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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Two-electron redox active molecules with high capacity and energy density for energy storage applications

A non-aqueous redox flow battery includes a catholyte including a compound of formula (I): wherein E1 and E2 are independently O, S, S═O, S(═O)2, Se, NR11, or PR11; The compounds of the present technology are capable of undergoing a reversible two-electron transfer process, thus leading to high efficiency of molecular design and an increase in the overall energy density.

Huang, Jinhua↗

Cycloturbine modular river current energy converter and method and apparatus for deploying marine hydrokinetic turbine assembly to harvest riverine and ocean tidal current energy

A hydrokinetic turbine system for harvesting energy from riverine and tidal sources, including a first floating dock, a marine hydrokinetic turbine mounted on the first floating dock, and a second floating dock. The system further includes a winch assembly mounted on the second floating dock and operationally connected to the first floating dock and a linkage assembly operationally connected to the first floating dock and to the second floating dock. The linkage assembly may be actuated to pull the first floating dock into contact with the second floating dock. The linkage assembly may be actuated to distance the first floating dock from the second floating dock, and the winch assembly may be energized to orient the first floating dock into a position wherein the marine hydrokinetic turbine is above the first floating dock and wherein the winch assembly may be energized to orient the first floating dock into a position wherein the marine hydrokinetic turbine is below the first floating dock.

Chen, Jun↗

Efficient continuous Energy-Multigroup hybrid depletion scheme using the Shift Monte Carlo code. Part I: Energy condensation sensitivity analysis

Monte Carlo (MC) codes coupled to depletion solvers are increasingly used to provide high fidelity fuel cycle modeling capabilities. Here, these coupled depletion-MC tools produce accurate results in general but can experience nonphysical spatial oscillations when time steps are large or when a system’s dominance ratio approaches unity. Two substepping techniques have been developed previously to remedy and dampen these spatial oscillations without needing to reduce step sizes. The first approach relied on higher-order techniques to account for spectral changes within steps (extrapolation and interpolation techniques). The second approach used the first order perturbation (FOP) theory to account for the change in the one-group spatial flux distribution within steps. This paper develops a hybrid depletion methodology which, in a way, combines how the flux is handled in both substepping techniques. Specifically, the multigroup (MG) MC Shift code is used to update the flux distribution within steps rather than a one-group FOP solver. A fully reflected pincell is investigated, which is not spatially dependent in the MG representation. Thus, the analysis in this paper is an initial demonstration of hybrid depletion. An upcoming companion paper will focus on how the hybrid depletion dampens spatial oscillations. The hybrid depletion approach is verified to be consistent with previous constant extrapolation depletion (CED) methods. This paper finds that the hybrid CED exhibits some error in the eigenvalue and one group constants within macro steps. To address this discrepancy, a simple interpolation scheme (CELI) is investigated. This work found that CELI sufficiently addresses the discrepancy in spectrum for macro steps up to 100 days. Overall, this work demonstrates that the hybrid depletion method can significantly reduce the number of high fidelity MC executions in a MC-coupled depletion with an acceptable eigenvalue error.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Insights into the Cathode–Electrolyte Interphases of High-Energy-Density Cathodes in Lithium-Ion Batteries

Here we present a comprehensive study of cycled high-Ni (LiNi 1–x M x O 2 , M = metals), Li-rich (Li 1+x Mn y M 1–x–y O 2 ), and high-voltage spinel (LiMn 1.5 Ni 0.5 O 4 ) electrodes with time-of-flight secondary ion mass spectrometry (TOF-SIMS) and X-ray photoelectron spectroscopy in conjunction with electrochemical techniques to better understand their evolving cathode–electrolyte interphase structure during cycling. TOF-SIMS provides fragment-specific information regarding the surface film content for each of the electrodes. High-Ni cathodes show thick surface films initially containing Li 2 CO 3 , later developing oxidized organic carbonates throughout cycling. Li-rich electrode surface films develop strong characteristics during their first activation cycles, where released O 2 oxidizes organic carbonates to form polymeric carbons and decomposes LiPF 6 . High-voltage spinel electrodes operate outside the standard electrolyte stability window, generating reactive oxidized electrolyte species that further decompose LiPF 6 . The distribution and concentration of these different chemical fragments measured by TOF-SIMS are finally summarized by color-coded high-resolution images of cycled high-Ni, Li-rich, and high-voltage spinel electrodes.

25 ENERGY STORAGE↗

Fault Response of Distributed Energy Resources Considering the Requirements of IEEE 1547-2018

Inverter-based DER responses to faults on the electric power system are different than those of conventional generators and are often poorly understood. Inverter fault responses are largely software-defined, within physics-based constraints. DERs are regulated by standards and grid codes that also constrain their responses. Though fault response of DERs will vary widely, for any DER following any particular standard, a pattern of fault response can be synthesized by observing that particular standard. In this paper, the recently published IEEE 1547-2018 is examined to explore the general fault response of any DER that follows IEEE 1547-2018. Additionally, an IEEE 1547-2018 compliant inverter model is developed and tested in simulation to find the fault response, and that response is compared with the fault response of a commercial off-the-shelf inverter.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Acoustic Doppler Velocimeter (ADV) data from the University of New Hampshire Atlantic Marine Energy Center (UNH-AMEC ) Tidal Energy Test Site during a Perigean Spring Tide

The ADV measurements contained in this submission were taken on the floating turbine deployment platform (TDP) located at the Memorial Bridge in Portsmouth, NH. The measurements were conducted 11/4/2021-11/9/2021 with the fastest currents occurring on 11/7/2021. Along with the submission of ADV data, a .ppt and text document further explaining the ADV deployment location is included.

16 TIDAL AND WAVE POWER↗