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NASA NTRS2002

The Effect of Transport and Circulation Differences on Stratospheric Ozone Recovery in Two 35-year Three-dimensional Simulations

The NASA Global Modeling Initiative (GMI) has completed two 35-year simulations with WMO future baseline boundary conditions that simulate increasing N2O and CH4 emissions and decreasing organic chlorine and bromine emissions. Simulations were done with the GMI offline chemistry and transport model using 1) 1 year of winds from the Finite-Volume General Circulation Model (FV-GCM), repeated for the 35 years, and 2) 1 year of winds from the Finite-Volume Data Assimilation System (FV-DAS), repeated for 35-years. The simulations have full stratospheric chemistry. To understand differences in simulated ozone recoveries, basic transport and circulation differences between these models are evaluated. The distribution of mean age of stratospheric air in the FV-GCM run agrees well with observations in the lower stratosphere but the FV-DAS ages are generally too low. This implies circulation and mixing differences that will affect the distributions of other trace species such as CH4, NO, and the organic halogens, all of which are responding to changing boundary conditions and are involved in ozone loss. Realism of model transport is evaluated, with particular attention given to regions and seasons where ozone recovery is expected. Preliminary results indicate increasing ozone trends in the lowermost stratosphere in summer and in the Antarctic and Arctic lower stratosphere in winter and spring.

Bhartia, P. K.↗
NASA NTRS2003

Chemistry Related to Possible Outgassing Sources on Mars

An earlier paper, Chemical markers of possible hot spots on Mars by A. S. Wong, S. K. Atreya and Th. Encrenaz, explored the modification of the atmosphere of Mars following an influx of methane, sulfur dioxide and hydrogen sulfide (CH4, SO2, H2S) from any outgassing sources which are referred to as hot spots. The feasibility of detection of the new species by Planetary Fourier Spectrometer on Mars Express is reported in a subsequent paper, Atmospheric photochemistry above possible martian hot spots by A. S. Wong, S. K. Atreya, V. Formisano, Th. Encrenaz and N. Ignatiev. This abstract is a follow-up on the previous two papers. Here we treat the effect of any outgassed halogens rigorously. We also make estimates of dilution factors relative to the source location following convection and meridional transport.

A S Wong↗
NASA NTRS2002

HALOE Observations of Perturbations in High Northern Latitude NO and O3 During the April 2002 Solar Storm Episode

The April 2002 solar storm event provides a unique opportunity to study the resulting effects on upper atmospheric constituents such as NO and O3. Two sources may perturb these constituents. For a magnetic-storm-source, energetic particles collide with and dissociate N2 in the lower thermosphere to produce excited nitrogen atoms which then combine with O to produce NO. The NO subsequently is transported down to lower altitudes where it reacts with and thus destroys mesospheric and possibly stratospheric ozone. For a solar-particle-event-source, high energy particles penetrate directly into the mesosphere, break apart N2 and water vapor, creating NOx and HOx to destroy ozone in the middle atmosphere. We present perturbations in high northern latitude NO and O3 as measured by the Halogen Occultation Experiment (HALOE) aboard the Upper Atmosphere Research Satellite between April 20-27. HALOE observations show an order of magnitude increase in mesospheric NO and a factor of approximately 2 decrease in mesospheric O3. We will also compare these observations with NASA GSFC 2D model computations.

Anderson, John↗
NASA NTRS2003

Volcanic Origin of Alkali Halides on Io

The recent observation of NaCl (gas) on Io confirms our earlier prediction that NaCl is produced volcanically. Here we extend our calculations by modeling thermochemical equilibrium of O, S, Li, Na, K, Rb, Cs, F, Cl, Br, and I as a function of temperature and pressure in a Pele-like volcanic gas with O/S/Na/Cl/K = 1.518/1/0.05/0.04/0.005 and CI chondritic ratios of the other (as yet unobserved) alkalis and halogens. For reference, the nominal temperature and pressure for Pele is 1760 plus or minus 210 K and 0.01 bars based on Galileo data and modeling.

Schaefer, L.↗
NASA NTRS2004

The Influence of Solar Proton Events in Solar Cycle 23 on the Neutral Middle Atmosphere

Solar proton events (SPEs) can cause changes in constituents in the Earth's middle atmosphere. The highly energetic protons cause ionizations, excitations, dissociations, and dissociative ionizations of the background constituents, which lead to the production of HO(x) (H, OH, HO2) and NO(y) (N, NO, NO2, NO3, N2O5, HNO3, HO2NO2, ClONO2, BrONO2). The HO(x) increases lead to short-lived ozone decreases in the mesosphere and upper stratosphere due to the short lifetimes of the HO, constituents. The NO(x) increases lead to long-lived stratospheric ozone changes because of the long lifetime of NO(y) constituents in this region. Solar cycle 23 was quite active with SPEs and very large fluxes of high energy protons occurred in July and November 2000, November 200 1, and April 2002. Smaller, but still substantial, proton fluxes impacted the Earth during other months in the 1997-2003 time period. The impact of the very large SPEs on the neutral middle atmosphere during solar cycle 23 will be discussed, including the HO(x), NO(y), ozone variations and induced atmospheric transport changes. Two multi-dimensional models, the Goddard Space Flight Center (GSFC) Two-dimensional (2D) Model and the Thermosphere Ionosphere Mesosphere Electrodynamic General Circulation Model (TIME-GCM), were used in computing the influence of the SPEs. The results of the GSFC 2D Model and the TIME-GCM will be shown along with comparisons to the Upper Atmosphere Research Satellite (UARS) Halogen Occultation Experiment (HALOE) and Solar Backscatter Ultraviolet 2 (SBUV/2) instruments.

Jackman, Charles H.↗
NASA NTRS2003

Using Neural Networks to Describe Tracer Correlations

Neural networks are ideally suited to describe the spatial and temporal dependence of tracer-tracer correlations. The neural network performs well even in regions where the correlations are less compact and normally a family of correlation curves would be required. For example, the CH4-N2O correlation can be well described using a neural network trained with the latitude, pressure, time of year, and CH4 volume mixing ratio (v.m.r.). In this study a neural network using Quickprop learning and one hidden layer with eight nodes was able to reproduce the CH4-N2O correlation with a correlation co- efficient of 0.9995. Such an accurate representation of tracer-tracer correlations allows more use to be made of long-term datasets to constrain chemical models. Such as the dataset from the Halogen Occultation Experiment (HALOE) which has continuously observed CH4, (but not N2O) from 1991 till the present. The neural network Fortran code used is available for download.

Lary, D. J.↗
NASA NTRS2003

Interannual and Long-Term Changes in Middle Atmosphere Temperature from Haloe

Radiative models of the middle atmosphere indicate that the largest temperature response due to steadily increasing amounts of atmospheric CO2 should occur at pressure altitudes between 1 and 0.1 hPa (about 48 to 64 km) and be of the order of 0.5 to 0.6 K/decade on a pressure surface . Such a rate assumes that there is no trend in ozone or in the dissipation of wave activity for that region of the middle atmosphere. This rate of cooling is only of the order of 0.20 to 0.25% per decade, which is a small trend to discern from observations. We have analyzed the 11-year, Version 19 (or V19) temperature versus pressure profile (or T(p)) time series from the UARS Halogen Occultation Experiment (HALOE) for such trends at selected pressure levels. The HALOE T(p) time series are being obtained using CO2 transmission data centered at 2.8 micrometers and from a single instrument that uses the limb solar occultation measurement geometry, which provides significant advantages for the calibration of its single profiles.

Remsbwerg, Ellis↗
NASA NTRS2004

Quantitative Mineralogical Analysis of Mars Analogues Using CHEMIN Data and Rietveld Refinement

Mineralogical analysis is a critical component of planetary surface exploration. Chemical data alone leave serious gaps in our understanding of the surfaces of planets where complex minerals may form in combination with H, S, and halogens. On such planets (e.g., Mars) a single chemical composition may represent a range of mineral assemblages. For example, Viking chemical analyses of excavated duricrust indicate that Mg and S are correlated and ~10% MgSO4 (anhydrous weight) is a likely cementing agent. Pathfinder chemical data support a similar abundance of MgSO4 in the most altered materials. However, there are many possible Mg-sulfates with widely varying hydration states (including dehydrated and 1-, 2-, 3-, 4-, 5-, 6-, and 7-hydrates). In addition, other sulfate minerals such as gypsum (CaSO4 .2H2O) and other salts containing Cl may also exist. X-ray diffraction (XRD) has the ability to decipher mixtures of these phases that would be difficult, if not impossible to unravel using only chemical or spectral data.

Bish, D. L.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Meteorites

The session "Meteorites" included the following reports:Description of a New Stony Meteorite Find from Bulloch County, Georgia; Meteorite Ablation Derived from Cosmic Ray Track Data Dhofar 732: A Mg-rich Orthopyroxenitic Achondrite Halogens, Carbon and Sulfur in the Tagish Lake Meteorite: Implications for Classification and Terrestrial Alteration; Electromagnetic Scrape of Meteorites and Probably Columbia Tiles; Pre-Atmospheric Sizes and Orbits of Several Chondrites; Research of Shock-Thermal History of the Enstatite Chondrites by Track, Thermoluminescence and Neutron-Activation (NAA) Methods; Radiation and Shock-thermal History of the Kaidun CR2 Chondrite Glass Inclusions; On the Problem of Search for Super-Heavy Element Traces in the Meteorites: Probability of Their Discovery by Three-Prong Tracks due to Nuclear Spontaneous Fission Trace Element Abundances in Separated Phases of Pesyanoe, Enstatite Achondrite; Evaluation of Cooling Rate Calculated by Diffusional Modification of Chemical Zoning: Different Initial Profiles for Diffusion Calculation; Mineralogical Features and REE Distribution in Ortho- and Clinopyroxenes of the HaH 317 Enstatite Chondrite Dhofar 311, 730 and 731: New Lunar Meteorites from Oman; The Deuterium Content of Individual Murchison Amino Acids; Clues to the Formation of PV1, an Enigmatic Carbon-rich Chondritic Clast from the Plainview H-Chondrite Regolith Breccia ;Numerical Simulations of the Production of Extinct Radionuclides and ProtoCAIs by Magnetic Flaring.

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NASA NTRS1999

New Method for Calibration for Hyperspectral Pushbroom Imaging Systems

A new, easy-to-implement approach for achieving highly accurate spectral and radiometric calibration of array-based, hyperspectral pushbroom imagers is presented in this paper. The equivalence of the plane of the exit port of an integrating sphere to a Lambertian surface is utilized to provide a field-filling radiance source for the imager. Several different continuous wave lasers of various wavelengths and a quartz-tungsten-halogen lamp internally illuminate the sphere. The imager is positioned to "stare" into the port, and the resultant data cube is analyzed to determine wavelength calibrations, spectral widths of channels, radiometric characteristics, and signal-to-noise ratio, as well as an estimate of signal-to-noise performance in the field. The "smile" (geometric distortion of spectra) of the system can be quickly ascertained using this method. As the price and availability of solid state laser sources improve, this technique could gain wide acceptance.

Ryan, Robert↗
NASA NTRS2003

Evaluation of a Multi-Decadal Simulation of Stratospheric Ozone by Comparison with Total Ozone Mapping Spectrometer (TOMS) Observations

One key application of atmospheric chemistry and transport models is prediction of the response of ozone and other constituents to various natural and anthropogenic perturbations. These include changes in composition, such as the previous rise and recent decline in emission of man-made chlorofluorcarbons, changes in aerosol loading due to volcanic eruption, and changes in solar forcing. Comparisons of hindcast model results for the past few decades with observations are a key element of model evaluation and provide a sense of the reliability of model predictions. The 25 year data set from Total Ozone Mapping Spectrometers is a cornerstone of such model evaluation. Here we report evaluation of three-dimensional multi-decadal simulation of stratospheric composition. Meteorological fields for this off-line calculation are taken from a 50 year simulation of a general circulation model. Model fields are compared with observations from TOMS and also with observations from the Stratospheric Aerosol and Gas Experiment (SAGE), Microwave Limb Sounder (MLS), Cryogenic Limb Array Etalon Spectrometer (CLAES), and the Halogen Occultation Experiment (HALOE). This overall evaluation will emphasize the spatial, seasonal, and interannual variability of the simulation compared with observed atmospheric variability.

Douglass, Anne R.↗
NASA NTRS2003

Stratospheric Ozone: Transport, Photochemical Production and Loss

Observations from various satellite instruments (e.g., Total Ozone Mapping Spectrometer (TOMS), Halogen Occultation Experiment (HALOE), Microwave Limb Sounder (MLS)) specify the latitude and seasonal variations of total ozone and ozone as a function of altitude. These seasonal variations change with latitude and altitude partly due to seasonal variation in transport and temperature, partly due to differences in the balance between photochemical production and loss processes, and partly due to differences in the relative importance of the various ozone loss processes. Comparisons of modeled seasonal ozone behavior with observations test the following: the seasonal dependence of dynamical processes where these dominate the ozone tendency; the seasonal dependence of photochemical processes in the upper stratosphere; and the seasonal change in the balance between photochemical and dynamical processes.

Douglass, A. R.↗
NASA NTRS2004

Neutral Middle Atmospheric Influences by the Extremely Large October 2003 Solar Proton Event

The huge coronal mass ejection (CME) on October 28,2003 caused an extremely large solar proton event (SPE) at the Earth, which impacted the middle atmospheric polar cap regions. The highly energetic protons produce ionizations, excitations, dissociations, and dissociative ionizations of the background constituents, which lead to the production of HOx (H, OH, HO2) and NOy (N, NO, NO2, NO3, N2O5, HNO3, HO2NO2, ClONO2, BrONO2). The total production of middle atmospheric NOy molecules by individual SPEs can be used to compare their sizes. Using this scale, the extremely large October 2003 SPE was the fourth largest in the past 40 years and the second largest of solar cycle 23. Only the October 1989, August 1972, and July 2000 SPEs were larger. The Goddard Space Flight Center (GSFC) Two-dimensional (2D) Model was used in computing the influence of this gigantic SPE. The NOy amount was increased by over two orders of magnitude in the mesosphere in both the GSFC 2D Model computations and Upper Atmosphere Research Satellite (UARS) Halogen Occultation Experiment (HALOE) measurements as a result of this noteworthy SPE. The model also calculated polar middle mesospheric ozone decreases of over 70% during the SPE. Other atmospheric impacts from both model predictions and measurements as a result of this major SPE will be discussed in this paper.

Jackman, C. H.↗
NASA NTRS2004

Neutral Middle Atmospheric Influences by the Extremely Large October 2003 Solar Proton

The huge coronal mass ejection (CME) on October 28, 2003 caused an extremely large solar proton event (SPE) 3t the Earth, which impacted the middle atmospheric polar cap regions. The highly energetic protons produce ionizations, excitations, dissociations, and dissociative ionizations of the background constituents, which lead to the production of HO(x) (H, OH, HO2) and NO(y) (N, NO, NO2, NO3, N2O5, HNO3, HO2NO2, ClONO2, BrONO2). The total production of middle atmospheric NO(y) molecules by individual SPEs can be used to compare their sizes. Using this scale, the extremely large October 2003 SPE was the fourth largest in the past 40 years and the second largest of solar cycle 23. Only the October 1989, August 1972, and July 2000 SPEs were larger. The Goddard Space Flight Center (CSFC) Two-dimensional (2D)) Model was used in computing the influence of this gigantic SPE The NO(y) amount was increased by over two orders of Atmosphere Research Satellite (UARS) Halogen Occultation Experiment (HALOE) measurements as a result of this noteworthy SPE. The model also calculated polar middle mesosphere ozone decreases of over 70% during the SPE. Other atmospheric impacts from both model predictions and measurements as a result of this major SPE will be discussed in this paper.

Jackman, C. H.↗
NASA NTRS2004

Chemistry and Transport in a Multi-Dimensional Model

Our work has two primary scientific goals, the interannual variability (IAV) of stratospheric ozone and the hydrological cycle of the upper troposphere and lower stratosphere. Our efforts are aimed at integrating new information obtained by spacecraft and aircraft measurements to achieve a better understanding of the chemical and dynamical processes that are needed for realistic evaluations of human impact on the global environment. A primary motivation for studying the ozone layer is to separate the anthropogenic perturbations of the ozone layer from natural variability. Using the recently available merged ozone data (MOD), we have carried out an empirical orthogonal function EOF) study of the temporal and spatial patterns of the IAV of total column ozone in the tropics. The outstanding problem about water in the stratosphere is its secular increase in the last few decades. The Caltech/PL multi-dimensional chemical transport model (CTM) photochemical model is used to simulate the processes that control the water vapor and its isotopic composition in the stratosphere. Datasets we will use for comparison with model results include those obtained by the Total Ozone Mapping Spectrometer (TOMS), the Solar Backscatter Ultraviolet (SBUV and SBUV/2), Stratosphere Aerosol and Gas Experiment (SAGE I and II), the Halogen Occultation Experiment (HALOE), the Atmospheric Trace Molecular Spectroscopy (ATMOS) and those soon to be obtained by the Cirrus Regional Study of Tropical Anvils and Cirrus Layers Florida Area Cirrus Experiment (CRYSTAL-FACE) mission. The focus of the investigations is the exchange between the stratosphere and the troposphere, and between the troposphere and the biosphere.

Yung, Yuk L.↗
NASA NTRS2004

The Influence of the Several Very Large Solar Proton Events in Years 2000-2003 on the Neutral Middle Atmosphere

Solar proton events (SPEs) are known to have caused changes in constituents in the Earth's neutral middle atmosphere. The highly energetic protons produce ionizations, excitations, dissociations, and dissociative ionizations of the background constituents, which lead to the production of HOx (H, OH, HO2) and NOy (N, NO, NO2, NO3, N2O5, HNO3, HO2NO2, ClONO2, BrONO2). The HOx increases lead to short-lived ozone decreases in the mesosphere and upper stratosphere due to the short lifetimes of the HOx constituents. The NOy increases lead to long-lived stratospheric ozone changes because of the long lifetime of the NOy family in this region. The past four years, 2000-2003, have been replete with SPEs and huge fluxes of high energy protons occurred in July and November 2000, September and November 2001, April 2002, and October 2003. Smaller, but still substantial, proton fluxes impacted the Earth during other months from year 2000 to 2003. The Goddard Space Flight Center (GSFC) Two-dimensional (2D) Model was used in computing the influence of the SPEs. The impact of these extremely large SPEs was calculated to be especially large in the upper stratosphere and mesosphere. The results of the GSFC 2D Model will be shown along with comparisons to the Upper Atmosphere Research Satellite (UARS) Halogen Occultation Experiment (HALOE) and Solar Backscatter Ultraviolet 2 (SBUV/2) instruments.

Jackman, Charles H.↗
NASA NTRS1992

Efficacy of copper and silver ions with iodine in the inactivation of Pseudomonas cepacia

Alternatives to chlorination of water have been sought for reasons which include trihalomethane formation, possible bacterial regrowth, the high concentrations of chlorine required in certain circumstances, and the taste, odour and bodily irritation in chlorine-treated water. Electrolytically generated Cu and Ag ions at low levels, in addition to very low chlorine concentrations, have been suggested as an alternative to routine chlorination. We have examined the combination of Cu and Ag ions with low levels of iodine. Pseudomonas cepacia was grown either in rich medium or under nutrient restriction prior to disinfection. Survival of the organism and its ability to regrow after treatment as well as the effects of varying buffers, metal ion and iodine concentrations were determined. Low concentrations of metal ions (100 ppb Cu and 11 ppb Ag) and iodine (200 ppb) were more effective than either metal ions or iodine alone against Ps. cepacia grown on rich agar or in low nutrient buffer. After iodination, buffer-grown suspensions recovered to their original cell concentrations within 7 d. When Cu and Ag ions were used with or without iodine, regrowth was prevented. The results show that low concentrations of Cu and Ag in combination with iodine permit effective disinfection of bacteria after cultivation on either rich media or under nutrient restriction. These results, along with published data, suggest that the combination of these metals with halogenation may have applications in the disinfection of both recreational and potable water.

NASA Discipline Environmental Health↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 17

The following topics were discussed: A Model for the Formation of Paterae on Io; LIBS-based Detection of As, Br, C, Cl, P, and S in the VUV Spectral Region in a Mars Atmosphere; Mass Independent Sulfur in Achondrites: Possible Evidence of Photochemistry in the Solar Nebula; Grain Size-dependent Viscosity and Oceans in Icy Satellites; Claritas Paleolake Studied from the MEX HRSC Data; Mars Express HRSC Colors of White Rock, Arabia, Mars; Lava and Flows of the Arcadia Region of Mars; Isotopic Composition of Lunar Soils and the Early Differentiation of the Moon; Trace Element Analysis of Lunar Soils by ICP-MS; Highly Siderophile Elements and Osmium Isotope Systematics in Ureilites: Are the Carbonaceous Veins Primary Components?; Evaporative Evolution of Martian Brines Based on Halogens in Nakhlites and MER Samples; Io from High-Resolution Galileo PPR Data Taken Simultaneously with SSI or NIMS Observations; Loki, Io: Groundbased Observations and a Model for Periodic Overturn; Deconstructing a Few Myths in the Interpretation of Satellite-Altitude Crustal Magnetic Field: Examples from Mars Global Surveyor; Semi-Autonomous Rover Operations: A Mars Technology Program Demonstration; Rotational Studies of Asteroids with Small Telescopes; Mineralogy and Temperature-induced Spectral Investigations of A-type Asteroids 246 Asporina and 446 Aeternitas; and Thermal History Calculations Versus Full Convection Models: Application to the Thermal Evolution of Mercury. Recent Solar-Proton Fluxes

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