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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

NASA Tech Briefs, July 2004

Topics: Optoelectronic Sensor System for Guidance in Docking; Hybrid Piezoelectric/Fiber-Optic Sensor Sheets; Multisensor Arrays for Greater Reliability and Accuracy; Integrated-Optic Oxygen Sensors; Ka-Band Autonomous Formation Flying Sensor; CMOS VLSI Active-Pixel Sensor for Tracking; Lightweight, Self-Deploying Foam Antenna Structures; Electrically Small Microstrip Quarter-Wave Monopole Antennas; A 2-to-28-MHz Phase-Locked Loop; Portable Electromyograph; Open-Source Software for Modeling of Nanoelectronic Devices; Software for Generating Strip Maps from SAR Data; Calibration Software for use with Jurassicprok; Software for Probabilistic Risk Reduction; Software Processes SAR Motion-Measurement Data; Improved Method of Purifying Carbon Nanotubes; Patterned Growth of Carbon Nanotubes or Nanofibers; Lightweight, Rack-Mountable Composite Cold Plate/Shelves; SiC-Based Miniature High-Temperature Cantilever Anemometer; Inlet Housing for a Partial-Admission Turbine; Lightweight Thermoformed Structural Components and Optics; Growing High-Quality InAs Quantum Dots for Infrared Lasers; Selected Papers on Protoplanetary Disks; Module for Oxygenating Water without Generating Bubbles; Coastal Research Imaging Spectrometer; Rapid Switching and Modulation by use of Coupled VCSELs; Laser-Induced-Fluorescence Photogrammetry and Videogrammetry; Laboratory Apparatus Generates Dual-Species Cold Atomic Beam; Laser Ablation of Materials for Propulsion of Spacecraft; Small Active Radiation Monitor; Hybrid Image-Plane/Stereo Manipulation; Partitioning a Gridded Rectangle into Smaller Rectangles; Digital Radar-Signal Processors Implemented in FPGAs; Part 1 of a Computational Study of a Drop-Laden Mixing Layer; and Some Improvements in Signal-Conditioning Circuits.

Source record↗
DOE OSTI2021

Shell-structure and asymmetry effects in level densities

Level density [Formula: see text] is derived for a nuclear system with a given energy [Formula: see text], neutron [Formula: see text], and proton [Formula: see text] particle numbers, within the semiclassical extended Thomas–Fermi and periodic-orbit theory beyond the Fermi-gas saddle-point method. We obtain [Formula: see text], where [Formula: see text] is the modified Bessel function of the entropy [Formula: see text], and [Formula: see text] is related to the number of integrals of motion, except for the energy [Formula: see text]. For small shell structure contribution one obtains within the micro–macroscopic approximation (MMA) the value of [Formula: see text] for [Formula: see text]. In the opposite case of much larger shell structure contributions one finds a larger value of [Formula: see text]. The MMA level density [Formula: see text] reaches the well-known Fermi gas asymptote for large excitation energies, and the finite micro-canonical limit for low excitation energies. Fitting the MMA [Formula: see text] to experimental data on a long isotope chain for low excitation energies, due mainly to the shell effects, one obtains results for the inverse level density parameter [Formula: see text], which differs significantly from that of neutron resonances.

Physics↗
DOE OSTI2024

Identification and characterization of small molecule inhibitors of the LINE-1 retrotransposon endonuclease

The long interspersed nuclear element-1 (LINE-1 or L1) retrotransposon is the only active autonomously replicating retrotransposon in the human genome. L1 harms the cell by inserting new copies, generating DNA damage, and triggering inflammation. Therefore, L1 inhibition could be used to treat many diseases associated with these processes. Previous research has focused on inhibition of the L1 reverse transcriptase due to the prevalence of well-characterized inhibitors of related viral enzymes. Here we present the L1 endonuclease as another target for reducing L1 activity. We characterize structurally diverse small molecule endonuclease inhibitors using computational, biochemical, and biophysical methods. We also show that these inhibitors reduce L1 retrotransposition, L1-induced DNA damage, and inflammation reinforced by L1 in senescent cells. These inhibitors could be used for further pharmacological development and as tools to better understand the life cycle of this element and its impact on disease processes.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2012

Microfocus x-ray imaging of traceable pointlike {sup 22}Na sources for quality control

Purpose: The purpose of this study is to propose a microfocus x-ray imaging technique for observing the internal structure of small radioactive sources and evaluating geometrical errors quantitatively, and to apply this technique to traceable pointlike {sup 22}Na sources, which were designed for positron emission tomography calibration, for the purpose of quality control of the pointlike sources. Methods: A microfocus x-ray imaging system with a focus size of 0.001 mm was used to obtain projection x-ray images and x-ray CT images of five pointlike source samples, which were manufactured during 2009-2012. The obtained projection and tomographic images were used to observe the internal structure and evaluate geometrical errors quantitatively. Monte Carlo simulation was used to evaluate the effect of possible geometrical errors on the intensity and uniformity of 0.511 MeV annihilation photon pairs emitted from the sources. Results: Geometrical errors were evaluated with sufficient precision using projection x-ray images. CT images were used for observing the internal structure intuitively. As a result, four of the five examined samples were within the tolerance to maintain the total uncertainty below {+-}0.5%, given the source radioactivity; however, one sample was found to be defective. Conclusions: This quality control procedure is crucial and offers an important basis for using the pointlike {sup 22}Na source as a basic calibration tool. The microfocus x-ray imaging approach is a promising technique for visual and quantitative evaluation of the internal geometry of small radioactive sources.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2017

On the Effect of Confinement on the Structure and Properties of Small-Molecular Organic Semiconductors

Many typical organic optoelectronic devices, such as light-emitting diodes, field-effect transistors, and photovoltaic cells, use an ultrathin active layer where the organic semiconductor is confined within nanoscale dimensions. However, the question of how this spatial constraint impacts the active material is rarely addressed, although it may have a drastic influence on the phase behavior and microstructure of the active layer and hence the final performance. Here, the small-molecule semiconductor p-DTS(FBTTh 2 ) 2 is used as a model system to illustrate how sensitive this class of material can be to spatial confinement on device-relevant length scales. It is also shown that this effect can be exploited; it is demonstrated, for instance, that spatial confinement is an efficient tool to direct the crystal orientation and overall texture of p-DTS(FBTTh 2 ) 2 structures in a controlled manner, allowing for the manipulation of properties including photoluminescence and charge transport characteristics. This insight should be widely applicable as the temperature/confinement phase diagrams established via differential scanning calorimetry and grazing-incidence X-ray diffraction are used to identify specific processing routes that can be directly extrapolated to other functional organic materials, such as polymeric semiconductors, ferroelectrics or high-refractive-index polymers, to induce desired crystal textures or specific (potentially new) polymorphs.

14 SOLAR ENERGY↗
NASA NTRS1981

Active regions from the photosphere to the chromosphere

The structures and physical conditions in that portion of a solar active region extending from the photosphere to the corona are considered. A horizontally averaged model of a solar plage is developed which is in reasonable agreement with observations, and significant discrepancies existing between quiet sun models and UV and IR spectra are noted which cast doubt on the reliability of such models. The nature of the flux tubes comprising the small-scale structure of the active regions is discussed, and the concept of filling factor is described as a basis for a flux tube model explaining changes in spectral properties. The effects of two-dimensional radiative transfer are examined for flux tubes of various cross-sectional size, and it is found that the neglect of explicit horizontal radiative interactions is a good approximation to the two-dimensional treatment. The radiative power loss from active regions is discussed for homogeneous and flux tube models, and a significant difference in total heating requirements is found. Finally, attention is given to the characteristics of the transition zone.

Chapman, G. A.↗
DOE OSTI2020

The structural basis of promiscuity in small multidrug resistance transporters

By providing broad resistance to environmental biocides, transporters from the small multidrug resistance (SMR) family drive the spread of multidrug resistance cassettes among bacterial populations. A fundamental understanding of substrate selectivity by SMR transporters is needed to identify the types of selective pressures that contribute to this process. Using solid-supported membrane electrophysiology, we find that promiscuous transport of hydrophobic substituted cations is a general feature of SMR transporters. To understand the molecular basis for promiscuity, we solved X-ray crystal structures of a SMR transporter Gdx-Clo in complex with substrates to a maximum resolution of 2.3 Å. These structures confirm the family’s extremely rare dual topology architecture and reveal a cleft between two helices that provides accommodation in the membrane for the hydrophobic substituents of transported drug-like cations.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

FORMATION AND ERUPTION OF A SMALL FLUX ROPE IN THE CHROMOSPHERE OBSERVED BY NST, IRIS, AND SDO

Using high-resolution images from the 1.6 m New Solar Telescope at Big Bear Solar Observatory, we report the direct evidence of chromospheric reconnection at the polarity inversion line between two small opposite polarity sunspots. Small jetlike structures (with velocities of ∼20–55 km s{sup −1}) were observed at the reconnection site before the onset of the first M1.0 flare. The slow rise of untwisting jets was followed by the onset of cool plasma inflow (∼10 km s{sup −1}) at the reconnection site, causing the onset of a two-ribbon flare. The reconnection between two sheared J-shaped cool Hα loops causes the formation of a small twisted (S-shaped) flux rope in the chromosphere. In addition, Helioseismic and Magnetic Imager magnetograms show the flux cancellation (both positive and negative) during the first M1.0 flare. The emergence of negative flux and the cancellation of positive flux (with shear flows) continue until the successful eruption of the flux rope. The newly formed chromospheric flux rope becomes unstable and rises slowly with a speed of ∼108 km s{sup −1} during a second C8.5 flare that occurred after ∼3 hr of the first M1.0 flare. The flux rope was destroyed by repeated magnetic reconnection induced by its interaction with the ambient field (fan–spine topology) and looks like an untwisting surge (∼170 km s{sup −1}) in the coronal images recorded by the Solar Dynamics Observatory/Atmospheric Imaging Assembly. These observations suggest the formation of a chromospheric flux rope (by magnetic reconnection associated with flux cancellation) during the first M1.0 flare and its subsequent eruption/disruption during the second C8.5 flare.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2008

The Role of Magnetic Reconnection in Solar Activity

The central challenge in solar/heliospheric physics is to understand how the emergence and transport of magnetic flux at the photosphere drives the structure and dynamics that we observe in the corona and heliosphere. This presentation focuses on the role of magnetic reconnection in determining solar/heliospheric activity. We demonstrate that two generic properties of the photospheric magnetic and velocity fields are responsible for the ubiquitous reconnection in the corona. First, the photospheric velocities are complex, which leads to the injection of energy and helicity into the coronal magnetic fields and to the efficient, formation of small-scale structure. Second, the flux distribution at the photosphere is multi-polar, which implies that topological discontinuities and, consequently, current sheets, must be present in the coronal magnetic field. We: present numerical simulations showing that photospherically-driven reconnection is responsible for the heating and dynamics of coronal plasma, and for the topology of the coronal/heliospheric magnetic field.

Antiochos, Spiro↗
DOE OSTI2020

Probing the structure of the initial state of heavy-ion collisions with p T -dependent flow fluctuations

The connection between initial-state geometry and anisotropic flow can be quantified through a well-established mapping between p T -integrated flow harmonics and cumulants of the initial transverse energy distribution. In this paper we successfully extend this mapping to also include p T -differential flow. In doing so, we find that subleading principal components of anisotropic flow can reveal previously unobserved details of the hydrodynamic response, in both the linear and the nonlinear regimes. Most importantly, we show that they provide novel information on the small-scale structures present in the initial stage of relativistic heavy-ion collisions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2013

EFFECTS OF MAGNETIC FIELD AND FAR-ULTRAVIOLET RADIATION ON THE STRUCTURES OF BRIGHT-RIMMED CLOUDS

The bright-rimmed cloud SFO 22 was observed with the 45 m telescope of Nobeyama Radio Observatory in the {sup 12}CO (J = 1-0), {sup 13}CO (J = 1-0), and C{sup 18}O (J = 1-0) lines, where well-developed head-tail structure and small line widths were found. Such features were predicted by radiation-driven implosion models, suggesting that SFO 22 may be in a quasi-stationary equilibrium state. We compare the observed properties with those from numerical models of a photoevaporating cloud, which include effects of magnetic pressure and heating due to strong far-ultraviolet (FUV) radiation from an exciting star. The magnetic pressure may play a more important role in the density structures of bright-rimmed clouds than the thermal pressure that is enhanced by the FUV radiation. The FUV radiation can heat the cloud surface to near 30 K; however, its effect is not enough to reproduce the observed density structure of SFO 22. An initial magnetic field of 5 {mu}G in our numerical models produces the best agreement with the observations, and its direction can affect the structures of bright-rimmed clouds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Metal cation coordination and solvation studied with infrared spectroscopy in the gas phase

Transition metal cation-molecular complexes are produced in the gas phase environment of a molecular beam using laser ablation in a supersonic expansion. Complexes with carbon monoxide, carbon dioxide, water, acetylene, or benzene are produced by entraining small partial pressures of these molecules into an expansion of either argon or helium. A specially designed time-of-flight mass spectrometer is employed to analyze the ions produced and to mass select them for spectroscopy. Mass-selected ions are excited in the infrared region of the spectrum with a tunable IR optical parametric oscillator laser system to measure photodissociation spectroscopy in the 2000-4500 cm -1 region. Finally, infrared band patterns, combined with structures and spectra predicted by density functional theory, reveal the coordination and solvation interactions in these systems, and how binding to metal distorts the structures of small molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

Evolution of symmetric reconnection layer in the presence of parallel shear flow

The development of the structure of symmetric reconnection layer in the presence of a shear flow parallel to the antiparallel magnetic field component is studied by using a set of one-dimensional (1D) magnetohydrodynamic (MHD) equations. The Riemann problem is simulated through a second-order conservative TVD (total variation diminishing) scheme, in conjunction with Roe's averages for the Riemann problem. The simulation results indicate that besides the MHD shocks and expansion waves, there exist some new small-scale structures in the reconnection layer. For the case of zero initial guide magnetic field (i.e., B{sub y0} = 0), a pair of intermediate shock and slow shock (SS) is formed in the presence of the parallel shear flow. The critical velocity of initial shear flow V{sub zc} is just the Alfven velocity in the inflow region. As V{sub z{infinity}} increases to the value larger than V{sub zc}, a new slow expansion wave appears in the position of SS in the case V{sub z{infinity}} < V{sub zc}, and one of the current densities drops to zero. As plasma {beta} increases, the out-flow region is widened. For B{sub y0} {ne} 0, a pair of SSs and an additional pair of time-dependent intermediate shocks (TDISs) are found to be present. Similar to the case of B{sub y0} = 0, there exists a critical velocity of initial shear flow V{sub zc}. The value of V{sub zc} is, however, smaller than the Alfven velocity of the inflow region. As plasma {beta} increases, the velocities of SS and TDIS increase, and the out-flow region is widened. However, the velocity of downstream SS increases even faster, making the distance between SS and TDIS smaller. Consequently, the interaction between SS and TDIS in the case of high plasma {beta} influences the property of direction rotation of magnetic field across TDIS. Thereby, a wedge in the hodogram of tangential magnetic field comes into being. When {beta}{yields}{infinity}, TDISs disappear and the guide magnetic field becomes constant.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Bloch-Zener oscillations in a tunable optical honeycomb lattice

Ultracold gases in optical lattices have proved to be a flexible tool to simulate many different phenomena of solid state physics [1, 2]. Recently, optical lattices with complex geometries have been realized [3, 4, 5, 6, 7], paving the way to simulating more realistic systems. The honeycomb structure has recently become accessible in an optical lattice composed of mutually perpendicular laser beams. This lattice structure exhibits topological features in its band structure – the Dirac points. At these points, two energy bands intersect linearly and the particles behave as relativistic Dirac fermions. In optical lattices, Bloch oscillations [8] resolved both in time and in quasi-momentum space can be directly observed. We make use of such Bloch-Zener oscillations to probe the vanishing energy gap at the Dirac points as well as their position in the band structure. In small band gap regions, we observe Landau-Zener tunneling [7, 9] to the second band and the regions of maximum transfer can be identified with the position of the Dirac points.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

THERMAL INSTABILITY BEHIND A SHOCK WAVE IN H I AND MOLECULAR CLOUDS

We performed one-dimensional hydrodynamic simulations with detailed cooling, heating, and chemical processes to examine the thermal stability of shocked gas in cold neutral medium (CNM) and molecular clouds. We find that both CNM and molecular clouds can be thermally unstable in the cooling layer behind the shock wave. The characteristic wavelength of the thermal instability ranges from 10{sup –5} pc to 0.1 pc in the CNM, and from 10{sup –7} pc to 0.1 pc in the molecular clouds. This coincides with the size of observed tiny scale structures in the CNM and molecular clouds, indicating that the thermal instability in the shocked gas could be a formation mechanism of these tiny structures in the interstellar medium. We have also calculated the e-folding number of the thermal instability to estimate the amplification of the density fluctuation in the shocked gas. Density perturbations in the CNM grow by a factor of exp (5) ≅ 150, whereas the perturbations in the molecular clouds grow only by a factor of a few behind a high Mach number shock. The amplification factor is larger at lower densities and higher velocities. Formation of very small scale structures by thermal instability in shocked gas is more effective in lower densities.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Scalable solution-phase epitaxial growth of symmetry-mismatched heterostructures on two-dimensional crystal soft template

Epitaxial heterostructures with precisely controlled composition and electronic modulation are of central importance for electronics, optoelectronics, thermoelectrics, and catalysis. In general, epitaxial material growth requires identical or nearly identical crystal structures with small misfit in lattice symmetry and parameters and is typically achieved by vapor-phase depositions in vacuum. We report a scalable solution-phase growth of symmetry-mismatched PbSe/Bi 2 Se 3 epitaxial heterostructures by using two-dimensional (2D) Bi 2 Se 3 nanoplates as soft templates. The dangling bond–free surface of 2D Bi 2 Se 3 nanoplates guides the growth of PbSe crystal without requiring a one-to-one match in the atomic structure, which exerts minimal restriction on the epitaxial layer. With a layered structure and weak van der Waals interlayer interaction, the interface layer in the 2D Bi 2 Se 3 nanoplates can deform to accommodate incoming layer, thus functioning as a soft template for symmetry-mismatched epitaxial growth of cubic PbSe crystal on rhombohedral Bi 2 Se 3 nanoplates. We show that a solution chemistry approach can be readily used for the synthesis of gram-scale PbSe/Bi 2 Se 3 epitaxial heterostructures, in which the square PbSe (001) layer forms on the trigonal/hexagonal (0001) plane of Bi 2 Se 3 nanoplates. We further show that the resulted PbSe/Bi 2 Se 3 heterostructures can be readily processed into bulk pellet with considerably suppressed thermal conductivity (0.30 W/m·K at room temperature) while retaining respectable electrical conductivity, together delivering a thermoelectric figure of merit ZT three times higher than that of the pristine Bi 2 Se 3 nanoplates at 575 K. Our study demonstrates a unique epitaxy mode enabled by the 2D nanocrystal soft template via an affordable and scalable solution chemistry approach. It opens up new opportunities for the creation of diverse epitaxial heterostructures with highly disparate structures and functions.

2D crystals↗
DOE OSTI2017

Bonding properties of FCC-like Au 44 (SR) 28 clusters from X-ray absorption spectroscopy

Thiolate-protected gold clusters with precisely controlled atomic composition have recently emerged as promising candidates for a variety of applications because of their unique optical, electronic, and catalytic properties. The recent discovery of the Au44(SR)28 total structure is considered as an interesting finding in terms of the face-centered cubic (FCC)-like core structure in small gold-thiolate clusters. Herein, the unique bonding properties of Au44(SR)28 is analyzed using temperature-dependent X-ray absorption spectroscopy (XAS) measurements at the Au L3-edge and compared with other FCC-like clusters such as Au36(SR)24 and Au28(SR)20. A negative thermal expansion was detected for the Au–Au bonds of the metal core (the first Au–Au shell) and was interpreted based on the unique Au core structure consisting of the Au4 units. EXAFS fitting results from Au28(SR)20, Au36(SR)24, and Au44(SR)28 show a size-dependent negative thermal expansion behavior in the first Au–Au shell, further highlighting the importance of the Au4 units in determining the Au core bonding properties and shedding light on the growth mechanism of these FCC-like Au clusters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Evaporation from thin porous Coatings: Pore size effects and predictive equation for homogeneous coatings

Evaporation of small water droplets on solids is hindered because surface tension pulls the droplet into a spherical cap that has a small perimeter. Our solution is to coat a solid with a very thin, porous layer into which the droplet flows to create a large-area disk with concomitant high rate of evaporation. We investigate evaporation by varying factors that have not been previously considered: pore size and distribution, contact angle, temperature, and relative humidity (RH). A larger pore size resulted in faster evaporation, which we explain through faster transport within the coating. Even faster evaporation occurred for a bilayer structure with small particles on the air side and larger particles on the solid side. Further, the water advancing contact angle had an insignificant effect in the range from < 10° through to 60°. Our results for different pore sizes, temperature, humidity, and contact angle all collapse onto a single curve when appropriately normalized. This validates an equation that can be used for the evaporation from a homogeneous coating that depends only one empirical factor and the droplet volume. Since the volume is often user-controlled, we envisage that this equation can be used to predict evaporation and guide design of fast-drying coatings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗