic properties of Ta-based resonators and identify vortex motion-induced loss as the source of thermally activated microwave loss. Through careful magnetoresistance and x-ray diffraction measurements, we observe that the increased loss occurs for films that are in the clean limit, where the superconducting coherence length (𝜉) is shorter than the mean free path (𝑙). Vortex motion-induced losses are suppressed for films in the dirty limit, which show evidence of structural defects that can pin vortices. We verify this hypothesis by explicitly pinning vortices via patterning, and we find that we can suppress the loss by microfabrication.

36 MATERIALS SCIENCE↗

Evaluating Radiation Impact on Superconducting Transmon Qubits in Above and Underground Facilities

Superconducting qubits can be sensitive to sudden energy deposits into the substrate from cosmic rays and ambient radioactivity. While previous studies have primarily focused on exploring correlated effects over time and distance due to cosmic rays, this study uniquely offers a direct comparison of a transmon qubit's response at Fermilab SQMS above-ground facilities and the deep-underground Gran Sasso Laboratory (INFN-LNGS, Italy). Despite the vastly different radiation environments, we observe a similar average qubit lifetime (T1) of approximately 80 microseconds at both sites. We then employ a fast decay detection protocol and investigate the time structure, sensitivity, and relative rates of triggered events due to radiation versus intrinsic noise. We compare the above and underground performance of several high-coherence qubits with similar designs. Our findings reveal no significant difference in events with radiation-like signatures between above-ground and underground conditions for these sapphire and niobium-based transmon qubits. This suggests that most such events are likely due to other noise sources, which predominantly contribute to single-qubit errors in contemporary transmon qubits. By exposing the qubits to gamma sources with varying activity levels, we further evaluate their response to radiation in a low-background environment. The results show that qubits can indeed detect particle impacts; however, this capability is only realized by substantially reducing other noise sources, which in turn affects detection efficiency [1].

Roy, Tanay↗

X-ray observations of M33 with the high resolution imager on the Einstein Observatory

Three observations, separated by 6 months, of the Local Group galaxy M33 using the high resolution imager (HRI) on the Einstein Observatory are reported. Eight X-ray sources with luminosites ranging from 8 x 10 to the 36th to 1.2 x 10 to the 39th ergs/s have been detected. For seven of these sources, finding charts with positions accurate to less than 5 arcsec are provided. The X-ray properties and possible identifications are discussed for the eight HRI-detected sources and for two other sources, previously described by Long et al. (1981), for which upper limits are provided. It is found that most of the sources are associated with Population I markers. One source may be coincident with an optical supernova remnant. The most luminous source (by a factor of at least 25) is that associated with the optical nucleus. Because the X-ray flux from the nucleus decreased by a factor of 1/2 between the first and second observations, it is most likely that a single, compact object is responsible for the X-ray emission. It is possible that this source may be an active galactic nucleus, a massive binary X-ray source, or a low-mass X-ray binary such as are found in globular clusters within the Galaxy.

Markert, T. H.↗

A Semi-Empirical Model for Forecasting Relativistic Electrons at Geostationary Orbit

We developed a new prediction model for forecasting relativistic (>2MeV) electrons, which provides a VERY HIGH correlation between predicted and actually measured electron fluxes at geostationary orbit. This model implies the multi-step particle acceleration and is based on numerical integrating two linked continuity equations for primarily accelerated particles and relativistic electrons. The model includes a source and losses, and used solar wind data as only input parameters. We used the coupling function which is a best-fit combination of solar wind/Interplanetary Magnetic Field parameters, responsible for the generation of geomagnetic activity, as a source. The loss function was derived from experimental data. We tested the model for four year period 2004-2007. The correlation coefficient between predicted and actual values of the electron fluxes for whole four year period as well as for each of these years is about 0.9. The high and stable correlation between the computed and actual electron fluxes shows that the reliable forecasting these electrons at geostationary orbit is possible. The correlation coefficient between predicted and actual electron fluxes is stable and incredibly high.

Lyatsky, Wladislaw↗

Relativistic Electrons at Geostationary Orbit: Modeling Results

We developed a new prediction model for forecasting relativistic (greater than 2MeV) electrons, which provides a VERY HIGH correlation between predicted and actually measured electron fluxes at geostationary orbit. This model implies the multi-step particle acceleration and is based on numerical integrating two linked continuity equations for primarily accelerated particles and relativistic electrons. The model includes a source and losses, and used solar wind data as only input parameters. We used the coupling function which is a best-fit combination of solar wind/interplanetary magnetic field parameters, responsible for the generation of geomagnetic activity, as a source. The loss function was derived from experimental data. We tested the model for four year period 2004-2007. The correlation coefficient between predicted and actual values of the electron fluxes for whole four year period as well as for each of these years is stable and incredibly high (about 0.9). The high and stable correlation between the computed and actual electron fluxes shows that the reliable forecasting these electrons at geostationary orbit is possible.

Khazanov, George V.↗

Prediction Model for Relativistic Electrons at Geostationary Orbit

We developed a new prediction model for forecasting relativistic (greater than 2MeV) electrons, which provides a VERY HIGH correlation between predicted and actually measured electron fluxes at geostationary orbit. This model implies the multi-step particle acceleration and is based on numerical integrating two linked continuity equations for primarily accelerated particles and relativistic electrons. The model includes a source and losses, and used solar wind data as only input parameters. We used the coupling function which is a best-fit combination of solar wind/interplanetary magnetic field parameters, responsible for the generation of geomagnetic activity, as a source. The loss function was derived from experimental data. We tested the model for four year period 2004-2007. The correlation coefficient between predicted and actual values of the electron fluxes for whole four year period as well as for each of these years is stable and incredibly high (about 0.9). The high and stable correlation between the computed and actual electron fluxes shows that the reliable forecasting these electrons at geostationary orbit is possible.

Khazanov, George V.↗

Microwave field effect transistor

Electrodes of a high power, microwave field effect transistor are substantially matched to external input and output networks. The field effect transistor includes a metal ground plane layer, a dielectric layer on the ground plane layer, a gallium arsenide active region on the dielectric layer, and substantially coplanar spaced source, gate, and drain electrodes having active segments covering the active region. The active segment of the gate electrode is located between edges of the active segments of the source and drain electrodes. The gate and drain electrodes include inactive pads remote from the active segments. The pads are connected directly to the input and output networks. The source electrode is connected to the ground plane layer. The space between the electrodes and the geometry of the electrodes extablish parasitic shunt capacitances and series inductances that provide substantial matches between the input network and the gate electrode and between the output network and the drain electrode. Many of the devices are connected in parallel and share a common active region, so that each pair of adjacent devices shares the same source electrodes and each pair of adjacent devices shares the same drain electrodes. The gate electrodes for the parallel devices are formed by a continuous stripe that extends between adjacent devices and is connected at different points to the common gate pad.

Huang, Ho-Chung↗

The Discovery of Lensed Radio and X-ray Sources Behind the Frontier Fields Cluster MACS J0717.5+3745 with the JVLA and Chandra

We report on high-resolution JVLA and Chandra observations of the Hubble Space Telescope (HST) Frontier Cluster MACS J0717.5+3745. MACS J0717.5+3745 offers the largest contiguous magnified area of any known cluster, making it a promising target to search for lensed radio and X-ray sources. With the high-resolution 1.0–6.5 GHz JVLA imaging in A and B configuration, we detect a total of 51 compact radio sources within the area covered by the HST imaging. Within this sample, we find seven lensed sources with amplification factors larger than two. None of these sources are identified as multiply lensed. Based on the radio luminosities, the majority of these sources are likely star-forming galaxies with star-formation rates (SFRs) of 10–50 M ⊙ yr -1 located at 1≲ z ≲ 2. Two of the lensed radio sources are also detected in the Chandra image of the cluster. These two sources are likely active galactic nuclei, given their 2–10 keV X-ray luminosities of ~ 10 43-44 erg s -1 . From the derived radio luminosity function, we find evidence for an increase in the number density of radio sources at 0.6 < z < 2.0, compared to a z < 0.3 sample. Lastly, our observations indicate that deep radio imaging of lensing clusters can be used to study star-forming galaxies, with SFRs as low as ~10M ⊙ yr -1 , at the peak of cosmic star formation history.

79 ASTRONOMY AND ASTROPHYSICS↗

A compact high-resolution X-ray ion mobility spectrometer

For the ionization of gaseous samples, most ion mobility spectrometers employ radioactive ionization sources, e.g., containing {sup 63}Ni or {sup 3}H. Besides legal restrictions, radioactive materials have the disadvantage of a constant radiation with predetermined intensity. In this work, we replaced the {sup 3}H source of our previously described high-resolution ion mobility spectrometer with 75 mm drift tube length with a commercially available X-ray source. It is shown that the current configuration maintains the resolving power of R = 100 which was reported for the original setup containing a {sup 3}H source. The main advantage of an X-ray source is that the intensity of the radiation can be adjusted by varying its operating parameters, i.e., filament current and acceleration voltage. At the expense of reduced resolving power, the sensitivity of the setup can be increased by increasing the activity of the source. Therefore, the performance of the setup can be adjusted to the specific requirements of any application. To investigate the relation between operating parameters of the X-Ray source and the performance of the ion mobility spectrometer, parametric studies of filament current and acceleration voltage are performed and the influence on resolving power, peak height, and noise is analyzed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Antimicrobial activity and mechanism of the human milk-sourced peptide Casein201

Introduction: Casein201 is one of the human milk sourced peptides that differed significantly in preterm and full-term mothers. This study is designed to demonstrate the biological characteristics, antibacterial activity and mechanisms of Casein201 against common pathogens in neonatal infection. Methodology: The analysis of biological characteristics was done by bioinformatics. Disk diffusion method and flow cytometry were used to detect the antimicrobial activity of Casein201. Killing kinetics of Casein201 was measured using microplate reader. The antimicrobial mechanism of Casein201 was studied by electron microscopy and electrophoresis. Results: Bioinformatics analysis indicates that Casein201 derived from β-casein and showed significant sequence overlap. Antibacterial assays showed Casein201 inhibited the growth of S taphylococcus aureus and Y ersinia enterocolitica. Ultrastructural analyses revealed that the antibacterial activity of Casein201 is through cytoplasmic structures disintegration and bacterial cell envelope alterations but not combination with DNA. Conclusion: We conclude the antimicrobial activity and mechanism of Casein201. Our data demonstrate that Casein201 has potential therapeutic value for the prevention and treatment of pathogens in neonatal infection.

60 APPLIED LIFE SCIENCES↗

Monitoring the Microgravity Environment Quality On-Board the International Space Station Using Soft Computing Techniques

This paper presents an artificial intelligence monitoring system developed by the NASA Glenn Principal Investigator Microgravity Services project to help the principal investigator teams identify the primary vibratory disturbance sources that are active, at any moment in time, on-board the International Space Station, which might impact the microgravity environment their experiments are exposed to. From the Principal Investigator Microgravity Services' web site, the principal investigator teams can monitor via a graphical display, in near real time, which event(s) is/are on, such as crew activities, pumps, fans, centrifuges, compressor, crew exercise, platform structural modes, etc., and decide whether or not to run their experiments based on the acceleration environment associated with a specific event. This monitoring system is focused primarily on detecting the vibratory disturbance sources, but could be used as well to detect some of the transient disturbance sources, depending on the events duration. The system has built-in capability to detect both known and unknown vibratory disturbance sources. Several soft computing techniques such as Kohonen's Self-Organizing Feature Map, Learning Vector Quantization, Back-Propagation Neural Networks, and Fuzzy Logic were used to design the system.

Jules, Kenol↗

Foundational Open Source Solar System Modeling Through Improvement and Validation of the System Advisor Model and PVWatts (FY19-FY21 Final Technical Report)

Accelerating intelligent deployment of solar energy technologies demands accurate system modeling every step of the way. From project development to policy research, grid integration studies to development of novel technologies, industry and researchers alike need validated, transparent, easy-to-use, extensible, cutting-edge, and accurate models of both the performance and financing of solar systems. The System Advisor Model (SAM) and PVWatts tools provide a platform to fill that need. The overarching goal of this set of software tools is to enable accurate PV system modeling across the industry, and our usage metrics indicate that we continue to succeed in that endeavor, with a user starting SAM every 2 minutes globally, and over 17 million PVWatts hits per month. This project leveraged DOEs past investment in the SAM and PVWatts platforms to continue to provide valuable and extensible PV, battery, and financial modeling resources to the larger solar community. We pursued multiple avenues in parallel: software maintenance and technical support that are foundational to the continued usability of the SAM and PVWatts platforms; platform and PV model improvements and stakeholder engagement activities that are core to the continued relevance of the platforms; and open source activities to foster the continued creation of a vibrant open-source community around the SAM and PVWatts tools, which opens up exciting new opportunities for industry interaction.

14 SOLAR ENERGY↗

ELAS - A geobased information system that is transferable to several computers

In the early years of remote sensing, emphasis was placed on the processing and analysis of data from a single multispectral sensor, such as the Landsat Multispectral Scanner System (MSS). However, in connection with attempts to use the data for resource management, it was realized that many deficiencies existed in single data sets. A need was established to geographically reference the MSS data and to register with it data from disparate sources. Technological transfer activities have required systems concepts that can be easily transferred to computers of different types in other organizations. ELAS (Earth Resources Laboratory Applications Software), a geographically based information system, was developed to meet the considered needs. ELAS accepts data from a variety of sources. It contains programs to geographically reference the data to the Universal Transverse Mercator grid. One of the primary functions of ELAS is to produce a surface cover map.

Whitley, S. L.↗