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At least 685 records · Page 38

Adsorption of neodymium, dysprosium, and ytterbium to goethite under varying aqueous chemistry conditions [dataset]

The adsorption of rare earth elements (REEs) to iron oxides can regulate the mobility of REEs in the environment and is heavily influenced by water chemistry. This study utilized batch experiments to examine the adsorption of Nd, Dy, and Yb to goethite under varying pH, electrolyte (type and concentration), and concentrations of dissolved inorganic carbon and citrate. REE adsorption was strongly influenced by pH, with an increase from essentially no adsorption at pH 3.0 to nearly complete adsorption at pH 6.5 and higher. Citrate enhanced the adsorption of REEs at low pH (< 5.0), likely by forming goethite-REE-citrate ternary surface complexes. However, citrate inhibited the adsorption of REEs at higher pH (> 5.0) by forming aqueous REE-citrate complexes. Ionic strength had a small influence on REE adsorption, and the presence of dissolved inorganic carbon had no discernible effect. Equilibrium adsorption was interpreted with a triple layer surface complexation model (SCM). The selection of surface complexation reactions was guided by extended X-ray absorption fine structure spectra. A SCM with a single bidentate inner-sphere surface complexation reaction for Nd and two inner-sphere surface complexation reactions (one monodentate and one bidentate reaction) for Dy and Yb effectively simulated adsorption across a broad range of conditions in the absence of citrate. Accounting for the effects of citrate on REE adsorption required the addition of up to two ternary REE-citrate-goethite surface complexes. The SCM can enable predictions of REE transport in subsurface environments that have goethite as an important adsorbent mineral. This predictive capability could contribute to identifying potential REE sources and facilitating efficient extraction of REEs.

58 GEOSCIENCES↗

The X-ray Emissivity of the Universe: 2-200 Kev

Observational results on the diffuse X-ray background between 2 and 200 keV are reported. Data are presented as a function of the volume emissivity function B (E) (ergs/sec cu Mpc keV emitted at energy E). The prescription for this is first to establish the spectral intensity I (E) (ergs/sec sq cm ster keV) measured at the earth, second to subtract the contribution due to known, discrete sources, and third to unfold the integral equation which relates the measured intensity to the emissivity.

Schwartz, D.↗

A comparison of electric and magnetic field data from the OGO-6 spacecraft

Electric and magnetic field disturbance characteristics from OGO-6 were studied. Examination of simultaneous patterns of disturbance below 600 km over the summer polar cap showed that pattern changes in electric field and in the disturbance in magnetic field magnitude are highly correlated. This correlation extends to pattern shapes boundary locations, and to the amplitudes of the correlated quantities. In the winter hemisphere, at altitudes above 800 km, correlations between boundaries exist, pattern correlations are present, and amplitude correlations are essentially absent. Below 600 km the region of positive delta B, from 2200 to 1000 MLT, has a significant contribution from ionospheric and nonionospheric sources. Above 800 km the nonionospheric sources dominate.

Langel, R. A.↗

Theoretical and experimental studies in ultraviolet solar physics

The processes and parameters in atomic and molecular physics that are relevant to solar physics are investigated. The areas covered include: (1) measurement of atomic and molecular parameters that contribute to discrete and continous sources of opacity and abundance determinations in the sun; (2) line broadening and scattering phenomena; and (3) development of an ion beam spectroscopic source which is used for the measurement of electron excitation cross sections of transition region and coronal ions.

Parkinson, W. H.↗

The isotopic composition of hydrogen and helium in low-energy cosmic rays

The isotopes H-2 and He-3 have been identified in low-energy cosmic rays during solar-quiet periods from 1973 January to 1974 October. These observations, made with the electron/isotope spectrometer on IMP-7, cover the energy intervals 5-29 MeV per nucleon for H-2 and 7-50 MeV per nucleon for He-3. The energy spectra of H-1, H-2, and He-3 fall rapidly with decreasing energy, giving H-2/H-1 and He-3/H-1 ratios which are essentially independent of energy as expected from current theories of the solar modulation of galactic cosmic rays. The measured He-4 spectrum, however, is essentially flat below 40 MeV per nucleon, suggesting that there may be contributions from a local, nonsolar source of He-4. Comparisons of the H-1, H-2, and He-3 observations with calculated spectra at 1 AU imply a mean interstellar path length of 7 plus or minus 2 g/sq cm. However, present low-energy measurements of H and He isotopes at 1 AU do not discriminate between possible cosmic-ray source spectra.

Mewaldt, R. A.↗

The effective temperature of Uranus

Uranus was observed in the spectral region from 40 to 250 microns with a 102-cm balloon-borne telescope, and the results were interpreted in terms of model atmosphere calculations to yield an effective temperature of 58 plus or minus 3 K; this sets an upper limit of about 28 per cent on the relative contribution of an internal heat source to the total thermal radiation. On the same flight, the brightness temperatures of Venus (215 plus or minus 13 K) and Jupiter (135 plus or minus 6 K) were also measured, thus reconfirming the existence of an internal heat source for Jupiter.

Fazio, G. G.↗

The determination of atmospheric trace gases using the correlation interferometer technique

The theoretical feasibility inherent in the correlation interferometry technique is demonstrated. High signal to noise and increased information content in a given partial interferogram are attractive features of the technique. The separation of interfering gas species is overcome by a precise measurement program for spectral line parameters of methane and other species. There are optical, mechanical, and electronic difficulties with the interferometry hardware design. Flight data from Cessna 402 over southeastern Virginia during April 1978 yielded amplitude fluctuations that are explainable only as internal nonlinearities. Misalignment of the AGC/interferometer optical axis also contributed to a large error source in the flight data. It is concluded that no useful data on gas burdens was obtained from these flights.

Kindle, E. C.↗

Effect of rawinsonde errors on rocketsonde density and pressure profiles: An error analysis of the Rawinsonde System

An initial value of pressure is required to derive the density and pressure profiles of the rocketborne rocketsonde sensor. This tie-on pressure value is obtained from the nearest rawinsonde launch at an altitude where overlapping rawinsonde and rocketsonde measurements occur. An error analysis was performed of the error sources in these sensors that contribute to the error in the tie-on pressure. It was determined that significant tie-on pressure errors result from radiation errors in the rawinsonde rod thermistor, and temperature calibration bias errors. To minimize the effect of these errors radiation corrections should be made to the rawinsonde temperature and the tie-on altitude should be chosen at the lowest altitude of overlapping data. Under these conditions the tie-on error, and consequently the resulting error in the Datasonde pressure and density profiles is less tha 1%. The effect of rawinsonde pressure and temperature errors on the wind and temperature versus height profiles of the rawinsonde was also determined.

Luers, J. K.↗

Computer program to predict aircraft noise levels

Methods developed at the NASA Lewis Research Center for predicting the noise contributions from various aircraft noise sources were programmed to predict aircraft noise levels either in flight or in ground tests. The noise sources include fan inlet and exhaust, jet, flap (for powered lift), core (combustor), turbine, and airframe. Noise propagation corrections are available for atmospheric attenuation, ground reflections, extra ground attenuation, and shielding. Outputs can include spectra, overall sound pressure level, perceived noise level, tone-weighted perceived noise level, and effective perceived noise level at locations specified by the user. Footprint contour coordinates and approximate footprint areas can also be calculated. Inputs and outputs can be in either System International or U.S. customary units. The subroutines for each noise source and propagation correction are described. A complete listing is given.

Clark, B. J.↗

Noise and performance characteristics of a model scale X-wing rotor system in hover

Noise data for the hover condition were measured for a 8 m diameter X-wing model rotor mounted on an outdoor whirl tower. The noise was found to be a function of operating condition, in general increasing with performance. The X-wing spectra obtained from narrowband and 1/3-octave band analyses were dominated by the blade passage frequency harmonics. The circulation control slot blowing produced 1 to 10 kHz broadband noise which exhibited a jet velocity to the 5.4 dependency. Under the rotor plane loading noise was dominant, except at low values of blade pressure ratio where a sharp decrease in the blade passage frequency harmonic levels was observed. In the rotor plane, the contribution of the broadband noise sources was greater than under the rotor plane. The X-wing rotor system in hover exhibited flexibility in operating conditions to achieve a specific level of performance. The high collective, low blade passage ratio combinations which meet a given level of performance were associated with low overall sound pressure levels.

Willshire, W. L., Jr.↗

Cosmic-ray abundances of the even charge elements from Sn-50 to Ce-58 measured on HEAO-3

Elements with even atomic number (Z) in the interval Z = 50-58 have been resolved in the cosmic radiation using the Heavy Nuclei Experiment on the HEAO-3 satellite. The observation that Sn-50 and Ba-56 are more abundant than Te-52 and Xe-54 indicates a substantial s-process contribution to the cosmic ray source. A significant abundance of Ce-58 provides further support for this finding.

Stone, E. C.↗

Secular cooling of the earth as a source of intraplate stress

As a result of secular cooling and contraction of the earth, an increasingly extensional horizontal stress is imposed on the central portions of the plates. While the rate of increase of this stress is small in most situations, it is enhanced for large plates and during any episodes of accelerated global cooling. This source of stress may have contributed to the rifting and breakup of long-lived supercontinental plates.

Solomon, Sean C.↗

A general model for attitude determination error analysis

An overview is given of a comprehensive approach to filter and dynamics modeling for attitude determination error analysis. The models presented include both batch least-squares and sequential attitude estimation processes for both spin-stabilized and three-axis stabilized spacecraft. The discussion includes a brief description of a dynamics model of strapdown gyros, but it does not cover other sensor models. Model parameters can be chosen to be solve-for parameters, which are assumed to be estimated as part of the determination process, or consider parameters, which are assumed to have errors but not to be estimated. The only restriction on this choice is that the time evolution of the consider parameters must not depend on any of the solve-for parameters. The result of an error analysis is an indication of the contributions of the various error sources to the uncertainties in the determination of the spacecraft solve-for parameters. The model presented gives the uncertainty due to errors in the a priori estimates of the solve-for parameters, the uncertainty due to measurement noise, the uncertainty due to dynamic noise (also known as process noise or measurement noise), the uncertainty due to the consider parameters, and the overall uncertainty due to all these sources of error.

Markley, F. Landis↗

Redshift and luminosity dependence of the linear sizes of powerful radio galaxies

The redshift and luminosity dependence of the linear sizes of powerful radio galaxies on epoch is investigated using samples of similar radio luminosity extending to z larger than about one. It is found that a strong evolution in linear sizes with epoch of a given form is required for q0 = 1/2. Fairly strong evolution is required even if the steep-spectrum compact sources which make an increasing contribution with redshift are excluded from the analysis. When linear size distributions of samples of radio galaxies of different luminosities are compared at similar redshifts, it is found that, at constant redshift, linear sizes increase with luminosity in a given way. Strong evidence is found that, for radio galaxies, the epoch and luminosity dependence of linear sizes can be factorized over the entire range of luminosity and redshift space.

Kapahi, Vijay K.↗

Attitude determination error analysis - General model and specific application

This paper presents a comprehensive approach to filter and dynamics modeling for attitude determination error analysis. The discussion includes models for both batch least-squares and sequential estimators, a specific dynamic model for attitude determination error analysis of a three-axis stabilized spacecraft equipped with strapdown gyros, and the incorporation of general attitude sensor observations. An analyst using this approach to perform an error analysis chooses a subset of the spacecraft parameters to be 'solve-for' parameters, which are to be estimated, and another subset to be 'consider' parameters, which are assumed to have errors but not to be estimated. The result of the error analysis is an indication of overall uncertainties in the 'solve-for' parameters, as well as the contributions of the various error sources to these uncertainties, including those of errors in the a priori 'solve-for' estimates, of measurement noise, of dynamic noise (also known as process noise or plant noise), and of 'consider' parameter uncertainties. The analysis of attitude, star tracker alignment, and gyro bias uncertainties for the Gamma Ray Observatory spacecraft provide a specific example of the use of a general-purpose software package incorporating these models.

Markley, F. Landis↗

Signal-to-noise considerations for sky-subtracted CCD data

The standard equation for calculating the uncertainty of photometry obtained from CCDs does not correctly consider the random errors, or 'noise', introduced into observations by procedures used in reducing the data. This paper presents a thorough derivation of the theoretical error equation that considers the contributions from all internal noise sources in the signal-to-noise ratio (S/N) of a sky-subtracted image. A simplified version used for estimating the internal errors from empirical data is also derived. The propagation of noise through the data-reduction process is illustrated through a series of equations for the change in S/N that results from a variety of different operations performed on a CCD frame. Comparing these effects with the results expected for an observation made with an ideal detector suggests a number of ways to improve the precision of photometry through the practices employed in obtaining and reducing the observations.

Newberry, Michael V.↗

Interior Noise

The generation and control of flight vehicle interior noise is discussed. Emphasis is placed on the mechanisms of transmission through airborne and structure-borne paths and the control of cabin noise by path modification. Techniques for identifying the relative contributions of the various source-path combinations are also discussed along with methods for the prediction of aircraft interior noise such as those based on the general modal theory and statistical energy analysis.

Mixson, John S.↗

Galileo Attitude Determination: Experiences with a Rotating Star Scanner

The Galileo experience with a rotating star scanner is discussed in terms of problems encountered in flight, solutions implemented, and lessons learned. An overview of the Galileo project and the attitude and articulation control subsystem is given and the star scanner hardware and relevant software algorithms are detailed. The star scanner is the sole source of inertial attitude reference for this spacecraft. Problem symptoms observed in flight are discussed in terms of effects on spacecraft performance and safety. Sources of thse problems include contributions from flight software idiosyncrasies and inadequate validation of the ground procedures used to identify target stars for use by the autonomous on-board star identification algorithm. Problem fixes (some already implemented and some only proposed) are discussed. A general conclusion is drawn regarding the inherent difficulty of performing simulation tests to validate algorithms which are highly sensitive to external inputs of statistically 'rare' events.

Merken, L.↗