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At least 685 records · Page 38

Room temperature slot-die coated perovskite layer modified with sulfonyl-γ-AApeptide for high performance perovskite solar devices

Perovskite solar cells (PSCs) exhibited remarkable progress for small aperture area cells, however, the performance of its counterpart, large aperture area cells, lags due to non-uniform and defective perovskite layers. Here, we fabricate reproducible large area homogeneous perovskite films at room temperature and without controlling humidity (up to 40 % RH) with a slot die coater on a c-TiO 2 layer deposited using a large area chemical bath. A new artificial peptide – sulfonyl-γ-AApeptide (F-GLU-S) was employed to modify the slot-die coated perovskite surface, grain boundaries and electronic defects. The multi-functional F-GLU-S with carbonyl, carboxyl, sulfonyl, benzene, and chloro groups was capable of strongly interacting with the perovskite layer and repairing the uncoordinated Pb 2+ ions and halide vacancies. As a result, both the electron and hole densities of defects were significantly suppressed; consequently, the non-radiative recombination was effectively suppressed for the modified device which can be explicitly seen in the device performance where both V oc and FF of the modified device improved considerably. Therefore, F-GLU-S modified slot-die coated MAPbI 3 – based devices demonstrated outstanding performance of 21.44 % PCE with a V oc of 1.13 V, J sc of 24.64 cm –2 , and FF 76.99 %. Furthermore, F-GLU-S passivation impeded the infiltration of moisture and oxygen due to its hydrophobic nature and defect repair potential. As a result, the modified device retained above 92 % of its original PCE after 720 h in air (room temperature and 40–60 % RH).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Leafweb: Dataset in Support of Coupled Modeling of Photophysics, Photochemistry, and Biochemistry of Photosynthesis, December 2022 Release

This data set contains measurements of leaf gas exchange and Pulse-Amplitude Modulated (PAM) fluorometry of light, carbon dioxide (CO2), oxygen (O2), and temperature responses from 26 C3 photosynthetic and four C4 photosynthetic species measured by independent researchers in Canada, China, Finland, Netherlands, and United States in the field, garden, or greenhouse. Data were collected between 1987 and 2021, however data for individual species only provide coverage over a few hours to one year. Species include three lianas, three shrubs, two boreal deciduous trees, two boreal evergreen needle-leaf tree, three temperate deciduous trees, four tropical deciduous trees, three tropical evergreen trees, one C3 grass, three C4 grasses, and six crop varieties. These measurements are conducted according to standard protocols in gas exchange (Long and Bernacchi 2003) and PAM fluorometry (Baker 2008). The Scots pine (Pinus sylvestris) dataset contains one-year continuous fluorometry observations made at intervals of 10 or 30 minutes in the field under natural environments using Walz monitoring PAM. Measurements from all other 29 species include simultaneous PAM fluorometry and gas exchange observations. Among these 29 species, seven species were measured with light response curves only (i.e., light intensity varied systematically with ambient CO2 concentration controlled at a constant level, e.g., 400 ppm). All the other 22 species were measured with both the light response and CO2 response (i.e., ambient CO2 concentration varied systematically with light intensity controlled at a constant level, e.g., 1200 µmolm-2s-1). For most species, measurements were made with temperature controlled at ~ 25 degrees Celsius (C) with the exceptions of Scots pine (natural diurnal and seasonal variations), tomato cultivar Basket Vee (~ 21 degrees C), and cotton which contained temperature stress experiments (9 to 40 degrees C). All measurements were made at ambient O2 concentration except for the tomato cultivar Basket Vee and cotton which used two O2 levels (2 and 21%) and rice and tomato cultivar Growdena which used five O2 levels (2, 10, 21, 35, and 50%). This dataset supports the complete modeling of photosynthesis at the leaf scale, including photophysical, photochemical, and biochemical reactions. It will support research in the applications of remotely sensed solar induced chlorophyll fluorescence and the responses of energy dissipation pathways to environmental variations across species and climates. This dataset contains 260 data files in comma separate (.csv) format contained inside 11 compressed (*.zip) files. Additional metadata are provided: one data dictionary, a species information table, and a file-level metadata file in comma separate (.csv) format and a user guide in PDF (*.pdf) format.

air temperature↗

Mountain Basin Controls on the Snow-to-Streamflow Signal: An AIC-Weighted Multiple Linear Regression Framework

A regression-based analysis quantifies how basin characteristics modulate the snow-to-streamflow signal. First, we use the ERA5-Land reanalysis gridded product (European Centre for Medium Range Weather Forecasts reanalysis 5 -Land component) for 4,655 hydrologic unit code - 10 (HUC10) mountain basins across the western United States (US) for water years 1987–2024. Linear regressions are performed for peak snow water equivalent (SWE) and annual streamflow for each mountain basin. Models use ordinary least squares in Python’s statsmodels package. After which, an Akaike Information Criterion (AIC)–weighted ensemble multiple linear regression (MLR) framework with 47 watershed traits is used to predict the linear regression coefficient of determination (r-squared) defining the ability of peak SWE to predict annual streamflow across all mountain basin. Predictor sets are constrained to avoid multicollinearity by excluding models with variance inflation factors (VIF) greater than 5. Mountain basin traits included in the MLR include seasonal climate, topography, vegetation type and structure, and bedrock geology. Accepted models are considered if their AIC is within 2.0 of the model with the minimum AIC, or best model. To compare predictor influence across acceptable models, we computed standardized regression coefficients. To evaluate structural redundancy among models, we constructed binary inclusion vectors for each acceptable model, denoting whether a predictor was present (1) or absent (0). Core predictor variables are defined as occurring in at least 67% of the acceptable models. For this regional analysis, only one model was found acceptable, with higher snow-to-streamflow translation (higher r-squared) occurring in colder mountain basins with higher relative winter precipitation, more snow accumulation and a lower fraction of annual precipitation that falls in the spring and summer. The second component of the data package uses previously published, high-resolution output from an integrated hydrological model of the East River watershed using the U.S. Geological Survey Groundwater and Surface water Flow model (GSFLOW, doi:10.15485/1998576). East River MLR expands upon the approach described above to explore the response of five streamflow metrics—annual streamflow, runoff efficiency, 7-day minimum flow, low-flow duration, and non-perennial stream fraction to snow system indicators including peak SWE, snow-covered area, snow disappearance date, and the fraction of basin area characterized by low-to-no snow, as well as seasonal precipitation and temperature, and annual hydrologic variables representing soil moisture, evapotranspiration (ET), the partitioning of incoming precipitation to evapotranspiration (ET/P), groundwater storage, and groundwater inflow to streams. MLR was done on all water years (P0: 1987-2024) and for each period as determined in the split analysis using pooled regression techniques (P1: 1987-2011 and P2: 2012-2024) to evaluate shifting predictor variable emphasis on streamflow generation. Results indicate that since 2012, peak SWE has lost statistical strength in its prediction of annual streamflow and runoff efficiency, and the indirect influence of spring temperature has emerged as critically important. Low-flow metrics remain largely influenced by soil moisture, vegetation water use and groundwater inflows with summer precipitation becoming a direct influence on minimum summer flow. Together, these data and Python-based analysis tools provide a framework for identifying the key watershed characteristics that control how streamflow responds to snow from year to year. The package also helps quantify uncertainty in statistical models and assess how snow–streamflow relationships vary across regions and over time. This dataset contains comma-separated values files (.csv), text files (.txt), python code files (.py), figure files (.png), and shapefiles (.cpg, .dbf, .prj, .sbn, .sbx, .shp, .xml). Further details on file contents and MLR execution can be found in the readme file and the FLMD files. Work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

54 ENVIRONMENTAL SCIENCES↗

NGEE Arctic CO2, CH4 and Energy Eddy-Covariance (EC) Flux Tower Auxiliary Measurements, Utqiagvik (Barrow), Alaska, 2012 - 2019

Measurements began in September 2012 and are generally made throughout the snow-free growing season starting from April (pre-thawing) until November (freeze-up) when the instrumentation is taken down for maintenance and instrument calibration. CO2, CH4 and energy fluxes using the Eddy Covariance (EC) technique (Baldocchi 2003) and meteorological measurements are reported as 30-minute averages. The tower site is registered with AmeriFlux as US-NGB. See http://ameriflux.lbl.gov/sites/siteinfo/US-NGB for more information. Reported data include: (1) additional/extra meteorological and eddy covariance CO2, CH4 and energy flux data, (2) binned spectra for the three wind components, the sonic temperature and gas densities together with the binned cospectra for covariances of w (vertical wind component) and gas densities, (3) binned ogives (cumulative (co)spectra) for the three wind components, the sonic temperature and gas densities, and (4) tower site footprint matrices. Meteorological and eddy covariance CO2, CH4 and energy flux data (AmeriFlux BASE data product) are available from AmeriFlux https://doi.org/10.17190/AMF/1436326. The tower site is adjacent to the NGEE Arctic Tram system with several complementary time-series measurements https://doi.org/10.5440/1558782.This dataset supersedes the previously released dataset "Eddy-Covariance and auxiliary measurements, NGEE-Barrow, 2012-2013" DOI:10.5440/1124200 as this new product includes data for the longer time period processed using consistent methods for the entire record. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) near Utqiagvik (Barrow), Alaska and 2) multiple areas in the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Raw soil carbon dioxide, moisture, temperature and micrometeorological data in the East River Watershed, Colorado June 2021-June 2024. (DE-SC0021139)

This dataset contains raw data from four tripod stations along an elevation gradient on Snodgrass Mountain in the East River Watershed, CO, USA. Each station contains a datalogger connected to 3 soil Carbon Dioxide CO2 gas probes, 3 soil temperature/moisture sensors and a micrometeorological station. Sensors are scanned every minute, and the 30 minute average is reported. The file snodgrass_soil_ESS.csv contains raw data, a row of column descriptors, and units of measurements. some data processing and QA/QC was done to filter out data from sensors that went bad and extreme outliers. CO2 sensors that went bad were replaced with new sensors as soon as possible. This research was performed to investigate the ecohydrological linkages of belowground carbon processes in the East River watershed forested communities to better understand how these ecosystems will respond to a changing cold-season moisture input. This is the second version of this data set and was modified on 10/01/2024. The primary change in the data was the addition of data from the fall of 2022 to June of 2024. In addition, minor QA/QC was done to filter out data from sensors that went bad and extreme outliers. THe filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. This is now the third version of the data set, and was modified 03/25/2026. The primary change in the data was the addition of data from the June of 2024 to December 2025. Further r QA/QC was done with the new data to filter out bad data from faulty sensors and extreme outliers. The filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. ##This additional data was funded under DE-SC0024218( Responses of Plant and Microbial Respiration Sources to Changing Cold Season Climate Drivers in the East River Watershed)

54 ENVIRONMENTAL SCIENCES↗

Upper-air soundings collected during the CROCUS Urban Canyons 2024 campaign in Chicago, Illinois USA

Funded by the Department of Energy’s Office of Science, Biological and Environmental Research program, Community Research on Climate and Urban Science (CROCUS) studies urban climate change and the impact it has on communities, with particular focus on disinvested, under-resourced communities. This information leads to new insights on urban climate challenges and informs future actions for mitigating and adapting to climate change at the street, neighborhood and regional levels.As part of the CROCUS effort, the Urban Canyons 2024 project was undertaken to study conditions at unprecedented detail over various neighborhoods in Chicago, Illinois. This dataset consists of upper air soundings that were collected as part of this effort. Soundings were launched during two intensive observing periods, IOP1 occurred on 22-23 July 2024, while IOP2 occurred on 27-28 July 2024. For IOP1, soundings were launched at coordinated times from three sites, Shedd Aquarium in Downtown Chicago, Abizu Campus High School in Humboldt Park, and Gary Comer Youth Center in West Woodlawn. For IOP2, the Gary Comer site was replaced by a neighborhood site in West Woodlawn, Chicago. The Abizu Campos site was operated by Valparaiso University and used iMET-4 rawinsondes, the other sites were operated by the University of Illinois Urbana-Champaign and used GRAW DFM-19 sondes.This dataset contains netCDF files containing quality-controlled temperature, dewpoint, geopotential height, pressure, and vector wind measurements at 1 second intervals following launch. These files are readable by the open-source netCDF software libraries available in many software packages (i.e., python, R, fortran, C++, etc.). The dataset also contains quicklook plots of each launch on a skew-T log-p thermodynamic diagram. These are in png format viewable by most web browsers.

54 ENVIRONMENTAL SCIENCES↗

Towards accelerating particle-resolved direct numerical simulation with neural operators

In this paper, we present our ongoing work aimed at accelerating a particle-resolved direct numerical simulation model designed to study aerosol–cloud–turbulence interactions. The dynamical model consists of two main components—a set of fluid dynamics equations for air velocity, temperature, and humidity, coupled with a set of equations for particle (i.e., cloud droplet) tracing. Rather than attempting to replace the original numerical solution method in its entirety with a machine learning (ML) method, we consider developing a hybrid approach. We exploit the potential of neural operator learning to yield fast and accurate surrogate models and, in this study, develop such surrogates for the velocity and vorticity fields. We discuss results from numerical experiments designed to assess the performance of ML architectures under consideration as well as their suitability for capturing the behavior of relevant dynamical systems.

54 ENVIRONMENTAL SCIENCES↗

Direct Numerical Simulation of hydrogen combustion at auto-ignitive conditions: Ignition, stability and turbulent reaction-front velocity

Direct Numerical Simulations (DNS) are performed to investigate the process of spontaneous ignition of hydrogen flames at laminar, turbulent, adiabatic and non-adiabatic conditions. Mixtures of hydrogen and vitiated air at temperatures representing gas-turbine reheat combustion are considered. Adiabatic spontaneous ignition processes are investigated first, providing a quantitative characterization of stable and unstable flames. Results indicate that, in hydrogen reheat combustion, compressibility effects play a key role in flame stability and that unstable ignition and combustion are consistently encountered for reactant temperatures close to the mixture’s characteristic crossover temperature. Furthermore, it is also found that the characterization of the adiabatic processes is also valid in the presence of non-adiabaticity due to wall heat-loss. Finally, a quantitative characterization of the instantaneous fuel consumption rate within the reaction front is obtained and of its ability, at auto-ignitive conditions, to advance against the approaching turbulent flow of the reactants, for a range of different turbulence intensities, temperatures and pressure levels.

42 ENGINEERING↗

Prototype energy models for data centers

Data centers in the United States consume about two percent of the nation’s electricity. Because heat gains from IT equipment drive cooling demand, data centers offer unique opportunities for energy savings. However, no prototype energy model for data centers is available in the suite of existing U.S. Department of Energy’s Commercial Prototype Building Models. Here we present the development of two new data center prototype models and their implementation in OpenStudio and EnergyPlus. The small-size data center model represents a computer room in a building served by computer room air conditioners (CRACs); while the large-sized model represents stand-alone data centers served by computer room air handlers (CRAHs) with a central chiller plant. For each data center model, two levels of IT equipment (ITE) load density were considered, to cover the wide range of IT power density of data centers: 40 and 100 W/ft 2 (430 and 1076 W/m 2 ) for the computer room, and 100 and 500 W/ft 2 (1076 and 5382 W/m 2 ) for the stand-alone data center. All other assumptions, such as building envelope, lighting, HVAC efficiencies and schedules, were based on the minimal requirements of ASHRAE Standard 90.1 at various vintages. We introduced a novel concept of supply and return air approach temperatures to capture the essential effects of non-uniform airflow and temperature distribution in data centers. The approach temperatures were pre-computed by computational fluid dynamics (CFD) simulations for various configurations of ITE loads and airflow containment management in data centers. A new feature was developed in EnergyPlus to implement the approach temperature method. A case study was conducted to demonstrate the use of the data center models. The two data center models cover all U.S. climate zones and can be used to evaluate energy saving measures for data centers, as well as to support development of data center energy efficiency codes and standards.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Soil Respiration Responses to Throughfall Exclusion Are Decoupled From Changes in Soil Moisture for Four Tropical Forests, Suggesting Processes for Ecosystem Models

Abstract Climatic drying is predicted for many tropical forests yet models remain poorly parameterized for these ecosystems, hampering predictions of forest‐climate interactions. We applied an integrated model–experiment approach, parameterizing an ecosystem model with tropical forest observational data and comparing model predictions to a field drying manipulation. We hypothesized that drying suppresses soil CO 2 fluxes (i.e., respiration) in relatively dry tropical forests but increases CO 2 fluxes in wetter tropical forests by alleviating anaerobiosis. We measured soil CO 2 fluxes during wet‐dry cycles from 2015 to 2022 in four Panamanian forests that vary in rainfall and soil fertility. Measured soil CO 2 fluxes declined in the dry season and peaked in the early wet season ahead of peak soil moisture, resulting in lower soil moisture optima for respiration than previously modeled. We then parameterized the model using field data and the new moisture‐respiration response functions. The updated model predicted increased soil CO 2 fluxes with drying in wetter and fertile forests and suppressed fluxes in drier, infertile forests. In contrast to model predictions, a chronic throughfall exclusion experiment initially suppressed soil respiration across forests, with sustained suppression for four years in the wettest forest only (−28% ± 4% during the dry season). In the fertile forest, drying eventually elevated CO 2 fluxes over this period (+75% ± 28% during the late wet season). The unexpected negative drying effect in the wettest, infertile forest could have resulted from reduced vertical flushing of nutrients into soils. Including hydro‐nutrient interactions in ecosystem models could improve predictions of tropical forest‐climate feedbacks.

54 ENVIRONMENTAL SCIENCES↗

Torsional force microscopy of van der Waals moirés and atomic lattices

In a stack of atomically thin van der Waals layers, introducing interlayer twist creates a moiré superlattice whose period is a function of twist angle. Changes in that twist angle of even hundredths of a degree can dramatically transform the system’s electronic properties. Setting a precise and uniform twist angle for a stack remains difficult; hence, determining that twist angle and mapping its spatial variation is very important. Techniques have emerged to do this by imaging the moiré, but most of these require sophisticated infrastructure, time-consuming sample preparation beyond stack synthesis, or both. In this work, we show that torsional force microscopy (TFM), a scanning probe technique sensitive to dynamic friction, can reveal surface and shallow subsurface structure of van der Waals stacks on multiple length scales: the moirés formed between bi-layers of graphene and between graphene and hexagonal boron nitride (hBN) and also the atomic crystal lattices of graphene and hBN. In TFM, torsional motion of an Atomic Force Microscope (AFM) cantilever is monitored as it is actively driven at a torsional resonance while a feedback loop maintains contact at a set force with the sample surface. TFM works at room temperature in air, with no need for an electrical bias between the tip and the sample, making it applicable to a wide array of samples. It should enable determination of precise structural information including twist angles and strain in moiré superlattices and crystallographic orientation of van der Waals flakes to support predictable moiré heterostructure fabrication.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Mathematical Models and Numerical Methods for High-Fidelity Simulation of Ignition of Reactive Mixtures by Nanosecond Plasma Discharges in Realistic Configurations

We present a newly developed framework for the numerical simulation of ignition of reactive mixtures using single or repeated nanosecond discharge pulses. The framework builds upon the AMReX library, using the existing compressible solver PeleC and low-Mach solver PeleLMeX and allowing for adaptive mesh refinement, complex geometries, and execution on next-generation high-performance computing (HPC) systems. High-fidelity elementary models are adopted for weakly-ionised plasma discharges with significant energy deposition, consistent with nanosecond discharge pulses, and then implemented in the solver. The treatment of non-thermal electrons and charged species, thermodynamics of non-equilbrium species, plasma kinetics, limiting time scales, and boundary conditions for charged species are discussed and addressed for computational efficiency. The framework is demonstrated for three relevant applications: single and multi-pulse discharges in air, single pulse ignition of an ethylene/air mixture, and a three-dimensional plasma discharge in air with temperature stratification. The successful application of the framework demonstrates the feasibility of high-fidelity simulation of ignition of air/hydrocarbon mixtures in three-dimensions with multiple discharge pulses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Slow control and monitoring system at the JSNS 2

The Sterile Neutrino Search at the J-PARC Spallation Neutron Source (JSNS$^2$) experiment aims to search for sterile neutrino oscillations using a neutrino beam from muon decays at rest. The JSNS$^2$ detector contains 17 tons of 0.1$\%$ gadolinium (Gd) loaded liquid scintillator (LS) as a neutrino target. Detector construction was completed in the spring of 2020. A slow control and monitoring system (SCMS) was implemented for reliable control and quick monitoring of the detector operational status and environmental conditions. It issues an alarm if any of the monitored parameters exceed a preset acceptable range. The SCMS monitors the high voltage of the photomultiplier tubes, the LS level in the detector, possible LS overflow and leakage, the temperature and air pressure in the detector, the humidity of the experimental hall, and the LS flow rate during filling and extraction. An initial 10 days of data-taking with a neutrino beam was done following a successful commissioning of the detector and SCMS in 2020 June. In this paper, we present a description of the assembly and installation of the SCMS and its performance.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Anoxia begets anoxia: A positive feedback to the deoxygenation of temperate lakes

Abstract Declining oxygen concentrations in the deep waters of lakes worldwide pose a pressing environmental and societal challenge. Existing theory suggests that low deep‐water dissolved oxygen (DO) concentrations could trigger a positive feedback through which anoxia (i.e., very low DO) during a given summer begets increasingly severe occurrences of anoxia in following summers. Specifically, anoxic conditions can promote nutrient release from sediments, thereby stimulating phytoplankton growth, and subsequent phytoplankton decomposition can fuel heterotrophic respiration, resulting in increased spatial extent and duration of anoxia. However, while the individual relationships in this feedback are well established, to our knowledge, there has not been a systematic analysis within or across lakes that simultaneously demonstrates all of the mechanisms necessary to produce a positive feedback that reinforces anoxia. Here, we compiled data from 656 widespread temperate lakes and reservoirs to analyze the proposed anoxia begets anoxia feedback. Lakes in the dataset span a broad range of surface area (1–126,909 ha), maximum depth (6–370 m), and morphometry, with a median time‐series duration of 30 years at each lake. Using linear mixed models, we found support for each of the positive feedback relationships between anoxia, phosphorus concentrations, chlorophyll a concentrations, and oxygen demand across the 656‐lake dataset. Likewise, we found further support for these relationships by analyzing time‐series data from individual lakes. Our results indicate that the strength of these feedback relationships may vary with lake‐specific characteristics: For example, we found that surface phosphorus concentrations were more positively associated with chlorophyll a in high‐phosphorus lakes, and oxygen demand had a stronger influence on the extent of anoxia in deep lakes. Taken together, these results support the existence of a positive feedback that could magnify the effects of climate change and other anthropogenic pressures driving the development of anoxia in lakes around the world.

54 ENVIRONMENTAL SCIENCES↗

Reversible Ketone Hydrogenation and Dehydrogenation for Aqueous Organic Redox Flow Batteries

Compared to traditional transition metal ion-based counterparts, the realization of organics in aqueous redox flow batteries offers an environmentally benign, tunable, and safe route to large-scale energy storage systems. But development so far has been limited to a small palette of organics that are aqueous soluble and tend to display the necessary redox reversibility within the water stability window. Here we show how molecular engineering of fluorenone enables the alcohol electro-oxidation needed for reversible ketone hydrogenation and dehydrogenation at room temperature without the use of a catalyst. Flow batteries based on these new fluorenone derivative anolytes operate efficiently and exhibit stable long-term cycling at ambient and mildly elevated temperatures in air. These results not only expand the palette to include reversible ketone/alcohol conversion but also suggest the potential for identifying other atypical organic redox couple candidates.

Ketone, Fluorenone, Hydrogenation / Dehydrogenatio↗