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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37

Electrically rechargeable redox flow cells

Considering the topographical and sizing requirements for a typical pumped water storage installation and the immergence of energy conversion schemes that are time-dependent as to their generating capability, a closer look is being given to nonpumped water storage schemes for storing electricity. An electrochemical bulk power storage concept, called a rechargeable redox flow cell, is described. This scheme, based on pumping a redox couple through a power conversion section, appears to offer high overall efficiency, no cycle life limitations for the electrodes, and deep discharge capability.

Thaller, L. H.↗

The UF6 Breeder - A solution to the problems of nuclear power

One of the major advantages of uranium hexafluoride reactors for power generation is the simplified fuel reprocessing scheme which the gaseous fuel makes possible. Critical experiments related to the development of the reactors for electric power generation are discussed along with UF6 breeder reactor studies. Previous energy conversion studies are reported, taking into account gas turbine power plants, thermionic conversion, and MHD conversion. Thermodynamic cycle analyses show that high efficiencies can be achieved using UF6 as the working fluid for Rankine or Brayton cycles without requiring excessive temperatures.

Williams, J. R.↗

Correlation of solar cell electrical properties with material characteristics of silicon cast by the ubiquitous crystallization process

Solar cells were fabricated using a conservative 'baseline' process on 1-3 Omega-cm p-type silicon from ingots cast by the ubiquitous crystallization process. Conversion efficiencies of the cells were measured, as well as spectral response and minority carrier diffusion length. Adjacent slices from the same ingot were studied for their grain size, dislocation distribution, and impurity distribution. Cell performance was related to the observed structural features, as well as to the chemical structure of the ingot.

Hyland, S.↗

Radioisotope Thermophotovoltaic (RTPV) Power System for Space Applications

Thermophotovoltaic (RTV) energy conversion, coupled to the radioisotope powered General Purpose Heat Source (GPHS) is currently being developed by NASA. The goal of the program is to develop a 100 watt electrical power system with an efficient of 20%. Special control is the key element in obtaining an efficient system. Results presented show that excellent spectral control can be achieved so that reaching the goal of 20% efficiency is possible. Excellent spectral control is achieved by using a combination of selective emitters and optical filters and by eliminating radiation leakage from the optical cavity.

Chubb, Donald L.↗

Development of Stirling Convertors for Radioisotope and Fission Power Systems

NASA has been developing free-piston Stirling-cycle power convertors over the past 22 years for use in nuclear power systems that would provide electricity for space science missions to dark, dusty, or distant destinations where solar power is not practical. These nuclear power systems would generate heat from either the radioactive decay of isotopes or fission nuclear reactors. That heat would be converted to usable electricity using highly efficient Stirling convertors for a wide range of power needs needing 10s of watts to 50 kWe. NASA’s Radioisotope Power Systems (RPS) Program is maturing advanced thermoelectric and dynamic conversion technologies that would increase the system efficiency beyond what is currently possible using heritage systems to enable a larger number of robotic missions or higher power missions to solar system bodies of interest. The Dynamic Radioisotope Power Systems (DRPS) Project has matured prototype Stirling convertors to sufficiently increase the technology readiness level for infusion into flight development. Flexure and gas-bearing free-piston Stirling convertors were developed under contract by commercial partners and delivered to enable government evaluation. Gas-bearing designs have met performance and robustness requirements and were selected for flight development. This paper provides the status of SRSC test campaign and maturity level.

Dynamic↗

Development of Stirling Convertors for Radioisotope and Fission Power Systems

NASA has been developing free-piston Stirling-cycle power convertors over the past 22 years for use in nuclear power systems that would provide electricity for space science missions to dark, dusty, or distant destinations where solar power is not practical. These nuclear power systems would generate heat from either the radioactive decay of isotopes or fission nuclear reactors. That heat would be converted to usable electricity using highly efficient Stirling convertors for a wide range of power needs needing 10s of watts to 50 kWe. NASA’s Radioisotope Power Systems (RPS) Program is maturing advanced thermoelectric and dynamic conversion technologies that would increase the system efficiency beyond what is currently possible using heritage systems to enable a larger number of robotic missions or higher power missions to solar system bodies of interest. The Dynamic Radioisotope Power Systems (DRPS) Project has matured prototype Stirling convertors to sufficiently increase the technology readiness level for infusion into flight development. Flexure and gas-bearing free-piston Stirling convertors were developed under contract by commercial partners and delivered to enable government evaluation. Gas-bearing designs have met performance and robustness requirements and were selected for flight development. This paper provides the status of SRSC test campaign and maturity level.

Dynamic↗

Underlying Mechanisms of Hot Carrier-Driven Reactivity on Bimetallic Nanostructures

Bimetallic nanostructures exhibit unique catalytic activity and selectivity that is not evident for their monometallic analogs. Such nanostructures contain plasmonic metals, such as gold or silver, that afford highly efficient harvesting of electromagnetic radiation and its conversion into hot carriers. These highly energetic species are transferred to the catalytic metal sub-component of the bimetallic nanostructure, where a large spectrum of chemical reactions may be catalyzed. The strength of the electric field and the interplay between catalytic and plasmonic metals at the nanoscale are thus critically important for the catalytic activity of bimetallic nanostructures. In this study, we investigate the relationship between the catalytic activity and local electric fields sustained on the surface of gold-palladium (Au@PdNPs) and gold-platinum (Au@PtNPs) nanoplates using tip-enhanced Raman spectroscopy (TERS). We image the spatially varying magnitudes of rectified (DC) local electric fields on the surface of these nanostructures and compare them to fields sustained on the surface of monometallic nanoplates. We find substantially larger electric field magnitudes on Au@PdNPs and Au@PtNPs as compared to their monometallic analogs. These findings suggest that catalytic efficiency of bimetallic nanostructures may be mediated and potentially tuned through precise control of electric fields sustained on their surfaces.

Li, Zhandong↗

Invited article: Broadband highly-efficient dielectric metadevices for polarization control

Metadevices based on dielectric nanostructured surfaces with both electric and magnetic Mie-type resonances have resulted in the best efficiency to date for functional flat optics with only one disadvantage: a narrow operational bandwidth. Here we experimentally demonstrate broadband transparent all-dielectric metasurfaces for highly efficient polarization manipulation. We utilize the generalized Huygens principle , with a superposition of the scattering contributions from several electric and magnetic multipolar modes of the constituent meta-atoms, to achieve destructive interference in reflection over a large spectral bandwidth. Furthermore, by employing this novel concept, we demonstrate reflectionless (~90% transmission) half-wave plates, quarter-wave plates, and vector beam q-plates that can operate across multiple telecom bands with ~99% polarization conversion efficiency.

36 MATERIALS SCIENCE↗

AlGaAs converters and arrays for laser power beaming

This study reports on the development of AlGaAs/GaAs-based laser power photovoltaic (PV) converters fabricated by LPE. The monochromatic (λ = 809 nm) conversion efficiency up to 58% is measured for cells with p-n junction in Al{sub 0.07}Ga{sub 0.93}As and low (x = 0.25-0.3) Al concentration ‘window’. Modules, which have converters of low and high power laser radiation and the voltage of 4V, have been designed and fabricated. Comparison of output parameters measured at two different conditions (i.e., under flash lamp and laser beam) has been performed.

14 SOLAR ENERGY↗

A new strategy on utilizing nitrogen doped TiO{sub 2} in nanostructured solar cells: Embedded multifunctional N-TiO{sub 2} scattering particles in mesoporous photoanode

Highlights: • N-doped TiO{sub 2} scattering particles were synthesized for embedding into commercial photoanode of dye sensitized solar cells. • Embedded scatterers improved optical and electrical features of the cells. • These multifunctional scatterers increased cell performance up to 17%. - Abstract: Aggregated sub-micron size nitrogen doped TiO{sub 2} (N-TiO{sub 2}) particles with superior optical and electrical features were successfully synthesized for embedding into commercial mesoporous TiO{sub 2} photoelectrode of dye sensitized solar cells (DSSCs) as the light scattering particles compared to undoped one. X-ray photoelectron spectroscopy and absorption spectra confirmed that the titanium dioxide is sufficiently doped by nitrogen in N-TiO{sub 2} sample. Employing these high-surface N-TiO{sub 2} in mesoporous photoelectrode of solar cells, the power conversion efficiency of 8% has been achieved which shows 17% improvement for the optimum embedded level of doping (30 wt%) compared to commercial photoelectrode without additive; while enhanced efficiency is only 3% embedding undoped sub-micron size TiO{sub 2} particles. These results can introduce the novel multifunctional photoelectrode for nanostructured solar cells with enhanced values of scattering efficiency and improved electrical features including trap states density reduction in comparison to commercial mesoporous photoelectrodes.

14 SOLAR ENERGY↗

Magnetogasdynamic Power Extraction and Flow Conditioning for a Gas Turbine

An extension of the Russian AJAX concept to a turbojet is being explored. This magnetohydrodynamic (MHD) energy bypass engine cycle incorporating conventional gas turbine technology has MHD flow conditioning at the inlet to electromagnetically extract part of the inlet air kinetic energy. The electrical power generated can be used for various on-board vehicle requirements including plasma flow control around the vehicle or it may be used for augmenting the expanding flow in the high speed nozzle by MHD forces to generate more thrust. In order to achieve this interaction, the air needs to be ionized by an external means even up to fairly high flight speeds, and the leading candidates may be classified as electrical discharge devices. The present kinetic modeling calculations suggest that the use of electron beams with characteristics close to the commercially available e-beam systems (electron energy approx. 60 keV, beam current approx. 0.2 mA/sq cm) to sustain ionization in intermediate pressure, low-temperature (P = 0.1 atm, T = 300 K) supersonic air flows allows considerable reduction of the flow kinetic energy (up to 10 to 20 percent in M = 3 flows). The calculations also suggest that this can be achieved at a reasonable electron beam efficiency (eta approx. 5), even if the e-beam window losses are taken into account. At these conditions, the exit NO and O atom concentrations due to e-beam initiated chemical reactions do not exceed 30 ppm. Increasing the beam current up to approx. 2 mA/sq cm, which corresponds to a maximum electrical conductivity of sigma(sub max) approx. 0.8 mho/m at the loading parameter of K = 0.5, would result in a much greater reduction of the flow kinetic energy (up to 30 to 40 percent). The MHD channel efficiency at these conditions would be greatly reduced (to eta approx. 1) due to increased electron recombination losses in the channel. At these conditions, partial energy conversion from kinetic energy to heat would result in a significant total pressure loss (P(sub 0)/P(sub 0i) approx. 0.3). The total pressure loss can be reduced operating at the loading parameter closer to unity, at the expense of the reduced electrical power output. Raising the beam current would also result in the increase of the exit O atom concentrations (up to 600 ppm) and NO (up to 150 ppm).

Adamovich, Igor V.↗

Realization of highly efficient hexagonal boron nitride neutron detectors

Here, we report the achievement of highly efficient 10 B enriched hexagonal boron nitride (h- 10 BN) direct conversion neutron detectors. These detectors were realized from freestanding 4-in. diameter h- 10 BN wafers 43 μm in thickness obtained from epitaxy growth and subsequent mechanical separation from sapphire substrates. Both sides of the film were subjected to ohmic contact deposition to form a simple vertical “photoconductor-type” detector. Transport measurements revealed excellent vertical transport properties including high electrical resistivity (>10 13 Ω cm) and mobility-lifetime (μτ) products. A much larger μτ product for holes compared to that of electrons along the c-axis of h- BN was observed, implying that holes (electrons) behave like majority (minority) carriers in undoped h- BN. Exposure to thermal neutrons from a californium-252 ( 252 Cf) source moderated by a high density polyethylene moderator reveals that 43 μm h- 10 BN detectors possess 51.4% detection efficiency at a bias voltage of 400 V, which is the highest reported efficiency for any semiconductor-based neutron detector. The results point to the possibility of obtaining highly efficient, compact solid-state neutron detectors with high gamma rejection and low manufacturing and maintenance costs.

36 MATERIALS SCIENCE↗

Demonstration of a modeling toolkit for the design of building electrical distribution systems

The deployment of building equipment (e.g., lighting, security) and miscellaneous electrical loads that fundamentally require DC power for operation is increasing. Powering these DC loads has traditionally required an AC/DC converter, but the installation of photovoltaic (PV) and battery energy storage systems that primarily produce DC power eliminates the need for AC/DC converters at each end-device. However, analyzing system energy efficiency and cost for different electrical distribution architectures can be challenging as software tools that support this are not readily available. This paper presents preliminary results from a laboratory verification of the Building Electrical Efficiency Analysis Model (BEEAM) toolkit that was developed to address this gap. Three different eight-luminaire lighting systems comprised of market-available products were designed and modeled: one that used traditional AC distribution, a second that used a hybrid AC -to- centralized DC electrical distribution architecture, and a third that used a hybrid AC -to- distributed DC architecture. Notably, AC/DC conversions are required in all three systems. BEEAM models for LED drivers as well as Power-over-Ethernet (PoE) switches were created using laboratory characterization data. The lighting systems were simulated in Modelica, and the results were compared with each other and physics-based expectations. Simulation results show that PoE system energy efficiency is highly dependent on both device specification (e.g., LED driver and PoE switch efficiency) and system architecture (e.g., PoE switch loading) choices, as expected. For the products and system architectures selected for this study, the two DC systems were found to be less efficient than the AC system over the course of typical operation. In future work, simulation results will be compared with laboratory measurements to validate the usefulness of this software for design, and lighting systems with integrated PV and battery energy storage will be simulated to quantify the energy performance improvements that result from the elimination of some AC/DC converters.

Waghale, Anay S.↗

Hybrid strategies and technologies for full spectrum solar conversion

Harvesting the full spectrum of sunlight using a hybrid approach offers the potential for higher efficiencies, lower power production costs, and increased power grid compatibility than any single technology by itself. In this article, the base technologies for converting sunlight into electricity, including photovoltaics and solar thermal approaches are discussed. Then feasible strategies for combining them to utilize the various portions of the solar spectrum most effectively are discussed. In this study, we particularly focus on the advantages of a spectral splitting approach. This helps to convert higher energy photons (UV and visible) directly into electrons using optimized single or tandem photovoltaic (PV) cells, while capturing lower energy photons as heat using a selective solar absorber, which absorbs photons within a range of energies, down to a cutoff in the mid-infrared. The solar heat is then thermally concentrated and driven through a high temperature thermoelectric generator on top of a high efficiency mechanical engine (e.g., a steam-driven Rankine cycle) through a heat exchanger, which connects to both thermal storage and the mechanical engine at 550 °C. The thermal storage allows for significant flexibility in the time of power generation (also known as dispatchability) at a modest cost. Furthermore, the system can produce power for hours after sunset. Ideally, the system can achieve efficiencies over 50% using a combination of an InAlAs/InGaP tandem photovoltaics, ErAs:(InGaAs) 1– x (InAlAs) x thermoelectrics, and mechanical Rankine cycles. The configuration and operating conditions can be optimized to minimize the levelized cost of energy (LCOE).

14 SOLAR ENERGY↗

Accelerating Photovoltaic Market Entry with Module Replacement

Today's approach to deploying solar photovoltaics (PV) implicitly assumes that module technology is fixed. Solar panels are installed and expected to operate for the system life of 30 years or more. However, many PV technologies are improving rapidly along several dimensions, including cost, power conversion efficiency, and reliability. Periodic module replacement or planned repowering takes advantage of this technological improvement and counteracts predictable degradation. Here, we show that a module replacement strategy allows a competitive levelized cost of electricity to be achieved with an initial module lifetime of less than 15 years, assuming backward compatibility with the original system design. We also assess the life-cycle environmental impacts of module replacement and find that all commercial PV technologies offer benefits in the majority of impact categories, regardless of the replacement strategy, compared to today's electric generation mix. Module replacement can thus accelerate the market introduction and decarbonization impact of emerging PV technologies that have achieved a competitive module efficiency (=20%), cost (=$0.30/W), and lifetime (=10 years) and have the potential to improve further on all three metrics but lack decades-long field deployment experience.

14 SOLAR ENERGY↗

Condenser design for AMTEC power conversion

The condenser and the electrodes are the two elements of an alkali metal thermal-to-electric conversion (AMTEC) cell which most greatly affect the energy conversion performance. A condenser is described which accomplishes two critical functions in an AMTEC cell: management of the fluid under microgravity conditions and optimization of conversion efficiency. The first function is achieved via the use of a controlled surface shape, along with drainage grooves and arteries to collect the fluid. Capillary forces manage the fluid in microgravity and dominate hydrostatic effects on the ground so the device is ground-testable. The second function is achieved via a smooth film of highly reflective liquid sodium on the condensing surface, resulting in minimization of parasitic heat losses due to radiation heat transfer. Power conversion efficiencies of 25 percent to 30 percent are estimated with this condenser using present technology for the electrodes.

Crowley, Christopher J.↗

Evaluation of Electrical System Requirements for Implementing Turbine Electrified Energy Management

Turbine Electrified Energy Management (TEEM) is a concept concerned with the management of energy in an electrified propulsion system. The management of energy in the hybrid-electric architecture has potential to benefit the turbomachinery and the aircraft it powers. The concept is particularly useful for improving operability during transient operation and could be leveraged to design a better performing engine. The concept utilizes electric machines coupled to the engine shafts and an electric power distribution system that includes energy storage. A controller is used to decide when and how energy is moved around the electrified propulsion system, particularly when considering energy conversion between mechanical and electrical forms. Prior work has shown that the electric machines can be used to supply/or extract supplemental power to/from the engine shafts to improve their operability and achieve or enable propulsion efficiency and performance benefits. However, the previous studies did not consider the practical constraints of the electrical machines and energy storage devices that are required for implementing the TEEM system architecture concept. This paper presents an integrated engine and electrical system model that is used to evaluate the electrical system requirements. The model captures the physics of the conceptual, Advanced Geared Turbofan 30,000lbf (AGTF30) engine, which features advanced technologies such as a compact gas turbine and a variable area fan nozzle. For this work, the engine is augmented with electrical system components that allow for the implementation of the TEEM concept. The evaluation presented suggests the potential of the TEEM concept to provide performance benefits for a turbofan engine.

electrified↗

Evaluation of Electrical System Requirements for Implementing Turbine Electrified Energy Management

Turbine Electrified Energy Management (TEEM) is a concept concerned with the management of energy in an electrified propulsion system. The management of energy in the hybrid-electric architecture has potential to benefit the turbomachinery and the aircraft it powers. The concept is particularly useful for improving operability during transient operation and could be leveraged to design a better performing engine. The concept utilizes electric machines coupled to the engine shafts and an electric power distribution system that includes energy storage. A controller is used to decide when and how energy is moved around the electrified propulsion system, particularly when considering energy conversion between mechanical and electrical forms. Prior work has shown that the electric machines can be used to supply/or extract supplemental power to/from the engine shafts to improve their operability and achieve or enable propulsion efficiency and performance benefits. However, the previous studies did not consider the practical constraints of the electrical machines and energy storage devices that are required for implementing the TEEM system architecture concept. This paper presents an integrated engine and electrical system model that is used to evaluate the electrical system requirements. The model captures the physics of the conceptual, Advanced Geared Turbofan 30,000lbf (AGTF30) engine, which features advanced technologies such as a compact gas turbine and a variable area fan nozzle. For this work, the engine is augmented with electrical system components that allow for the implementation of the TEEM concept. The evaluation presented suggests the potential of the TEEM concept to provide performance benefits for a turbofan engine.

hybrid electric propulsion↗