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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Investigation of critical burning of fuel droplets

The steady combustion characteristics of droplets were considered in combustion chamber environments at various pressures, flow conditions, and ambient oxidizer concentrations for a number of hydrocarbon fuels. Using data obtained earlier, predicted gasification rates were within + or - 30% of measurements when the correction for convection was based upon average properties between the liquid surface and the flame around the droplet. Analysis was also completed for the open loop response of monopropellant droplets, based upon earlier strand combustion results. At the limit of large droplets, where the effect of flame curvature is small, the results suggest sufficient response to provide a viable mechanism for combustion instability in the frequency and droplet size range appropriate to practical combustors. Calculations are still in progress for a broader range of droplet sizes, including conditions where active combustion effects are small.

Faeth, G. M.↗

Survey study of the efficiency and economics of hydrogen liquefaction

The production of liquid hydrogen, with coal as the starting material, is reported. The minimum practicable energy and cost for liquefaction of gaseous hydrogen in the 1985-2000 time period is presented to investigate the possible benefits of the integration of coal gasification processes with the liquefaction process.

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Combustion of liquid fuels in a flowing combustion gas environment at high pressures

The combustion of fuel droplets in gases which simulate combustion chamber conditions was considered both experimentally and theoretically. The fuel droplets were simulated by porous spheres and allowed to gasify in combustion gases produced by a burner. Tests were conducted for pressures of 1-40 atm, temperatures of 600-1500 K, oxygen concentrations of 0-13% (molar) and approach Reynolds numbers of 40-680. The fuels considered in the tests included methanol, ethanol, propanol-1, n-pentane, n-heptane and n-decane. Measurements were made of both the rate of gasification of the droplet and the liquid surface temperature. Measurements were compared with theory, involving various models of gas phase transport properties with a multiplicative correction for the effect of forced convection.

Canada, G. S.↗

Environmental considerations

A comparison was made between the environmental impact of the present nuclear-heated process and the currently commercial hydrogen-producing process utilizing coal for heating, i.e., the Lurgi coal gasification process. This comparison is based on the assumption that both plants produce the same quantity of H2, i.e., 269 cu m/sec of approximately the same purity, that all pollution abatement equipment is of the same design and efficiency for both the Lurgi process and the nuclear process, and that the energy required for the fresh nuclear fuel and the fuel recycle is generated in a power plant which is also provided with pollution abatement equipment. The pollution caused by the auxiliary units is also taken into account. As regards process water usage, the data show that the water required for the nuclear route, including the nuclear fuel production, is approximately 78% of that required for the Lurgi route.

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Hydrogen production

The state of hydrogen production technology is evaluated. Specific areas discussed include: hydrogen production fossil fuels; coal gasification processes; electrolysis of water; thermochemical production of hydrogen; production of hydrogen by solar energy; and biological production of hydrogen. Supply options are considered along with costs of hydrogen production.

England, C.↗

Conservation in the energy industry

The basic energy supply and utilization problems faced by the United States were described. Actions which might alleviate the domestic shortfall of petroleum and natural gas are described, analyzed and overall impacts are assessed. Specific actions included are coal gasification, in situ shale oil production, improved oil and gas recovery, importation of liquid natural gas and deregulation of natural gas prices. These actions are weighed against each other as alternate techniques of alleviating or overcoming existing shortfalls.

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The Conceptual Design of an Integrated Nuclearhydrogen Production Plant Using the Sulfur Cycle Water Decomposition System

A hydrogen production plant was designed based on a hybrid electrolytic-thermochemical process for decomposing water. The sulfur cycle water decomposition system is driven by a very high temperature nuclear reactor that provides 1,283 K helium working gas. The plant is sized to approximately ten million standard cubic meters per day of electrolytically pure hydrogen and has an overall thermal efficiently of 45.2 percent. The economics of the plant were evaluated using ground rules which include a 1974 cost basis without escalation, financing structure and other economic factors. Taking into account capital, operation, maintenance and nuclear fuel cycle costs, the cost of product hydrogen was calculated at $5.96/std cu m for utility financing. These values are significantly lower than hydrogen costs from conventional water electrolysis plants and competitive with hydrogen from coal gasification plants.

Farbman, G. H.↗

Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 3: Combustors, furnaces and low-BTU gasifiers

Information is presented on the design, performance, operating characteristics, cost, and development status of coal preparation equipment, combustion equipment, furnaces, low-Btu gasification processes, low-temperature carbonization processes, desulfurization processes, and pollution particulate removal equipment. The information was compiled for use by the various cycle concept leaders in determining the performance, capital costs, energy costs, and natural resource requirements of each of their system configurations.

Hamm, J. R.↗

Sulfidation of 310 stainless steel at sulfur potentials encountered in coal conversion systems

The sulfidation of SAE 310 stainless steel was carried out in gas mixtures of hydrogen and hydrogen sulfide over a range of sulfur potentials anticipated in advanced coal gasification processes. The kinetics, composition, and morphology of sulfide scale formation were studied at a fixed temperature of 1,065 K over a range of sulfur potentials from .00015 Nm to the -2nd power to 900 Nm to the -2nd power. At all sulfur potentials investigated, the sulfide scales were found to be multilayered. The relative thickness of the individual layers as well as the composition was found to depend on the sulfur potential. The reaction was found to obey the parabolic rate law after an initial transient period. Considerably longer transient periods were found to be due to unsteady state conditions resulting from compositional variations in the spinel layer. The sulfur pressure dependence on the parabolic rate constant was found to best fit the equation K sub p equals const. (P sub S2) to the 1/nth power, where n equals 3.7. The growth of the outer layers was found to be primarily due to the diffusion of metal ions, iron being the predominant species. The inner layer growth was due to the dissociation of the primary product at the alloy scale interface and depended on the activity of chromium.

Rao, D. B.↗

Analytical investigation of thermal barrier coatings on advanced power generation gas turbines

An analytical investigation of present and advanced gas turbine power generation cycles incorporating thermal barrier turbine component coatings was performed. Approximately 50 parametric points considering simple, recuperated, and combined cycles (including gasification) with gas turbine inlet temperatures from current levels through 1644K (2500 F) were evaluated. The results indicated that thermal barriers would be an attractive means to improve performance and reduce cost of electricity for these cycles. A recommended thermal barrier development program has been defined.

Amos, D. J.↗

The NASA Hydrogen Energy Systems Technology study - A summary

This study is concerned with: hydrogen use, alternatives and comparisons, hydrogen production, factors affecting application, and technology requirements. Two scenarios for future use are explained. One is called the reference hydrogen use scenario and assumes continued historic uses of hydrogen along with additional use for coal gasification and liquefaction, consistent with the Ford technical fix baseline (1974) projection. The expanded scenario relies on the nuclear electric economy (1973) energy projection and assumes the addition of limited new uses such as experimental hydrogen-fueled aircraft, some mixing with natural gas, and energy storage by utilities. Current uses and supply of hydrogen are described, and the technological requirements for developing new methods of hydrogen production are discussed.

Laumann, E. A.↗

Sulfidation of 310 stainless steel at sulfur potentials encountered in coal conversion systems

The sulfidation of SAE 310 stainless steel was carried out in gas mixtures of hydrogen and hydrogen sulfide over a range of sulfur potentials anticipated in advanced coal gasification processes. The kinetics, composition, and morphology of sulfide scale formation were studied at a fixed temperature of 1065 K over a range of sulfur potentials from .00015N/sqm to 900N/sqm. At all sulfur potentials investigated, the sulfide scales were found to be multilayered. The relative thickness of the individual layers as well as the composition was found to depend on the sulfur potential. The reaction was found to obey the parabolic rate law after an initial transient period. Considerably longer transient periods were found to be due to unsteady state conditions resulting from compositional variations in the spinel layer.

Rao, D. B.↗

Comparative assessment of orbital and terrestrial central power plants

Recent studies of the space power system (SPS) are integrated into a total social cost framework developed for terrestrial central electric power systems. Total social costs include the projection of commercial economics to the time frame of interest as well as the federal research, development and demonstration (RD&D) costs, the health impacts, the resources required, the environmental impacts and other social costs. The SPS system is limited to transporting all materials from the earth's surface to geosynchronous orbit. Only silicon photovoltaic is considered as the SPS energy conversion technique. Costs and impacts of the LWR are considered as a reference for nuclear systems, and the low BTU coal gasification with combined cycle gas and steam turbines is considered as a reference for a fossil central electric plant. The ground solar systems considered are solar thermal using the central receiver approach with thermal storage, and solar photovoltaic using the silicon cell with battery storage.

Caputo, R.↗

Proceedings of the conference on Coal Feeding Systems

Development of coal feed systems for coal gasification, fluidized bed combustion, and magnetohydrodynamic applications is discussed. Process operations experience, energy conversion efficiency, and environment effects are among the factors considered.

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Dry coal feeder development program at Ingersoll-Rand Research, Incorporated

A dry coal screw feeder for feeding coal into coal gasification reactors operating at pressures up to 1500 psig is described. Results on the feeder under several different modes of operation are presented. In addition, three piston feeder concepts and their technical and economical merits are discussed.

Mistry, D. K.↗

Interdisciplinary research and development on the effects of the nature and properties of ceramic materials in the design of advanced structural components

An educational development and supportive research program on ceramic materials established to advance design methodology, improve materials, and develop engineers knowledgable in design with and use of high performance ceramic materials is described. Emphasis is on the structures and related materials problems in a ceramic turbine engine, but applications in coal gasification, solar conversion, and magnetohydrodynamic technologies are considered. Progress of various research projects in the areas of new materials, processing, characterization, and nondestructive testing is reported. Fracture toughness determination, extended X-ray absorption fine structure measurements, and grain boundary effects in beta-alumina are among the topics covered.

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Stability of chromium (III) sulfate in atmospheres containing oxygen and sulfur

The stability of chromium sulfate in the temperature range from 880 K to 1040 K was determined by employing a dynamic gas-solid equilibration technique. The solid chromium sulfate was equilibrated in a gas stream of controlled SO3 potential. Thermogravimetric and differential thermal analyses were used to follow the decomposition of chromium sulfate. X-ray diffraction analysis indicated that the decomposition product was crystalline Cr2O3 and that the mutual solubility between Cr2(SO4)3 and Cr2O3 was negligible. Over the temperature range investigated, the decomposition pressure were significantly high so that chromium sulfate is not expected to form on commercial alloys containing chromium when exposed to gaseous environments containing oxygen and sulfur (such as those encountered in coal gasification).

Jacob, K. T.↗