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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Resolution dependence of the turbulent atmospheric boundary layer in global storm-resolving climate simulations

The current generation of state-of-the-art global climate models are being run at increasingly higher horizontal resolutions, with the goal of resolving organised deep convection explicitly. How a kilometre-scale resolution impacts the representation of the atmospheric boundary layer is, however, not well known. Using statistical analysis on global fields as well as high-frequency data at selected locations, produced with the Integrated Forecasting System (IFS) model for the Next Generation Earth-system Models (nextGEMS) project, we investigate the horizontal resolution dependence of some boundary-layer processes. We find that a change in resolution from 9 to 2.8 km causes no substantial changes to boundary-layer properties and processes at most of the locations studied, although some global changes are detected that indicate circulation changes. Small changes to the boundary-layer depth and structure are found in the Tropics. The short simulation length and lack of data for optimal boundary-layer analysis limits the conclusions, especially in relation to the connection between the boundary layer and the atmosphere general circulation.

54 ENVIRONMENTAL SCIENCES↗

Turbulence-Resolving Simulations of Hurricane Laura (2020): Insights Into Extreme Winds and Eyewall Turbulence

Extreme weather events pose significant risks to coastal and offshore energy infrastructure. In this work, we investigate the structure of mean winds and turbulence near the surface ( z < 300 m) that occurred during Hurricane Laura in 2020 on the US Gulf Coast. To this end, we perform turbulence-resolving simulations (..delta..x = 33.33 m) that encompass the entire eyewall of Hurricane Laura by introducing a novel method that we will refer to as Moving-Mesoscale to Static-LES Integrated Coupling (MOSAIC). The simulation results are validated against surface, boundary-layer, and mid-tropospheric observations. Our analysis of the extreme wind conditions near the surface indicates that the mean wind and turbulence profiles vary greatly at and near the eyewall, resulting in extreme values of mean wind speed (U > 50 m * s-1) and turbulence kinetic energy (k ~ 50 m2 * s-2) at altitudes above 50 m . To investigate in detail the nature of turbulence within the eyewall of the storm, we conduct higher-resolution simulations (..delta..x = 11.11 m) of a portion of the hurricane. We provide a comprehensive statistical description of turbulence in the eyewall region, highlighting the need to employ ..delta..x ~ 10 m grid spacing to capture the integral length-scales near the surface, second- and higher-order central moments (i.e., skewness and kurtosis), and spectral coherence in the flow accurately. These numerical simulations provide the most detailed description of mean winds and turbulent conditions within the eyewall of a historical tropical cyclone to date, illustrating how high-resolution simulations can enhance limited turbulence measurements in hurricanes and giving insight into the extreme conditions threatening offshore and coastal infrastructure.

17 WIND ENERGY↗

Identification of Recombination Losses in CdSe/CdTe Solar Cells from Spectroscopic and Microscopic Time-Resolved Photoluminescence

Due to the lowest-cost and best reliability, CdTe solar cells are the leading thin-film photovoltaic technology. Increasing open-circuit voltage by reducing recombination represents the most promising path toward further improvements. Analysis is needed to identify limitations that cause efficiency losses. To achieve this goal for Cu-doped CdSe/CdTe solar cells, time-resolved spectroscopy and microscopy are developed and applied. Recombination lifetimes and radiative efficiency identify that defect-mediated recombination is the dominant voltage loss mechanism. When carrier lifetimes are averaged over many crystalline grains, they increase from 180 to 430 ns when Al2O3 is applied to the back contact. The quasi-Fermi-level splitting correspondingly increases from 880–905 to 906–931 mV, indicating a pathway to overcome the long-standing 900 mV voltage limitation. However, the dominant recombination losses are attributed to the absorber bulk. From microscopic carrier lifetime measurements, it is identified that space charge fields due to charged grain boundaries (GBs) lead to recombination in the CdTe absorber bulk. At high injection, GB space charge fields are screened, but that occurs above 1 Sun excitation conditions. Alloying with selenium in the near-interface CdSeTe absorber region reduces GB losses and is identified as one of the factors leading to high radiative and power conversion efficiency.

14 SOLAR ENERGY↗

Resolving environmental effects of wind energy

Concerns for potential wildlife impacts resulting from land-based and offshore wind energy have created challenges for wind project development. Research is not always adequately supported, results are neither always readily accessible nor are they satisfactorily disseminated, and so decisions are often made based on the best available information, which may be missing key findings. The potential for high impacts to avian and bat species and marine mammals have been used by wind project opponents to stop, downsize, or severely delay project development. The global nature of the wind industry - combined with the understanding that many affected species cross-national boundaries, and in many cases migrate between continents - also points to the need to collaborate on an international level. The International Energy Agency (IEA) Wind Technology Collaborative Programs facilitates coordination on key research issues. IEA Wind Task 34 - WREN: Working Together to Resolve Environmental Effects of Wind Energy-is a collaborative forum to share lessons gained from field research and modeling, including management methods, wildlife monitoring methods, best practices, study results, and successful approaches to mitigating impacts and addressing the cumulative effects of wind energy on wildlife.

17 WIND ENERGY↗

Assessing free tropospheric quasi-equilibrium for different GCM resolutions using a cloud-resolving model simulation of tropical convection

Abstract This study examines the free-tropospheric quasi-equilibrium at different global climate model (GCM) resolutions using the simulation of tropical convection by a cloud-resolving model during the Tropical Western Pacific International Cloud Experiment. The simulated dynamic and thermodynamic fields within the model domain are averaged over subdomains of different sizes equivalent to different GCM resolutions. These coarse-grained fields are then used to compute CAPE and its change with time, and their relationships with simulated convection. Results show that CAPE change with time is controlled predominantly by variations of thermodynamic properties in the planetary boundary layer for all subdomain sizes ranging from 64 to 4 km. Lag correlation analysis shows that CAPE generation by the free-tropospheric dynamical advection (dCAPE ls ) leads convective precipitation but is in phase with convective mass flux at 600 mb and 500 mb vertical velocity for all subdomain sizes. However, the correlation coefficients and regression slopes decrease as the subdomain size decreases for subdomain sizes smaller than 16 km. This is probably due to increased randomness of convection and more scale-dependence of the relationships when the subdomain size reaches the grey zone. By examining the sensitivity of the relationships of convection with dCAPE ls to temporal scales in different subdomain size, it shows that the quasi-equilibrium between dCAPE ls and convection holds well for timescales of 30 min or longer at all subdomain sizes. These results suggest that the free tropospheric quasi-equilibrium assumption may still be useable even for GCM resolutions in the grey zone.

54 ENVIRONMENTAL SCIENCES↗

Resolving the black hole causality paradox

The black hole information paradox is actually a combination of two problems: the causality paradox and the entanglement problem. The causality paradox arises because in the semiclassical approximation infalling matter gets causally trapped inside its own horizon; it is therefore unable to send its information back to infinity if we disallow propagation outside the light cone. We show how the causality paradox is resolved in the fuzzball paradigm. One needs to consider between two kinds of Rindler spaces: (a) Rindler space obtained by choosing accelerating coordinates in Minkowski space and (b) `pseudo-Rindler' space, which describes the region near the surface of a fuzzball. These two spaces differ in their vacuum fluctuations. While low energy waves propagate the same way on both spaces, infalling objects with energies $E\gg T$ suffer an `entropy enhanced tunneling' in the pseudo-Rindler spacetime (b); this leads to the nucleation of a fuzzball before the infalling object gets trapped inside a horizon.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

How the black hole puzzles are resolved in string theory

String theory has provided a resolution of the puzzles that arise in the quantum theory of black holes. The emerging picture of the hole, encoded in the ‘fuzzball paradigm’, offers deep lessons about the role of quantum gravity on macroscopic length scales. Here, in this article we list these puzzles and explain how they get resolved. We extract the lessons of this resolution in a form that does not involve the technical details of string theory; it is hoped that this form will allow the lessons to be absorbed into other approaches to quantum gravity.

black holes↗

Time-resolved 3D characterisation of early-age microstructural development of Portland cement

Abstract Time-resolved in-situ synchrotron X-ray microtomography reveals new levels of detail about the chemical and physical processes that take place as Portland cement hardens. The conversion of a fluid paste into a hardened product can be monitored on a sub-minute time-scale, and with sample movement/settlement corrections applied to enable individual particles to be tracked as they react, hydrate, and become interconnected into a single strong monolith. The growth of the strength-giving hydrate phases surrounding cement grains, and of the fluid-filled pore network that surrounds them, is able to be directly viewed at the level of individual cement particles through the application of this tracking protocol. When cement is brought into contact with water, a layer which differs in density from the bulk of the cement grains becomes observable on the grain surfaces during the induction period (during which time the heat evolution from the paste is relatively low). As hydration continues, reaction products grow both from particle surfaces into the initially fluid-filled region, and also into the space originally occupied by the cement particles, forming a density gradient within the microstructure. As the reaction accelerates and larger volumes of solid phases precipitate, the newly-formed solid structure percolates via interconnection of agglomerated low-density outer hydrates, which then densify as hydration continues. This eventually leads to solidification of the structure into a hardened porous matrix. Graphical abstract

36 MATERIALS SCIENCE↗

Angle-Resolved Transport Measurements Reveal Electronic Nematicity in Cuprate Superconductors

Observations of spontaneous breaking of the rotational symmetry in an electron fluid, the so-called “electronic nematicity,” have been reported in several quantum materials. We have developed several different methods, based on angle-resolved transport measurements, to determine the amplitude and the director of the nematic order. Here, we present methods that are applicable to thin films or single crystals, illustrate them with transport data obtained on copper oxide superconductors, and discuss their relative advantages and disadvantages.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Analytic in a Sector Resolving Families of Operators for Degenerate Evolution Fractional Equations

We introduce a class of pairs of operators defining a linear homogeneous degenerate evolution fractional differential equation in a Banach space. Reflexive Banach spaces are represented as the direct sums of the phase space of the equation and the kernel of the operator at the fractional derivative. In a sector of the complex plane containing the positive half-axis, we construct an analytic family of resolving operators that degenerate only on the kernel. The results are used in the study of the solvability of initial-boundary value problems for partial differential equations containing fractional time-derivatives and polynomials in the Laplace operator with respect to the spatial variable.

97 MATHEMATICS AND COMPUTING↗

Tracking the first electron transfer step at the donor side of oxygen-evolving photosystem II by time-resolved infrared spectroscopy

In oxygen-evolving photosystem II (PSII), the multi-phasic electron transfer from a redox-active tyrosine residue (TyrZ) to a chlorophyll cation radical (P680 + ) precedes the water-oxidation chemistry of the S-state cycle of the Mn 4 Ca cluster. Here we investigate these early events, observable within about 10 ns to 10 ms after laser-flash excitation, by time-resolved single-frequency infrared (IR) spectroscopy in the spectral range of 1310–1890 cm -1 for oxygen-evolving PSII membrane particles from spinach. Comparing the IR difference spectra at 80 ns, 500 ns, and 10 µs allowed for the identification of quinone, P680 and TyrZ contributions. A broad electronic absorption band assignable P680 + was used to trace largely specifically the P680 + reduction kinetics. The experimental time resolution was taken into account in least-square fits of P680 + transients with a sum of four exponentials, revealing two nanosecond phases (30–46 ns and 690–1110 ns) and two microsecond phases (4.5–8.3 µs and 42 µs), which mostly exhibit a clear S-state dependence, in agreement with results obtained by other methods. Our investigation paves the road for further insight in the early events associated with TyrZ oxidation and their role in the preparing the PSII donor side for the subsequent water oxidation chemistry.

59 BASIC BIOLOGICAL SCIENCES↗

Combining Structural Probes in the Gas Phase - Ion Mobility-Resolved Action-FRET

In the context of native mass spectrometry, the development of gas-phase structural probes sensitive to the different levels of structuration of biomolecular assemblies is necessary to push forward conformational studies. In this paper, we provide the first example of the combination of ion mobility (IM) and Förster resonance energy transfer (FRET) measurements within the same experimental setup. The possibility to obtain mass- and mobility-resolved FRET measurements is demonstrated on a model peptide and applied to monitor the collision-induced unfolding of ubiquitin. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Time-Resolved Geometric Feature Tracking Elucidates Laser-Induced Keyhole Dynamics

In this report, during laser melting of metals, localized metal evaporation resulting in the formation of a keyhole shaped cavity can occur if processing conditions are chosen with high power density. An unstable keyhole can have deleterious effects in certain applications (e.g., laser powder bed fusion) as it increases the likelihood of producing defects such as porosity. In this work, we propose a pipeline that enables complete segmentation and extraction of various geometric features in keyholing conditions. In situ synchrotron high-speed X-ray visualization at the Advanced Photon Source provides large datasets of experimental images with a high spatio-temporal resolution across a range of laser parameters for Ti-6Al- 4 V. Computer vision image processing techniques were used to extract time-resolved quantitative geometric features (e.g., depth, width, front wall angle) throughout keyhole evolution which were subsequently analyzed to understand the relationship between the variation of local keyhole geometry and processing conditions. This analysis is the first to employ a data-driven approach to further our understanding of the keyholing process regime.

36 MATERIALS SCIENCE↗

Complete collision data set for electrons scattering on molecular hydrogen and its isotopologues: I. Fully vibrationally-resolved electronic excitation of H 2 $X^1Σ^+_g)$

Here, we present a comprehensive set of vibrationally-resolved cross sections for electron-impact electronic excitation of molecular hydrogen suitable for implementation in collisional-radiative models. The adiabatic-nuclei molecular convergent close-coupling method is used to calculate cross sections for excitation of all bound vibrational levels and dissociative excitation of the B 1 &#x3A3; u + , C 1 &#x3A0; u , E F 1 &#x3A3; g + , B &#x2032; 1 &#x3A3; u + , G K 1 &#x3A3; g + , I 1 &#x3A0; g , J 1 &#x394; g , D 1 &#x3A0; u , H 1 &#x3A3; g + , b 3 &#x3A3; u + , c 3 &#x3A0; u , a 3 &#x3A3; g + , e 3 &#x3A3; u + , d 3 &#x3A0; u , h 3 &#x3A3; g + , g 3 &#x3A3; g + , i 3 &#x3A0; g , and j 3 &#x394; g electronic states from all –14 bound vibrational levels of the ground electronic ($\text{X}$ $^1&#x3A3^+_g$) state. The data set consists of cross sections from threshold to 500 eV for over 5000 transitions, representing all possible electronic and vibrational transitions between the state and the –3 singlet and triplet states (where refers to the united-atoms-limit principle quantum number). The cross sections are presented in graphical form and provided as both numerical values and analytic fit functions in supplementary data files.

74 ATOMIC AND MOLECULAR PHYSICS↗

Complete collision data set for electrons scattering on molecular hydrogen and its isotopologues: II. Fully vibrationally-resolved electronic excitation of the isotopologues of H 2 (X 1 $Σ^{+}_{g}$)

Here, we present a comprehensive set of vibrationally-resolved cross sections for electron-impact electronic excitation of the isotopologues of molecular hydrogen (D 2 , T 2 , HD, HT, and DT) initially in the ground electronic state. We apply the adiabatic-nuclei molecular convergent close-coupling (MCCC) method to calculate cross sections from threshold to 500 eV for excitation of all bound vibrational levels and dissociative excitation of the B 1 $Σ^{+}_{g}$, C 1 Π u , EF 1 $Σ^{+}_{g}$, B' 1 $Σ^{+}_{g}$, GK 1 $Σ^{+}_{g}$, I 1 Π g , J 1 Δ g , D 1 Π u , H 1 $Σ^{+}_{g}$, b 1 $Σ^{+}_{g}$, c 3 Π u , a 3 $Σ^{+}_{g}$, e 3 $Σ^{+}_{u}$, d 3 Π u , h 3 $Σ^{+}_{g}$, g 3 $Σ^{+}_{g}$, i 3 Π g , and j 3 Δ g electronic states from all bound vibrational levels of the ground electronic (X 1 $Σ^{+}_{g}$) state. Including the previously-published MCCC e-H2 cross sections the data set contains cross sections for over 60,000 electronic and vibrational transitions. The cross sections are presented in graphical form and provided as both numerical values and analytic fit functions in supplementary data files. The data can also be downloaded from the MCCC database at mccc-db.org.

74 ATOMIC AND MOLECULAR PHYSICS↗

Vibrationally resolved ionization cross sections for the ground state and electronically excited states of the hydrogen molecule and its isotopomeres

An existing set of vibrationally resolved ionization cross section for the ground state and the first excited states of the hydrogen molecule, based on the Gryzinski method, is extended by cross sections for the isotopomeres of H{sub 2} (i.e. D{sub 2}, T{sub 2}, HD, HT, and DT), both for non-dissociative and dissociative ionizations. The comparison of cross sections for non-dissociative ionization of H{sub 2} with results obtained by the Molecular Convergent Close-Coupling method gives a very good agreement. The compiled tables give non-dissociative and dissociative cross sections for the ground state and the five energetically lowest electronically excited states of H{sub 2} and its isotopomeres, in each case for the first 9 vibrational levels. Data for all vibrational levels of the excited states is available online.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Complete collision data set for electrons scattering on molecular hydrogen and its isotopologues: IV. Vibrationally-resolved ionization of the ground and excited electronic states

Here, we present a comprehensive set of vibrationally-resolved cross sections for electron-impact ionization of molecular hydrogen and its isotopologues (H 2 , D 2 , T 2 , HD, HT, and DT) in both the ground and excited electronic states. We apply the adiabatic-nuclei molecular convergent close-coupling (MCCC) method to calculate cross sections from threshold to 1000 eV for ionization of the ground and excited vibrational levels of the X 1 Σ$^{+}_{g}$, B 1 Σ$^{+}_{u}$, C 1 π u , EF 1 Σ$^{+}_{g}$, a 3 Σ$^{+}_{g}$, and c 3 π u electronic states, representing all states with united-atoms-limit principle quantum number n=1–2. The cross sections are presented in graphical form and provided as both numerical values and analytic fit functions in supplementary data files. The data can also be downloaded from the MCCC database at mccc-db.org.

74 ATOMIC AND MOLECULAR PHYSICS↗