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At least 667 records · Page 37

Co diffusion and growth of buried single-crystal CoSi2 in Si(111) by endotaxy

At a growth temperature of 800 C, Co deposited on a Si capping layer exhibits oriented growth on buried CoSi2 grains on Si(111), a process referred to as endotaxy. This occurs preferentially to surface nucleation of CoSi2, provided the thickness of the Si cap is less than a critical value of about 100 nm for deposition rates of 0.003-0.01 nm/s. The steady-state process is modeled using known values of the Co diffusion coefficient and solid solubility in Si, allowing some conclusions to be drawn regarding parameters relevant to CoSi2 epitaxy. Using this technique, single-crystal continuous layers of CoSi2 can be formed under a high-quality Si capping layer.

Fathauer, R. W.↗

The effects of titanium impurities in N/+//P silicon solar cells

Microscopic and electrical measurements were performed to explain the degradation mechanisms associated with the presence of titanium impurities in silicon. The measurements included X-ray topography, transmission electron microscopy, and deep level transient spectroscopy, before and after processing. The results indicated the presence of TiO2 precipitates, the density of which increased after phosphorus diffusion. A majority carrier trapping level was observed in the wafers before processing. It was concluded that 10% of the Ti in the N(+)/P silicon solar cells formed electrically active centers which caused degradation of the cell junction. 14% of the remaining Ti precipitated out as TiO2, forming electrically active defects, which also caused junction degradation.

Salama, A. M.↗

The kinetics of the Au-InP interaction

An analysis of the reaction of Au and Au-In alloys with InP has permitted the identification of the mechanisms occurring during the first two stages of the Au-InP interaction. The first stage of the interaction, during which the Au is converted to a saturated Au (In) solution, is controlled by the vacancy-generation rate at the free surface of the metallization. The activation energy for this process is the activation energy for Au self-diffusion. Evidence is presented for the existence of large localized variations in this value due to surface related effects. At the completion of stage I stage II becomes active and continues until the metallization is converted to Au3In. This process, proceeding via an interstitial interchange mechanism, is many orders of magnitude slower than stage I. The rate-limiting step, with an activation energy of 2.8 eV, is shown to be the diffusion of In from the InP-metal interface. The P atoms that are released when In enters the metallization during stage I leave the system without reacting, whereas in stage II they form a compound (Au2P3) at the InP-metal interface. The presence of the Au2P3 severely retards the stage II interaction rate.

Fatemi, Navid S.↗

Turbulent solutions of the equations of fluid motion

Some turbulent solutions of the unaveraged Navier-Stokes equations (equations of fluid motion) are reviewed. Those equations are solved numerically in order to study the nonlinear physics of incompressible turbulent flow. Initial three-dimensional cosine velocity fluctuations and periodic boundary conditions are used in most of the work considered. The three components of the mean-square velocity fluctuations are initially equal for the conditions chosen. The resulting solutions show characteristics of turbulence such as the linear and nonlinear excitation of small-scale fluctuations. For the stronger fluctuations, the initially nonrandom flow develops into an apparently random turbulence. Thus randomness or turbulence can arise as a consequence of the structure of the Navier-Stokes equations. The cases considered include turbulence which is statistically homogeneous or inhomogeneous and isotropic or anisotropic. A mean shear is present in some cases. A statistically steady-state turbulence is obtained by using a spatially periodic body force. Various turbulence processes, including the transfer of energy between eddy sizes and between directional components, and the production, dissipation, and spatial diffusion of turbulence, are considered. It is concluded that the physical processes occurring in turbulence can be profitably studied numerically.

Deissler, R. G.↗

Turbulent solutions of equations of fluid motion

Some turbulent solutions of the unaveraged Navier-Stokes equations (equations of fluid motion) are reviewed. Those equations are solved numerically in order to study the nonlinear physics of incompressible turbulent flow. The three components of the mean-square velocity fluctuations are initially equal for the conditions chosen. The resulting solutions show characteristics of turbulence, such as the linear and nonlinear excitation of small-scale fluctuations. For the stronger fluctuations the initially nonrandom flow develops into an apparently random turbulence. The cases considered include turbulence that is statistically homogeneous or inhomogeneous and isotropic or anisotropic. A statistically steady-state turbulence is obtained by using a spatially periodic body force. Various turbulence processes, including the transfer of energy between eddy sizes and between directional components and the production, dissipation, and spatial diffusion of turbulence, are considered. It is concluded that the physical processes occurring in turbulence can be profitably studied numerically.

Deissler, R. G.↗

Diffusion bonding of metals.

Diffusion bonding of metals, discussing interface joining processes and application to flueric devices, jet engine servovalves and porous woven structures

Kiwak, R. S.↗

Heat flow and convection demonstration experiments aboard Apollo 14.

A group of experiments was conducted by Apollo 14 astronaut Stuart A. Roosa during the lunar flyback on Feb. 7, 1971, to obtain information on heat flow and convection in gases and liquids in an environment of less than 0.000001 g gravity. Flow observations and thermal data have shown that: (1) there are, as expected, convective motions caused by surface tension gradients in a plane liquid layer with a free upper surface; (2) heat flow in enclosed liquids and gases occurs mainly by diffusive heat conduction; and (3) some convective processes, whose characteristics are not fully known, add to the heat transfer.

Grodzka, P. G.↗

Dispersive waves in a seeded MHD generator.

The equations giving the response of a slightly ionized plasma with monatomic components to sinusoidal perturbations have been formulated. Included in the model equations were the electron Hall effect, electron thermal diffusion, radiation, and electron-atom rate processes. Plasma conditions were limited to those where viscous effects, the induced magnetic field, ion slip, and atom-atom inelastic processes can be neglected. Presented are results of numerical calculations for MHD generators with a working fluid of potassium seeded argon.

Harstad, K. G.↗

Heat flow and convection demonstration (Apollo 14)

Apollo 14 Astronaut Stuart A. Roosa conducted a group of experiments during the lunar flyback on February 7, 1971, to obtain information on heat flow and convection in gases and liquids in an environment of less than 0.000001 g. Flow observations and thermal data have shown that: (1) as expected, there are convective motions caused by surface tension gradients in a plane liquid layer with a free upper surface; (2) heat flow in enclosed liquids and gases occurs mainly by diffusive heat conduction; and (3) some convective processes, whose characteristics are not fully known, add to the heat transfer. The raw data are presented, and the analysis approach is given.

Bannister, T. C.↗

A reliable all-silver front contact for silicon solar cells.

Methods have been found to apply an adherent and humidity resistant silver-only front contact to n on p silicon solar cells. The critical processing step was the removal of the diffused oxide layer. Humidity resistance is superior to present day commercial titanium-silver contacts and the electrical characteristics of the cells are excellent. Titanium, which is degraded by humidity and which is a source of heavy metal poisoning, has been eliminated from the contact.

Lamneck, J. H., Jr.↗

Optical damage and internal fields in pyroelectrics.

The physical conditions under which the models of optical damage in pyroelectrics suggested by Johnston (1970) and by Amodei (1971) might be valid are described. Whether the zero-internal-field final state described by Johnston or the no-current-flow steady state of Amodei can be reached depends on the pattern of excitation and the dynamics of the damage process. In view of the small carrier diffusion lengths, the one-dimensional models generally used may not be entirely satisfactory for investigation of dynamics.

Wood, V. E.↗

Gamma rays, cosmic rays, and galactic structure

Observations of cosmic and gamma radiation by SAS-2 satellite are summarized and analyzed to determine processes responsible for producing observed galactic radiation. In addition to the production of gamma rays in discrete galactic objects such as pulsars, there are three main mechanisms by which high-energy (greater than 100 MeV) radiation is produced by high-energy interactions involving cosmic rays in interstellar space. These processes, which produce what may be called diffuse galactic gamma-rays, are: (1) the decay of pi mesons produced by interactions of cosmic ray nucleons with interstellar gas nuclei; (2) the bremsstrahlung radiation produced by cosmic ray electrons interacting in the Coulomb fields of nuclei of interstellar gas atoms; and (3) Compton interactions between cosmic ray electrons and low-energy photons in interstellar space.

Stecker, F. W.↗

Aerospike thrust chamber program

An existing, but damaged, 25,000-pound thrust, flightweight, oxygen/hydrogen aerospike rocket thrust chamber was disassembled and partially repaired. A description is presented of the aerospike chamber configuration and of the damage it had suffered. Techniques for aerospike thrust chamber repair were developed, and are described, covering repair procedures for lightweight tubular nozzles, titanium thrust structures, and copper channel combustors. Effort was terminated prior to completion of the repairs and conduct of a planned hot fire test program when it was found that the copper alloy walls of many of the thrust chamber's 24 combustors had been degraded in strength and ductility during the initial fabrication of the thrust chamber. The degradation is discussed and traced to a reaction between oxygen and/or oxides diffused into the copper alloy during fabrication processes and the hydrogen utilized as a brazing furnace atmosphere during the initial assembly operation on many of the combustors. The effects of the H2/O2 reaction within the copper alloy are described.

Campbell, J., Jr.↗