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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Towards optimal sensor placement for inverse problems in spaces of measures

The objective of this work is to quantify the reconstruction error in sparse inverse problems with measures and stochastic noise, motivated by optimal sensor placement. To be useful in this context, the error quantities must be explicit in the sensor configuration and robust with respect to the source, yet relatively easy to compute in practice, compared to a direct evaluation of the error by a large number of samples. In particular, we consider the identification of a measure consisting of an unknown linear combination of point sources from a finite number of measurements contaminated by Gaussian noise. The statistical framework for recovery relies on two main ingredients: first, a convex but non-smooth variational Tikhonov point estimator over the space of Radon measures and, second, a suitable mean-squared error based on its Hellinger–Kantorovich distance to the ground truth. To quantify the error, we employ a non-degenerate source condition as well as careful linearization arguments to derive a computable upper bound. This leads to asymptotically sharp error estimates in expectation that are explicit in the sensor configuration. Thus they can be used to estimate the expected reconstruction error for a given sensor configuration and guide the placement of sensors in sparse inverse problems.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Identification of Known and Novel Monomers for Poly(hydroxyurethanes) from Biobased Materials

Sourcing polymers from biobased materials is desirable for a transition to a more sustainable world. However, finding new monomers sourced from biobased molecules requires extensive experimental effort, due to the fact that most biomolecules lack the functional groups or properties needed to serve as a monomer in a particular polymeric system without chemical modification. In this work, we demonstrate a computational screening method to obtain monomers of a non-isocyanate polyurethane (NIPU), polyhydroxyurethane (PHU), from biomolecules. Our method generates candidate monomers from a list of 15 selected biobased starting molecules by performing chemical transformations that are standard to chemical catalysis and organic synthesis on these starting molecules and then screening the results for molecules with moieties that can be used as monomers for a PHU. Product molecules from two generations of reaction, a total number of 20,057, were analyzed automatically to identify molecules that have two or more epoxy or cyclic carbonate functional groups as candidates for further derivatization. These 21 candidate molecules were then subjected to another two generations of reaction, producing a set of 17,913 additional molecules. Further scrutiny of this set for desired functional groups characterizing PHUs and querying against the PubChem database was carried out, and 15 known molecules that are commercially available were identified, with the desirable features that they are predicted to be derived from biobased starting molecules in four or fewer steps. Moreover, molecule space generated from this process was primarily comprised of molecules that were not known to PubChem, indicating the framework also has the ability to generate novel candidate monomers that originate from biobased starting points.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Discovery and optical identification of 2S0921-630

The discovery of a faint X-ray source at approximately 282 deg galactic longitude, -9 deg galactic latitude with the rotation modulation collimator X-ray detectors aboard SAS 3 is reported. The source is designated 2S 0921-630 and is tentatively identified, on the basis of an optical search, with a 17th magnitude star exhibiting the He II line at 4686 A and H-beta in emission. The optical spectrum of this star is shown to be similar to those of the optical counterparts of Sco X-1 and other such galactic X-ray sources. It is suggested that 2S 0921-630 may belong to the class of low-luminosity galactic X-ray binaries.

Li, F. K.↗
NASA NTRS2001

An AGN Identification for 3EG J2006-2321

We present a multiwavelength analysis of the high-energy gamma-ray source 3EG J2006-2321 (l = 18 deg.82, b = -26 deg.26). The flux of this source above 100 MeV is shown to be variable on time scales of days and months. Optical observations and careful examination of archived radio data indicate that its most probable identification is with PMN J2005-2310, a flat-spectrum radio quasar with a 5GHz flux density of 260 mJy. Study of the V = 19.3 optical counterpart indicates a redshift of 0.833 and variable linear polarization. No X-ray source has been detected near the position of PMN J2005-2310, but an X-ray upper limit is derived from ROSAT data. This upper limit provides for a spectral energy distribution with global characteristics similar to those of known gamma-ray blazars. Taken together, these data indicate that 3EG J2006-2321, listed as unidentified in the 3rd EGRET Catalog, is a member of the blazar class of AGN. The 5-GHz radio flux density of this blazar is the lowest of the 68 EGRET-detected AGN. The fact that EGRET has detected such a source has implications for unidentified EGRET sources, particularly those at high latitudes (absolute value of b greater than 30 deg), many of which may be blazars.

Wallace, P. M.↗
DOE OSTI2020

Using Multiple Signatures to Improve Accuracy of Substorm Identification

Abstract We have developed a new procedure for combining lists of substorm onset times from multiple sources. We apply this procedure to observational data and to magnetohydrodynamic (MHD) model output from 1–31 January 2005. We show that this procedure is capable of rejecting false positive identifications and filling data gaps that appear in individual lists. The resulting combined onset lists produce a waiting time distribution that is comparable to previously published results, and superposed epoch analyses of the solar wind driving conditions and magnetospheric response during the resulting onset times are also comparable to previous results. Comparison of the substorm onset list from the MHD model to that obtained from observational data reveals that the MHD model reproduces many of the characteristic features of the observed substorms, in terms of solar wind driving, magnetospheric response, and waiting time distribution. Heidke skill scores show that the MHD model has statistically significant skill in predicting substorm onset times.

Haiducek, John D.↗
DOE OSTI2018

Relativistic MR–MP Energy Levels for L-shell Ions of Silicon

Level energies are reported for Si v, Si vi, Si vii, Si viii, Si ix, Si x, Si xi, and Si xii. The energies have been calculated with the relativistic Multi-Reference Møller–Plesset Perturbation Theory method and include valence and K-vacancy states with nl up to 5f. The accuracy of the calculated level energies is established by comparison with the recommended data listed in the National Institute of Standards and Technology (NIST) online database. The average deviation of valence level energies ranges from 0.20 eV in Si v to 0.04 eV in Si xii. For K-vacancy states, the available values recommended in the NIST database are limited to Si xii and Si xiii. The average energy deviation is below 0.3 eV for K-vacancy states. The extensive and accurate data set presented here greatly augments the amount of available reference level energies. Here, we expect our data to ease the line identification of L-shell ions of Si in celestial sources and laboratory-generated plasmas, and to serve as energy references in the absence of more accurate laboratory measurements.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1987

Main rotor broadband noise study in the DNW

An acoustics test of a 2/5 scale model BO-105 helicopter main rotor was conducted in the Duits-Nederlandse Windtunnel (DNW). A range of operating conditions was tested from hover to moderately high flight speeds for various climb and descent rates at different thrust settings. Diagnostic tests including rotor speed and blade geometry changes were made to better isolate and study particular broadband self noise sources. Acoustic data in the form of acoustic pressure time histories and power spectra are used to demonstrate the regions of importance of the different broadband noise sources and their sensitivity to operating conditions. To help interpret the data, comparisons are made to predictions of rotor broadband noise. The predictions are based on self noise data previously obtained from isolated airfoil sections and the use of the NASA ROTONET program to define rotor performance and to sum contributions of noise from individual blade segments. An important result herein is the identification and articulation of a previously unheralded rotor broadband noise source. This source is blade-turbulent wake interaction (BWI) noise which dominates the spectra in the mid-frequencies for off-peak blade-vortex interaction (BVI) noise flight conditions.

Brooks, Thomas F.↗
NASA NTRS2019

Alternative Datasets for Identification of Earth Science Events and Data

Alternative, or non-traditional, data sources can be used to generate datasets which can in turn be analyzed for temporal, spatial and climatological patterns. Events and case studies inferred from the analysis of these patterns can be used by the remote sensing community to more effectively search for Earth observation data. In this paper, we present a new alternative Earth science dataset created from the National Weather Service’s Area Forecast Discussion (AFD) documents. We then present an exploratory methodology for identifying interesting climatological patterns within the AFD data and a corresponding motivating example as to how these data and patterns can be used to search for relevant events or case studies.

Alternative data↗
NASA NTRS1990

Improved solution for system identification equations by Epsilon-Decomposition

Matrix eigenvalue theory is used to examine the source of ill-conditioning in linear algebraic equations. This approach highlights the crucial role played by the zero and near-zero eigenvalues and corresponding eigenvectors of poorly conditioned systems. Insight gained from this approach is used to significantly improve a recently developed solution procedure called Epsilon-Decomposition (E-D). E-D is an efficient alternative to Singular Value Decomposition (SVD) for ill-conditioned systems arising in parameter estimation and system identification studies. The efficiency of the improved E-D over SVD resides in the need to only obtain the zero and near-zero eigenvalues of the coefficient matrix as opposed to all of its eigenvalues and vectors (as required by SVD). Thus, the efficiency of E-D is significant for large matrices with small rank deficiency.

Ojalvo, Irving U.↗
DOE OSTI2020

Microbial Community Composition in Deep‐Subsurface Reservoir Fluids Reveals Natural Interwell Connectivity

Abstract The identification of natural fractures and the wells they connect is crucial for the development of geological reservoirs because it may have an important impact on reservoir model construction and hydraulic fracture propagation. In this study we investigated the use of a novel data source, the microbial community composition in the reservoir formation fluids, for identification of interwell connectivity caused by natural fractures. We verified this concept at a newly developed mesoscale enhanced geothermal system (EGS) field testbed located 4,850 ft (1,478 m) beneath ground surface at the Sanford Underground Research Facility in Lead, SD. Fluids produced at or near the EGS testbed were sampled and subjected to high‐throughput 16S rRNA gene amplicon sequencing to analyze the microbial community profile therein. Despite the typically substantial heterogeneity across the community profiles of samples spatially distributed (10 m to 1.9 km apart) throughout the site, samples from two wells at the EGS testbed showed highly similar microbial community composition, suggesting the two wells intersected the same natural fracture. This evidence of natural connectivity between the two wells at the EGS testbed was later corroborated by core log analysis and sewer camera surveys into the boreholes. Besides the field case described in this study, microbial community composition as a reservoir diagnostic tool would be applicable in a much broader context such as unconventional hydrocarbon exploitation, groundwater reservoir characterization, and environmental remediation, adding valuable “hard” data capable of pinpointing the origins of fluids unambiguously.

Zhang, Yuran↗
NASA NTRS1995

A catalog of far-ultraviolet point sources detected with the fast FAUST Telescope on ATLAS-1

We list the photometric measurements of point sources made by the Far Ultraviolet Space Telescope (FAUST) when it flew on the ATLAS-1 space shuttle mission. The list contains 4698 Galactic and extragalactic objects detected in 22 wide-field images of the sky. At the locations surveyed, this catalog reaches a limiting magnitude approximately a factor of 10 fainter than the previous UV all-sky survey, TDl. The catalog limit is approximately 1 x 10(exp -14) ergs A sq cm/s, although it is not complete to this level. We list for each object the position, FUV flux, the error in flux, and where possible an identification from catalogs of nearby stars and galaxies. These catalogs include the Michigan HD (MHD) and HD, SAO, the HIPPARCOS Input Catalog, the Position and Proper Motion Catalog, the TD1 Catalog, the McCook and Sion Catalog of white dwarfs, and the RC3 Catalog of Galaxies. We identify 2239 FAUST sources with objects in the stellar catalogs and 172 with galaxies in the RC3 catalog. We estimate the number of sources with incorrect identifications to be less than 2%.

Bowyer, Stuart↗
NASA NTRS1976

Discovery of a nonsolar extreme-ultraviolet source

Results are reported for observations of EUV emission from an extrasolar object which were made with a grazing-incidence telescope during the Apollo-Soyuz mission. The total energy flux in the spectral band between 170 and 620 A is estimated to be approximately 4 by 10 to the -9th power erg/sq cm per sec. It is shown that the data support the identification of the EUV object with the ultrasoft X-ray source in Coma Berenices. The source of both emissions is suggested to be the hot white dwarf HZ 43, located at right ascension 13 hr 43 min and declination +29 deg 22 min (1950). The temperature of HZ 43 is estimated as 110,000 K, giving it the highest temperature of any known white dwarf.

Lampton, M.↗
NASA NTRS1972

Identification of the X-ray pulsar in Hercules: A new optical pulsar

A series of photographic, photoelectric, and spectroscopic observations beginning June 1, 1972 has led to the optical identification of Her X-1 (2U 1705 + 34), a pulsed X-ray source in an eclipsing binary system, with the thirteenth magnitude blue variable star HZ Herculis. The detection of optical pulses at the frequency of the X-ray pulsar on three nights makes the identification conclusive and establishes HZ Her as the second known optical pulsar. The strength of the optical pulses may be correlated with the orbital phase but is not obviously related to the high or low intensity states of the X-ray source.

Davidsen, A.↗
NASA NTRS2015

Investigation of the Makeup, Source, and Removal Strategies for Total Organic Carbon in the Oxygen Generation System Recirculation Loop

Since 2007, the Oxygen Generation System (OGS) on board the International Space Station (ISS) has been producing oxygen for crew respiration via water electrolysis. As water is consumed in the OGS recirculating water loop, make-up water is furnished by the ISS potable water bus. A rise in Total Organic Carbon (TOC) was observed beginning in February, 2011, which continues through the present date. Increasing TOC is of concern because the organic constituents responsible for the TOC were unknown and had not been identified; hence their impacts on the operation of the electrolytic cell stack components and on microorganism growth rates and types are unknown. Identification of the compounds responsible for the TOC increase, their sources, and estimates of their loadings in the OGA as well as possible mitigation strategies are presented.

Bowman, Elizabeth M.↗
DOE OSTI2020

Stereoscopic high-speed microscopy to understand transient internal flow processes in high-pressure nozzles

The flow and cavitation behavior inside fuel injectors is known to affect spray development, mixing and combustion characteristics. We discuss that while diesel fuel injectors with converging and hydro-eroded holes are generally known to limit cavitation and feature higher discharge coefficients during the steady period of injection, less is known about the flow during transient periods corresponding to needle opening and closing. Multiple injection strategies involve short injections, multiplying these aspects and giving them a growing importance as part of the fuel delivery process. In this study, single-hole transparent nozzles were manufactured with the same hole inlet radius and diameter as the Engine Combustion Network Spray D nozzle, mounted to a modified version of a common-rail Spray A injector body and needle. Needle opening and closing periods were visualized with stereoscopic high-speed microscopy at injection pressures relevant to modern diesel engines. Time-resolved sac pressure was extracted via elastic deformation analysis of the transparent nozzles. Sources of cavitation were observed and tracked, enabling the identification of a gas exchange process after the end of injection with ingestion of chamber gas into the sac and orifice. We observed that the gas exchange contributed widely to disrupting the start of injection and outlet flow during the subsequent injection event.

42 ENGINEERING↗
DOE OSTI2021

AutoCCS: automated collision cross-section calculation software for ion mobility spectrometry–mass spectrometry

Abstract Motivation Ion mobility spectrometry (IMS) separations are increasingly used in conjunction with mass spectrometry (MS) for separation and characterization of ionized molecular species. Information obtained from IMS measurements includes the ion’s collision cross section (CCS), which reflects its size and structure and constitutes a descriptor for distinguishing similar species in mixtures that cannot be separated using conventional approaches. Incorporating CCS into MS-based workflows can improve the specificity and confidence of molecular identification. At present, there is no automated, open-source pipeline for determining CCS of analyte ions in both targeted and untargeted fashion, and intensive user-assisted processing with vendor software and manual evaluation is often required. Results We present AutoCCS, an open-source software to rapidly determine CCS values from IMS-MS measurements. We conducted various IMS experiments in different formats to demonstrate the flexibility of AutoCCS for automated CCS calculation: (i) stepped-field methods for drift tube-based IMS (DTIMS), (ii) single-field methods for DTIMS (supporting two calibration methods: a standard and a new enhanced method) and (iii) linear calibration for Bruker timsTOF and non-linear calibration methods for traveling wave based-IMS in Waters Synapt and Structures for Lossless Ion Manipulations. We demonstrated that AutoCCS offers an accurate and reproducible determination of CCS for both standard and unknown analyte ions in various IMS-MS platforms, IMS-field methods, ionization modes and collision gases, without requiring manual processing. Availability and implementation https://github.com/PNNL-Comp-Mass-Spec/AutoCCS. Supplementary information Supplementary data are available at Bioinformatics online. Demo datasets are publicly available at MassIVE (Dataset ID: MSV000085979).

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Low Pathogenicity H7N3 Avian Influenza Viruses Have Higher Within-Host Genetic Diversity Than a Closely Related High Pathogenicity H7N3 Virus in Infected Turkeys and Chickens

Within-host viral diversity offers a view into the early stages of viral evolution occurring after a virus infects a host. In recent years, advances in deep sequencing have allowed for routine identification of low-frequency variants, which are important sources of viral genetic diversity and can potentially emerge as a major virus population under certain conditions. We examined within-host viral diversity in turkeys and chickens experimentally infected with closely related H7N3 avian influenza viruses (AIVs), specifically one high pathogenicity AIV (HPAIV) and two low pathogenicity AIV (LPAIVs) with different neuraminidase protein stalk lengths. Consistent with the high mutation rates of AIVs, an abundance of intra-host single nucleotide variants (iSNVs) at low frequencies of 2–10% was observed in all samples collected. Furthermore, a small number of common iSNVs were observed between turkeys and chickens, and between directly inoculated and contact-exposed birds. Notably, the LPAIVs have significantly higher iSNV diversities and frequencies of nonsynonymous changes than the HPAIV in both turkeys and chickens. These findings highlight the dynamics of AIV populations within hosts and the potential impact of genetic changes, including mutations in the hemagglutinin gene that confers the high pathogenicity pathotype, on AIV virus populations and evolution.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Infrared Galaxies Detected by the Atacama Cosmology Telescope

We report on 167 infrared (IR) galaxies selected by AKARI and IRAS and detected in the Atacama Cosmology Telescope (ACT) Data Release 5 (DR5) sky maps at the 98, 150, and 220 GHz frequency bands. Of these detections, 134 (80%) of the millimeter counterparts are first-time identifications with ACT. We expand the previous ACT extragalactic source catalogs, by including new 98 GHz detections and measurements from ACT DR5. We also report flux density measurements at the 98, 150, and 220 GHz frequency bands. We compute α 98-150 , α 98-220 , and α 150-220 millimeter-wave spectral indices and far-IR to millimeter-wave spectral indices between 90 μm and 98, 150, and 220 GHz. We specify the galaxy type, based on α 150-220 . We combine publicly available multiwavelength data—including ultraviolet, optical, near-IR, mid-IR, far-IR, and the millimeter measurements obtained in this work—and perform spectral energy distribution (SED) fitting with CIGALE. With the radio emission decomposition advantage of CIGALE V2022.0, we identify the origins of the millimeter emissions for 69 galaxies in our sample. Our analysis also shows that millimeter data alone indicates the need for a radio synchrotron component in the SEDs that are produced by active galactic nuclei (AGNs) and/or star formation. We present SEDs and measured physical properties of these galaxies, such as the dust luminosity, AGN luminosity, the total IR luminosity, and the ratio of the IR and radio luminosity. We quantify the relationships between the total IR luminosity and the millimeter-band luminosities, which can be used in the absence of SED analysis.

79 ASTRONOMY AND ASTROPHYSICS↗