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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Fully Nonlinear Modeling and Analysis of Precision Membranes

High precision membranes are used in many current space applications. This paper presents a fully nonlinear membrane theory with forward and inverse analyses of high precision membrane structures. The fully nonlinear membrane theory is derived from Jaumann strains and stresses, exact coordinate transformations, the concept of local relative displacements, and orthogonal virtual rotations. In this theory, energy and Newtonian formulations are fully correlated, and every structural term can be interpreted in terms of vectors. Fully nonlinear ordinary differential equations (ODES) governing the large static deformations of known axisymmetric membranes under known axisymmetric loading (i.e., forward problems) are presented as first-order ODES, and a method for obtaining numerically exact solutions using the multiple shooting procedure is shown. A method for obtaining the undeformed geometry of any axisymmetric membrane with a known inflated geometry and a known internal pressure (i.e., inverse problems) is also derived. Numerical results from forward analysis are verified using results in the literature, and results from inverse analysis are verified using known exact solutions and solutions from the forward analysis. Results show that the membrane theory and the proposed numerical methods for solving nonlinear forward and inverse membrane problems are accurate.

Pai, P. Frank↗

Concepts for a theoretical and experimental study of lifting rotor random loads and vibrations. Phase 5B: Analysis of gust alleviation methods and rotor dynamic stability

The effects of various gust alleviation methods on the random blade response in flapping were studied analytically, assuming a rigid rotor support. The analytical model assumes rigid flapping blades with elastic root restraints. Linearized equations which are approximately valid at low lift conditions were used. Because of the interblade coupling from the feedback devices, the method of multiblade generalized coordinates was most convenient and was extended to include coning, differential coning, and warping of the rotor. The numerical examples cover the dynamic stability characteristics as affected by feedback gains of three- to six-bladed rotors. The number of blades had large effects on stability limits and modal time functions at these limits. The random flapping response of the blades to atmospheric turbulence was determined at 1.6 rotor advance ratio using feedback gains below the stability limit. The most effective reduction of the flapping response per unit gain was achieved with a rotor coning angle feedback.

Hohenemser, K. H.↗

Hierarchical multi-time-scale predictive thermal management and fuel optimization for heavy-duty compression ignition engines

For heavy-duty diesel engines, NO X emissions reduction is strongly constrained by fuel efficiency. This paper presents a hierarchical model predictive controller (H-MPC) for coordinated control of tailpipe NO X emissions and fuel consumption. The H-MPC uses the separation of slow and fast dynamics that exist in the engine and its aftertreatment system. The controller is synthesized with an architecture in which a high-level MPC uses a longer prediction horizon compared to the low-level predictive controller which tracks the high-level controller command and manages the thermal dynamics of the aftertreatment system. Engine load preview enables the high-level controller to estimate the desired catalyst temperature ahead of time and addresses the selective catalytic reduction (SCR) slow thermal dynamics. Calculated by the high-level controller, the intake manifold pressure, and the start of injection (SOI) crank angle is used as reference trajectories in the low-level controller that regulates fast dynamical behaviors such as engine out NO X emissions. Hardware-in-the-loop (HIL) validation of this integrated H-MPC on a rapid prototype controller shows that when the SCR catalyst temperature is above light-off temperature (warmed-up condition), the engine operation is shifted to operate with the best fuel economy since the warmed-up SCR can efficiently reduce the engine-out NO X emissions. Results indicate that up to 0.8% benefit in cycle averaged BSFC along with a 13% reduction in tailpipe NO X compared to a stock engine calibration can be achieved with the coordinated engine and aftertreatment system through H-MPC.

Engineering↗

The role of the CeO 2 /BiVO 4 interface in optimized Fe–Ce oxide coatings for solar fuels photoanodes

Solar fuel generators entail a high degree of materials integration, and efficient photoelectrocatalysis of the constituent reactions hinges upon the establishment of highly functional interfaces. Our recent application of high throughput experimentation to interface discovery for solar fuels photoanodes has revealed several surprising and promising mixed-metal oxide coatings for BiVO 4 . Furthermore, when using sputter deposition of composition and thickness gradients on a uniform BiVO 4 film, we systematically explore photoanodic performance as a function of the composition and loading of Fe–Ce oxide coatings. This combinatorial materials integration study not only enhances the performance of this new class of materials but also identifies CeO 2 as a critical ingredient that merits detailed study. A heteroepitaxial CeO 2 (001)/BiVO4(010) interface is identified in which Bi and V remain fully coordinated to O such that no surface states are formed. Ab initio calculations of the integrated materials and inspection of the electronic structure reveals mechanisms by which CeO 2 facilitates charge transport while mitigating deleterious recombination. Our results support the observations that addition of Ce to BiVO 4 coatings greatly enhances photoelectrocatalytic activity, providing an important strategy for developing a scalable solar fuels technology.

14 SOLAR ENERGY↗

An Integrated Paradigm for the Management of Delivery Risk in Electricity Markets: From Batteries to Insurance and Beyond [Slides]

In wholesale electricity markets today, flexibility from a limited number of distributed energy resources (DERs) is offered daily, and the value of flexibility is not yet recognized for economic hedging of delivery risk. Under a three-year project funded by the ARPA-E PERFORM program, a collaborative team is working towards developing an integrated risk management framework that will leverage flexibility from distributed and bulk resources to cost-effectively and reliably manage delivery risk of intermittent resources. Two concepts are at the core of the proposed integrated risk management framework: (A) flexibility options, which are a novel type of options and enable wholesale electricity market participants to hedge uncertainty by buying flexibility. (B) DER flexibility scores, which provide a way for utilities or aggregators to classify assets in groups with different likelihood of delivering contracted flexibility. This report presentation will focus on the proposed ISO-product "flexibility options," which is complementary to ramp and other products being introduced by ISOs/RTOs to manage net load uncertainties. Participating resources with imbalance risk can buy flexibility options to hedge their production, whereas grid-connected resources that can provide physical flexibility can offer flexibility options. We will present basics of the formulation for a day-ahead ISO market that matches buyers and sellers of this hedge in coordination with existing capabilities to schedule energy and ancillary services, and outline how their settlements mitigate the impact of imbalance risk.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A variational approach to three-dimensional elasticity solutions of laminated composite plates

The displacements in a laminated composite are represented as products of two sets of unknown functions, one of which is only a function of the thickness coordinate and the other is a function of the in-plane coordinates (i.e., separation of variables approach), and the minimization of the total potential energy is reduced to a sequence of iterative linear problems. Analytical solutions are developed for cross-ply and angle-ply laminated composite rectangular plates. The solution for simply-supported cross-ply plates under sinusoidal transverse load reduces to that of Pagano. Numerical results for stresses and is placements for antisymmetric angle-ply laminates are presented. The three-dimensional elasticity solutions developed are important because they can be used to study the behavior of composite laminates, in addition to serving as reference for approximate solutions by numerical methods and two-dimensional theories.

Savoia, M.↗

Composite Nozzle/Thrust Chambers Analyzed for Low-Cost Boosters

The Low Cost Booster Technology Program is an initiative to minimize the cost of future liquid engines by using advanced materials and innovative designs, and by reducing engine complexity. NASA Marshall Space Flight Center s 60K FASTRAC Engine is one example where these design philosophies have been put into practice. This engine burns a liquid kerosene/oxygen mixture. It uses a one-piece, polymer composite thrust chamber/nozzle that is constructed of a tape-wrapped silica phenolic liner, a metallic injector interface ring, and a filament-wound epoxy overwrap. A cooperative effort between NASA Lewis Research Center s Structures Division and Marshall is underway to perform a finite element analysis of the FASTRAC chamber/nozzle under all the loading and environmental conditions that it will experience during its lifetime. The chamber/nozzle is a complex composite structure. Of its three different materials, the two composite components have distinctly different fiber architectures and, consequently, require separate material model descriptions. Since the liner is tape wrapped, it is orthotropic in the nozzle global coordinates; and since the overwrap is filament wound, it is treated as a monoclinic material. Furthermore, the wind angle on the overwrap varies continuously along the length of the chamber/nozzle.

Sullivan, Roy M.↗

Nonlinear response of graphite-epoxy wide columns subject to eccentric load

It is shown that including the effects of bend-twist coupling and material nonlinearity on the large displacement flexural response of graphite-epoxy wide columns is necessary to adequately model their response. Results from static tests on 0(30)T and (30/0/-30 sub 5)s laminated specimens under eccentric axial compression are compared to a nonlinear analysis. The analysis is based on a Kantrovich expansion of the displacements in the width coordinate and a finite element representation in the axial coordinate. An incremental, updated Lagrangian formulation and element corotational coordinates are employed. Nonlinear elastic material behavior was measured in a separate set of material characterization tests, and these data are used to compute tangent stillnesses in the updated configuration.

Griffin, O. H., Jr.↗

Loads and Aeroelasticity Division research and technology accomplishments for FY 1984 and plans for FY 1985

The loads and aeroelasticity divisions research accomplishments are presented. The work under each branch or technical area, described in terms of highlights of accomplishments during the past year and highlights of plans for the current year as they relate to 5 year plans for each technical area. This information will be useful in program coordination with other government organizations and industry in areas of mutual interest.

Gardner, J. E.↗

Procedures for shape optimization of gas turbine disks

Two procedures, the feasible direction method and sequential linear programming, for shape optimization of gas turbine disks are presented. The objective of these procedures is to obtain optimal designs of turbine disks with geometric and stress constraints. The coordinates of the selected points on the disk contours are used as the design variables. Structural weight, stress and their derivatives with respect to the design variables are calculated by an efficient finite element method for design senitivity analysis. Numerical examples of the optimal designs of a disk subjected to thermo-mechanical loadings are presented to illustrate and compare the effectiveness of these two procedures.

Cheu, Tsu-Chien↗

Higher order finite element analysis of thick composite laminates

A higher order, sub-parametric, laminated, 3D solid finite element was used for the analysis of very thick laminated composite plates. The geometry of this element is defined by four nodes in the X-Y plane which define a prism of material through the thickness of the laminate. There are twenty-four degrees of freedom at each node; translations at the upper and lower surfaces of the laminate in each of the three coordinate directions, and the derivatives of these translations with respect to each coordinate. This choice of degrees of freedom leads to displacement and strain compatibility at the corners. Stacking sequence effects are accounted for by explicitly integrating the strain energy density through the thickness of the element. The laminated solid element was combined with a gap-contact element to analyze thick laminated composite lugs loaded through flexible pins. The resulting model accounts for pin bending effects that produce non-uniform bearing stresses through the thickness of the lug. A thick composite lug experimental test program was performed, and provided data that was used to validate the analytical model. Two lug geometries and three stacking sequences were tested.

Goering, J.↗

The Substorm Cycle as Reproduced by Global MHD Models

Recently, Gordeev et al. (2015) suggested a method to test global MHD models against statistical empirical data. They showed that four community-available global MHD models supported by the Community Coordinated Modeling Center (CCMC) produce a reasonable agreement with reality for those key parameters (the magnetospheric size, magnetic field, and pressure) that are directly related to the large-scale equilibria in the outer magnetosphere. Based on the same set of simulation runs, here we investigate how the models reproduce the global loading-unloading cycle. We found that in terms of global magnetic flux transport, three examined CCMC models display systematically different response to idealized2 h north then 2 h south interplanetary magnetic field (IMF) Bz variation. The LFM model shows a depressed return convection and high loading rate during the growth phase as well as enhanced return convection and high unloading rate during the expansion phase, with the amount of loaded unloaded magnetotail flux and the growth phase duration being the closest to their observed empirical values during isolated substorms. Two other models exhibit drastically different behavior. In the BATS-R-US model the plasma sheet convection shows a smooth transition to the steady convection regime after the IMF southward turning. In the Open GGCM a weak plasma sheet convection has comparable intensities during both the growth phase and the following slow unloading phase. We also demonstrate potential technical problem in the publicly available simulations which is related to post processing interpolation and could affect the accuracy of magnetic field tracing and of other related procedures.

Gordeev, E.↗

A13H-2546: Intercomparison of biomass burning aerosol properties from in-situ and remote-sensing instruments in ORACLES-2016

The magnitude of the cumulative effects of aerosols, both directly and on cloud properties, remains the biggest source of uncertainty in our understanding of anthropogenic radiative forcing on the climate. The magnitude of aerosol effects in any given region will depend on not just the aerosol concentration, but also on the characteristics of the aerosol under consideration. The NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign was conducted in 2016-2018 over three deployments in the Southeast Atlantic Ocean (SEA), with the goal of making observations of seasonal biomass burning (BB) smoke plumes overlying persistent stratocumulus cloud decks. During the first ORACLES deployment (September 2016), two NASA aircraft (a P-3 and an ER-2) were flown with a suite of aerosol, cloud, radiation, and meteorological instruments for remote-sensing and in-situ observations. In ORACLES, data collected by eight different instrument teams are used to derive aerosol properties over this region by independent methods. Here we present a comparison of results from the different instrument retrievals with a focus on the measures of aerosol absorption. We focus on specific cases with near-coincident measurements from in-situ (PSAP or PTI for aerosol absorption combined with a nephelometer for aerosol scattering) and remote sensing (4STAR, AirMSPI, RSP, and SSFR) instruments from coordinated flights between the two aircraft. We use the single scattering albedo (SSA), a measure of the relative absorption versus total extinction by aerosols, as the main comparable property between the various remote sensing and in-situ methods. For the remote sensing instruments, we see general good agreement in the total aerosol loading (aerosol optical depth, AOD), though see some differences in the absorbing component (AAOD). We report values for the retrieved aerosol parameters measured in the ORACLES flights and comment upon the observed variability between different instruments. Finally, we discuss these ORACLES results in the context of previous measurements of BB aerosol over the SEA.

Kristina Pistone↗

Investigation of Silica-Supported Vanadium Oxide Catalysts by High-Field 51 V Magic-Angle Spinning NMR

Supported V2O5/SiO2 catalysts were studied using solid state 51V MAS NMR at a sample spinning rate of 36 kHz and at a magnetic field of 19.975 T for a better understanding of the coordination of the vanadium oxide as a function of environmental conditions . Structural transformations of the supported vanadium oxide species between the catalyst in the dehydrated state and hydrated state under an ambient environment were revisited to examine the degree of oligomerization and the effect of water. The experimental results indicate the existence of a single dehydrated surface vanadium oxide species that resonates at -675 ppm and two vanadium oxide species under ambient conditions that resonate at -566 and -610 ppm, respectively. No detectable structural difference was found as a function of vanadium oxide loading on SiO2 (3% V2O5/SiO2 and 8% V2O5/SiO2). Quantum chemistry simulations of the 51V NMR chemical shifts on predicted surface structures were used as an aide in understanding potential surface vanadium oxide species on the silica support. The results suggest the formation of isolated surface VO4 units for the dehydrated catalysts with the possibility of dimer and cyclic trimer presence. The absence of bridging V-O-V vibrations (~200-300 cm-1) in the Raman spectra [Gao et al. J. Phys. Chem. B 1998, 102, 10842-10852], however, indicates that the isolated surface VO4 sites are the dominant dehydrated surface vanadia species on silica. Upon exposure to water, hydrolysis of the bridging V-O-Si bonds is most likely responsible for the decreased electron shielding experienced by vanadium. No indicators for the presence of hydrated decavanadate clusters or hydrated vanadia gels previously proposed in the literature were detected in this study.

Environmental Molecular Sciences Laboratory↗

Coordinated Ramping Product and Regulation Reserve Procurements in CAISO and MISO using Multi-Scale Probabilistic Solar Power Forecasts (Pro2R)

How can probabilistic solar forecasts lower costs and improve reliability for independent system operator (ISO) markets? We tackle this question in three steps. First, we enhance an existing solar forecasting system to provide well-calibrated hours-ahead probabilistic forecasts. We then relate the degree of uncertainty in those forecasts to error distributions for net load ramps for the California ISO (CAISO) using statistical and machine learning methods. Projected net load errors conditioned on solar uncertainty are translated into flexible ramp requirements that therefore reflect real-time meteorological and solar conditions, improving on typical ISO procedures. Finally, a multi-period look-ahead production cost model quantifies how conditional ramp requirements can a) decrease operating costs by lowering requirements compared to often conservative unconditional methods, and b) reduce generation scarcity events and consequently improve reliability by increasing flexibility requirements at times when unconditional forecast-based requirements understate actual ramp uncertainty. In addition to the products just described (quantification of solar uncertainty, its translation into requirements for ramp capability product, and quantification of the benefits of more accurate ramp requirements), this project also developed a visualization system that alerts system operators of ramp and uncertainty conditions within the network based on solar forecasts. The system is called Resource Forecast and Ramp Visualization for Situational Awareness (RaVIS). These four products represent significant advances in the state-of-the-art of probabilistic solar forecasting, development of weather-informed reserve requirements, production costing methods for estimating the benefits of more accurate reserve requirements, and visualization of system status, respectively. Yet the products are also practical and can be immediately implemented, potentially enabling system operators to save millions of dollars in ramp product procurement costs per year.

14 SOLAR ENERGY↗

Accuracy of hourly energy predictions for demand flexibility applications

Decarbonization goals in the United States electricity sector are increasing the levels of renewable energy generation in the electricity supply system, and are driving increased attention to building electrification, which will increase the magnitude and shift the timing of the electricity system peak. These changes are motivating new approaches to coordinate building electricity demand with low-carbon renewable generation, elevating the importance of demand flexibility (DF) in buildings and the need to quantify the temporal impacts of DF. In this paper, we first characterize the hourly predictive accuracy of six commonly used baseline models in an application context of quantifying building-level load shift. Our analysis revealed insights such as hours of the day (afternoons), periods of the week (weekends), and seasons (summer) that were predicted with more accuracy than other time periods. In addition, the analysis showed tendencies toward overprediction or underprediction of load. Secondly, we provide the first published investigation of baseline erosion from repeated dispatch of building load shifting. We observed that as the baseline period is pushed back further from the prediction day, the distribution of errors across baseline model predictions increases, with notable inflection points near the three-week erosion point for two of the three models.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Mesoporous Fe-doped MgO nanoparticles as a heterogeneous photo-Fenton-like catalyst for degradation of salicylic acid in wastewater

Mesoporous Fe-doped MgO nanoparticles were synthesized using a facile sol-gel method and utilized for photo-Fenton-like degradation of salicylic acid (SA). The MgO surface dissolution facilitated an increase in the pH under the reaction conditions that allowed the Fe-MgO catalyst to be active without detectable iron leaching. Under simulated solar radiation, SA was completely degraded with an initial rate constant of 0.048 min -1 at the optimal reaction conditions of 500 ppm loading of 5% Fe-MgO, 20 mM H 2 O 2 concentration, and 50 ppm SA concentration. The catalyst was stable over 5 reaction cycles. The Fe-MgO catalyst was shown to have a surface area up to 171 m 2 /g and contain hematite (Fe 2 O 3 ) nanoparticles with octahedrally coordinated iron catalytic centers, as inferred from diffuse reflectance UV–vis measurements. Post-reaction catalyst characterization showed that some Fe 2+ was present in the catalyst due to the redox cycle during the chain initiation and propagation steps of the reaction.

36 MATERIALS SCIENCE↗

Interoperable, Inverter - Based Distributed Energy Resources Enable 100% Renewable and Resilient Utility Microgrids

As microgrids transition away from use of conventional generating resources and increasingly rely on renewable resources towards decarbonization goals, it is crucial to evaluate the capability inverter-based resources to provide microgrid stability and resilience. Particularly, microgrids with a high contribution of intermittent solar photo voltaic generation and higher load variability present unique challenges requiring fast voltage and frequency support. At the San Diego Gas & Electric Company(R) (SDG&E(R)) Borrego Springs Microgrid, a battery inverter was upgraded with grid-forming (GFM) capability to serve as island leader, transitioning responsibility away from diesel generators. An interoperable microgrid control scheme was developed, coordinating GFM and grid-following (GFL) inverters. Hardware-in-the-loop (HIL) simulations using relevant power and controller HIL interfaces between real-time simulators and field equipment are being conducted to de-risk field deployment.

battery energy storage↗