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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells: SnS absorber and Zn(O,S) buffer materials for improved solar cells

Thin-film solar cells consisting of earth-abundant and non-toxic materials were created from pulsed chemical vapor deposition (pulsed-CVD) of SnS as the p-type absorber layer and atomic layer deposition (ALD) of Zn(O,S) as the n-type buffer layer. The effects of deposition temperature and annealing conditions of the SnS absorber layer were investigated for solar cells with a structure of Mo/SnS/Zn(O,S)/ZnO/ITO. Solar cells were further optimized by varying the stoichiometry of Zn(O,S) and the annealing conditions of SnS. Post-deposition annealing in pure hydrogen sulfide improved crystallinity and increased the carrier mobility by one order of magnitude, and a power conversion efficiency up to 2.9% was achieved.

14 SOLAR ENERGY↗

Direct nanoscale mapping of open circuit voltages at local back surface fields for PERC solar cells

The open circuit voltage (V OC) is a critical and common indicator of solar cell performance as well as degradation, for panel down to lab-scale photovoltaics. Detecting V OC at the nanoscale is much more challenging, however, due to experimental limitations on spatial resolution, voltage resolution, and/or measurement times. Accordingly, in this work an approach based on Conductive Atomic Force Microscopy is implemented to directly detect the local V OC , notably for monocrystalline Passivated Emitter Rear Contact (PERC) cells which are the most common industrial-scale solar panel technology in production worldwide. This is demonstrated with cross-sectioned monocrystalline PERC cells around the entire circumference of a poly-Aluminum-Silicide via through the rear emitter. The V OC maps reveal a local Back Surface Field extending ~2 μm into the underlying p-type Si absorber due to Al in-diffusion as designed. Such high spatial resolution methods for photovoltaic performance mapping are especially promising for directly visualizing the effects of processing parameters, as well as identifying signatures of degradation for silicon and other solar cell technologies.

14 SOLAR ENERGY↗

Barrier Design to Prevent Metal-Induced Degradation and Improve Thermal Stability in Perovskite Solar Cells

Metal-contact-induced degradation and escape of volatile species from perovskite solar cells necessitate excellent diffusion barrier layers. We show that metal-induced degradation limits thermal stability in several perovskite chemistries with Au, Cu, and Ag gridlines even when the metal is separated from the perovskite by a layer of indium tin oxide (ITO). Channels in a sputtered ITO layer that align with perovskite grain boundaries are pathways for metal and halide diffusion into or out of the perovskite. Planarizing the perovskite morphology with a spin-cast organic charge-transport layer results in a subsequently deposited ITO layer that is uniform and impermeable. We show that it is critical to seal the edges of the active layers to prevent escape of volatile species. We demonstrate 1000 h thermal stability at 85 °C in CH 3 NH 3 PbI 3 solar cells with complete-coverage silver contacts. Lastly, our barrier layer design enables long-term thermal stability of perovskite solar cells, a critical step to commercialization.

14 SOLAR ENERGY↗

Scalable fabrication and coating methods for perovskite solar cells and solar modules

Since the report in 2012 of a solid-state perovskite solar cell (PSC) with a power-conversion efficiency (PCE) of 9.7% and a stability of 500 h, intensive efforts have been made to increase the certified PCE, reaching 25.2% in 2019. The PCE of PSCs now exceeds that of conventional thin-film solar-cell technologies, and the rate at which this increase has been achieved is unprecedented in the history of photovoltaics. Moreover, the development of moisture-stable and heat-stable materials has increased the stability of PSCs. Small-area devices (<1 cm2) are typically fabricated using a spin-coating method; however, this approach may not be suitable for the preparation of the large-area (>100 cm2) substrates required for commercialization. Thus, materials and methods need to be developed for coating large-area PSCs. In this Review, we discuss solution-based and vapour-phase coating methods for the fabrication of large-area perovskite films, examine the progress in performance and the parameters affecting the properties of large-area coatings, and provide an overview of the methodologies for achieving high-efficiency perovskite solar modules.

14 SOLAR ENERGY↗

Suppressed phase segregation for triple-junction perovskite solar cells

The tunable band gaps and facile fabrication of perovskites make them attractive for multi-junction photovoltaics. However, light-induced phase segregation limits their efficiency and stability: this occurs in wide band gap (> 1.65 eV) I/Br mixed perovskite absorbers, and becomes even more acute in the top cells of triple-junction solar photovoltaics that requires a fully 2.0 eV band gap absorber. We report herein that lattice distortion in I/Br mixed perovskites is correlated with the suppression of phase segregation, generating an increased ion migration energy barrier arising from the decreased average interatomic distance between A-site cation and iodide. Using a ~2.0 eV Rb/Cs mixed-cation inorganic perovskite with large lattice distortion in the top subcell, we fabricated all-perovskite triple-junction solar cells and achieved an efficiency of 24.3% (23.3% certified quasi-steady-state efficiency) with an open-circuit voltage of 3.21 V. This is, to our knowledge, the first reported certified efficiency for perovskite-based triple-junction solar cells. The triple-junction devices retain 80% of their initial efficiency following 420 hours of operation at the maximum power point.

14 SOLAR ENERGY↗

Cobalt and Yttrium Modified TiO{sub 2} Nanotubes Based Dye-Sensitized Solar Cells for Solar-Energy Conversion

The solar-energy conversion in eosin-sensitized solar cells based on cobalt and yttrium modified TiO2 nanotubes has been studied.It is established that the doping with metal ions shifts the absorption edge for Co and Y doped titanium dioxide samples to longer and shorter wavelengths, respectively. The efficiency of solar energy conversion depends on the wide bandgap of the semiconductor anode and reaches a maximum (4.4%) for yttrium-doped TiO{sub 2} in comparison to that (4.1%) for pure titanium dioxide.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Power Router for Distributing Solar in Communities (Solar Prize): Cooperative Research and Development, CRADA Number CRD-20-16809 (Final Report)

The American Made Solar Prize is a prize competition from the U.S. Department of Energy (DOE) that is designed to revitalize U.S. solar manufacturing. The competition aims to support the growth of U.S. solar manufacturing and reenergize American energy innovation by tapping into American's competitive spirit and the nation's unparalleled innovation ecosystem leveraging national labs, incubators, facilities and more.

14 SOLAR ENERGY↗

DC Solar for All: Implementation Plan to Scale Low- and Moderate- Income Community Solar + Storage Resilience Hubs in the District of Columbia

This implementation plan discusses the District of Columbia's strategy to combine low-income community solar projects with resilience technologies. Through the technical and financial support offered by the Inclusive Shared Solar Initiative and building on extensive stakeholder engagement in LMI neighborhoods around the District, the District of Columbia team expects to reduce energy burdens for LMI residents, address barriers to and streamline SfA program enrollment, and support the development of innovative benefit delivery models, including a community solar-supported climate resilience center.

14 SOLAR ENERGY↗

Community Planning for Solar: Conducting a Community Solar Survey

This guide is designed to assist community officials, volunteers, and regional planning agency staff in conducting a survey of residents to learn about attitudes and development preferences towards solar energy within the community. The guide will provide the key steps, timelines, distribution options, ethics, and considerations that should be made in developing a survey distribution strategy. The guide also contains an overview of various question types and response categories, with considerations for the type of data that are needed for the study. The guide concludes with recommendations for managing data and databases, data visualization, and reporting results. The appendix includes samples of materials used in a solar energy survey, from invitation letters to the survey. This document is intended to provide a practical guide for implementing a survey in communities that are proactively planning for solar development. The guide offers a practical “how-to” plan for conducting a survey. It may be advantageous to consult with an expert in survey development who will be familiar with any methods and techniques described in this guide, but this is not necessary. This guide offers basic considerations and examples of questions and analyses to help a community understand preferences of the community.

14 SOLAR ENERGY↗

BAYES’ THEOREM AND EARLY SOLAR SHORT-LIVED RADIONUCLIDES: THE CASE FOR AN UNEXCEPTIONAL ORIGIN FOR THE SOLAR SYSTEM

The presence of excesses of short-lived radionuclides in the early solar system evidenced in meteorites has been taken as testament to close encounters with exotic nucleosynthetic sources, including supernovae or AGB stars. An analysis of the likelihoods associated with different sources of these extinct nuclides in the early solar system indicates that, rather than being exotic, their abundances were typical of star-forming regions like those observed today in the Galaxy. The radiochemistry of the early solar system is therefore unexceptional, being the consequence of extensive averaging of solids from molecular clouds.

79 ASTRONOMY AND ASTROPHYSICS↗

Hard X-Ray Emission from Partially Occulted Solar Flares: RHESSI Observations in Two Solar Cycles

Flares close to the solar limb, where the footpoints are occulted, can reveal the spectrum and structure of the coronal looptop source in X-rays. We aim at studying the properties of the corresponding energetic electrons near their acceleration site, without footpoint contamination. To this end, a statistical study of partially occulted flares observed with Reuven Ramaty High-Energy Solar Spectroscopic Imager is presented here, covering a large part of solar cycles 23 and 24. We perform detailed spectra, imaging, and light curve analyses for 116 flares and include contextual observations from SDO and STEREO when available, providing further insights into flare emission that were previously not accessible. We find that most spectra are fitted well with a thermal component plus a broken power-law, non-thermal component. A thin-target kappa distribution model gives satisfactory fits after the addition of a thermal component. X-ray imaging reveals small spatial separation between the thermal and non-thermal components, except for a few flares with a richer coronal source structure. A comprehensive light curve analysis shows a very good correlation between the derivative of the soft X-ray flux (from GOES ) and the hard X-rays for a substantial number of flares, indicative of the Neupert effect. The results confirm that non-thermal particles are accelerated in the corona and estimated timescales support the validity of a thin-target scenario with similar magnitudes of thermal and non-thermal energy fluxes.

79 ASTRONOMY AND ASTROPHYSICS↗

The Solar Energetic Particle Event of 2010 August 14: Connectivity with the Solar Source Inferred from Multiple Spacecraft Observations and Modeling

We analyze one of the first solar energetic particle (SEP) events of solar cycle 24 observed at widely separated spacecraft in order to assess the reliability of models currently used to determine the connectivity between the sources of SEPs at the Sun and spacecraft in the inner heliosphere. This SEP event was observed on 2010 August 14 by near-Earth spacecraft, STEREO-A (∼80° west of Earth) and STEREO-B (∼72° east of Earth). In contrast to near-Earth spacecraft, the footpoints of the nominal magnetic field lines connecting STEREO-A and STEREO-B with the Sun were separated from the region where the parent fast halo coronal mass ejection (CME) originated by ∼88° and ∼47° in longitude, respectively. We discuss the properties of the phenomena associated with this solar eruption. Extreme ultraviolet and white-light images are used to specify the extent of the associated CME-driven coronal shock. We then assess whether the SEPs observed at the three heliospheric locations were accelerated by this shock or whether transport mechanisms in the corona and/or interplanetary space provide an alternative explanation for the arrival of particles at the poorly connected spacecraft. A possible scenario consistent with the observations indicates that the observation of SEPs at STEREO-B and near Earth resulted from particle injection by the CME shock onto the field lines connecting to these spacecraft, whereas SEPs reached STEREO-A mostly via cross-field diffusive transport processes. The successes, limitations, and uncertainties of the methods used to resolve the connection between the acceleration sites of SEPs and the spacecraft are evaluated.

79 ASTRONOMY AND ASTROPHYSICS↗

Solar and Battery Storage Permitting and Siting Requirements - Solar Prize Round 7 (CRADA Final Report)

The purpose of this research project was to aggregate zoning and permitting data for utility-scale solar PV and battery energy storage systems. The ultimate goal of this collaboration is to lower solar and battery energy storage system soft costs by streamlining regulatory due diligence and reducing the burden of conducting feasibility assessments for solar and storage systems. The below sections describe the specific research completed by NLR (the contractor) in furtherance of the agreement with Vanox (the participant).

14 SOLAR ENERGY↗

The Three-Dimenstional Solar Wind at Solar Activity Minimum

In late 1997, the Ulysses spacecraft completed its first orbit around the Sun, observing the properties of the heliosphere at all latitudes between 80 degrees South and 80 degrees North. Because the mission occurred during a period of near-minimum solar activity, the configuration of the solar wind and interplanetary magnetic field were particularly simple, thus allowing confident comparisons between the properties of the polar corona observed by instruments of the Spartan and SOHO spacecraft and the resulting properties of the solar wind.

Solar Wind Ulysses Solar Activity polar corona↗

(abstract) Interplanetary Lyman-alpha Observations with the Galileo Ultraviolet Spectrometer: Solar Wind Latitude Variations and Multiple Scattering at Solar Maximum

The Galileo Ultraviolet Spectrometer obtained a Lyman-alpha celestrial sphere map on 13,14 December 1990 near the first Earth encounter, with spacecraft near the interstellar wind downwind axis. The data show solar flux longitudinal and latitudinal asymmetries which are modeled with He 10830 Ssolar images. The difference between the observed brightness and a single scattering model is attributed to multiple scattering effects, which we also calculate. The data constrain the solar wind flux latitude variation at solar maximum. Other 1990-1992 Galileo Lyman-alpha data will be discussed.

solar wind ultraviolet spectrometer solar flux cel↗

The FIELDS Instrument Suite for Solar Probe Plus Measuring the Coronal Plasma and Magnetic Field, Plasma Waves and Turbulence, and Radio Signatures of Solar Transients

NASA's Solar Probe Plus (SPP) mission will make the first in situ measurements of the solar corona and the birthplace of the solar wind. The FIELDS instrument suite on SPP will make direct measurements of electric and magnetic fields, the properties of in situ plasma waves, electron density and temperature profiles, and interplanetary radio emissions, amongst other things. Here, we describe the scientific objectives targeted by the SPP/FIELDS instrument, the instrument design itself, and the instrument concept of operations and planned data products.

Solar Probe Plus↗