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At least 667 records · Page 37

Assessment of diagenesis in archaeological human second metacarpal bones using the intensity of the small angle X-ray scattering D -period peak

Bone consists mainly of carbonated apatite (cAp) nanoplatelets embedded in a matrix of collagen fibrils. Earlier, high-energy small angle X-ray scattering (SAXS) studies of archaeological adult human second metacarpal bones (mc2) found collagen D-period peaks with high-intensity I D in specimens in which microcomputed tomography (microCT) showed little diagenesis and I D ~ 0 for specimens where microCT revealed severe diagenesis (Park et al. 2022 Int. J. Osteoarchaeol. 32, 170–181 (doi:10.1002/oa.3053); Stock et al. 2022 Int. J. Osteoarchaeol. 32, 120–131 (doi:10.1002/oa.3049)). Here, the present paper uses SAXS at beamline 1-ID, Advanced Photon Source, Argonne National Laboratory and other techniques to study a set of 10 mc2 from an early Medieval cemetery at Greding, Germany. We hypothesized that non-invasive measurement of I D would provide an accurate and rapid (approx. 6 min/specimen) assessment of diagenesis in archaeological mc2. Results of Raman spectroscopy, laboratory microCT and backscattered electron, reflected light and polarized transmitted light microscopies confirmed the SAXS determinations, but lattice parameter values from X-ray diffraction were uncorrelated with I D value. Age-at-death estimates placed the 10 mc2 in three age categories (young adult, middle adult, old adult): lattice parameters from X-ray diffraction were uncorrelated with age at death. Cross-sectional bone area fraction from microCT dropped noticeably for the older age cohort.

Raman spectroscopy↗

Electrifying Education: Insights into Charging Electric School Buses in the United States

To combat climate change, the United States joined 193 Parties in committing to the Paris Agreement, which aims to limit global warming to 2 degrees C or less, and decarbonizing transportation will be a key requirement for achieving this goal. School buses (SBs) are a common form of student transport in the U.S. with nearly all SBs today powered by fossil fuels (primarily diesel). As a result, SBs have historically been a concerning source of both greenhouse gas (GHG) emissions and local air pollutants with negative health impacts for students and others living nearby. Electric SBs (ESBs) are a promising emerging technology for decarbonizing student transport, however, ESB adoption in the U.S. remains at an early stage (approximate 1.1%) with many outstanding uncertainties. This study aims to elucidate several of these by taking inventory of the total SB stock within U.S. states and studying real-world SB operating profiles to infer potential battery range requirements, daily charging opportunities, and charging infrastructure requirements for ESBs. In addition, we observe the geographic trends of early-stage ESB adoption, which can be used to better understand early adopter patterns and train vehicle technology adoption models.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

End-Use Savings Shapes Measure Documentation: Heat Pump Rooftop Units With Exhaust Air Energy Recovery

This technical report documents the Advanced Rooftop Unit Control End Use Savings Shapes (EUSS) measure, including providing a description of the technology, modeling methods, and the energy savings calculated from applying the measure to applicable across the US commercial building stock using ComStock to quantify its potential. This measure replaces gas furnace and electric resistance rooftop units with high-efficiency variable speed heat pump rooftop units (HP-RTU) that include exhaust air heat or energy recovery. The measure uses the same assumptions and technology as the variable speed HP-RTU measure from EUSS 2023 release 1 but adds energy recovery to precondition outdoor ventilation air to reduce HVAC loads. The HP-RTU compressor lockout temperature is modeled as 0 degrees Fahrenheit; below this temperature, the heat pump is set to shut off. The unit is sized based on the design cooling loads, with backup electric resistance heating addressing any remaining loads including heating hours below the compressor lockout temperature when there is no heat pump heating.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

End-Use Savings Shapes Measure Documentation: Heat Pump Rooftop Units

The heat pump rooftop units (RTUs) measure replaces gas furnace and electric resistance RTUs with high-efficiency heat pump rooftop units (HP-RTUs). The HP-RTUs are intended to be top-of-the line, including high-efficiency fans and heat pump systems. The fans are variable speed, allowing the HP-RTUs to operate as single-zone variable air volume systems. The heat pumps are also variable speed, allowing for high part load performance. All schedules in the existing RTUs are transferred to the new HP-RTUs for consistency. Furthermore, any energy efficiency features in the existing baseline RTUs such as energy recovery or economizers are also transferred to the new HP-RTUs for consistency. This measure is applicable to approximately 45% of the ComStock floor area. The HP-RTU measure demonstrates 10.3% total site energy savings (449 trillion British thermal units [TBtu]) for the U.S. commercial building stock modeled in ComStock.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

End-Use Savings Shapes Measure Documentation: Window Film

This documentation focuses on a single end-use savings shape measure - window film. The window film studied in this analysis, called solar control film, is a passive retrofit solution for windows that does not involve window replacement. This type of film is composed of transparent, tinted, or metalized laminated polyester layers and can be attached to an existing window surface (either on the exterior or interior side of the window). The properties of the window film are designed to shift the thermal and optical performances of the overall glazing system in order to serve various needs the customer would have (e.g., heat, glare). While the practical goal of purchasing and installing a window film varies widely in the real market, this study only focuses on the goal of energy savings, and highlighting the corresponding emissions. Other important aspects that customers typically consider include visual comfort, privacy, aesthetics, ultraviolet protection, etc. Thus, in practice, customers often choose a window film product not only to save energy (or cost) but also to mitigate issues around glare, excessive light, daytime privacy, or inconsistent appearance of the building. Window film products that were modeled in this analysis significantly reduced the solar heat gain coefficient of the overall glazing system, resulting in better energy savings for buildings in hot climate regions. However, significantly reducing the solar heat gain coefficient that can block unfavorable heat during the summer can actually harm blocking favorable heat during the winter. By applying window films on a stock of buildings covering various load and weather conditions, this analysis highlights when (e.g., time of day) and where (e.g., geospacial location) we can save energy with window films.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

ComStock Measure Documentation: Ideal Thermal Air Loads

This study provides hypothetical thermal heating and cooling loads for ComStock models representing the U.S. commercial building stock. This measure scenario removes all HVAC models from the baseline ComStock building model and instead uses "ideal air" to meet loads. "Ideal air" can be thought of as an HVAC unit that mixes air at the zone exhaust condition with the specified amount of outdoor air, and then adds or removes heat and moisture at 100% efficiency to produce a supply air stream at the specified conditions. The resulting ideal thermal loads are represented under the "district" fuel type for both heating and cooling and can be found in both annual and timeseries results in the ComStock public dataset. This measure scenario does not represent any real technology or improvement, but rather, serves as a resource for thermal heating and cooling loads for buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

ComStock Measure Documentation: Photovoltaics With 40% Rooftop Coverage

This study investigates the impact of adding 40% rooftop coverage of photovoltaics to the U.S. commercial building stock. Panels are modeled as higher performance with 21% rated efficiency, 96% inverter efficiency, 1.10 DC/AC ratio,14% system losses, and azimuth/tilt angles that vary by location. Total panel area is modeled at 40% of the roof area for each model. Total rated PV power for a building is based on the calculated total panel area and the assumed efficiency of 21%. This measure is applied to all buildings modeled in ComStock.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

ComStock Measure Scenario Documentation: Laboratory-Informed Modeling of Standard Performance Heat Pump Rooftop Units

This measure scenario replaces gas and electric resistance RTUs in the U.S. commercial building stock with standard efficiency commercial off the shelf heat pump rooftop units. This study uses performance data informed by NREL laboratory testing of a standard efficiency 7.5-ton heat pump RTU. This is the key distinction between this measure scenario and a similar ComStock measure scenario - Standard Performance Heat Pump Rooftop Units - that uses published manufacturer data tables to inform performance. These two scenarios are compared in this report.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

ResStock Measure Documentation: Cold Climate Air-Source Heat Pump

This report is part of series describing a variety of different ResStock™ measures. "Measures" refers to energy efficiency retrofits that can be applied to buildings during modeling. This documentation covers the "Cold Climate Air-Source Heat Pump" measure upgrade methodology and briefly discusses key results. All results can be accessed on the ResStock Open Energy Data Initiative "End-Use Load Profiles for the U.S. Building Stock" data lake and on the data viewer at resstock.nlr.gov.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

GHG policy impacts for Seattle’s buildings: targets, timing, and scope

Many US cities are addressing climate change by setting goals to reduce their greenhouse gas (GHG) emissions by a specified amount within a specified time period. In order to achieve these goals, reducing emissions from existing buildings is crucial. Many cities are passing legislation to target existing buildings through benchmarking, auditing, retuning, or energy or emissions performance standards. As cities design legislation, they must consider the timing of the policies, how to prioritize building types and sizes, and how these design decisions will impact the city’s emissions. This paper addresses these questions for one particular US city: Seattle, Washington. A model of Seattle’s building stock was created with benchmarking and tax assessor data. It was then used to predict GHG emissions reductions due to different policy implementations for existing commercial and multifamily buildings. Key findings are: (1) the proposed emissions policy is expected to reduce cumulative emissions from buildings by 19% between 2020 and 2050; (2) delaying the implementation of the policy by five years could limit savings to 12%; and (3) including smaller buildings in the policy could increase savings to 34%. The lessons learned and how this can be used by other cities are discussed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

New X-ray and optical observations of the X-ray discovered QSO-galaxy pair 1E 0104.2 + 3153

New X-ray and optical observations are presented of the QSO-galaxy pair 1E 0104.2 + 3153, originally discovered as a serendipitous source in the Einstein Observatory Medium Sensitivity Survey (Gioia et al., 1984). Results from an extremely deep Exosat observation are used to suggest that the QSO rather than the compact group of galaxies is the optical counterpart of the IPC source. High-resolution (1-A) spectroscopy of the broad-absorption-line QSO, which fails to confirm the Ca II H and K absorption features reported by Stocke et al., (1984), is presented and discussed. The presence of broad absorption lines in the QSO spectrum may indicate that intrinsic absorption is the cause of the nondetection of this source in the soft Exosat energy band. Optical monitoring of the QSO over a 2-yr period indicates variability. Possible interpretations of this phenomenon are intrinsic luminosity variation or a cessation of a gravitational lensing effect acting at the time of the Einstein observation.

Gioia, I. M.↗

The Medium Sensitivity Survey and the X-ray selected quasar sample

Statistical investigations of X-ray-emitting quasars are reviewed, focusing on the possible incompleteness of the Einstein IPC Medium Sensitivity Survey (MSS) (Maccacaro et al., 1982; Stocke et al., 1983; Gioia et al., 1984). The criteria used in constructing the MSS and calculating the source parameters are discussed, and the corrections determined for each line of sight by Maccacaro and Gioia (1986) on the basis of the H I measurements of Stark et al. (1986) are shown to have no effect on the completeness of the MSS extragalactic sample as a whole and of the quasar sample in particular. Other possible reasons for inconsistencies between the MSS sample and optically selected quasar samples are considered; ongoing efforts to expand the MSS sample are described; and some preliminary results are presented in graphs.

Gioia, Isabella M.↗

Probing the Interstellar Medium of External Galaxies Using Quasar Absorption Lines: the 3C 232/NGC 3067 System

Quasar absorption lines offer unique opportunities to probe the interstellar medium of external galaxies. Researchers present new optical and UV absorption line spectroscopy of the quasar 3C232 (z=0.55) revealing new detail in the foreground absorption system due to the bright, spiral galaxy NGC 3067 (cz=1420 km/s). Specifically, the spectra show evidence for two and possibly three separate absorption components in CaII and Na I spanning approx. 150 km/s. The original HI detection of Haschick and Burke (1975) corresponds to the strongest of these metal systems which exhibits doublet ratios consistent with saturation in both CaII and Na I. Due to the recent detection in HI emission of a tidal tail or finger of HI extending from the western edge of NGC 3067 through the position of 3C 232 (Carilli, van Gorkom and Stocke, 1989), the morphology of the HI absorber is now known and is not either a warped disk nor a spherical halo as had been proposed. New deep continuum and H alpha imaging provides a sensitive upper limit on the the ionizing continuum impinging upon this cloud (and thus a limit on the intensity of the extragalactic ionizing radiation field). Together with the observed UV spectrum of 3C 232, the optical emission line ratios and the deep H alpha imaging set a minimum distance between the quasar and the HI cloud disregarding redshift information. This limit strains the non-cosmological redshift interpretation for 3C 232 -- and this quasar is one of the original 5 3C quasars found to be too close to NGC galaxies as if by chance (Burbidge, Burbidge, Solomon and Strittmatter, 1972).

Stocke, John T.↗

Discovery of neutral hydrogen 21 centimeter absorption at redshift 0.25 toward PKS 1413+135

A strong H I 21-cm absorption line is identified toward PKS 1413+135 at the redshift of the host galaxy and argued to indicate that the IR-optical cutoff of the BL Lac object's spectrum is caused by extinction. The BL Lac object is shown to have strong neutral 21-cm absorption at the redshift range z = 0.24671 +/- 0.00001, and the implied H I column density is derived. The H I covering factor is assumed to be not more than 0.1, suggesting that a high degree of extinction exists in the galaxy. The host galaxy is theorized to be a spiral of type later than S0 based on the redshift of the H I absorption line and the host. The statistical and observational conclusions are found to support the theories of Stock et al. (1992) regarding the red spectrum of the object.

Carilli, C. L.↗

The new BL Lacertae objects discovered by an efficient X-ray/radio/optical technique

We report the recent discovery of ten BL Lac objects in the Einstein IPC Slew Survey by means of X-ray/radio versus X-ray/optical color-color diagrams and confirming optical spectroscopy. These ten BL Lac objects were discovered using a technique proposed by Stocke et al. (1989) which exploits the characteristic broad-band spectra of BL Lac objects. New VLA detections provide accurate fluxes (limiting f(6 cm) about 0.5 mJy) and about 1 arcsec positions, facilitating the determination of an optical counterpart. All ten new BL Lac objects show essentially featureless optical spectra and lie within the range of radio/X-ray/optical colors of known X-ray-selected BL Lac objects, when about 1 mag optical variability is included. We expect about 50 new BL Lac objects in total, from complete optical follow-up of our now completed VLA work and recent Australia Telescope observations, yielding a complete Slew Survey sample of about 90 BL Lac objects.

Schachter, Jonathan F.↗

Intergalactic Hydrogen Clouds at Low Redshift: Connections to Voids and Dwarf Galaxies

We provide new post-COSTAR data on one sightline (Mrk 421) and updated data from another (I Zw 1) from our Hubble Space Telescope (HST) survey of intergalactic Ly(alpha) clouds located along sightlines to four bright quasars passing through well-mapped galaxy voids (16000 km/s pathlength) and superclusters (18000 km/s). We report two more definite detections of low-redshift Ly(alpha) clouds in voids: one at 3047 km/s (heliocentric) toward Mrk 421 and a second just beyond the Local Supercluster at 2861 km/s toward I Zw 1, confirming our earlier discovery of Ly(alpha) absorption clouds in voids (Stocke et al., ApJ, 451, 24). We have now identified ten definite and one probable low-redshift neutral hydrogen absorption clouds toward four targets, a frequency of approximately one absorber every 3400 km/s above 10(exp 12.7/sq cm column density. Of these ten absorption systems, three lie within voids; the probable absorber also lies in a void. Thus, the tendency of Ly(alpha) absorbers to 'avoid the voids' is not as clear as we found previously. If the Ly(alpha) clouds are approximated as homogeneous spheres of 100 kpc radius, their masses are approximately 10(exp 9)solar mass (about 0.01 times that of bright L* galaxies) and they are 40 times more numerous, comparable to the density of dwarf galaxies and of low-mass halos in numerical CDM simulations. The Ly(alpha) clouds contribute a fraction Omega(sub cl)approximately equals 0.003/h(sub 75) to the closure density of the universe, comparable to that of luminous matter. These clouds probably require a substantial amount of nonbaryonic dark matter for gravitational binding. They may represent extended haloes of low-mass protogalaxies which have not experienced significant star formation or low-mass dwarf galaxies whose star formation ceased long ago, but blew out significant gaseous material.

Shull, J. Michael↗

Tree Growth Enhancement Drives a Persistent Biomass Gain in Unmanaged Temperate Forests

While enhanced tree growth over the last decades has been reported in forests across the globe, it remains unclear whether it drives persistent biomass increases of forest stands, particularly in mature forests. Enhanced tree growth and stand-level biomass are often linked with a simultaneous increase in density-driven mortality and a reduction in tree longevity. Identifying empirical evidence regarding the balance between these processes is challenging due to the confounding effects of stand history, management, and environmental changes. Here, we investigate the link between growth and biomass via the negative relationship between average tree size and stand density (tree number per area). We find increasing stand density for a given mean tree size in unmanaged closed-canopy forests in Switzerland over the past six decades and a positive relationship between tree growth and stand density across forest plots—qualitatively consistent with our simulations using a mechanistic, cohort-resolving ecosystem model (BiomeE). Model simulations show that, in the absence of other disturbances, enhanced tree growth persistently increases biomass stocks despite simultaneous decreases in carbon residence time and tree longevity. However, the magnitude of simulated biomass changes for a given growth enhancement critically depends on the shape of the mortality functions. Our analyses reconcile reports of growth-induced reductions of tree longevity with model predictions of persistent biomass increases, and with our finding of trends toward denser forests in response to growth—also in mature stands.

biomass stocks↗

BETO 2021 Peer Review - Biological Upgrading of Sugars (BUS) 2.3.2.105

The Biological Upgrading of Sugars (BUS) project directly targets the anaerobic conversion of lignocellulosic feedstocks into intermediate molecules readily upgradeable to fuel precursors. Recent efforts on the BUS project have a particular emphasis on the biological production of butyric acid, an intermediate that can be readily upgraded to sustainable aviation fuel, diesel blend-stocks, and high value chemicals. The BUS project approaches this direction through a combination of strain engineering, fermentation process engineering, development of novel separations technologies, and the design and build of pilot scale systems. Our ultimate project goal is to develop an integrated cost-effective process at pilot scale to achieve DOE's MYPP targets of $2.50/GGE. The major thrust of the BUS project over the last project cycle was on the development of integrated processes surrounding the anaerobic production of carboxylic acids using diverse Clostridium species. We developed and expanded genetic tools for several Clostridium species and rewired microbial metabolism in an attempt to maximize substrate utilization and flux towards butyric acid. We designed and built novel bioreactors with an in situ product recovery system enabling the biological production and recovery of highly purified acids. We leveraged this system to generate 100s of grams of acid from corn stover hydrolysate. In this presentation we highlight data surrounding our proposed process and accompanying results from technoeconomic and life-cycle analyses of our integrated process. Finally, we detail plans of our pilot scale reactor system that is in process and discuss our future routes towards achieving economically viable and sustainable diesel and jet blendstocks.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗