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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

39Ar/Ar measurements using ultra-low background proportional counters

Age dating groundwater and seawater using 39Ar/Ar ratios is an important tool to understand water mass flow rates and mean residence time. For modern or contemporary argon, the 39Ar activity is 1.8 mBq per liter of argon. Radiation measurements at these activity levels require ultra low-background detectors. Low-background proportional counters have been developed at Pacific Northwest National Laboratory. These detectors use traditional mixtures of argon and methane as counting gas, and the residual 39Ar from commercial argon has become a predominant source of background activity in these detectors. We demonstrated sensitivity to 39Ar by using geological or ancient argon from gas wells in place of commercial argon. The low level counting performance of these proportional counters is then demonstrated for sensitivities to 39Ar/Ar ratios sufficient to date water masses as old as 1000 years.

39Ar/Ar measurements using ultra-low background pr↗
DOE OSTI2022

Kinetic Probes of the Origin of Activity in MOF-Based C–H Oxidation Catalysis

The development of homogeneous catalysis is enabled by the availability of a rich toolkit of kinetics experiments, such as the Hgdrop test, that differentiate catalytic activity at ligand-supported metal complexes from potential heterogeneous catalysts derived from decomposition of molecular species. Metal-organic frameworks (MOFs) have garnered significant attention as platforms for catalysis at site-isolated, interstitial catalyst sites. Unlike homogeneous catalysis, relatively few strategies have been advanced to evaluate the origin of catalytic activity in MOF-promoted reactions. Many of the MOFs that have been examined as potential catalysts are comprised of molecular constituents that represent viable catalysts in the absence of the extended MOF lattice, and thus interfacial sites and leached homogeneous species represent potential sources of catalyst activity. Here, we demonstrate that analysis of deuterium kinetic isotope effects (KIEs) and olefin epoxidation diastereoselectivity provides probes of the origin of catalytic activity in MOF-promoted oxidation reactions. These analyses support involvement of lattice-based Fe sites in the turnover-limiting step of C–H activation with Fe-MOF-74-based materials (i.e., the MOF functions as a bona fide catalyst) and evidence that Cu 2 -based MOF MIL-125-Cu 2 O 2 functions as a solid-state initiator for solution-phase oxidation chemistry and is not involved in the turnover limiting step (i.e., the MOF does not function as a catalyst for substrate functionalization). furthermore, we anticipate that the simple experiments described here will provide a valuable tool for clarifying the role of MOFs in C–H oxidation reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

On the nature of the nonthermal radio emission from the galactic center

Some recent observations of the galactic center appear at first sight to have made the character of the radio source Sgr A unclear. The flatness of the usually quoted spectrum, the lack of any measured polarization, the presence of hydrogen recombination lines, and the radio-infrared luminosity ratio are all consistent with Sgr A being a rather hot H II region. It is shown here, however, that when flux measurements between 80 MHz and 91000 MHz are all included and the multiple nature of the source is accounted for, the spectral index exceeds 0.4 - much too steep to be bremsstrahlung. There is, therefore, no question that Sgr A is a nonthermal source. It is further argued on the basis of a comparison of appearance, energetics and the recent results which no longer put Sgr A exactly at the center of the galaxy that Sgr A could be a supernova remnant rather than a miniature of active extragalactic radio sources.

Jones, T. W.↗
NASA NTRS1985

Search for optical bursts from the gamma ray burst source GBS 0526-66

Attempts were made to detect optical bursts from the gamma-ray burst source GBS 0526-66 during Dec. 31, 1984 to Jan. 2, 1985 and Feb. 23 to Feb. 24, 1985, using the one meter reflector of the Kavalur Observatory. Jan. 1, 1985 coincided with the zero phase of the predicted 164 day period of burst activity from the source (Rothschild and Lingenfelter, 1984). A new optical burst photon counting system with adjustable trigger threshold was used in parallel with a high speed photometer for the observations. The best time resolution was 1 ms and maximum count rate capability was 255,000 counts s(-1). Details of the instrumentation and observational results are presented.

Seetha, S.↗
NASA NTRS2002

Monitoring the Microgravity Environment Quality On-board the International Space Station Using Soft Computing Techniques: Preliminary System Performance Results - Part 2

This paper presents the preliminary performance results of the artificial intelligence monitoring system in full operational mode using near real time acceleration data downlinked from the International Space Station. Preliminary microgravity environment characterization analysis result for the International Space Station (Increment-2), using the monitoring system is presented. Also, comparison between the system predicted performance based on ground test data for the US laboratory "Destiny" module and actual on-orbit performance, using measured acceleration data from the U.S. laboratory module of the International Space Station is presented. Finally, preliminary on-orbit disturbance magnitude levels are presented for the Experiment of Physics of Colloids in Space, which are compared with on ground test data. The ground test data for the Experiment of Physics of Colloids in Space were acquired from the Microgravity Emission Laboratory, located at the NASA Glenn Research Center, Cleveland, Ohio. The artificial intelligence was developed by the NASA Glenn Principal Investigator Microgravity Services Project to help the principal investigator teams identify the primary vibratory disturbance sources that are active, at any moment of time, on-board the International Space Station, which might impact the microgravity environment their experiments are exposed to. From the Principal Investigator Microgravity Services' web site, the principal investigator teams can monitor via a dynamic graphical display, implemented in Java, in near real time, which event(s) is/are on, such as crew activities, pumps, fans, centrifuges, compressor, crew exercise, structural modes, etc., and decide whether or not to run their experiments, whenever that is an option, based on the acceleration magnitude and frequency sensitivity associated with that experiment. This monitoring system detects primarily the vibratory disturbance sources. The system has built-in capability to detect both known and unknown vibratory disturbance sources. Several soft computing techniques such as Kohonen's Self-Organizing Feature Map, Learning Vector Quantization, Back-Propagation Neural Networks, and Fuzzy Logic were used to design the system.

Jules, Kenol↗
NASA NTRS1976

Solar radio continuum storms

The paper reviews the current status of research on solar radio continuum emissions from metric to hectometric wave frequencies, emphasizing the role of energetic electrons in the 10-100 keV range in these emissions. It is seen that keV-energy electrons generated in active sunspot groups must be the sources of radio continuum storm emissions for wide frequency bands. These electrons excite plasma oscillations in the medium, which in turn are converted to electromagnetic radiation. The radio noise continuum sources are usually associated with type III burst activity observed above these sources. Although the mechanism for the release of the energetic electrons is not known, it seems they are ejected from storm source regions in association with rapid variation of associated sunspot magnetic fields due to their growth into complex types. To explain some of the observed characteristics, the importance of two-stream instability and the scattering of ambient plasma ions on energetic electron streams is pointed out.

Sakurai, K.↗
DOE OSTI2012

SGR J1550-5418 BURSTS DETECTED WITH THE FERMI GAMMA-RAY BURST MONITOR DURING ITS MOST PROLIFIC ACTIVITY

We have performed detailed temporal and time-integrated spectral analysis of 286 bursts from SGR J1550-5418 detected with the Fermi Gamma-ray Burst Monitor (GBM) in 2009 January, resulting in the largest uniform sample of temporal and spectral properties of SGR J1550-5418 bursts. We have used the combination of broadband and high time-resolution data provided with GBM to perform statistical studies for the source properties. We determine the durations, emission times, duty cycles, and rise times for all bursts, and find that they are typical of SGR bursts. We explore various models in our spectral analysis, and conclude that the spectra of SGR J1550-5418 bursts in the 8-200 keV band are equally well described by optically thin thermal bremsstrahlung (OTTB), a power law (PL) with an exponential cutoff (Comptonized model), and two blackbody (BB) functions (BB+BB). In the spectral fits with the Comptonized model, we find a mean PL index of -0.92, close to the OTTB index of -1. We show that there is an anti-correlation between the Comptonized E{sub peak} and the burst fluence and average flux. For the BB+BB fits, we find that the fluences and emission areas of the two BB functions are correlated. The low-temperature BB has an emission area comparable to the neutron star surface area, independent of the temperature, while the high-temperature BB has a much smaller area and shows an anti-correlation between emission area and temperature. We compare the properties of these bursts with bursts observed from other SGR sources during extreme activations, and discuss the implications of our results in the context of magnetar burst models.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

NGC 1980 Is Not a Foreground Population of Orion: Spectroscopic Survey of Young Stars with Low Extinction in Orion A

We perform a spectroscopic survey of the foreground population in Orion A with MMT/Hectospec. We use these data, along with archival spectroscopic data and photometric data, to derive spectral types, extinction values, and masses for 691 stars. Using the Spitzer Space Telescope data, we characterize the disk properties of these sources. We identify 37 new transition disk (TD) objects, 1 globally depleted disk candidate, and 7 probable young debris disks. We discover an object with a mass of less than 0.018–0.030 M {sub ⊙}, which harbors a flaring disk. Using the H α emission line, we characterize the accretion activity of the sources with disks, and confirm that the fraction of accreting TDs is lower than that of optically thick disks (46% ± 7% versus 73% ± 9%, respectively). Using kinematic data from the Sloan Digital Sky Survey and APOGEE INfrared Spectroscopy of the Young Nebulous Clusters program (IN-SYNC), we confirm that the foreground population shows similar kinematics to their local molecular clouds and other young stars in the same regions. Using the isochronal ages, we find that the foreground population has a median age of around 1–2 Myr, which is similar to that of other young stars in Orion A. Therefore, our results argue against the presence of a large and old foreground cluster in front of Orion A.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2012

SGR J1550-5418 Bursts Detected with the Fermi Gamma-Ray Burst Monitor during Its Most Prolific Activity

We have performed detailed temporal and time-integrated spectral analysis of 286 bursts from SGR J1550-5418 detected with the Fermi Gamma-ray Burst Monitor (GBM) in 2009 January, resulting in the largest uniform sample of temporal and spectral properties of SGR J1550-5418 bursts. We have used the combination of broadband and high time-resolution data provided with GBM to perform statistical studies for the source properties.We determine the durations, emission times, duty cycles, and rise times for all bursts, and find that they are typical of SGR bursts. We explore various models in our spectral analysis, and conclude that the spectra of SGR J15505418 bursts in the 8-200 keV band are equally well described by optically thin thermal bremsstrahlung (OTTB), a power law (PL) with an exponential cutoff (Comptonized model), and two blackbody (BB) functions (BB+BB). In the spectral fits with the Comptonized model, we find a mean PL index of -0.92, close to the OTTB index of -1. We show that there is an anti-correlation between the Comptonized E(sub peak) and the burst fluence and average flux. For the BB+BBfits, we find that the fluences and emission areas of the two BB functions are correlated. The low-temperature BB has an emission area comparable to the neutron star surface area, independent of the temperature, while the high temperature BB has a much smaller area and shows an anti-correlation between emission area and temperature.We compare the properties of these bursts with bursts observed from other SGR sources during extreme activations, and discuss the implications of our results in the context of magnetar burst models.

bursts↗
DOE OSTI2018

A unified mechanism for plant polyketide biosynthesis derived from in silico modeling

Highlights: • A unitary mechanism for the cyclization of tetraketides in stilbene and chalcone synthase. • The identification of an active water that functions as a “Claisen switch” in chalcone synthase. • QM-MM and FMO analysis of model tetraketide ligands highlighting common and disparate components of binding pockets and cyclization sites in stilbene and chalcone synthase. The polyketide synthases found in a variety of plants and fungi provide a varied source of biologically active compounds of pharmacological and medicinal interest. Stilbene synthase and chalcone synthase catalyze the formation of a common tetraketide intermediate, but use different cyclization mechanisms to produce distinct and separate natural products. While key structural differences have been identified to explain this functional diversity, a fuller explication of the factors responsible for this mechanistic disparity is required. Based on the energetics of our models of the bound tetraketides, and our structural analysis of the active sites we propose that a key tautomeric conversion provides a mechanistic framework common to both cyclizations. A previously unidentified active water molecule facilitates cyclization in chalcone synthase through a Claisen mechanism. Such a “Claisen switch” is comparable to the previously characterized “aldol switch” mechanism proposed for the biosynthesis of resveratrol in stilbene synthase.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1984

Multifrequency light curves of low-frequency variable radio sources

Light curves for the low-frequency variable sources AO 0235 + 16, NRAO 140, PKS 1117 + 14, DA 406, CTA 102, and 3C 454.3, obtained in monthly observations at 318, 430, and 606 MHz using the 305-m telescope at Arecibo and in bimonthly observations at 880 MHz and 1.4 GHz using the 91-m Green Bank transit telescope during 1980-1983, are presented and analyzed. AO 0235 + 16 is found to have basically canonical variability which is attributed to relativistically moving evolving synchrotron components; but in the other sources, strong simultaneous variations at 318, 430, and 606 MHz are observed to be greatly diminished in amplitude at 880 MHz and 1.4 GHz, confirming the existence of the intermediate-frequency gap at about 1 GHz proposed by Spangler and Cotton (1981). The possibility that a second variability mechanism is active in these sources is explored.

Altschuler, D. R.↗
NASA NTRS1990

Transition control of instability waves over a flexible surface in the presence of an acoustic field

Experimental results are presented which demonstrate the coupling of a laminar boundary layer flow with a typical flexible aircraft panel. It is shown that the boundary layer induces plate oscillations which, in turn, perturb the flow at the same frequencies. This feedback mechanism is an inherent property of laminar boundary layer flow passing over a flexible plate. As a result, the flexibility of the plate becomes a source of early transition. The laminar boundary layer at the leading edge of the plate reacts to small, upstream, unsteady disturbances due to a streamwise pressure gradient. The experiments demonstrate that a nominal sound pressure incident at the leading edge triggers early transition. It is shown that transition can be delayed by activating a heat source at the leading edge of the plate which results in downstream cooling.

Maestrello, L.↗
NASA NTRS2004

Earth's Early Biosphere and the Biogeochemical Carbon Cycle

Our biosphere has altered the global environment principally by influencing the chemistry of those elements most important for life, e g., C, N, S, O, P and transition metals (e.g., Fe and Mn). The coupling of oxygenic photosynthesis with the burial in sediments of photosynthetic organic matter, and with the escape of H2 to space, has increased the state of oxidation of the Oceans and atmosphere. It has also created highly reduced conditions within sedimentary rocks that have also extensively affected the geochemistry of several elements. The decline of volcanism during Earth's history reduced the flow of reduced chemical species that reacted with photosynthetically produced O2. The long-term net accumulation of photosynthetic O2 via biogeochemical processes has profoundly influenced our atmosphere and biosphere, as evidenced by the O2 levels required for algae, multicellular life and certain modem aerobic bacteria to exist. When our biosphere developed photosynthesis, it tapped into an energy resource that was much larger than the energy available from oxidation-reduction reactions associated with weathering and hydrothermal activity. Today, hydrothermal sources deliver globally (0.13-1.1)x10(exp l2) mol yr(sup -1) of reduced S, Fe(2+), Mn(2+), H2 and CH4; this is estimated to sustain at most about (0.2-2)xl0(exp 12)mol C yr(sup -1) of organic carbon production by chemautotrophic microorganisms. In contrast, global photosynthetic productivity is estimated to be 9000x10(exp 12) mol C yr(sup -1). Thus, even though global thermal fluxes were greater in the distant geologic past than today, the onset of oxygenic photosynthesis probably increased global organic productivity by some two or more orders of magnitude. This enormous productivity materialized principally because oxygenic photosynthesizers unleashed a virtually unlimited supply of reduced H that forever freed life from its sole dependence upon abiotic sources of reducing power such as hydrothermal emanations and weathering. Communities sustained by oxygenic photosynthesis apparently thrived wherever supplies of sunlight, moisture and nutrients were sufficient. Prior to the development of oxygenic photosynthesis, the net global effect of the ancient global biosphere was to facilitate chemical equilibrium between reduced species from thermal activity and weathering and more oxidized constituents in the surface environment. But even this ancient biosphere might have been globally pervasive. The global geothermal heat flow was substantially higher during Earth's first billion years, and thus reduced chemical species might have persisted in sunlit aquatic environments. Perhaps the substantial decline in thermal activity between 4000 and 3000 Ma created a driver for oxygenic photosynthesis to develop.

DesMarais, David↗
DOE OSTI2013

Discovery of a highly variable dipping ultraluminous X-ray source in M94

We report the discovery of a new ultraluminous X-ray source (ULX) 2XMM J125048.6+410743 within the spiral galaxy M94. The source has been observed by ROSAT, Chandra, and XMM-Newton on several occasions, exhibiting as a highly variable persistent source or a recurrent transient with a flux variation factor of ≳100, a high duty cycle (at least ∼70%), and a peak luminosity of L {sub X} ∼ 2 × 10{sup 39} erg s{sup –1} (0.2-10 keV, absorbed). In the brightest observation, the source is similar to typical low-luminosity ULXs, with the spectrum showing a high-energy cutoff but harder than that from a standard accretion disk. There are also sporadical short dips, accompanied by spectral softening. In a fainter observation with L {sub X} ∼ 3.6 × 10{sup 38} erg s{sup –1}, the source appears softer and is probably in the thermal state seen in Galactic black hole X-ray binaries (BHBs). In an even fainter observation (L {sub X} ∼ 9 × 10{sup 37} erg s{sup –1}), the spectrum is harder again, and the source might be in the steep-power-law state or the hard state of BHBs. In this observation, the light curve might exhibit ∼7 hr (quasi-)periodic large modulations over two cycles. The source also has a possible point-like optical counterpart from Hubble Space Telescope images. In terms of the colors and the luminosity, the counterpart is probably a G8 supergiant or a compact red globular cluster containing ∼2 × 10{sup 5} K dwarfs, with some possible weak UV excess that might be ascribed to accretion activity. Thus, our source is a candidate stellar-mass BHB with a supergiant companion or with a dwarf companion residing in a globular cluster. Our study supports that some low-luminosity ULXs are supercritically accreting stellar-mass BHBs.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1974

Electrode kinetics of a water vapor electrolysis cell

The anodic electrochemical behavior of the water vapor electrolysis cell was investigated. A theoretical review of various aspects of cell overvoltage is presented with special emphasis on concentration overvoltage and activation overvoltage. Other sources of overvoltage are described. The experimental apparatus controlled and measured anode potential and cell current. Potentials between 1.10 and 2.60 V (vs NHE) and currents between 0.1 and 3000 mA were investigated. Different behavior was observed between the standard cell and the free electrolyte cell. The free electrolyte cell followed typical Tafel behavior (i.e. activation overvoltage) with Tafel slopes of about 0.15, and the exchange current densities of 10 to the minus 9th power A/sq cm, both in good agreement with literature values. The standard cell exhibitied this same Tafel behavior at lower current densities but deviated toward lower than expected current densities at higher potentials. This behavior and other results were examined to determine their origin.

Jacobs, G.↗
DOE OSTI2025

Ultra-sensitive radon assay using an electrostatic chamber in a recirculating system

Rare event searches such as neutrinoless double beta decay and Weakly Interacting Massive Particle detection require ultra-low background detectors. Radon contamination is a significant challenge for these experiments, which employ highly sensitive radon assay techniques to identify and select low-emission materials. This work presents the development of ultra-sensitive electrostatic chamber (ESC) instruments designed to measure radon emanation in a recirculating gas loop, for future lower background experiments. Unlike traditional methods that separate emanation and detection steps, this system allows continuous radon transport and detection. This is made possible with a custom-built recirculation pump. A Python-based analysis framework, PyDAn, was developed to process and fit time-dependent radon decay data. Radon emanation rates are given for various materials measured with this instrument. A radon source of known activity provides an absolute calibration, enabling statistically-limited minimal detectable activities of 20 uBq. These devices are powerful tools for screening materials in the development of low-background particle physics experiments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1990

Theory of accretion disk coronae

Accretion disk coronae are likely to be the dominant site for X-ray absorption and reprocessed emission in low mass X-ray binaries, and may be present in other classes of compact X-ray sources such as active galactic nuclei and cataclysmic variables. In spite of this fact, and in spite of the observational evidence for their existence, there remain many uncertainties about the structure of accretion disk coronae. This paper will discuss the coronal structure and dynamics, their X-ray spectral signatures including coupling to the variability behavior of compact X-ray sources, and the major unsolved theoretical issues surrounding them.

Kallman, T. R.↗
NASA NTRS1994

VLA stereoscopy of solar active regions. 2: Altitude, relative motion, and center-to-limb darkening of 20 centimeter emission

A newly developed method of stereoscopic correlation is applied to solar radio maps at a wavelength of 20 cm. On the basis of stereoscopic correlations between radio maps obtained on 6 different days we establish the presence of 66 radio source components associated with 22 active regions. We find the following statistical results for active region source structures at 20 cm: 1. The observed lifetime is consistent with an exponential distribution having an e-folding time scale of greater than 18 days. 2. The average altitude of 20 cm sources is 25 +/- 15 Mm; 90% of the sources are found in heights less than 40 Mm. 3. The average diameter of discrete source structures is 48 +/- 15 Mm, implying a vertical/horizontal aspect ratio of q(sub A) approx. = 0.5. 4. No significant source motion has been found with respect to the standard differential rotation rate of Omega = 13.45 deg - ((3 deg (sin(exp 2)B)). 5. We find a statistical limb darkening, which can be described by the relation (T(sub B)(alpha))/T(sub B)(0)) = 0.4 + ((0.6(cos(exp 2) alpha)) for sources with T(sub B) greater than 0.5 MK. 6. The degree of source polarization is 15% +/- 10% and is independent of source location. 7. Bright sources (greater than or approximately equal to 0.5 MK), or equivalently, long-lived sources (greater than or approximately equal to 5 days) show a systematic variation of their altitude as function of the center-limb distance.

Aschwanden, Markus J.↗