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Laser Atmospheric Wind Sounder (LAWS) phase 1. Volume 2

This report summarizes and documents the results of the 12-month phase 1 work effort. The objective of phase 1 was to establish the conceptional definition of the laser atmospheric wind sounder (LAWS) sensor system, including accommodations analyses to ensure compatibility with the Space Station Freedom (SSF) and the Earth Observing System (EOS) Polar Orbiting Platform (POP). Various concepts were investigated with trade studies performed to select the configuration to be carried forward to the phase 2 Preliminary Design Definition. A summary of the LAWS system and subsystem trade studies that were performed leading to the baseline design configuration is presented in the appendix. The overall objective of the LAWS Project is to define, design, and implement an operational space based facility, LAWS, for accurate measurement of Earth wind profiles. Phase 1 addressed three major areas: (1) requirements definition; (2) instrument concepts and configurations; and (3) performance analysis. For the LAWS instrument concepts and configurations, the issues which press the technological state of the art are reliable detector lifetime and laser performance and lifetime. Lag angle compensation, pointing accuracy, satellite navigation, and telescope design are significant technical issues, but they are considered to be currently state of the art. The primary issues for performance analysis concern interaction with the atmosphere in terms of backscatter and attenuation, wind variance, and cloud blockage. The phase 1 tasks were formulated to address these significant technical issues and demonstrate the technical feasibility of the LAWS concept. Primary emphasis was placed on analysis/trade and identification of candidate concepts. Promising configurations were evaluated for performance, sensitivities, risks, and budgetary costs. Lockheed's baseline LAWS configuration is presented.

Source record↗

Microwave Polarized Signatures Generated within Cloud Systems: SSM/I Observations Interpreted with Radiative Transfer Simulations

Special Sensor Microwave /Imager (SSM/I) observations in cloud systems are studied over the tropics. Over optically thick cloud systems, presence of polarized signatures at 37 and 85 GHz is evidenced and analyzed with the help of cloud top temperature and optical thickness extracted from visible and IR satellite observations. Scattering signatures at 85 GHz (TbV(85) less than or = 250 K) are associated with polarization differences greater than or = 6 K, approx. 50%, of the time over ocean and approx. 40% over land. In addition. over thick clouds the polarization difference at 37 GHz is rarely negligible. The polarization differences at 37 and 85 GHz do not stem from the surface but are generated in regions of relatively homogeneous clouds having high liquid water content. To interpret the observations, a radiative transfer model that includes the scattering by non-spherical particles is developed. based on the T-matrix approach and using the doubling and adding method. In addition to handling randomly and perfectly oriented particles, this model can also simulate the effect of partial orientation of the hydrometeors. Microwave brightness temperatures are simulated at SSM/I frequencies and are compared with the observations. Polarization differences of approx. 2 K can be simulated at 37 GHz over a rain layer, even using spherical drops. The polarization difference is larger for oriented non-spherical particles. The 85 GHz simulations are very sensitive to the ice phase of the cloud. Simulations with spherical particles or with randomly oriented non-spherical ice particles cannot replicate the observed polarization differences. However, with partially oriented non-spherical particles, the observed polarized signatures at 85 GHz are explained, and the sensitivity of the scattering characteristics to the particle size, asphericity, and orientation is analyzed. Implications on rain and ice retrievals are discussed.

Prigent, Catherine↗

Parameterization of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

Cloud Integrating Nephelometers (CIN) were flown on the U. North Dakota Citation aircraft and the NASA WB-57 aircraft for the purpose of measuring in-situ the optical extinction coefficient and the asymmetry parameter (g) at a wavelength of 635 nm of primarily ice particles encountered during the NASA CRYSTAL-FACE study of large cumulus clouds (Cu) and their anvils found in the southern Florida region. The probes performance was largely successful and produced archived data for vertical profiles of extinction, asymmetry parameter, and effective radius (Re), the latter being obtained by combining CIN and CVI (total water; Oregon State U.) measurements. Composites of the CIN and CVI data describing the average microphysical and optical behavior of the Cu and their anvils showed the following: The extinction increases with height as a result of the size of the particles also decreasing with height as shown by the Re measurements; near the top of anvils the size of the primary ice particles is about 10-um radius; and the value of g does not vary significantly with height and has a mean value of about 0.73 consistent with the idea that ambient ice crystals are primarily of complex shape and reflect solar radiation more efficiently than particles of pristine crystal shape. Other observations include: The g measurements were found to be an indicator of the phase of the cloud permitting identification of the clouds with water droplets, rain, and ice; visual ranges as small as several tens of meters were occasionally found in "extinction cores" that coincided with strong updraft cores; and comparison of the cloud probes on the Citation showed significant disagreement.

Gerber, Hermann E.↗

Detection of multi-modal Doppler spectra – Part 1: Establishing characteristic signals in radar moment data

Vertically pointing millimeter-wavelength radars provide a wealth of information about cloud and precipitation particle properties. Doppler spectral data can inform on how particles of varying vertical velocities contribute to the total backscattered power observed. It is more computationally cost effective to process moment data instead of spectra data, but doing so leaves valuable information on the cutting room floor. To confidently identify a multi-modal spectra event, in which two or more modes are present within a layer, Doppler spectral data are essential. This means long-term identification of layers featuring multi-modal spectra can be cost prohibitive. To address this, we explore three multi-modal spectra cases from winter precipitation events to determine characteristic signatures of these layers in the moment data averaged over short time periods (∼ 145 s) and explore how these layers differ from the rest of the vertical profiles. We find that the mean spectrum width and the standard deviation of mean Doppler velocity can be used to determine whether or not a layer is multi-modal. In particular, multi-modal layers in mixed-phase and ice clouds feature larger mean spectrum width (exceeding 0.17 m s −1 ) and smaller standard deviation of the mean Doppler velocity (below 0.1 m s −1 ). In Part 1 of this study, the identification criteria and methods are described. In Part 2 (Wugofski and Kumjian, 2025), we perform a verification of the method for three years of vertically pointing radar data, and explore the meteorological conditions associated with identified multi-modal spectral events.

Wugofski, Sarah [Pennsylvania State Univ., Univers↗

Physical conditions of the earliest phases of massive star formation: Single-dish and interferometric observations of ammonia and CCS in infrared dark clouds

Infrared Dark Clouds (IRDCs) harbor the earliest phases of massive star formation, and many of the compact cores in IRDCs, traced by millimeter continuum or by molecular emission in high critical density lines, host massive young stellar objects (YSOs). We used the Robert C. Byrd Green Bank Telescope and the Karl G. Jansky Very Large Array (VLA) to map NH{sub 3} and CCS in nine IRDCs to reveal the temperature, density, and velocity structures and explore chemical evolution in the dense (>10{sup 22} cm{sup −2}) gas. Ammonia is an excellent molecular tracer for these cold, dense environments. The internal structure and kinematics of the IRDCs include velocity gradients, filaments, and possibly colliding clumps that elucidate the formation process of these structures and their YSOs. We find a wide variety of substructure including filaments and globules at distinct velocities, sometimes overlapping at sites of ongoing star formation. It appears that these IRDCs are still being assembled from molecular gas clumps even as star formation has already begun, and at least three of them appear consistent with the morphology of “hub-filament structures” discussed in the literature. Furthermore, we find that these clumps are typically near equipartition between gravitational and kinetic energies, so these structures may survive for multiple free-fall times.

79 ASTRONOMY AND ASTROPHYSICS↗

Exploring natural aerosol formation from DMS oxidation and implications for aerosol forcing (Final Technical Report)

Because of their interactions with sunlight and with clouds, aerosol particles in the atmosphere can play an important role in the Earth’s climate. Understanding this role, and climate change in general, requires understanding the sources of these aerosol particles – not only anthropogenic sources (such as particles emitted from fossil fuel combustion) but also natural sources as well. One of the most important natural aerosol sources is the atmospheric oxidation of dimethyl sulfide (DMS). DMS, a gas emitted by oceanic phytoplankton, is the largest natural source of sulfur to the atmosphere. Once in the air it undergoes natural oxidation processes, converting the sulfur into sulfate, a major component of atmospheric aerosol. However, the chemical mechanism by which DMS oxidation forms sulfate particles is highly complex and uncertain. The goal of this project was therefore to better understand the chemistry of DMS oxidation, via laboratory and global-modeling studies. In the laboratory studies, DMS was oxidized in an environmental chamber (a large Teflon bag surrounded by UV lights to simulate sunlight), under a range of atmospheric conditions. A number of instruments were used to measure the reaction products (gases and particles) within the chamber. The total sulfur in the products equaled the sulfur in the reacted DMS, indicating that all major sulfur-containing species were measured. Yields of these products, and rates of important processes within the mechanism, were determined, providing improved parameters for use in chemical mechanisms. On the global modeling side, a detailed DMS oxidation scheme (that included chemistry occurring in both the gas phase and in cloud droplets) was incorporated into the Community Earth System Model (CESM), and the effects of this more complex mechanism on predicted sulfate levels and climate effects were explored. The expanded chemistry scheme was found to increase global sulfate levels under present-day conditions (~9%) and even more substantially (~30%) under preindustrial conditions. This additional predicted sulfate has implications for our understanding of the role of present-day aerosol pollution on climate, though because of in-cloud chemistry this effect is quite complex, highlighting the need for additional study.

54 ENVIRONMENTAL SCIENCES↗

Modeling Broadband Phase Noise from Extended Targets in a 170 GHz Cloud-Imaging Radar

VIPR (Vapor Inside-cloud Profiling Radar) is a differential absorption radar operating over 155-175 GHz, covering a portion of the lower frequency flank of the 183 GHz water vapor absorption resonance. Transmitting at a ~1.9 mm wavelength, VIPR is highly sensitive to scattering from small particles comprising clouds and precipitation. Variation of VIPR’s cloud and precipitation echo power with frequency is often dominated by water vapor absorption, allowing humidity profiles to be retrieved along the radar’s beam path. One confounding effect in practical measurements is phase noise carried by the radar’s transmit signal, which can result in strong range sidelobes extending from bright targets and obscuring the echo signals of more weakly scattering clouds. Here we show that the magnitude and shape of phase-noise induced clutter from extended, bright cloud signals can be accurately modeled using a combination of empirical measurements of surface-echo phase noise and an analytic model based on the phase-noise sidelobe magnitude from a theoretical point target. This improved understanding of a potential clutter source in millimeter-wave imagine radar can lead to better performance modeling, and it provides motivation to improve the phase noise of very high frequency local oscillators.

Cooper, Ken B.↗

Discovery of a z = 0.65 post-starburst BAL quasar in the DES supernova fields

We present the discovery of a z=0.65 low-ionization broad absorption line (LoBAL) quasar in a post-starburst galaxy in data from the Dark Energy Survey (DES) and spectroscopy from the Australian Dark Energy Survey (OzDES). LoBAL quasars are a minority of all BALs, and rarer still is that this object also exhibits broad FeII (an FeLoBAL) and Balmer absorption. This is the first BAL quasar that has signatures of recently truncated star formation, which we estimate ended about 40 Myr ago. The characteristic signatures of an FeLoBAL require high column densities, which could be explained by the emergence of a young quasar from an early, dust-enshrouded phase, or by clouds compressed by a blast wave. The age of the starburst component is comparable to estimates of the lifetime of quasars, so if we assume the quasar activity is related to the truncation of the star formation, this object is better explained by the blast wave scenario.

79 ASTRONOMY AND ASTROPHYSICS↗

Tethered balloon-borne profile measurements of atmospheric properties in the cloudy atmospheric boundary layer over the Arctic sea ice during MOSAiC: Overview and first results

The tethered balloon-borne measurement system BELUGA (Balloon-bornE moduLar Utility for profilinG the lower Atmosphere) was deployed over the Arctic sea ice for 4 weeks in summer 2020 as part of the Multidisciplinary drifting Observatory for the Study of Arctic Climate expedition. Using BELUGA, vertical profiles of dynamic, thermodynamic, aerosol particle, cloud, radiation, and turbulence properties were measured from the ground up to a height of 1,500 m. BELUGA was operated during an anomalously warm period with frequent liquid water clouds and variable sea ice conditions. Three case studies of liquid water phase, single-layer clouds observed on 3 days (July 13, 23, and 24, 2020) are discussed to show the potential of the collected data set to comprehensively investigate cloud properties determining cloud evolution in the inner Arctic over sea ice. Simulated back-trajectories show that the observed clouds have evolved within 3 different air masses (“aged Arctic,” “advected over sea ice,” and “advected over open ocean”), which left distinct fingerprints in the cloud properties. Strong cloud top radiative cooling rates agree with simulated results of previous studies. The weak warming at cloud base is mostly driven by the vertical temperature profile between the surface and cloud base. In-cloud turbulence induced by the cloud top cooling was similar in strength compared to former studies. From the extent of the mixing layer, it is speculated that the overall cloud cooling is stronger and thus faster in the warm oceanic air mass. Larger aerosol particle number concentrations and larger sizes were observed in the air mass advected over the sea ice and in the air mass advected over the open ocean.

Arctic↗

Investigating the Atmospheric Sources and Sinks of Perfluorooctanoic Acid Using a Global Chemistry Transport Model

Perfluorooctanoic acid, PFOA, is one of the many concerning pollutants in our atmosphere; it is highly resistant to environmental degradation processes, which enables it to accumulate biologically. With direct routes of this chemical to the environment decreasing, as a consequence of the industrial phase out of PFOA, it has become more important to accurately model the effects of indirect production routes, such as environmental degradation of precursors; e.g., fluorotelomer alcohols (FTOHs). The study reported here investigates the chemistry, physical loss and transport of PFOA and its precursors, FTOHs, throughout the troposphere using a 3D global chemical transport model, STOCHEM-CRI. Furthermore, this investigation includes an important loss process of PFOA in the atmosphere via the addition of the stabilised Criegee intermediates, hereby referred to as the “Criegee Field.” Whilst reaction with Criegee intermediates is a significant atmospheric loss process of PFOA, it does not result in its permanent removal from the atmosphere. Additionally, the atmospheric fate of the resultant hydroperoxide product from the reaction of PFOA and Criegee intermediates resulted in a ≈0.04 Gg year-1 increase in the production flux of PFOA. Furthermore, the physical loss of the hydroperoxide product from the atmosphere (i.e., deposition), whilst decreasing the atmospheric concentration, is also likely to result in the reformation of PFOA in environmental aqueous phases, such as clouds, precipitation, oceans and lakes. As such, removal facilitated by the “Criegee Field” is likely to simply result in the acceleration of PFOA transfer to the surface (with an expected decrease in PFOA atmospheric lifetime of ≈10 h, on average from ca. 80 h without Criegee loss to 70 h with Criegee loss).

54 ENVIRONMENTAL SCIENCES↗

Changing Characteristics of Tropical Extreme Precipitation–Cloud Regimes in Warmer Climates

In this study, we investigated the changing characteristics of climatic scale (monthly) tropical extreme precipitation in warming climates using the Energy Exascale Earth System Model (E3SM). The results are from Atmospheric Model Intercomparison Project (AMIP)-type simulations driven by (a) a control experiment with the present-day sea surface temperature (SST) and CO 2 concentration, (b) P4K, the same as in (a) but with a uniform increase of 4K in the SST globally, and (c) the same as in (a), but with an imposed SST and CO 2 concentration from the outputs of the coupled E3SM forced by a 4xCO 2 concentration. We found that as the surface warmed under P4K and 4xCO 2 , both convective and stratiform rain increased. Importantly, there was an increasing fractional contribution of stratiform rain as a function of the precipitation intensity, with the most extreme but rare events occurring preferentially over land more than the ocean, and more so under 4xCO 2 than P4K. Extreme precipitation was facilitated by increased precipitation efficiency, reflecting accelerated rates of recycling of precipitation cloud water (both liquid and ice phases) in regions with colder anvil cloud tops. Changes in the vertical profiles of clouds, condensation heating, and vertical motions indicate increasing precipitation–cloud–circulation organization from the control and P4K to 4xCO 2 . The results suggest that large-scale ocean warming, that is, P4K, was the primary cause contributing to an organization structure resembling the well-known mesoscale convective system (MCS), with increased extreme precipitation on shorter (hourly to daily) time scales. Additional 4xCO 2 atmospheric radiative heating and dynamically consistent anomalous SST further amplified the MCS organization under P4K. Analyses of the surface moist static energy distribution show that increases in the surface moisture (temperature) under P4K and 4xCO 2 was the key driver leading to enhanced convective instability over tropical ocean (land). However, a fast and large increase in the land surface temperature and lack of available local moisture resulted in a strong reduction in the land surface relative humidity, reflecting severe drying and enhanced convective inhibition (CIN). It is argued that very extreme and rare “record-breaking” precipitation events found over land under P4K, and more so under 4xCO 2 , are likely due to the delayed onset of deep convection, that is, the longer the suppression of deep convection by CIN, the more severe the extreme precipitation when it eventually occurs, due to the release of a large amount of stored surplus convective available potential energy in the lower troposphere during prolonged CIN.

54 ENVIRONMENTAL SCIENCES↗

SÍGAME Simulations of the [C II], [O I], and [O III] Line Emission from Star-forming Galaxies at z≃6

Of the almost 40 star-forming galaxies at z≳5 (not counting quasi-stellar objects) observed in [C II] to date, nearly half are either very faint in [C II] or not detected at all, and fall well below expectations based on locally derived relations between star formation rate and [C II] luminosity. This has raised questions as to how reliable [C II] is as a tracer of star formation activity at these epochs and how factors such as metallicity might affect the [C II] emission. Combining cosmological zoom simulations of galaxies with SÍGAME (SImulator of GAlaxy Millimeter/submillimeter Emission), we modeled the multiphased interstellar medium (ISM) and its emission in [C II], as well as in [O i] and [O iii], from 30 main-sequence galaxies at z≃6 with star formation rates ∼3–23 M{sub ⊙} yr{sup −1}, stellar masses ∼(0.7--8)×10{sup 9} M{sub ⊙}, and metallicities ∼(0.1--0.4)×Z{sub ⊙}. The simulations are able to reproduce the aforementioned [C II] faintness of some normal star-forming galaxy sources at z⩾5. In terms of [O i] and [O iii], very few observations are available at z≳5, but our simulations match two of the three existing z≳5 detections of [O iii] and are furthermore roughly consistent with the [O i] and [O iii] luminosity relations with star formation rate observed for local starburst galaxies. We find that the [C II] emission is dominated by the diffuse ionized gas phase and molecular clouds, which on average contribute ∼66% and ∼27%, respectively. The molecular gas, which constitutes only ∼10% of the total gas mass, is thus a more efficient emitter of [C II] than the ionized gas, which makes up ∼85% of the total gas mass. A principal component analysis shows that the [C II] luminosity correlates with the star formation activity of a galaxy as well as its average metallicity. The low metallicities of our simulations together with their low molecular gas mass fractions can account for their [C II] faintness, and we suggest that these factors may also be responsible for the [C II]-faint normal galaxies observed at these early epochs.

79 ASTRONOMY AND ASTROPHYSICS↗

The aerosol distribution in Uranus' atmosphere - Interpretation of the hydrogen spectrum

New observations of Uranus' combined H2 spectrum have been obtained. An analysis, emphasizing the leverage provided by the S3(0) quadrupole line, leads to strong constraints on Uranus' bulk aerosol distribution with depth. Using an inhomogeneous model atmosphere program which includes Rayleigh scattering for gases and a 1 plus cos theta phase function for cloud layers, it is shown that Uranus' H2 spectrum implies a cloud layer (or dense aerosol) at a depth from 500 to 700 km-amagat H2. It also implies negligible aerosol scattering in the 280 to 450 km-amagat H2 region and a thin haze at 100 to 200 km-amagat H2 depths. The low albedo in very strong CH4 bands indicates that there is negligible aerosol scattering in Uranus' radiative zone. Hydrogen appears to be more abundant than the sum of all other atmospheric gases. The C/H ratio deep in Uranus' atmosphere is strongly enhanced over the solar value. Accurate limb-darkening measurements in and near strong CH4 bands would be effective in specifying Uranus' aerosol distribution in greater detail.

Trafton, L.↗

Infrared observations of Nova Cygni 1975

Infrared photometry from 1 to 20 microns and spectroscopy at about 2 microns are presented for Nova Cygni 1975 for the period from 2 days before to 1 yr after maximum light. The data can be explained by a simple model in which the expanding gas expelled during the explosion is always a plasma at approximately 10,000 K. Initially the gas is optically thick; this phase clearly defines the time of onset of the nova. Later, as the gas continues to expand, it becomes optically thin. The temporal dependence of the observed flux suggests that in this phase the expanding cloud is in the form of a shell. After about 300 days, long-wavelength emission which may be attributable to thermal reradiation from dust is observed.

Ennis, D.↗

Motions of the cloud medium behind large scale galactic shocks

Mechanisms of decelerating the cloud medium in the large-scale galactic shock are studied. It is shown that the process of cloud-cloud collisions, which results in diffusive momentum transport and hence gives rise to the turbulent viscosity, is very effective in slowing down the cloud medium so that the postshock velocity of the intercloud medium can be matched within a short distance behind the shock front. The drag force exerted by the slow-moving intercloud medium alone is simply not enough to effectively decelerate the cloud medium in the shock. By the use of the results of Shu et al (1972), the internal structure of the shock of the cloud medium is analyzed by including turbulent viscous effects. The thickness of the shock is found to be on the order of 100 pc if the turbulent viscosity is taken proportional to the mean free path of the cloud-cloud collisions. The phase transition takes place in an even thinner layer on the order of 10 pc immediately after the viscous shock front of the intercloud medium.

Yuan, C.↗

The mechanisms of fine particle generation and electrification during Mount St. Helens volcanic eruption

Microscopical investigation of volcanic ash collected from ground stations during Mount St. Helens eruptions reveal a distinctive bimodel size distribution with high concentrations of particle ranges at (1) 200-100 microns and (2) 20-0.1 microns. Close examination of individual particles shows that most larger ones are solidified magma particles of porous pumice with numerous gas bubbles in the interior and the smaller ones are all glassy fragments without any detectable gas bubbles. Elemental analysis demonstrates that the fine fragments all have a composition similar to that of the larger pumice particles. Laboratory experiments suggest that the formation of the fine fragments is by bursting of glassy bubbles from a partially solidified surface of a crystallizing molten magma particle. The production of gas bubbles is due to the release of absorbed gases in molten magma particles when solubility decreases during phase transition. Diffusion cloud chamber experiments strongly indicate that sub-micron volcanic fragments are highly hygroscopic and extremely active as cloud condensation nuclei. Ice crystals also are evidently formed on those fragments in a supercooled (-20 C) cloud chamber. It has been reported that charge generation from ocean volcanic eruptions is due to contact of molten lava with sea water. This seems to be insufficient to explain the observed rapid and intense lightning activities over Mount St. Helens eruptions. Therefore, a hypothesis is presented here that highly electrically charged fine solid fragments are ejected by bursting of gas bubbles from the surface of a crystallizing molten magma particles.

Cheng, R. J.↗

Extinct radioactivities - A three-phase mixing model

A new class of models is advanced for interpreting the relationship of radioactive abundances in the early solar system to their average concentration in the interstellar medium. The model assumes that fresh radioactivities are ejected from supernovae into the hot interstellar medium, and that the time scales for changes of phase into molecular clouds determine how much survives for formation therein of the solar system. A more realistic and physically motivated understanding of the low observed concentrations of I-129, Pu-244, and Pd-107 may result.

Clayton, D. D.↗

Tropospheric Chemistry

The fundamental processes that control the chemical composition and cycles of the global troposphere and how these processes and properties affect the physical behavior of the atmosphere are examined. The long-term information needs for tropospheric chemistry are: to be able to predict tropospheric responses to perturbations, both natural and anthropogenic, of these cycles, and to provide the information required for the maintenance and effective future management of the atmospheric component of our global life support system. The processes controlling global tropospheric biogeochemical cycles include: the input of trace species into the troposphere, their long-range transport and distribution as affected by the mean wind and vertical venting, their chemical transformations, including gas to particle conversion, leading to the appearance of aerosols or aqueous phase reactions inside cloud droplets, and their removal from the troposphere via wet (precipitation) and dry deposition.

Mohnen, V.↗